CN101027381A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- CN101027381A CN101027381A CN 200580030817 CN200580030817A CN101027381A CN 101027381 A CN101027381 A CN 101027381A CN 200580030817 CN200580030817 CN 200580030817 CN 200580030817 A CN200580030817 A CN 200580030817A CN 101027381 A CN101027381 A CN 101027381A
- Authority
- CN
- China
- Prior art keywords
- composition
- anionic surfactant
- washing
- taurine
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a detergent composition comprising a taurine derivative (a) shown by Formula I and an anionic surfactant (b) at a specific ratio, wherein the anionic surfactant (b) is at least one anionic surfactant selected from the group consisting of an anionic surfactant that has a sulfate group or a sulfonic acid group, an acyl amino acid anionic surfactant, and a fatty acid salt having 8 to 22 carbon atoms. The detergent composition of the present invention has good foamability (including foamability in the presence of oil components) and provides a creamy foam texture. When the detergent is used for washing, it does not produce a slimy feeling during rinsing, and its foam can be rinsed off quickly. After washing (after drying), the composition can provide an excellent washed feeling and does not leave the skin feeling tight or rough.
Description
Technical field
The present invention relates to health or hair detergent composition such as body lotion, Liquid soap, cleansing milk, shampoo.More particularly, relate to foaming (being included in the foaming under the coexistence of oiliness composition) good, alveolar substance fine and smooth (Network リ-ミ-), when using the said composition washing, when rinsing, there is not smooth sense, go bubble rapidly, and washing back (dry back) skin does not have the detergent composition of the detergency excellence of tight sense and dry sensation.
Background technology
In the past, healths such as body lotion, Liquid soap, cleansing milk, shampoo usefulness or hair are with using the anionic surfactant as main component in the detergent composition, in order to improve the sensation of washings such as tight sense after the use, dry sensation, wetting Agent for Printing Inks, various tensio-active agent (amphoterics, nonionic surfactant etc.) etc. have also been used.The anionic surfactant is known have have sulfate or sulfonic anionic surfactant, acyl amino acid type anionic surfactant, soap etc.
Contain that above-mentioned tool sulfate or sulfonic anionic surfactant's composition of detergent is published to be had:the composition of detergent (the special fair 4-79399 communique of Japan) that contains alkyl ether sulphate type anionic surfactant and amidoamino acid type amphoteric surfactant and alkanolamide type nonionic surfactant; Contain acyl group alkyl taurine ester type anionic surfactant and oxyneurine type amphoteric surfactant and alkanolamide type nonionic surfactant composition of detergent (Japanese Patent Publication 59-42038 communique), contain acyl group isethionic acid ester type anionic surfactant and betaine type amphoteric surfac-tant's composition of detergent (Japanese kokai publication sho 60-161498 communique), contain the composition of detergent (Japanese kokai publication hei 6-172785 communique) of amide ether sulfuric acid ester type anionic surfactant and alkyl imino dicarboxylic ester type amphoteric surfactant etc.
The above-mentioned detergent composition that contains acyl amino acid type anionic surfactant is disclosed to be had: the detergent composition (Japanese kokai publication sho 60-42496 communique) that contains N-acyl glutamate and amide betaine type amphoterics; the detergent composition (Japanese kokai publication hei 2-180811 communique) that contains N-acyl amino hydrochlorate and alkylolamide type nonionic surfactant, containing the N-acyl glutamic acid is detergent composition (Japanese kokai publication hei 1-287017 communique) of tensio-active agent and Voranol EP 2001 type nonionic surfactant etc.
But, thick, light by the washing composition alveolar substance that these compositions form, the alveolar substance of people's demand exquisiteness.And these washing composition have a smooth sense attached to residual on the skin.
The above-mentioned detergent composition that contains soap is disclosed to be had: the detergent composition (Japanese kokai publication hei 8-20795 communique) that contains the epoxide adduct of fatty acid soaps and glycerine or Glycerol dimer; the detergent composition (Japanese kokai publication hei 9-104618 communique) that contains soap and specific quaternary ammonium salt cationic surfacant; the detergent composition (Japanese kokai publication hei 5-17341 communique) that contains higher fatty acid and acyl group isethionic acid ester type anionic surfactant and sequestrant contains the detergent composition (Japanese kokai publication hei 5-156284 communique) of lauroleate and secondary amide type N-acyl amino hydrochlorate etc.
But when using the washing composition that is made of these compositions, foaming that soap itself is had and alveolar substance are well and go to steep that characteristic is impaired rapidly.And residual smooth sense when rinsing descends the salubrious sense of washing.Dried skin has dry sensation, and this is an open question still at present.
And, particularly use in the detergent composition at hairs such as shampoo, for submissive when having one's hair wash and clean, use the silicone derivatives such as polymethyl siloxane of high-polymerization degree mostly.Said detergent composition has: contain acyl group alkyl taurine ester type anionic surfactant and silicone derivative detergent composition (Japanese kokai publication hei 4-296398 communique), contain the detergent composition (Japanese kokai publication hei 11-29446 communique) of alkyl ether sulphate type anionic surfactant and acyl glutamic acid ester type anionic surfactant and betaine type amphoteric surfac-tant and polymethyl siloxane etc.
But these hairs contain silicone derivative with detergent composition, so the initial stage foaming is impaired.And the detergent composition that contains tool sulfate or sulfonic anionic surfactant and acyl amino acid type anionic surfactant is when coexisting with silicone derivative oiliness composition in addition, and its foaming is poor.
The object of the present invention is to provide foaming good (comprising the foaming when coexisting), alveolar substance exquisiteness with the oiliness composition, when using said composition to wash, not having smooth sense during rinsing, going to steep rapid and washing back (after dry) skin does not have the detergent composition of the detergency excellence of tight sense and dry sensation.
Summary of the invention
Detergent composition of the present invention is the detergent composition that contains taurine derivatives (a) and anionic surfactant (b).This taurine derivatives (a) is a compound shown in (I):
R
1CONR
2C
2H
4SO
3M (I)
(in the formula, R
1CO is the acyl group of carbonatoms 6～10, R
2Be the alkyl of hydrogen or carbonatoms 1～3, M is hydrogen, basic metal, alkaline-earth metal, ammonium, replacement ammonium, from amino acid whose group or its an alkali metal salt or from the group of taurine, from the group of N methyl taurine or their an alkali metal salt); This anionic surfactant is at least a anionic surfactant who is selected from the soap with sulfate or sulfonic anionic surfactant, acyl amino acid type anionic surfactant and carbonatoms 8～22; in the said composition; this taurine derivatives (a) contains with the ratio of 0.05～30% quality; and this anionic surfactant (b) contains with the ratio of 1～50% quality, and this taurine derivatives (a) and this anionic surfactant's (b) mass ratio is 1/100～1/1.
