CN101012079A - Natural organism coagulant aid and preparing method theroef - Google Patents
Natural organism coagulant aid and preparing method theroef Download PDFInfo
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- CN101012079A CN101012079A CN 200710056589 CN200710056589A CN101012079A CN 101012079 A CN101012079 A CN 101012079A CN 200710056589 CN200710056589 CN 200710056589 CN 200710056589 A CN200710056589 A CN 200710056589A CN 101012079 A CN101012079 A CN 101012079A
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- coagulant aids
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Abstract
The invention discloses a natural biological coagulant aid and making method, which comprises the following parts: 1-10% modified algae biological molecular material, 0.1-1% modifier and 89-98.9% water. The invention can be applied with aluminate flocculant, which sediments micro-suspending particle rapidly.
Description
Technical field
The invention relates to a kind of preparation method of coagulant aids, particularly about a kind of natural biological coagulant aids and preparation method thereof.
Background technology
In water treatment method, flocculence is one of important method.Present employed flocculation agent and coagulant aids are mainly mineral compound and artificial synthetic organic materials.The inorganic flocculating agent consumption is big, easily produces secondary pollution, and the particularly extensive application of aluminium salt becomes increasingly conspicuous to the influence of environment, especially to the processing of tap water, uses aluminium salt in a large number, can cause the senile dementia sickness rate to rise.Because most of synthetic macromolecular organic compounds are as the use of flocculation agent or coagulant aids, the monomer that remains in the water has toxicity, is detrimental to health, as the polyacrylamide of present widespread usage.The research of current emerging biological flocculant has caused people's attention, and it has effect stability, biodegradable, non-secondary pollution, excellent characteristic such as safe and harmless.Because biological flocculant still is in conceptual phase, and industrial scale is little, cost is big, fails to be used widely at present.
Summary of the invention
For solving the problem that exists in the above-mentioned technology, the purpose of this invention is to provide by waterplant being carried out a kind of natural biological coagulant aids that modification develops and preparation method thereof.Another object of the present invention is to solve the excessive and raising drinking water safety problem of the flocculation agent consumption that exists in the flocculation technique in the existing water treatment procedure.
For achieving the above object, technical scheme of the present invention provides a kind of natural biological coagulant aids, and its component prescription is: by weight percentage, the algae bio molecular substance after 1～10% the modification, 0.1～1% properties-correcting agent, 89～98.9% is water; Described properties-correcting agent is a kind of of commercially available ammonium acetate, potassium permanganate, water glass, is mixed with 0.1～1% modification liquid during use on demand.
A kind of natural biological coagulant aids preparation method also is provided, and this method may further comprise the steps:
(1) gathering of raw material: gather, fish for 4～8 ° of Be ' of algae bio molecular substance (degree Beaume: the algae in the bittern a kind of statement unit of salinity);
(2) to the pre-treatment of above-mentioned raw materials: the algae of fishing for is placed on the mesh screen, with former bittern dash drench clean, air-dry then; Place air seasoning place to preserve.
(3) pulverization process: be ground into the algae after air-dry Powdered;
(4) modification, water bath processing: place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours;
(5) separating treatment: with the screening of 70～100 μ m bolting silks, remove the macrobead foreign material earlier; Use 20～30 μ m membrane filtrations then
(6) pH value adjustment: use water glass to adjust that the pH value of liquid is 6.5～7.5 after the above-mentioned filter;
(7) seal up for safekeeping, take care of: add 40ppm formaldehyde, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
Effect of the present invention is that the starting material of preparation natural biological coagulant aids are algae, obtains easily, and complete processing is simple, and this product is the liquid that contains cell wall polysaccharide and other macromolecular substance.Be used with aluminum salt flocculant, can increase the effect that net is caught small suspended particle, the throw out alumen ustum of formation is big, and sedimentation is rapid, reduces the usage quantity of aluminium salt greatly.This product has characteristics such as consumption is few, and it is wide, easy to use to adapt to the PH scope, safe and harmless.This natural biological coagulant aids is not a kind of flocculation agent, but a kind of coagulant aids that cooperates aluminum salt flocculant to use.Prove by repetition test, can make the usage quantity of aluminium salt reduce by 50～70% by adding this biological coagulant aids.And can meet or exceed the flocculating effect of a large amount of aluminum salt flocculants of independent use.
