CN101007244A - Preparation method of active liquid containing micro-gas and implementation method using said liquid - Google Patents

Preparation method of active liquid containing micro-gas and implementation method using said liquid Download PDF

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Publication number
CN101007244A
CN101007244A CNA2006100069178A CN200610006917A CN101007244A CN 101007244 A CN101007244 A CN 101007244A CN A2006100069178 A CNA2006100069178 A CN A2006100069178A CN 200610006917 A CN200610006917 A CN 200610006917A CN 101007244 A CN101007244 A CN 101007244A
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liquid
stationary pipes
mentioned
tubercle
bubble
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中岛竹志
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Tian Enguo
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention discloses an active liquid manufacturing method containing micro-bubbles and the method achieved by using the liquid. The active liquid manufacturing method containing micro-bubbles prepares active liquid containing bubbles which diameter below 10 micrometre through using far infrared rays generated by at least one spherical activating machine and/or repulsion magnetic field generated by at least one pair of permanent magnet components. Furthermore, in accordance with the properties of said active liquid, the invention uses the liquid to remove hazardous air bubbles or uses the active liquid in the form of droplets.

Description

The method that contains the manufacture method of micro air bubble active liquid and use this liquid to realize
Technical field
The present invention relates to the new method that contains the manufacture method of micro air bubble active liquid and use this liquid to realize, can be used for purifying contaminated seawater, lake water, wetland, reservoir, river or the like, or be used for purifying drinking water, water for industrial use, agricultural water, cooling water and the waste oil of discharging from factory, gas station or the like, also can be used for the cleaning of food (as agricultural product and marine product) and sterilization, medical treatment, removal useless bubble, food fresh keeping and in liquid, store gases such as hydrogen, carbon dioxide, methane.
Background technology
Except the purify waste water characteristic of aspect of known can be used for, the present inventor finds in experiment, this be included in activity (ionization) liquid, diameter also shown the characteristic that some are new less than 10 microns micro air bubble, for example can eliminate bigger bubble, especially those be mixed in the viscous liquid than air pocket; Can store hydrogen, carbon dioxide and methane etc.; But the long period is preserved food, vegetables and meat; Can sterilize; Can be used for medical treatment; Can make the injection of fire extinguisher safer, more effective; But humidification; Can be used for the fertilising of soil; And utilize its effect that contaminated liquid is carried out more effective purification, these effects comprise and thisly contain caused gas and the contact-making surface between liquid, the capillary hydroxyl ion that weakens, produces that has increased of micro air bubble active liquid and break up the associated water micel.
Purpose of the present invention is exactly to propose how to make the new method that contains the micro air bubble active liquid that can be used for such use.Another purpose is to propose the new method that the above-mentioned active liquid of use is realized.Manufacturing contains the equipment that diameter is not less than 10 micron bubble liquid and once was used to purify contaminated water, and discloses in Japanese Laid-Open Patent Application P 2003-53373A.This equipment ideally is used for the purification of contaminated seawater, lake water, wetland, dam and river.Cleaning equipment described in the foregoing invention comprises (as shown in figure 10): place in the stationary pipes (21), by the rotor (25) of motor (23) driven rotary; Be installed in the fixedly liquid-inlet (27) and the gas feed (29) of the close one end of tube wall (21); Elder generation is mixed liquid with gas agitator (6); Be connected the junction chamber (31) of the stationary pipes other end; And the pump formula device (33) that drives by motor; One group permanent-magnet (35,37), these magnet or be installed in linear tubercle (45,47) top (these tubercles all are common trapezoidal cross-section, the top is short than the bottom, be attached to the inner surface of stationary pipes (21) and the outer surface of rotor (25) respectively), or be embedded on inner surface or the outer surface in the groove between two linear tubercles.When rotor (25) when rotated, liquids and gases flow into stationary pipes (21) by import (27) and (29) respectively, why liquids and gases can flow is because machine is extracted into machine exterior by pump formula device from junction chamber (31) with liquid, thereby the pressure that causes space between stationary pipes (21) and the rotor (25) weakens.The liquids and gases that are incorporated into stationary pipes in this way earlier carry out mechanical mixture by agitator (6), are incorporated into the space between stationary pipes inner surface and the rotor outer surface then.Liquid previous and that gas mixed flows through the zigzag space then, be subjected to magnetic field reaction and sharp pounding, simultaneously at once by shear, activation and mixing, to carry out circumference between stationary pipes (21) and lip-deep permanent magnet of rotor (25) and the linear tubercle mobile installing, be embedded in for liquid, formed the active liquid that is rich in bubble and a large amount of dissolved active gases at last.The active liquid that is rich in bubble of Chan Shenging is pumped to the outside by pump formula device (33) by this method, is used for the purification of external source liquid.Although the said equipment is successfully used to the reduction of good water environment, also need further optimization, make its operation more effective, use more extensive.