In the embodiment preferred, above-mentioned anionic surfactant (b) has sulfate or sulfonic anionic surfactant.
In the embodiment preferred, above-mentioned anionic surfactant (b) is acyl amino acid type anionic surfactant.
In the embodiment preferred, above-mentioned anionic surfactant (b) is the soap of carbonatoms 8～22.
Therefore, the present invention can realize following purpose: foaming good (being included in the foaming under the coexistence of oiliness composition), alveolar substance exquisiteness are provided, when using the said composition washing, when rinsing, do not have smooth sense, go bubble rapidly, washing back (dry back) skin do not have the detergent composition of the detergency excellence of tight sense and dry sensation.
The best mode that carries out an invention
Detergent composition of the present invention contains following taurine derivatives (a) (below can be described as a composition) and specific anionic surfactant (b) (below can be described as the b composition), can contain solvent (for example water) and additive as required.Below these compositions are described.
(taurine derivatives (a))
The taurine derivatives that uses in the detergent composition of the present invention (a) is suc as formula shown in (I):
R
1CONR
2C2H
4SO
3M (I)
(in the formula, R
1CO is the acyl group of carbonatoms 6～10, R
2Be the alkyl of hydrogen or carbonatoms 1～3, M is hydrogen, basic metal, alkaline-earth metal, ammonium, replacement ammonium, from amino acid whose group or its an alkali metal salt or from the group of taurine, from the group of N methyl taurine or their an alkali metal salt);
R in the formula (I)
1CO is the acyl group of carbonatoms 6～10, R
1Part can be the arbitrary form of linear chain structure and branched structure.Carbonatoms is 5 when following, and the washing composition that contains this taurine derivatives (a) is strong to the stimulation of skin and hair, and alveolar substance is thick.And variation foams in the presence of the oiliness composition.Carbonatoms is 11 when above, and alveolar substance is thick, and smooth sense is arranged during rinsing.And variation foams in the presence of the oiliness composition.
R in the formula (I)
2Be the alkyl of hydrogen or carbonatoms 1～3, methyl, ethyl, propyl group etc. are arranged.During for the alkyl of carbonatoms more than 4, foaming (being included in the foaming under the coexistence of oiliness composition) variation, alveolar substance is thick.
M in the formula (I) is hydrogen, basic metal, alkaline-earth metal, ammonium, replacement ammonium, from amino acid whose group (basic aminoacids, acidic amino acid and neutral amino acids) or its an alkali metal salt or from the group of taurine, from the group of N methyl taurine or their an alkali metal salt.Hydrogen is specifically arranged; sodium; potassium; 1/2 calcium, 1/2 magnesium, ammonium; triethanol ammonium; from the group of Methionin, arginine, glycine, L-glutamic acid, Sodium glycocollate, glycine potassium, disodium glutamate etc., from the group of taurine, Sodium taurine salt, taurine potassium etc., from group of N methyl taurine, N methyl taurine sodium etc. etc.
(anionic surfactant (b))
The employed anionic surfactant of detergent composition of the present invention (b) is for having at least a in the soap (b.3) of sulfate or sulfonic anionic surfactant (b.1), acyl amino acid type anionic surfactant (b.2) and carbonatoms 8～22.Below these tensio-active agents are described.
(1) has sulfate or sulfonic anionic surfactant (b.1)
The anionic surfactant's (b.1) with sulfate or taurine base who uses in the detergent composition of the present invention for example has: alkyl ether sulphate type anionic surfactant, amide ether sulfuric acid ester type anionic surfactant, acyl group isethionic acid type anionic surfactant, acyl group alkyl taurine ester type anionic surfactant etc.
The alkyl ether sulphate type anionic surfactant can followingly obtain: will have alkyl and carry out sulphating from the polyoxyalkylene alkyl of the polyoxyalkylenes of the epoxide of carbonatoms 2～4, adding can form the compound of counterion, makes salt.Abovementioned alkyl is a carbonatoms 8～22, can be the arbitrary form of linear chain structure and branched structure, can be the arbitrary form of saturated alkyl and unsaturated alkyl.The average addition mole number of the above-mentioned epoxide of above-mentioned formation polyoxyalkylenes is 0.5～8mol.The object lesson of above-mentioned tensio-active agent has polyoxyethylene lauryl ether sodium sulfate etc.
The amide ether sulfuric acid ester type anionic surfactant can followingly obtain: will have acyl group, carry out sulphating from polyoxyalkylene one glycollic amide of the polyoxyalkylenes of the epoxide of carbonatoms 2～4; adding can form the compound of counterion, makes salt.Above-mentioned acyl group is a carbonatoms 8～22, can be the arbitrary form of linear chain structure and branched structure, can be the arbitrary form of saturated acyl group and unsaturated acyl group.The average addition mole number of the above-mentioned epoxide of above-mentioned formation polyoxyalkylenes is 0.5～8mol.The object lesson of above-mentioned tensio-active agent has polyoxyethylene coco-nut oil fatty acid one glycollic amide sodium sulfate etc.
Acyl group isethionic acid ester type the anionic surfactant can followingly obtain: the isethionic acid that will have acyl group adds the compound that can form counterion, makes salt.Above-mentioned acyl group is a carbonatoms 8～22, can be the arbitrary form of linear chain structure and branched structure, can be the arbitrary form of saturated acyl group and unsaturated acyl group.The object lesson of above-mentioned tensio-active agent has coco-nut oil fatty acid hydroxyethyl acyl sodium sulfonate etc.
Acyl group alkyl taurine ester type the anionic surfactant can followingly obtain: with the hydrogen acyl substituted on the amino of N-alkyl taurine, this amido linkage compound is added the compound that can form counterion, make salt.The carbonatoms of above-mentioned acyl group is 8～22, can be the arbitrary form of linear chain structure and branched structure, can be the arbitrary form of saturated acyl group and unsaturated acyl group.The object lesson of above-mentioned tensio-active agent has the taurine sodium salt of coco-nut oil fatty acid acyl group N-methyltaurine sodium, coco-nut oil fatty acid acyl group N-methyltaurine etc.
The atom or the group that form above-mentioned counterion for example have: hydrogen atom, basic metal, alkaline-earth metal, ammonium, replacement ammonium, from the group of amino acid (basic aminoacids, acidic amino acid and neutral amino acids) or its an alkali metal salt, from the group of taurine, from the group of N methyl taurine or their an alkali metal salt etc.Sodium is specifically arranged, potassium, 1/2 calcium; 1/2 magnesium, ammonium, triethanol ammonium; from the group of Methionin, arginine, Sodium glycocollate, glycine potassium, disodium glutamate etc., from group of taurine, N methyl taurine, Sodium taurine salt, taurine potassium, N methyl taurine sodium etc. etc.
