CN101024755A - Pressure-sensitive binder - Google Patents
Pressure-sensitive binder Download PDFInfo
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- CN101024755A CN101024755A CNA2006100774262A CN200610077426A CN101024755A CN 101024755 A CN101024755 A CN 101024755A CN A2006100774262 A CNA2006100774262 A CN A2006100774262A CN 200610077426 A CN200610077426 A CN 200610077426A CN 101024755 A CN101024755 A CN 101024755A
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- psa
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- protective membrane
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/40—Compositions for pressure-sensitive adhesives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention relates to a PSA compound used to covering sensitive base material. It includes 70-90%w/w hydroxyl function acrylic polymer, BA, HEA, and HEMA, 10-30%w/w polyether polyhydric alcohol, and 2-10% w/w polyfunctional isocyanate and/or TDI. The constituents could be mixed in the same container in room temperature. The PSA has good removability and good wettability.
Description
The present invention relates to pressure sensitive adhesive (PSA) field.
The application of PSA is that protective membrane is covered on the responsive surface (for example glass of mobile telephone or LCD display panel).
It is very important that PSA can easily remove (even aging back) from these extremely sensitive display surfaces.At first PSA is coated onto on the film (for example PET), applies it to sensing surface with low-down contact force then.Therefore for this purposes, people wish PSA can be in the several seconds wetting these surfaces do not have the coating in visual slit with formation.These PSA not necessarily contain adding antistatic filler wherein to avoid the accumulation of static charge.
Removable PSA in the past utilizes the combining so that it can be removed of acrylic acid series PSA of polyisocyanates and hydroxyl-functional.Yet these tackiness agent wetting speeds are too slow.
JP 2001-131513-A (Ipposha Oil) has described the method for a kind of blend polyether polyol and polyisocyanates.The reaction of this blend forms the polyether polyols with reduced unsaturation with isocyanide ester functional group, then with the acrylic acid series PSA blend with hydroxy functional group to obtain removable PSA.The shortcoming of this method is that preparation PSA needs two steps.
US 4,471, and 103 (Takeda) have described and a kind ofly comprised polyvalent alcohol and by isocyanic ester and diazine-2,4,2 component PSA compositions of the urethane of 6-triketone ring preparation.These unconventional prices of raw and semifnished materials are expensive and be difficult to obtain.
CN 1517422 has described a kind of removable PSA that comprises the emulsion acrylic based polymer and comprise the linking agent of water-based polyisocyanates (for example MDI), and described emulsion acrylic based polymer is prepared by alkyl acrylate (for example vinylformic acid tertiary butyl ester) and hydroxyl polar monomer (for example Hydroxyethyl acrylate).Yet the document does not advise using polyol component (for example polyether polyol).
The applicant finds a kind of improved PSA, and it has partly or entirely solved the problem of prior art tackiness agent.Advantageously, PSA of the present invention can be easy to remove from the surface of sensitivity and do not have significant ghost image, has shown good wettability and cheap, preparation easily.
Therefore according to the present invention, provide a kind of removable pressure sensitive adhesive (PSA) composition generally, it is suitable for use in the protective membrane that covers sensitive substrates, and this PSA composition comprises:
I) component I-hydroxy-functional acrylic acid polymer
Ii) component I I-polyether polyol; And
Iii) component III-polyfunctional isocyanate.
Advantageously, the content of component I (acrylate copolymer) in composition is counted about 70%-about 90% with the gross weight of component I and II.
Any suitable acrylic monomer can be as the comonomer that forms component I.Preferred monomer can comprise: silicon/fluorine modified acrylic monomer; With acid, hydroxyl, amine, epoxide functional groups or any other can with the functional group's bonded acrylate and/or the vinyl ester of isocyanate reaction.Other suitable comonomer is described in " polyurethane handbook " lining that Baeyer is published.
More preferably component I comprises at least two kinds of monomeric multipolymers, and described monomer is selected from ethyl acrylate (EHA), n-butyl acrylate (BA), Hydroxyethyl acrylate (HEA) and hydroxyethyl methylacrylate (HEMA).
Advantageously, the content of component I I (polyhydric alcohol polymer) in composition is counted about 10%-about 30% with the gross weight of component I and II.
The preferred polyvalent alcohol that constitutes component I I can comprise following structure division: polypropylene glycol (PPG); Polyoxyethylene glycol (PEG); Hydroxyl-functional siloxanes and/or hydroxyl-functional polyester and their multipolymer.More preferably component I I comprises PPG and/or PEG.
Aptly, the polyvalent alcohol molecular weight is about 200-10, and 000 dalton is preferably from about 2, about 3,000 dalton of 000-.Favourable polyvalent alcohol is to form those of clear saturating cast film when being PSA and polyfunctional isocyanate's (for example component III) blend with solvent-type acrylic.