Embodiment
In conjunction with the embodiments natural biological coagulant aids of the present invention and preparation method thereof is illustrated.
Natural biological coagulant aids of the present invention, its component prescription is: by weight percentage, and the algae bio molecular substance after 1～10% the modification, 0.1～1% properties-correcting agent, 89～98.9% is water; Described properties-correcting agent is a kind of of commercially available ammonium acetate, potassium permanganate, water glass, is mixed with 0.1～1% modification liquid during use on demand.
Natural biological coagulant aids preparation method of the present invention may further comprise the steps:
(1) gathering of raw material: gather, fish for 4～8 ° of Be ' in coastal beach salt pan (degree Beaume: the algae in the bittern a kind of statement unit of salinity);
(2) to the pre-treatment of above-mentioned raw materials: the algae of fishing for is placed on the mesh screen, with former bittern dash drench clean, air-dry then; Place air seasoning place to preserve.
(3) pulverization process: be ground into the algae after air-dry Powdered;
(4) modification, water bath processing: place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours;
(5) separating treatment: with the screening of 70～100 μ m bolting silks, remove the macrobead foreign material earlier; Use 20～30 μ m membrane filtrations then
(6) pH value adjustment: use water glass to adjust that the pH value of liquid is 6.5～7.5 after the above-mentioned filter;
(7) seal up for safekeeping, take care of: add 40ppm formaldehyde, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
Natural biological coagulant aids of the present invention is operated when using according to the following steps:
1. at first, the usage quantity of aluminium salt is used in the definite former water flocculation of chamber beaker test separately by experiment, and the former water flocculation of tap water uses the usage quantity of aluminium salt to be generally 20～60PPM separately; General sewage flocculation uses the usage quantity of aluminium salt to be generally 80～140PPM separately.
2. then, biological coagulant aids consumption is determined in beaker test in chamber by experiment, at first reduces by half according to aluminium salt usage quantity and adds aluminium salt, adds the biological coagulant aids of 0.05～1.00PPM different concns gradient then and carries out flocculating experiment, determines biological coagulant aids consumption.The former water flocculation of tap water is handled biological coagulant aids optimum amount and is generally 0.05～0.5PPM.The biological coagulant aids optimum amount of general sewage flocculation treatment is generally 0.3～1.0PPM.
The medicament usage quantity of determining with reference to above-mentioned test in production reality gets final product.
Embodiment 1:
In the 5 ° of Be ' bittern in elementary system halogen district, certain salt pan, saltern, fish for algae, place on the mesh screen, dash with former bittern and drench totally, air-dry then; Be ground into the algae after air-dry Powdered; Place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours; With the screening of 70 μ m bolting silks, remove the macrobead foreign material earlier; Use 20 μ m membrane filtrations then; Use water glass to adjust that the pH value of liquid is 7 after the above-mentioned filter; Add 40ppm formaldehyde at last, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
Application example 1:
Certain raw water of waterworks is carried out flocculation treatment, use polymerize aluminum chloride to make flocculation agent, the optimum quantum of utilization of polymerize aluminum chloride is used in the definite former water flocculation of chamber beaker test separately at first by experiment.If optimum quantum of utilization is 20PPM, then, biological coagulant aids optimum amount is determined in beaker test in chamber by experiment, at first reduce by half and add aluminium salt 10PPM according to the best aluminium salt usage quantity of independent use aluminium salt, add the biological coagulant aids of 0.05～1.00PPM different concns gradient then, determine biological coagulant aids optimum amount.If biological coagulant aids optimum amount is 0.2PPM, with reference to above-mentioned test-results water body is carried out flocculation treatment in the production reality, at first add polymerize aluminum chloride 10PPM, add biological coagulant aids 0.2PPM then, can reach good flocculating effect.
By adding biological coagulant aids, the amount of application that makes former water flocculation handle aluminium salt reduces 50%, has reduced aluminium residual in the water body, can weaken effectively simultaneously because of a large amount of use aluminium salt to the secondary pollution that water body causes, strengthened sedimentary natural degradation ability.