(2) acyl amino acid type anionic surfactant (b.2)
The acyl amino acid type anionic surfactant (b.2) who uses in the detergent composition of the present invention for example has: acyl glutamic acid ester type anionic surfactant, acylaspartic acid ester type anionic surfactant, acylglycine ester type anionic surfactant, acyl sarcosine ester type anionic surfactant, acyl group-Beta-alanine ester type anionic surfactant etc.
These tensio-active agents can followingly obtain: the hydrogen on any one amino acid whose amino is by acyl substituted, and the amide compound of this form is added the compound that can form counterion, makes salt.Above-mentioned acyl group is a carbonatoms 8～22, can be any form of linear chain structure and branched structure, can be the arbitrary form of saturated acyl group and unsaturated acyl group.The object lesson of above-mentioned tensio-active agent has: coco-nut oil fatty acid acyl glutamic acid sodium, coco-nut oil fatty acid acylaspartic acid potassium, coco-nut oil fatty acid acylglycine potassium, sodium N-lauroyl sarcosinate, lauroyl-Beta-alanine sodium etc.
Counterion has the above-mentioned counterion that exemplifies.
(3) soap (b.3)
The lipid acid that uses in the detergent composition of the present invention is that carbonatoms is 8～22 soap.The lipid acid that constitutes soap can be any form of linear chain structure and branched structure, can be any form of saturated fatty acid and unsaturated fatty acids.Carbonatoms is 7 when following, and it is poor to foam, the alveolar substance chap.Carbonatoms is 23 when above, foams and goes bubble property poor, and dry back skin is experienced tight sense and dry sensation strongly.
The atom or the group that form the counterion of soap for example have: an alkali metal salt of an alkali metal salt, taurine or the N methyl taurine of basic metal, ammonium or replacement ammonium, basic aminoacids, acidity or neutral amino acids etc.Sodium is specifically arranged, potassium, ammonium, triethanol ammonium is from the group of Methionin, arginine, Sodium glycocollate, glycine potassium, disodium glutamate etc., from group of Sodium taurine salt, taurine potassium, N methyl taurine sodium etc. etc.
The soap of carbonatoms 8～22 specifically has sodium laurate; potassium laurate; the lauric acid triethanol ammonium; lauroyl Methionin; the lauroyl arginine; the salt of lauric acid and Sodium glycocollate; the salt of lauric acid and disodium glutamate; the salt of lauric acid and Sodium taurine salt; the salt of lauric acid and taurine potassium; the salt of lauric acid and N methyl taurine sodium; nutmeg acid potassium; potassium palmitate; potassium stearate; potassium oleate; coco-nut oil fatty acid potassium; the coco-nut oil fatty acid triethanol ammonium; Oleum Cocois fatty acyl Methionin; Oleum Cocois fatty acyl arginine, the salt of coco-nut oil fatty acid and Sodium glycocollate; the salt of coco-nut oil fatty acid and disodium glutamate; the salt of coco-nut oil fatty acid and Sodium taurine salt; the salt of coco-nut oil fatty acid and taurine potassium; the salt of coco-nut oil fatty acid and N methyl taurine sodium etc.
(additive)
In the scope of not damaging effect of the present invention, detergent composition of the present invention can contain additive.Additive is a washing composition additive commonly used, lower alcohol, polyvalent alcohol, hydrocarbon system oil, natural oil lipid, synthetic glycerine three esters, ester oil, wax class, silicone derivative, amphoterics, nonionic surfactant, cationic surfactant, water-soluble polymer, organic or inorganic salt, pH regulator agent, disinfectant, sequestrant, antioxidant, UV light absorber, vitamins is for example arranged, from vegeto-animal natural extract, dyestuff, pigment, essence etc.
(detergent composition)
As mentioned above, health of the present invention contains taurine derivatives (a) and specific anionic surfactant (b) with detergent composition with specific ratio, can contain solvent (for example water) and additive as required.
Taurine derivatives (a) contains with the ratio of 0.05～30% quality, preferred 0.1～20% quality in detergent composition.When being lower than 0.05% quality, the washing composition alveolar substance that contains this taurine derivatives (a) is thick, can experience smooth sense when foaming variation, rinsing under the coexistence of oiliness composition.And dry back skin feel is to tight sense and dry sensation.When surpassing 30% quality, smooth sense is experienced in the alveolar substance chap during rinsing.The a composition can use separately, also can be used in combination two or more.
Anionic surfactant (b) is contained with the ratio of 1～50% quality, preferred 2～40% quality in detergent composition.When being lower than 1% quality, contain this anionic surfactant's (b) thick, the foaming variation of washing composition alveolar substance.When surpassing 50% quality, alveolar substance is thick, and the variation that foams under the coexistence of oiliness composition has smooth sense during rinsing.And pungency is strong, and dry back skin is experienced tight sense and dry sensation strongly.The b composition can use separately, also can be used in combination two or more.
The mass ratio of a composition and b composition (a/b) is 1/100～1/1.When use has sulfate or sulfonic anionic surfactant (b.1) or acyl amino acid type anionic surfactant (b.2) as the b composition, the mass ratio (a/b) preferred 1/50～1/2 of a composition and b composition.When using soap (b.3) as the b composition, the mass ratio (a/b) preferred 1/50～2/3 of a composition and b composition.Than 1/100 hour, alveolar substance was thick, and the variation that foams under the coexistence of oiliness composition has smooth sense during rinsing.And dry back skin is experienced tight sense and dry sensation strongly.When bigger than 1/1, the alveolar substance chap has smooth sense during rinsing.
Embodiment
Further describe the present invention below by embodiment.
(embodiment 1)
Use taurine derivatives (a) and as anionic surfactant's (b) tool sulfate or sulfonic anionic surfactant (b.1), preparation liquid health washing composition as follows.
According to 0.2% quality as the taurine derivatives 1 of a composition, 5% quality as polyoxyethylene (2mol) Zetesol NL of b composition, add up to the mixed of each additive shown in 1～6 in 3.5% quality table 1 (following they are called common added ingredients 1) and 91.3% quality pure water, preparation liquid health washing composition.Taurine derivatives 1 is in the formula (I), R
1CO is straight chain acyl group (positive decanoyl), the R of carbonatoms 10
2For methyl, M are the taurine derivatives of sodium.
Table 1
| Additive (common added ingredients 1) | Addition (% quality) | |
| 1 | Natvosol | 0.5 |
| 2 | Diglycol stearate | 1.7 |
| 3 | Sodium-chlor | 0.5 |
| 4 | The hydroxyl ethane disulfonic acid | 0.1 |
| 5 | Disodium ethylene diamine tetraacetate | 0.3 |
| 6 | Essence | 0.4 |
| Add up to | 3.5 | |
For the gained washing composition, by the following method, go the evaluation of bubble property during to foaminess under the coexistence of oiliness composition of (1) skin irritation, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.