Advantageously, the content of component III (polyfunctional isocyanate) in composition is counted about 2%-about 10% with the gross weight of component I and II.
Preferred one or more isocyanate-monomers comprise at least two suitable functional groups, for example aromatic isocyanate (for example TDI, MIDI and/or XDI), aliphatic isocyanate (for example: HDI, IPDI and/or HMDI) and derived from these one or more monomeric one or more polymkeric substance (for example PAPI, prepolymer and urea oligopolymer).
Advantageously, one or more isocyanate-monomers with component (I) and (II) can form clear saturating cast film during blend.One or more more favourable isocyanic ester are to have permanent, good storage period thereby help those of coating.Form film by tackiness agent from the shifting process in the isolation liner.Therefore can before forming film, keep the functional group of PSA and can not produce the problem that is affixed to (film coalescence) on the film.
Preferred ingredient III comprises poly-diphenylmethanediisocyanate (MDI) and/or polymethyl benzene vulcabond (TDI).
Another aspect of the present invention provides a kind of method for preparing contact adhesive composition generally, comprises following steps:
(a) with following component in same container, mixing under the room temperature:
I) component I-hydroxy-functional acrylic acid series PSA; With
Ii) component I I-polyether polyol;
To form a blend;
(b) at room temperature in described blend, add
Iii) component III-polyfunctional isocyanate,
Be suitable for use in the removable tackiness agent of the protective membrane that covers sensitive substrates with formation.
Advantageously before being applied to protective membrane, PSA carries out step (b) immediately.
PSA of the present invention has excellent wettability and removable property, and because blend at room temperature, it is more cheap than the PSA of prior art.
Removable tackiness agent has many important industrial application and new purposes to emerge in an endless stream.The inventory that the protective membrane that non exhaustive usefulness scribbles removable PSA covers sensing surface comprises mobile phone display screen, LCD panel etc.These films also can be as the surrogate of " cling film " class protective membrane (for example PVC).The invention provides a kind of method of simple, the cheap removable tackiness agent of preparation.
Apparent to those skilled in the art and this conversion of many other conversion of the present invention is included in the present invention widely in the scope.
Claims of this paper have provided other aspects of the present invention and its preferable feature.
Embodiment
The present invention describes in detail now with reference to following indefiniteness embodiment, and these embodiment only play the explaination effect.These embodiment routine analysis technology, for example NMR, IR and/or GC/MS characterize.Obviously, by selecting the combination of suitable functionalized polyvalent alcohol and acrylic acid series PSA, those skilled in the art can adjust composition of the present invention comprehensive with wetting speed, removable property and the aging resistance of the excellence that obtains expectation.
Below abbreviation be used for representing those with chemical name and/or trade name and the nonessential heterogeneity that can represent by its manufacturer who buys or supplier here.
The benzoic ether softening agent that " Benzoflex 50 " expression can be buied by Vesicol Corp. with this trade(brand)name.
The polyether polyol that " GMN 3050 " expression can be buied by Sinopec with this trade(brand)name.
The hydroxy-functional acrylic acid polymer that " GMS 1151 " expression can be buied by Cytec with this trade(brand)name.
" PPG 330 " expression molecular weight is that 3000 dalton, hydroxyl value are the trifunctional base polypropylene glycol of 54-58mg KOH/g.
" PPG 220 " expression molecular weight is that 2000 dalton, hydroxyl value are two functional group's polypropylene glycols of 54-58mg KOH/g.
The isocyanate crosslinking that " Voranate M220 " expression can be buied by Dow with this trade(brand)name." M220 " is that a kind of molecular-weight average is that 340-380 dalton, functionality are 2.7 low viscosity polymethylene polyphenyl isocyanate.
Standard method
Polyether polyol (" i " gram component I) at room temperature with hydroxy-functional acrylic acid polymer (the component I I of " ii " gram) blend.Behind the blend thorough mixing, isocyanate crosslinking (component III of " iii " gram) also at room temperature adds wherein.Also can add any other nonessential additive (for example catalyst/solvent/static inhibitor/filler) to form the PSA composition in this stage, described then composition is coated on the face material by transfer coating, then for after fixing at room temperature makes it aging, test the performance of PSA coating at last with ordinary method and/or the method that describes below.
The wettability testing method
The slide glass of a slice cleaning is placed on is marked with 1cm on it
2On the paper of grid.Lining (laminating material in protective membrane PSA and the isolation liner) is cut into the test square of 5cm * 5cm.Coated film is removed in isolation liner, and tackiness agent faces down and is applied on the slide glass, then with PSA under the time record of 9 grid of covering on glass.