Embodiment 2:
In the 6 ° of Be ' bittern in elementary system halogen district, certain salt pan, saltern, fish for algae, place on the mesh screen, dash with former bittern and drench totally, air-dry then; Be ground into the algae after air-dry Powdered; Place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours; With the screening of 100 μ m bolting silks, remove the macrobead foreign material earlier; Use 30 μ m membrane filtrations then; Use water glass to adjust that the pH value of liquid is 7.5 after the above-mentioned filter; Add 40ppm formaldehyde at last, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
Application example 2:
Certain raw water of waterworks is carried out flocculation treatment, use polymerize aluminum chloride to make flocculation agent, the optimum quantum of utilization of polymerize aluminum chloride is used in the definite former water flocculation of chamber beaker test separately at first by experiment.If optimum quantum of utilization is 40PPM, then, biological coagulant aids optimum amount is determined in beaker test in chamber by experiment, at first reduce by half and add aluminium salt 20PPM according to the best aluminium salt usage quantity of independent use aluminium salt, add the biological coagulant aids of 0.05～1.00PPM different concns gradient then, determine biological coagulant aids optimum amount.If biological coagulant aids optimum amount is 0.5PPM, with reference to above-mentioned test-results water body is carried out flocculation treatment in the production reality, at first add polymerize aluminum chloride 20PPM, add biological coagulant aids 0.5PPM then, can reach good flocculating effect.
By adding biological coagulant aids, the amount of application that makes former water flocculation handle aluminium salt reduces 50%, has reduced aluminium residual in the water body, can weaken effectively simultaneously because of a large amount of use aluminium salt to the secondary pollution that water body causes, strengthened sedimentary natural degradation ability.
Embodiment 3:
In the 7 ° of Be ' bittern in elementary system halogen district, certain salt pan, saltern, fish for algae, place on the mesh screen, dash with former bittern and drench totally, air-dry then; Be ground into the algae after air-dry Powdered; Place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours; With the screening of 90 μ m bolting silks, remove the macrobead foreign material earlier; Use 25 μ m membrane filtrations then; Use water glass to adjust that the pH value of liquid is 7 after the above-mentioned filter; Add 40ppm formaldehyde at last, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
Application example 3:
Certain factory's sewage is carried out flocculation treatment, use polymerize aluminum chloride to make flocculation agent, beaker test in chamber determines that sewage flocculation uses the optimum quantum of utilization of polymerize aluminum chloride separately at first by experiment.If optimum quantum of utilization is 80PPM, then, biological coagulant aids optimum amount is determined in beaker test in chamber by experiment, at first reduce by half and add aluminium salt 40PPM according to the best aluminium salt usage quantity of independent use aluminium salt, add the biological coagulant aids of 0.05～1.00PPM different concns gradient then, determine biological coagulant aids optimum amount.If biological coagulant aids optimum amount is 0.8PPM, with reference to above-mentioned test-results water body is carried out flocculation treatment in the production reality, at first add polymerize aluminum chloride 40PPM, add biological coagulant aids 0.8PPM then, can reach good flocculating effect.
By adding biological coagulant aids, make the amount of application of sewage flocculation treatment aluminium salt reduce 50%, reduced aluminium residual in the water body, can weaken effectively simultaneously because of a large amount of use aluminium salt to the secondary pollution that water body causes, strengthened sedimentary natural degradation ability.
Claims (3)
1, a kind of natural biological coagulant aids, its component prescription is: by weight percentage, and the algae bio molecular substance after 1～10% the modification, 0.1～1% properties-correcting agent, 89～98.9% is water;
Described properties-correcting agent is a kind of of commercially available ammonium acetate, potassium permanganate, water glass, is mixed with 0.1～1% modification liquid during use on demand.
2, according to the described natural biological coagulant aids of claim 1, it is characterized in that: the algae bio molecular substance after the described modification is coastal beach Bittern of Salt Pan.