The invention still further relates to the technology that how to reduce or remove the harmful bubble that produces in the processes such as industrial production, environmental renovation, industrial waste water purifying.
The present invention also further relates to how making and use the activated liquid that contains the special gas micro air bubble, be used to sterilize, the exchangeable cations of fresh-keeping, humidification, fire extinguishing, fertilising, crumb structure improvement and soil etc.
Summary of the invention
The present invention proposes following method.The active liquid that hereinafter will contain micro air bubble abbreviates " liquid " as.
One, the manufacture method of " liquid "
Two, the using method of " liquid "
1, removes the method for bubble
2, " liquid " application in other respects
One, the manufacture method of " liquid "
The present invention proposes a kind of new method, compare with last invention, new method produces by the far infrared ray that uses at least one annular activator and produce and/or the repulsion magnetic field that produced by at least one pair of permanent magnet assembly and contains the more active liquid (" liquid ") of diameter less than 10 micron bubbles.
Fig. 1 is a schematic diagram of explaining embodiments of the invention.By being positioned at least 1 liquid-inlet (27) and the gas feed (29) on stationary pipes (21) the one end tube walls, enter into the space between stationary pipes (21) and the rotor (25) from the liquids and gases of external source respectively.When motor (23) drives rotor (25) rotation, linear tubercle (47) and magnet (37) by one group of rotation on the rotor outer surface and be positioned on stationary pipes (21) inner surface linear tubercle (45) and the magnet (35) that another group is fixed, liquids and gases are promptly mixed.When South Pole (or arctic) of magnet (35) during, experiment showed, with other several magnet combinations and compare that this structure can produce diameter less than 10 microns bubble in the face of South Pole (or arctic) of magnet (37).When liquid is water and gas when being air, the South Pole is faced one another to produce best result.Like this, when liquids and gases flow through the space rapidly, change shape repeatedly, liquids and gases are mixed, activate and be transformed into " liquid ".Although preferably can be with all South Pole (or arctic) to getting up to increase the generation of micro air bubble,, according to different operation objects, general 30% ratio is comparatively satisfied.Then, " liquid " discharges outside the machine by pump formula device (33).
An annular activator (81) of being made by magnetic material is installed in the middle of import and the agitator, and this magnetic material contains far infrared disperses material, as the germanium between different metallographics.
Two, the using method of " liquid "
1, removes the method for bubble
According to newfound " liquid " characteristic, the present invention relates generally to the method for removing the harmful bubble that produces in industrial production, environmental renovation, the industrial refuse regulation.
2, utilize the method for " liquid " with the drop form
According to newfound " liquid " characteristic, the present invention relates generally to its effective application at aspects such as sterilization, humidification, fire extinguishing, soil applications.
3, special " liquid "
Might produce " liquid " of some specific types now, and if be impossible with former way.
Description of drawings
Fig. 1 is about making the schematic diagram that contains a kind of embodiment of micro air bubble active liquid equipment among the present invention.
Fig. 2 goes up the schematic diagram of a kind of embodiment of the basic magnetic pole component of permanent magnet about being embedded in stationary pipes (21) and rotor (25).
Fig. 3 is the schematic diagram of a kind of embodiment of annular activator.
Fig. 4 schematic diagram has shown half cross section of stationary pipes (21) and rotor (25), and the linear tubercle vertical with rotor arranged on this section cross section, forms groove between stationary pipes and epitrochanterian two tubercles, and groove is embedded with one group of magnet.
Fig. 5 schematic diagram has shown half cross section of stationary pipes (21) and rotor (25), and the linear tubercle vertical with rotor arranged on this section cross section, in stationary pipes and epitrochanterian tubercle top one group of magnet is housed.
Fig. 6 schematic diagram has shown half cross section of stationary pipes (21) and rotor (25), and the linear tubercle vertical with rotor arranged on this section cross section, at the tubercle top of stationary pipes one group of magnet is housed, and the groove between two tubercles on the rotor is embedded with another group magnet.