(1) skin irritation
With 1g gained detergent use 99g pure water dilution, use this diluent, carry out closed patch test by each 10 valuator of men and women of healthy skin.After 24 hours on-tests, each trier's of visual observation arm inboard is followingly judged.
2 minutes: obviously visible erythema of skin and edema
1 minute: the more visible erythema of skin
0 minute: skin was not seen variation fully
Obtain 20 people's mean value, be lower than 0.5 timesharing, be evaluated as the weak washing composition of skin irritation.Table 2 expression average mark.Average mark be lower than 0.5 minute with zero expression, more than 0.5 minute with * expression.
Be lower than 0.5 fen: a little less than the skin irritation
0.5 divide above but be lower than 1.0 fens: skin irritation is moderate
1.0 more than dividing: skin irritation is strong
(2) foaminess under the coexistence of oiliness composition
1g gained detergent use 99g pure water is diluted.Weighing 50g gained diluent then is to wherein adding the 0.5g Macadamia ternifolia oil.The diluent that has added this Macadamia ternifolia oil was stirred 5 seconds with stirring test machine (Iwatani makes IFM-100) at 40 ℃.Left standstill 1 minute after ending to stir, measure the foamy height.The foamy height is 7cm when above, is evaluated as the good washing composition of foaminess under the coexistence of oiliness composition.Table 2 expression foamy height.Foam height be more than the 7cm then with zero expression, be lower than 7cm then with * expression.
(3) foamy exquisiteness
1g gained detergent use 99g pure water is diluted.Weighing 50g gained diluent stirred 5 seconds with stirring test machine (Iwatani makes IFM-100) down at 40 ℃ then.Left standstill 1 minute after stopping to stir.Note not destroying the foam that produces, remove the aqueous solution simultaneously, measure residual froth quality and volume in the cup.By quality and volume calculation foamy density, following judgement.
20 minutes: foamy density was 0.04 when above.
15 minutes: foamy density was more than 0.03 but is lower than at 0.04 o'clock.
10 minutes: foamy density was more than 0.02 but is lower than at 0.03 o'clock.
5 minutes: foamy density was more than 0.01 but is lower than at 0.02 o'clock.
0 minute: foamy density was lower than at 0.01 o'clock.
Same test is carried out 5 times, is asked its average mark, with behind the radix point 1 round up, be 15 minutes when above, be evaluated as the washing composition of foam exquisiteness.Table 2 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(4) washing sensation
As the valuator, use 3g gained washing composition by men and women 20 people (20～40 years old), arm and finger before the washing are to feeling following and judge after the washing.
20 minutes: washing back skin was not tight fully, and feels very salubrious.
15 minutes: washing back skin was tight slightly, but salubrious sense is arranged.
10 minutes: washing back skin was tight slightly, a little less than the salubrious sense.
5 minutes: washing back skin was tight, a little less than the salubrious sense.
0 minute: washing back skin was very tight, not salubrious sense.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the washing composition that washing is felt good more than 15 minutes.Table 2 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(5) go bubble property during rinsing
As the valuator, use 3g gained washing composition with men and women 20 people (20～40 years old), arm and finger before the washing, during with the tap water rinsing to going bubble property to carry out following judgement.
20 minutes: go to steep very fast when feeling rinsing.
15 minutes: go bubble fast when feeling rinsing.
10 minutes: go bubble fast slightly when feeling rinsing.
5 minutes: go bubble slow slightly when feeling rinsing.
0 minute: go bubble slow when feeling rinsing.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is 15 minutes when above, removes the good washing composition of bubble property when being evaluated as rinsing.Table 2 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
The above results is as shown in table 2.
(embodiment 2～5)
Similarly to Example 1, each composition shown in the table 2 is pressed mixed shown in the table 2, preparation liquid health washing composition.Taurine derivatives 2 is in the formula (I), R
1CO is straight chain acyl group (positive decanoyl), the R of carbonatoms 10
2For methyl, M are the taurine derivatives of Sodium taurine salt.
Go the evaluation of bubble property during similarly to Example 1, to foaminess under the coexistence of oiliness composition of (1) skin irritation of each washing composition of gained, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.The result is as shown in table 2.
(comparative example 1～7)
Similarly to Example 1, each composition shown in the table 2 is pressed mixed shown in the table 2, preparation liquid health washing composition.
Go the evaluation of bubble property during similarly to Example 1, to foaminess under the coexistence of oiliness composition of (1) skin irritation of each washing composition of gained, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.The result is as shown in table 2.
Table 2
| Embodiment | Comparative example | ||||||||||||
| 1 | 2 | 3 | 4 | 5 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | ||
| The a composition | Taurine derivatives 1 | 0.2 | 1 | - | 5 | - | 0.02 | 35 | - | 5 | - | - | - |
| Taurine derivatives 2 | - | - | 3 | 5 | 15 | - | - | 0.5 | 5 | 0.1 | 10 | - | |
| The b composition | Polyoxyethylene (2mol) Zetesol NL | 5 | 3 | - | - | - | 2 | 20 | - | - | - | - | 5 |
| Polyoxyethylene (3mol) coco-nut oil fatty acid monoethanolamine amido sodium sulfate | - | 3 | - | - | - | - | 10 | - | - | - | - | - | |
| Oleum Cocois fatty acyl group hydroxyl second sulfonyl glycine potassium | - | 5 | - | - | - | - | 5 | - | - | - | - | - | |
| Oleum Cocois fatty acyl group N-methyltaurine sodium | - | - | 10 | 7 | - | - | - | - | 25 | - | - | 0.2 | |
| Oleum Cocois fatty acyl group N-methyltaurine Sodium taurine salt | - | - | - | 13 | 25 | - | - | 0.5 | 30 | 20 | 5 | - | |
| The mass ratio of a composition and b composition (a/b) | 1/25 | 1/11 | 3/10 | 1/2 | 3/5 | 1/100 | 1/1 | 1/1 | 2/11 | 1/200 | 2/1 | - | |
| Common added ingredients 1 | 3.5 | 3.5 | |||||||||||
| Pure water | Surplus | Surplus | |||||||||||
| Add up to (% quality) | 100 | 100 | |||||||||||
| (1) skin irritation | ○(0.3) | ○(0.2) | ○(0.2) | ○(0.1) | ○(0.1) | ○(0.3) | ○(0.3) | ○(0.3) | ×(0.6) | ○(0.2) | ○(0.3) | ○(0.3) | |
| (2) foaminess (cm) under the coexistence of oiliness composition | ○(7.2) | ○(8.2) | ○(8.8) | ○(8.9) | ○(9.2) | ×(5.2) | ○(8.5) | ○(7.3) | ×(6.5) | ×(6.4) | ○(7.5) | ×(5.8) | |
| (3) foamy exquisiteness (branch) | ○(17) | ○(19) | ○(19) | ○(19) | ○(18) | ×(12) | ×(13) | ×(11) | ×(12) | ×(13) | ×(13) | ×(13) | |
| (4) Xi Di sensation (branch) | ○(16) | ○(19) | ○(19) | ○(19) | ○(17) | ×(11) | ○(16) | ○(16) | ×(12) | ×(13) | ○(16) | ×(11) | |
| (5) go bubble property (branch) during rinsing | ○(16) | ○(19) | ○(19) | ○(19) | ○(17) | ×(12) | ○(17) | ○(17) | ×(12) | ×(12) | ○(16) | ×(12) | |
The unit of the value of each composition is the % quality
As shown in table 2, among the embodiment 1～5 washing composition of the present invention of gained be that skin irritation is weak, the foaminess in the presence of the oiliness composition and washing is felt good, do not have the good washing agent of smooth sense when alveolar substance exquisiteness and rinsing.