3, a kind of preparation method of natural biological coagulant aids, this method may further comprise the steps:
(1) gathering of raw material: gather, fish for 4～8 ° of Be ' of algae bio molecular substance (degree Beaume: the algae in the bittern a kind of statement unit of salinity);
(2) to the pre-treatment of above-mentioned raw materials: the algae of fishing for is placed on the mesh screen, with former bittern dash drench clean, air-dry then; Place air seasoning place to preserve.
(3) pulverization process: be ground into the algae after air-dry Powdered;
(4) modification, water bath processing: place described modification liquid to boil 1 hour in the algae powder, be cooled to soak at room temperature then 24 hours;
(5) separating treatment: with the screening of 70～100 μ m bolting silks, remove the macrobead foreign material earlier; Use 20～30 μ m membrane filtrations then
(6) pH value adjustment: use water glass to adjust that the pH value of liquid is 6.5～7.5 after the above-mentioned filter;
(7) seal up for safekeeping, take care of: add 40ppm formaldehyde, seal up for safekeeping then in plastic containers, In Shade preservation is standby.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2007100565897A CN100434369C (en) | 2007-01-25 | 2007-01-25 | Natural organism coagulant aid and preparing method theroef |
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| CNB2007100565897A CN100434369C (en) | 2007-01-25 | 2007-01-25 | Natural organism coagulant aid and preparing method theroef |
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| CN101012079A true CN101012079A (en) | 2007-08-08 |
| CN100434369C CN100434369C (en) | 2008-11-19 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102351292A (en) * | 2011-07-21 | 2012-02-15 | 浙江商达环保有限公司 | Biologically active flocculating agent for treating waste water generated in production of vitamin E and preparation method thereof |
| CN102992462A (en) * | 2012-11-25 | 2013-03-27 | 溧阳市天目湖保健品有限公司 | Method for producing coagulant aid through utilizing sheep manure |
| CN103159308A (en) * | 2013-03-01 | 2013-06-19 | 溧阳市天目湖保健品有限公司 | Method utilizing biological soil crust to prepare coagulant aids |
| CN105330105A (en) * | 2015-10-30 | 2016-02-17 | 南京农业大学 | Inorganic-organic-microorganism flocculating integrated device |
| CN107098454A (en) * | 2016-02-19 | 2017-08-29 | 天津润沃供水安装工程有限公司 | The method that malvaceae plant prepares organic coagulant aid |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1205308A (en) * | 1997-07-10 | 1999-01-20 | 上海华超电器科技有限公司 | Compounded flocculant and its prepn. process |
| CN1191203C (en) * | 2002-12-12 | 2005-03-02 | 中国科学院生态环境研究中心 | High efficiency algae flooculation agent, method for treating red tide and plakton bloom using same |
-
2007
- 2007-01-25 CN CNB2007100565897A patent/CN100434369C/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102351292A (en) * | 2011-07-21 | 2012-02-15 | 浙江商达环保有限公司 | Biologically active flocculating agent for treating waste water generated in production of vitamin E and preparation method thereof |
| CN102351292B (en) * | 2011-07-21 | 2014-04-02 | 浙江商达环保有限公司 | Biologically active flocculating agent for treating waste water generated in production of vitamin E and preparation method thereof |
| CN102992462A (en) * | 2012-11-25 | 2013-03-27 | 溧阳市天目湖保健品有限公司 | Method for producing coagulant aid through utilizing sheep manure |
| CN103159308A (en) * | 2013-03-01 | 2013-06-19 | 溧阳市天目湖保健品有限公司 | Method utilizing biological soil crust to prepare coagulant aids |
| CN103159308B (en) * | 2013-03-01 | 2014-12-31 | 溧阳市天目湖保健品有限公司 | Method utilizing biological soil crust to prepare coagulant aids |
| CN105330105A (en) * | 2015-10-30 | 2016-02-17 | 南京农业大学 | Inorganic-organic-microorganism flocculating integrated device |
| CN105330105B (en) * | 2015-10-30 | 2017-11-24 | 南京农业大学 | The flocculation integrated device of inorganic-organic microbial |
| CN107098454A (en) * | 2016-02-19 | 2017-08-29 | 天津润沃供水安装工程有限公司 | The method that malvaceae plant prepares organic coagulant aid |
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| CN100434369C (en) | 2008-11-19 |
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