Embodiment 1
According to above-mentioned standard method and following table 1 preparation PSA.
Table 1 (embodiment 1)
| Component | Consumption/gram |
| I＝GMN 3050 II＝GMS 1151 III＝Voranate M220 | (i)＝10 (ii)＝100 (iii)＝6.5 |
With embodiment 1 with 20gm
-2Coating weight be applied on the PET lining of 100 micron thickness.Peel value after 24 hours is 18 grams, wetting rate: 5 " (pilot scale coating) or 7.7 " (laboratory coating).After 7 days under 70 ℃, when protective membrane is not produced ghost image when glass baseplate removes.As finding, embodiment 1 has shown that ultralow the peeling off in excellence on glass also has good wettability simultaneously.
Comparative examples A-E
Prepare the comparing embodiment that does not have isocyanate crosslinking according to the method that is similar to standard method, explained excellent place of the present invention.
Table 2
| Component/ | Comparative examples A | Comparative example B | Comparative example C | Comparative Example D | Comparative Example E |
| I=GMS 1151 (" i " gram) | 50 | 50 | 50 | 50 | 50 |
| II=PPG 330 (" ii " gram) | - | 5 | 10 | - | - |
| II=PPG 220 (" ii " gram) | - | - | - | 5 | - |
| Other=Benzoflex 50 | - | - | - | - | 10 |
Embodiment 2-5
Isocyanic ester is added among above-mentioned Comparative examples A-E successively to prepare PSA of the present invention.
Table 3
| Embodiment- | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Comparative example | A | B | C | D | E | A |
| Amount/the gram of comparative example | 20 | 20 | 20 | 20 | 20 | 20 |
| III＝Voranate | 0.4 | 1.124 | 1.72 | 1.124 | 0.32 | 1 |
| M220 (" iii " gram) |
It should be noted that the excessive part of the isocyanate crosslinking (Voranate M220) that is used for preparing embodiment 2-5 is used for compensating the polyether glycol (for example PPG 330 or 220) of employed equivalent weight.By being that 2/1 ratio adds toluene with toluene/M220, make used isocyanic ester be diluted to 10% from 30.9%NCO content.This mixture forms saturating clearly solution and clear saturating binder film.With the protective membrane that method test recited above is coated with, the results list is as follows.
The evaluation of table 4 wetting speed
| Embodiment 2 | Embodiment 3 (experiment) | Embodiment 3 (machine) | Embodiment 4 | Embodiment 5 | Embodiment 6 | GMS 1151 | The removable PSA of prior art | Embodiment 7 | ||
| The time of wetting/second | 1 | 18.46 | 7.78 | 4.97 | 7.31 | 13.50 | 4.67 | 14.56 | 4.91 | 11.12 |
| 2 | 17.12 | 7.72 | 5.77 | 6.65 | 14.50 | 4.99 | 14.78 | 5.46 | 11.23 | |
Table 4 shows that PSA of the present invention has showed excellent wetting speed, even not worse than uncrosslinked GMS 1151, has also obtained the similar performance to existing removable PSA simultaneously.
Table 5 ghost image test (70 ℃ on glass following 7 days)
| Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| By | By | By | By | Slight ghost image |
Table 5 shows that PSA of the present invention does not leave ghost image after aging, has also kept stable, acceptable removable performance.
Table 6 is peeled off (on stainless steel)
| Embodiment | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Peel value after 24 hours (gram) | 63～68 | 18～19 | PSA is from the precoat layering | 16～17 | 15 |
| 70 ℃ of peel value (gram) after following 7 days | 73～74 | 22～23 | The same | 18 | 23～24 |
Table 6 shows that PSA of the present invention compares with unmodified sample, and the protective membrane with ultralow peel value is provided, and has ideal after wearing out and peels off stability.
Because the increase that polyvalent alcohol makes wetting speed is bigger than merely adding more linking agent (polyfunctional isocyanate) role, thus comparing embodiment 3,4 and 5 and embodiment 7 shown the benefit of adding suitable polyether polyol.Comparing embodiment 6 shows that with embodiment 3,4 and 5 adding fluidizers can significantly improve wetting speed, but has damaged low stripping performance (70 ℃ following 7 days after at the ghost image that stays on glass).
Claims (15)
1, a kind of removable pressure sensitive adhesive (PSA) composition that is suitable for use in the protective membrane that covers sensitive substrates, described PSA composition comprises:
I) component I-hydroxy-functional acrylic acid polymer
Ii) component I I-polyether polyol; And
Iii) component III-polyfunctional isocyanate.
2, PSA as claimed in claim 1, wherein the content of component I (acrylic acid polymer) in composition is counted about 70%-about 90% with the gross weight of component I and II.