And the washing composition of gained does not obtain sufficient performance in the comparative example 1～7.In the comparative example 1, the content of a composition lacks than scope of the present invention, so alveolar substance is thick, goes bubble property poor when the foaminess in the presence of the oiliness composition, the sensation of washing and rinsing.In the comparative example 2, the content of a composition is more than scope of the present invention, so alveolar substance is thick.In the comparative example 3, the content of b composition lacks than scope of the present invention, so alveolar substance is thick.In the comparative example 4, the content of b composition is more than scope of the present invention, so skin irritation is strong, goes bubble property poor when the foaminess in the presence of the oiliness composition, the sensation of washing and rinsing, and alveolar substance is thick.In the comparative example 5, the mass ratio (a/b) of a composition and b composition is littler than scope of the present invention, so alveolar substance is thick, the sensation after the foaminess in the presence of the oiliness composition, the washing and go bubble property poor during rinsing.In the comparative example 6, the mass ratio (a/b) of a composition and b composition is bigger than scope of the present invention, so alveolar substance is thick.In the comparative example 7, do not contain a composition, so alveolar substance is thick, goes bubble property poor when the foaminess in the presence of the oiliness composition, washing sensation and rinsing.
(embodiment 6)
Use taurine derivatives (a) and as anionic surfactant's (b) acyl amino acid type anionic surfactant (b2), as follows, preparation liquid health washing composition.
According to 0.2% quality as the taurine derivatives 1 of a composition, 5% quality coco-nut oil fatty acid acyl glutamic acid sodium, the common added ingredients shown in 3.5% quality table 1 and the mixed of 91.3% quality pure water, preparation liquid health washing composition as the b composition.
Go the evaluation of bubble property during similarly to Example 1, to foaminess under the coexistence of oiliness composition of (1) skin irritation of gained washing composition, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.The result is as shown in table 3.
(embodiment 7～10)
Similarly to Example 6, each composition shown in the table 3 according to mixed shown in the table 3, is prepared liquid health washing composition.
Go the evaluation of bubble property during similarly to Example 1, to foaminess under the coexistence of oiliness composition of (1) skin irritation of each washing composition of gained, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.The result is as shown in table 3.
(comparative example 8～14)
Similarly to Example 6, each composition shown in the table 3 according to mixed shown in the table 3, is prepared liquid health washing composition.
Go the evaluation of bubble property during similarly to Example 1, to foaminess under the coexistence of oiliness composition of (1) skin irritation of each washing composition of gained, (2), (3) foamy exquisiteness, (4) washing sensation and (5) rinsing.The result is as shown in table 3.
Table 3
| Embodiment | Comparative example | ||||||||||||
| 6 | 7 | 8 | 9 | 10 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | ||
| The a composition | Taurine derivatives 1 | 0.2 | 1 | - | 5 | - | 0.02 | 35 | - | 5 | - | - | - |
| Taurine derivatives 2 | - | - | 3 | 5 | 15 | - | - | 0.5 | 5 | 0.1 | 10 | - | |
| The b composition | Oleum Cocois fatty acyl group Sodium Glutamate | 5 | 3 | - | 13 | - | 2 | 20 | - | - | - | 5 | 5 |
| Oleum Cocois fatty acyl group glycine potassium | - | 3 | - | - | 10 | - | 15 | - | 30 | 20 | - | - | |
| Lauroyl-Beta-alanine disodium glutamate | - | - | 10 | 7 | 15 | - | - | 0.5 | 25 | - | - | - | |
| Oleum Cocois fatty acyl group N-methyltaurine sodium | - | - | - | - | - | - | - | - | - | - | - | 0.2 | |
| The mass ratio of a composition and b composition (a/b) | 1/25 | 1/6 | 3/10 | 1/2 | 3/5 | 1/100 | 1/1 | 1/1 | 2/11 | 1/200 | 2/1 | - | |
| Common added ingredients 1 | 3.5 | 3.5 | |||||||||||
| Pure water | Surplus | Surplus | |||||||||||
| Add up to (% quality) | 100 | 100 | |||||||||||
| (1) skin irritation | ○(0.2) | ○(0.2) | ○(0.2) | ○(0.2) | ○(0.2) | ○(0.2) | ○(0.3) | ○(0.3) | ×(0.6) | ○(0.3) | ○(0.3) | ○(0.3) | |
| (2) foaminess (cm) under the coexistence of oiliness composition | ○(7.5) | ○(8.0) | ○(8.2) | ○(8.3) | ○(8.5) | ×(6.1) | ○(8.5) | ○(7.2) | ×(6.3) | ×(6.5) | ○(7.5) | ×(6.0) | |
| (3) foamy exquisiteness (branch) | ○(17) | ○(19) | ○(19) | ○(19) | ○(18) | ×(12) | ×(13) | ×(12) | ×(12) | ×(13) | ×(13) | ×(13) | |
| (4) Xi Di sensation (branch) | ○(17) | ○(19) | ○(19) | ○(19) | ○(18) | ×(11) | ○(16) | ○(16) | ×(12) | ×(13) | ○(16) | ×(11) | |
| (5) go bubble property (branch) during rinsing | ○(17) | ○(19) | ○(19) | ○(19) | ○(17) | ×(12) | ○(17) | ○(17) | ×(12) | ×(12) | ○(16) | ×(12) | |
The unit of the value of each composition is the % quality
As shown in table 3, the washing composition of the present invention of embodiment 6～10 gained is that skin irritation is weak, do not have the washing composition of the excellence of smooth sense when the feeling good of the foaminess in the presence of the oiliness composition and washing, alveolar substance exquisiteness, rinsing.