Fig. 7 schematic diagram has shown half cross section of stationary pipes (21) and rotor (25), the linear tubercle vertical with rotor arranged on this section cross section, groove between two tubercles on the stationary pipes is embedded with one group of magnet, and another group magnet is housed at epitrochanterian tubercle top.
Fig. 8 makes the schematic diagram that contains another pattern of micro air bubble active liquid equipment among the present invention, wherein motor (23) is installed in the bottom of equipment.
Fig. 9 is about eliminating the schematic diagram of obstinate bubble method.
Figure 10 is the schematic diagram that contains a kind of embodiment of micro-bubble active liquid equipment and technology about be used for making in the past.
The specific embodiment
One, the manufacture method of " liquid "
How the present invention makes less than the active liquid (to call " liquid " in the following text) of 10 microns micro air bubbles and uses about being rich in diameter.Compare with inventor's invention in the past, that the present invention has been developed is more effective, purposes method widely.
As shown in Figure 1, make the equipment of " liquid ", compare, increased annular activator (81) with the equipment of invention in the past described in Figure 10.From Fig. 3, can see, activator is dispersed material (811) by far infrared and is formed with auxiliary material (812) (as the germanium between different metallographics), activator exhales the molecule swing that far infrared ray (813) comes the activated liquid molecule, activator is placed between import and the agitator (6), import can be used and annular activator identical materials or other materials, permanent magnet (35,37) the South Pole is facing to the space (as shown in Figure 2) between stationary pipes (21) and the rotor (25), produce powerful, magnetic field variation rapidly, and because the quick variation in this magnetic field causes electrolysis, thereby produce active fine fluid molecule group.Be fixed on the agitator that disk (63) on the armature spindle and one group of pottery (61) and bar magnet (62) constitute by one and in rotation, liquids and gases mixed, produce ion stream.In Figure 10,2 and 8, two cover agitators have been used.
When liquid is flowed through activator when inner, the fluid molecule RESONANCE ABSORPTION is by the energy of dispersing the far infrared ray (813) that material sends, even also can be activated under the situation of low temperature.The molecular vibration of liquid can prevent that external magnetic particle is attached to the magnet surface that is embedded on solid tube (21) and the rotor (25).By the magnet deterioration that prevents from may cause because of external magnetisable material, the performance of equipment is improved, and has guaranteed longer service life.Especially when liquid is water, because aquation, oxygen molecule is brought in the water, and the hydrogen atom that the oxygen atom of hydrone aligns the absorption of ionized air and hydrone all is accelerated the absorption of negative ionization.Therefore, annular activator can be accelerated and double to strengthen the activating effect that is taken place in the space between stationary pipes and rotor.
Fig. 2 is schematically illustrated in a pair of magnet assembly on the plane, comprises armature spindle, and Fig. 4 is half cross-sectional view vertical with armature spindle.The South Pole of each magnet is designated as " S ", and the arctic is designated as " N ".Permanent magnet (351,352,353 etc.) (distinguished as unnecessary, then be referred to as permanent magnet group 35) or be embedded on the surface of linear tubercle (45) (these tubercles are trapezoidal cross-section, indicate with ABCD, are contained on the inner surface of stationary pipes (21)); Or be embedded in groove (49) lining that forms by two adjacent nubs.Permanent magnet (371,372,373 etc.) (distinguished as unnecessary, then be referred to as permanent magnet group 37) or be embedded on the surface of linear tubercle (47) (these tubercles are trapezoidal cross-section, indicate with EFGH, are contained on the outer surface of rotor (25)); Or be embedded in groove (51) lining that forms by two adjacent nubs.
As shown in these figures, the space between stationary pipes (21) and the rotor (25) is all faced in all South Pole.When two magnet homopolarities were relative, repelled mutually in the magnetic field of two magnet, forms two strong magnetic fields in the space.This brings the intense electromagnetic effect for the physics and the chemical state of the liquid in corresponding magnetic field intensity, and in other words, liquid is split into littler micel by electromagnetic activation, produces micro air bubble.When one group of magnet very opposite, magnet attracts each other, and it is very level and smooth that magnetic field becomes, and peakedness ratio situation in the past is lower.In other words, the activation of liquid is become very weak, strong effect can not take place.
When rotor rotated, the magnetic field of repelling each other that produces in the space between stationary pipes and rotor was changing apace along with the rotation of rotor.When liquids and gases were flowed through the space, because the mutual rotation (seeing Fig. 4 sectional view) of two hackly surfaces, liquids and gases were promptly mixed, by strong magnetic field activation.This liquid stream that rotates to be has brought magnetic at random to change and the variation of high-frequency machinery, thereby produces active fine micel and micro air bubble.The result is to have produced the active liquid (" liquid ") that contains the capacity micro air bubble.