3, PSA as claimed in claim 2, wherein component I comprises at least two kinds of monomeric multipolymers, described monomer be selected from ethyl acrylate (EHA), n-butyl acrylate (BA), Hydroxyethyl acrylate (HEA) and hydroxyethyl methylacrylate (HEMA), Isooctyl acrylate monomer or any have can with the functional group's of isocyanate reaction acrylate or vinyl ester.
4, as the described PSA of any one claim of front, wherein the content of component I I (polyhydric alcohol polymer) in composition is counted about 10%-about 30% with the gross weight of component I and II.
5, PSA as claimed in claim 4, wherein component I I comprises polypropylene glycol (PPG) and/or polyoxyethylene glycol PEG.
6, as the described PSA of any one claim of front, wherein the content of component III (polyfunctional isocyanate) in composition is counted about 2%-about 10% with the gross weight of component I and II.
7, PSA as claimed in claim 4, wherein component III comprises poly-diphenylmethanediisocyanate (MDI) and/or polymethyl benzene vulcabond (TDI).
8, a kind of method for preparing contact adhesive composition may further comprise the steps:
(a) with following component in same container, mixing under the room temperature:
I) component I-hydroxy-functional acrylic acid series PSA; With
Ii) component I I-polyether polyol;
To form a blend;
(b) at room temperature add to described blend
Iii) component III-polyfunctional isocyanate,
Be suitable for use in the removable tackiness agent of the protective membrane that covers sensitive substrates with formation.
9, method as claimed in claim 8 was wherein carried out step (b) immediately before PSA is applied to protective membrane.
10, obtain and/or obtainable removable pressure sensitive adhesive (PSA) composition that is suitable for use in the protective membrane that covers sensitive substrates of a kind of method according to claim 8-9.
11, a kind of removable pressure sensitive adhesive (PSA) composition of describing as embodiment 1-6 basically.
12, a kind of with any one the protective membrane of PSA coating of claim 1-7,10-11.
13, a kind of sensitive substrates of protecting with the protective membrane of claim 12.
14, require 13 sensitive substrates as power, wherein base material is for example sheet glass or a LCD display of indicating meter.
15, a kind of method of protecting any one described sensitive substrates of claim 13-14, described method comprise with very low contact force the described protective membrane of claim 12 are applied to step on the base material.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100774262A CN101024755A (en) | 2006-02-22 | 2006-02-22 | Pressure-sensitive binder |
| PCT/EP2007/051551 WO2007096324A1 (en) | 2006-02-22 | 2007-02-19 | Pressure sensitive adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100774262A CN101024755A (en) | 2006-02-22 | 2006-02-22 | Pressure-sensitive binder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101024755A true CN101024755A (en) | 2007-08-29 |
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ID=37891820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006100774262A Pending CN101024755A (en) | 2006-02-22 | 2006-02-22 | Pressure-sensitive binder |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN101024755A (en) |
| WO (1) | WO2007096324A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105408437A (en) * | 2013-05-21 | 2016-03-16 | 巴斯夫欧洲公司 | Preparation of pressure sensitive adhesive dispersions from multi-stage emulsion polymerization for applications of protective films |
| CN110167985A (en) * | 2017-01-12 | 2019-08-23 | 巴斯夫欧洲公司 | The physical property of polyurethane is improved |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6463737B2 (en) * | 2013-05-21 | 2019-02-06 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Production of pressure-sensitive adhesive dispersions by multi-stage emulsion polymerization for the application of protective films |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4572005B2 (en) * | 1999-06-28 | 2010-10-27 | 日東電工株式会社 | Water-dispersed pressure-sensitive adhesive composition, process for producing the same, and sheet for surface protection |
| WO2004089431A1 (en) * | 2003-04-09 | 2004-10-21 | Beiersdorf Ag | Antimicrobial materials |
-
2006
- 2006-02-22 CN CNA2006100774262A patent/CN101024755A/en active Pending
-
2007
- 2007-02-19 WO PCT/EP2007/051551 patent/WO2007096324A1/en active Application Filing
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105408437A (en) * | 2013-05-21 | 2016-03-16 | 巴斯夫欧洲公司 | Preparation of pressure sensitive adhesive dispersions from multi-stage emulsion polymerization for applications of protective films |
| CN105408437B (en) * | 2013-05-21 | 2018-05-18 | 巴斯夫欧洲公司 | Pressure-sensitive adhesive agent dispersion for protective film is prepared by multistage emulsion polymerization |
| CN110167985A (en) * | 2017-01-12 | 2019-08-23 | 巴斯夫欧洲公司 | The physical property of polyurethane is improved |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007096324A1 (en) | 2007-08-30 |
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