On the other hand, the washing composition of gained does not obtain sufficient performance in the comparative example 8～14.In the comparative example 8, the content of a composition lacks than scope of the present invention, so alveolar substance is thick, goes bubble property poor when the foaminess in the presence of the oiliness composition, washing sensation and rinsing.In the comparative example 9, the amount of a composition is more than scope of the present invention, so alveolar substance is thick.In the comparative example 10, the content of b composition lacks than scope of the present invention, so alveolar substance is thick.In the comparative example 11, the content of b composition is more than scope of the present invention, so skin irritation is strong, goes bubble property poor when the foaminess in the presence of the oiliness composition, the sensation of washing and rinsing, and alveolar substance is thick.In the comparative example 12, the mass ratio (a/b) of a composition and b composition is littler than scope of the present invention, so alveolar substance is thick, the sensation after the foaminess in the presence of the oiliness composition, the washing and go bubble property poor during rinsing.In the comparative example 13, the mass ratio (a/b) of a composition and b composition is bigger than scope of the present invention, so alveolar substance is thick.In the comparative example 14, do not contain a composition, so alveolar substance is thick, goes bubble property poor when the foaminess in the presence of the oiliness composition, washing sensation and rinsing.
(embodiment 11)
Use taurine derivatives (a) and as the soap (b.3) of anionic surfactant (b), preparation liquid health washing composition as follows.
According to 0.2% quality as the taurine derivatives 1 of a composition, 5% quality potassium laurate, the common added ingredients shown in 3.5% quality table 1 and the mixed of 91.3% quality pure water, preparation liquid health washing composition as the b composition.
Go the evaluation of bubble property during to above-mentioned (3) foamy exquisiteness of gained washing composition and (5) rinsing.The dry sensation of the tight sense of the smooth sense when estimating (6) foaminess, (7) rinsing in accordance with the following methods, (8) dry back skin and (9) dry back skin.
(6) foaminess
1g gained detergent use 99g pure water is diluted.Weighing 50g gained diluent then is under 40 ℃, with stirring test machine (Iwatani makes IFM-100) stirring 5 seconds.Left standstill 1 minute after ending to stir, measure the foamy height.The foamy height is 7cm when above, is evaluated as the good washing composition of foaminess.Table 4 expression foamy height.Foam height be more than the 7cm then with zero expression, be lower than 7cm then with * expression.
(7) the smooth sense during rinsing
As the valuator, use 3g gained washing composition by men and women 20 people (20～40 years old), arm and finger before the washing are to feeling following and judge after the washing.
20 minutes: do not feel smooth sense, feel very salubrious.
15 minutes: feel smooth sense slightly, but sensation is salubrious.
10 minutes: feel smooth sense, feel not too salubrious.
5 minutes: feel tangible smooth sense, feel clouding.
0 minute: feel serious smooth sense, feel clouding fully.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the washing composition that does not have smooth sense more than 15 minutes.Table 4 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(8) the tight sense of drying back skin
As the valuator, use 3g gained washing composition by men and women 20 people (20～40 years old), arm and finger are judged the tight sense of skin after the drying is following before the washing.
20 minutes: dried skin was not felt tight sense.
15 minutes: dried skin was felt tight sense slightly, but did not make us uncomfortable.
10 minutes: dried skin was felt tight sense slightly, made us uncomfortable slightly.
5 minutes: dried skin was felt tight sense.
0 minute: dried skin was obviously felt tight sense.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the washing composition that does not have tight sense more than 15 minutes.Table 4 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(9) dry sensation of drying back skin
As the valuator, use 3g gained washing composition by men and women 20 people (20～40 years old), arm and finger are judged the dry sensation of skin after the drying is following before the washing.
20 minutes: dried skin was not felt dry sensation.
15 minutes: dried skin was felt dry sensation slightly, but did not make us uncomfortable.
10 minutes: dried skin was felt dry sensation slightly, made us uncomfortable slightly.
5 minutes: dried skin was felt dry sensation.
0 minute: dried skin was obviously felt dry sensation.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the washing composition that does not have dry sensation more than 15 minutes.Table 4 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
The above results is as shown in table 4.
(embodiment 12～15)
Similarly to Example 11, each composition shown in the table 4 according to mixed shown in the table 4, is prepared liquid health washing composition.
During similarly to Example 11, to (3) foamy exquisiteness of each washing composition of gained, (5) rinsing go bubble property, (6) foaminess, (7) rinsing the time smooth sense, the tight sense of (8) dry back skin and dry sensation of (9) dry back skin estimate.The result is as shown in table 4.
(comparative example 15～21)
Similarly to Example 11, each composition shown in the table 4 according to mixed shown in the table 4, is prepared liquid health washing composition.
During similarly to Example 11, to (3) foamy exquisiteness of each washing composition of gained, (5) rinsing go bubble property, (6) foaminess, (7) rinsing the time smooth sense, the tight sense of (8) dry back skin and dry sensation of (9) dry back skin estimate.The result is as shown in table 4.
Table 4
| Embodiment | Comparative example | ||||||||||||
| 11 | 12 | 13 | 14 | 15 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | ||
| The a composition | Taurine derivatives 1 | 0.2 | 1 | - | 5 | - | 0.02 | 35 | - | 5 | - | - | - |
| Taurine derivatives 2 | - | - | 3 | 5 | 15 | - | - | 0.5 | 5 | 0.1 | 10 | - | |
| The b composition | Potassium laurate | 5 | 5 | 5 | 10 | 12 | 2 | 20 | - | 30 | 10 | 5 | 5 |
| Lauroyl taurine sodium | - | 3 | - | - | 3 | - | 5 | - | 10 | 5 | - | - | |
| Potassium myristate | - | - | 5 | 5 | 10 | - | 10 | 0.5 | 15 | 5 | - | - | |
| Oleum Cocois fatty acyl group N-methyltaurine sodium | - | - | - | - | - | - | - | - | - | - | - | 0.2 | |
| The mass ratio of a composition and b composition (a/b) | 1/25 | 1/8 | 3/10 | 2/3 | 3/5 | 1/100 | 1/1 | 1/1 | 2/11 | 1/200 | 2/1 | - | |
| Common added ingredients 1 | 3.5 | 3.5 | |||||||||||
| Pure water | Surplus | Surplus | |||||||||||
| Add up to (% quality) | 100 | 100 | |||||||||||
| (6) foaminess (cm) | ○(8.8) | ○(9.2) | ○(9.3) | ○(9.5) | ○(9.6) | ○(8-3) | ○(9.5) | ×(6.5) | ○(9.4) | ○(9.3) | ○(8.7) | ○(8.0) | |
| (3) foamy exquisiteness (branch) | ○(17) | ○(17) | ○(19) | ○(18) | ○(18) | ○(17) | ×(14) | ×(12) | ○(17) | ○(17) | ×(12) | ○(17) | |
| (7) the smooth sense during rinsing | ○(18) | ○(19) | ○(19) | ○(19) | ○(18) | ○(18) | ×(14) | ○(16) | ○(17) | ○(18) | ×(13) | ×(14) | |
| (5) go bubble property (branch) during rinsing | ○(18) | ○(19) | ○(19) | ○(19) | ○(19) | ○(17) | ○(16) | ○(16) | ○(17) | ○(17) | ○(17) | ×(13) | |
| (8) the tight sense (branch) of drying back skin | ○(17) | ○(18) | ○(18) | ○(18) | ○(17) | ×(12) | ○(17) | ○(17) | ×(11) | ×(10) | ○(17) | ○(16) | |
| (9) dry sensation (branch) of drying back skin | ○(17) | ○(18) | ○(18) | ○(18) | ○(17) | ×(12) | ○(17) | ○(17) | ×(10) | ×(11) | ○(18) | ×(14) | |
The unit of the value of each composition is the % quality
As shown in table 4, the washing composition of the present invention of gained is that foaming is good, alveolar substance is fine and smooth, does not have smooth sense during rinsing, goes bubble rapidly among the embodiment 11～15, and dry back skin is not felt the washing composition of the excellence of tight sense and dry sensation.
And the washing composition of gained does not obtain sufficient performance in the comparative example 15～21.In the comparative example 15, the content of a composition lacks than scope of the present invention, and the tight sense and the dry sensation of dried skin are strong.In the comparative example 16, the amount of a composition is more than scope of the present invention, so alveolar substance is thick, feels smooth sense during rinsing.In the comparative example 17, the content of b composition lacks than scope of the present invention, so foaminess is poor, and alveolar substance is thick.In the comparative example 18, the content of b composition is more than scope of the present invention, and therefore tight sense of dried skin and dry sensation are strong.In the comparative example 19, the mass ratio (a/b) of a composition and b composition is littler than scope of the present invention, and therefore tight sense of dried skin and dry sensation are strong.In the comparative example 20, the mass ratio (a/b) of a composition and b composition is bigger than scope of the present invention, so alveolar substance is thick, feels smooth sense during rinsing.In the comparative example 21, do not contain a composition, so feel smooth sense during rinsing, go bubble property poor during rinsing, and dry back skin is felt dry sensation.
(embodiment 16)
According to 5% quality as the taurine derivatives of a composition, 7% quality as each additive (common added ingredients 2) shown in 1～9 and the mixed of 82.1% quality pure water in the coco-nut oil fatty acid acyl glutamic acid sodium of b composition, 5.9% quality table 5, preparation shampoo.
Table 5
| Additive (common added ingredients 2) | Addition (% quality) | |
| 1 | Chlorination O-[2-hydroxyl-3-(trimethylammonium amino) propyl group] hydroxy ethyl cellulose | 0.7 |
| 2 | Coconut oil fatty acid monoethanolamide | 0.5 |
| 3 | Diglycol stearate | 1.7 |
| 4 | Polydimethylsiloxaneemulsions emulsions *1 | 2 |
| 5 | Citric acid | 0.2 |
| 6 | Trisodium citrate | 0.2 |
| 7 | Methyl p-hydroxybenzoate | 0.2 |
| 8 | Propylparaben | 0.1 |
| 9 | Sodium salicylate | 0.3 |
| Add up to | 5.9 |
*1: SHIN-ETSU HANTOTAI's chemical industry (strain) preparation KM-902
To the gained shampoo, go bubble property during according to the sensation of the exquisiteness of following method evaluation (10) foaminess, (11) bubble, (12) washing and (13) rinsing.
(10) foaminess
As the in-service evaluation person, use 5g gained shampoo to have one's hair wash with men and women 20 people (20～40 years old), the foaminess of this moment is carried out following judgement.
20 minutes: feel that foaming is very good.
15 minutes: feel that foaming is good slightly.
10 minutes: the sensation foaming was common.
5 minutes: the sensation foaming was poor slightly.
0 minute: the sensation foaming was poor.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the good shampoo of foaminess more than 15 minutes.Table 6 expression average mark.And, average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(11) foamy exquisiteness
1g gained detergent use 99g pure water is diluted.Weighing 50g gained diluent stirred 5 seconds with stirring test machine (Iwatani makes IFM-100) down at 40 ℃ then.Left standstill 1 minute after stopping to stir.Note not destroying the foam that produces, remove the aqueous solution simultaneously, measure residual froth quality and volume in the cup.By quality and volume calculation foamy density, following judgement.
20 minutes: foamy density was 0.04 when above.
15 minutes: foamy density was more than 0.03 but is lower than at 0.04 o'clock.
10 minutes: foamy density was more than 0.02 but is lower than at 0.03 o'clock.
5 minutes: foamy density was more than 0.01 but is lower than at 0.02 o'clock.
0 minute: foamy density was lower than at 0.01 o'clock.
Same test is carried out 5 times, is asked its average mark, with behind the radix point 1 round up, be 15 minutes when above, be evaluated as the shampoo of foam exquisiteness.Table 6 expression average mark.Average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(12) Xi Di sensation
As the in-service evaluation person, use 5g gained shampoo washing hair and scalp with men and women 20 people (20～40 years old), to feeling to carry out following judgement after cleaning.
20 minutes: feel very salubrious after the cleaning.
15 minutes: feel salubrious after the cleaning.
10 minutes: after the cleaning, hair was puckery slightly, a little less than the salubrious sense.
5 minutes: after the cleaning, hair was puckery, a little less than the salubrious sense.
0 minute: after the cleaning, hair was very puckery, not salubrious sense.
Obtain 20 people's mean value, 1 rounds up behind the radix point, is evaluated as the shampoo that washing is felt good more than 15 minutes.Table 6 expression average mark.And, average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
(13) go bubble property during rinsing
As the in-service evaluation person, use 5g gained shampoo washing hair and scalp with men and women 20 people (20～40 years old), the bubble property of going to the tap water rinsing time is carried out following judgement.
20 minutes: go bubble very fast when feeling rinsing.
15 minutes: go bubble fast when feeling rinsing.
10 minutes: go bubble fast slightly when feeling rinsing.
5 minutes: go bubble slow slightly when feeling rinsing.
0 minute: go bubble slow when feeling rinsing.
Obtain 20 people's mean value, 1 rounds up behind the radix point, removes the good shampoo of bubble property when being evaluated as rinsing more than 15 minutes.Table 6 expression average mark.And, average mark more than 15 minutes then with zero the expression, be lower than 15 fens then with * expression.
This result is as shown in table 6.
(embodiment 17)
Similarly to Example 16, each composition shown in the table 6 is pressed mixed shown in the table 6, the preparation shampoo.
Go the evaluation of bubble property during similarly to Example 16, to (10) foaminess of gained shampoo, (11) foamy exquisiteness, (12) washing sensation and (13) rinsing.The result is as shown in table 6.
(comparative example 22～25)
Similarly to Example 16, each composition shown in the table 6 is pressed mixed shown in the table 6, the preparation shampoo.
Go the evaluation of bubble property during similarly to Example 16, to (10) foaminess of gained shampoo, (11) foamy exquisiteness, (12) washing sensation and (13) rinsing.The result is as shown in table 6.
Table 6
| Embodiment | Comparative example | ||||||
| 16 | 17 | 22 | 23 | 24 | 25 | ||
| The a composition | Taurine derivatives 1 | 5 | - | - | - | - | - |
| Taurine derivatives 2 | - | 2 | - | - | - | - | |
| The b composition | Oleum Cocois fatty acyl group N-methyltaurine taurine sodium | - | 5 | - | - | 7 | 5 |
| Polyoxyethylene (2 moles) Zetesol NL | - | 5 | 5 | - | 5 | 5 | |
| Coco-nut oil fatty acid acyl group N-methyltaurine sodium | - | - | - | 5 | - | 2 | |
| Oleum Cocois fatty acyl group Sodium Glutamate | 7 | - | 7 | 7 | - | - | |
| The mass ratio of a composition and b composition (a/b) | 2/7 | 1/5 | - | - | - | - | |
| Common added ingredients 2 | 5.9 | 5.9 | |||||
| Pure water | Surplus | Surplus | |||||
| Add up to (% quality) | 100 | 100 | |||||
| (10) foaminess (branch) | ○(17) | ○(18) | ×(12) | ×(13) | ×(13) | ×(13) | |
| (11) foamy exquisiteness (branch) | ○(18) | ○(18) | ×(13) | ×(12) | ×(13) | ×(12) | |
| (12) washing sensation (branch) | ○(18) | ○(18) | ×(14) | ×(11) | ×(13) | ×(13) | |
| (13) go bubble property (branch) during rinsing | ○(18) | ○(19) | ×(13) | ×(12) | ×(13) | ×(12) | |
The unit of the matter of each composition is the % quality
As shown in table 6, the washing composition of the present invention (shampoo) of embodiment 16 and 17 gained is that foaming is good, alveolar substance is fine and smooth, do not have smooth sense during rinsing, go to steep rapidly and dry back skin is not felt the washing composition of the excellence of tight sense and dry sensation.
And the shampoo of comparative example 22～25 gained does not all contain a composition, so alveolar substance is thick, goes bubble property poor when the sensation of foaminess, washing and rinsing.
Industrial applicability
Composition of detergent foaming of the present invention good (being included in the foaming under the coexistence of oiliness composition), alveolar substance exquisiteness, when using said composition to wash, there is not smooth sense during rinsing, go bubble rapidly, (after dry) skin is not felt tight sense and dry sensation after the washing, therefore the clean result excellence can be used for body lotion, hand cleanser, mildy wash, shampoo etc.
Claims (4)
1. detergent composition, this detergent composition contains taurine derivatives (a) and anionic surfactant (b),
This taurine derivatives (a) is a compound shown in (I):
R
1CONR
2C
2H
4SO
3M (I)
In the formula, R
1CO is the acyl group of carbonatoms 6～10, R
2Be the alkyl of hydrogen or carbonatoms 1～3, M is hydrogen, basic metal, alkaline-earth metal, ammonium, replacement ammonium, from amino acid whose group or its an alkali metal salt or from the group of taurine, from the group of N methyl taurine or their an alkali metal salt;
This anionic surfactant is at least a anionic surfactant who is selected from the soap with sulfate or sulfonic anionic surfactant, acyl amino acid type anionic surfactant and carbonatoms 8～22;
In the said composition; this taurine derivatives (a) contains with the ratio of 0.05～30% quality; and this anionic surfactant (b) contains with the ratio of 1～50% quality, and this taurine derivatives (a) and this anionic surfactant's (b) mass ratio is 1/100～1/1.
2. the detergent composition of claim 1, wherein above-mentioned anionic surfactant (b) has sulfate or sulfonic anionic surfactant.
3. the detergent composition of claim 1, wherein above-mentioned anionic surfactant (b) is acyl amino acid type anionic surfactant.
4. the detergent composition of claim 1, wherein above-mentioned anionic surfactant (b) is the soap of carbonatoms 8～22.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004271972 | 2004-09-17 | ||
| JP271972/2004 | 2004-09-17 | ||
| JP271973/2004 | 2004-09-17 | ||
| JP362807/2004 | 2004-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101027381A true CN101027381A (en) | 2007-08-29 |
Family
ID=38744800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200580030817 Pending CN101027381A (en) | 2004-09-17 | 2005-09-16 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101027381A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103957866A (en) * | 2011-05-27 | 2014-07-30 | 盖尔德玛公司 | Wash composition |
| CN115554214A (en) * | 2022-08-03 | 2023-01-03 | 广州丝芬化妆品有限公司 | Gel-like oil-controlling skin-cleaning composition and preparation method and application thereof |
-
2005
- 2005-09-16 CN CN 200580030817 patent/CN101027381A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103957866A (en) * | 2011-05-27 | 2014-07-30 | 盖尔德玛公司 | Wash composition |
| CN103957866B (en) * | 2011-05-27 | 2017-04-12 | 盖尔德玛公司 | Wash composition |
| CN115554214A (en) * | 2022-08-03 | 2023-01-03 | 广州丝芬化妆品有限公司 | Gel-like oil-controlling skin-cleaning composition and preparation method and application thereof |
| CN115554214B (en) * | 2022-08-03 | 2024-04-19 | 广州极男化妆品有限公司 | Gel-like oil-control skin-cleaning composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8053400B2 (en) | Liquid cleansing composition comprising a ternary mixture of anionic surfactants | |
| WO2004092315A1 (en) | Cleaning agent composition | |
| JPWO2006030990A1 (en) | Cleaning composition | |
| JP2004143072A (en) | Cleaner composition | |
| US6602848B2 (en) | Detergent composition comprising salts of hydroxyalkyl ether carboxylic acids | |
| CN101027381A (en) | Detergent composition | |
| JP2003048822A (en) | Detergent composition | |
| JPH0641579A (en) | Detergent composition | |
| JPH09208989A (en) | Liquid cleanser composition | |
| JP2006306908A (en) | Detergent composition | |
| JPH06116135A (en) | Skin detergent composition | |
| JP2956268B2 (en) | Detergent composition | |
| JPH08283785A (en) | Detergent composition | |
| CN110354014A (en) | Skin cleansing composition | |
| JPH0616534A (en) | Detergent composition | |
| JP3630264B2 (en) | Hair shampoo composition | |
| JP3770184B2 (en) | Hair cleaning composition | |
| JPH04198125A (en) | Detergent composition | |
| JP2001181675A (en) | Cleansing agent composition | |
| JPH06330090A (en) | Detergent composition | |
| JPH09208456A (en) | Skin cleaning material composition | |
| JPS6159601B2 (en) | ||
| JP3417783B2 (en) | Detergent composition | |
| JPH05117139A (en) | Detergent composition | |
| JP2023514099A (en) | Method for increasing the foaming properties of detergent compositions through the use of isomerized sugar |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20070829 |