Effective manufacturing about " liquid ", as shown in Figure 4, the angle b of the angle a of stationary pipes (21) corresponding recesses end face AD and rotor (25) corresponding recesses end face EH is remained between 20 to 60 degree in good condition, and the depth d between tubercle (45) top and magnet (35) top is bigger than the degree of depth c between tubercle (47) top and magnet (37) top.Be noted that different flow velocitys is depended in the shear of current, and flow velocity different because of the degree of depth of stationary pipes and rotor surface groove that is to say that d may be slower than the flow velocity of c.
About linear tubercle of the present invention, linearity not only means straight line, also can be curve or helix.
There is the position to close the variation of fastening between group of magnets and the linear tubercle, promptly, whole group magnet is embedded in the top (see figure 5) of whole group tubercle, one group of magnet is embedded in the one group of linear tubercle top that is positioned at stationary pipes (21) inner surface, another group magnet is embedded in (see figure 6) in the groove that rotor (25) forms, and what Fig. 7 showed then is opposite situation.
That Fig. 8 shows is another embodiment of the present invention.Motor (23) is installed in the bottom of equipment.Compared with the above case, on function, this embodiment does not have the difference of what essence.
Find in the experiment, use laser defusing measure, when equipment is the operation of 1500 revolutions per at rotating speed, produce 40% diameter and be 5 to 10 microns bubble and 20% diameter at 2 to 3 microns bubble.Observing the pH value that causes because of the water ion diffusion simultaneously changes.This has proved that micro air bubble is manufactured and has come out.It will be further appreciated that, find that also can stably there be the longer time in diameter less than 10 microns active bubble in liquid, the possibility of activated liquid atom and molecule is further increased, dissolved oxygen is further increased, thereby make purification faster, more effective.
The characteristics of " liquid " comprising:
(1) chief component of " liquid " is: contain dissolved gas interior active liquid and contain the same gas composition, diameter is less than 10 microns micro air bubble.
(2) chief component of " liquid " is: contain special dissolved gas (as hydrogen) interior active liquid and contain the same gas composition, diameter is less than 10 microns micro air bubble.
(3) gas of any kind of all can be used for " liquid ".But, preferably use air, oxygen, ozone, nitrogen, carbon dioxide or hydrogen, or the mixing of these gases.
" liquid " has following effect:
1, increases the contact area of liquids and gases.Along with reducing of bubble diameter, be contained in the increase that is inversely proportional to of the bubble surface gross area in the constant volume and diameter.This just means that its reaction speed will be accelerated greatly if use bubble than minor diameter.
2, surface tension reduces.If see hydrone, can find that each molecule always moves (as shown in " Blang's linearity and rotational motion ") randomly, collides simultaneously repeatedly.Weaken along with capillary, bubble divides in the precipitation that causes because of Brownian movement, has dissolved more oxygen.The life of bubble becomes longer, flows regularly simultaneously.
3, electrolysis.Because the reaction in magnetic field, hydrone is ionized, and produces hydroxyl ion, and micel is broken down into littler polymerization, can be used for sterilization, cleaning.
In addition, can cause rotatablely moving of aqueous electron, produce deoxidation.
4, the ordered molecular motion that causes of magnetic field.Molecular motion becomes in order, and its direction of motion has reduced the chance that reacts with other molecules.
5, the sterilization of food and preservation.
When micro air bubble disappears, can produce H ion, OH ion and H3O2 ion, thereby destroy bacterium.The destruction of bacterium is because oxidation, the minimizing of hydrogenization and reducing of surface tension or osmotic pressure.Because micro air bubble is electronegative, the common positively charged of bacterium, the exchange of ion causes the death of bacterium.There is the bacterium of non-intact cell nuclear membrane structure to infiltrate potential difference the killing that causes because of ion-exchange and because of anion by selectivity.Those have the then unaffected of complete structure.Glaucous microorganism packing is destroyed by anion, then microbial death.Micro air bubble reacts with the bacterium that has cation selectively and kills these bacteriums.Because good microorganism band anion, so micro air bubble is to they not influences.
When the liquid part of agricultural product has positive electricity, oxidation in air, its color relation can change.By the ion of this liquid part (alkali lye) and the exchange interaction between " liquid " middle anion, can prevent the oxidation of agricultural product, thereby reach food insurance effect.
6, " liquid " has new function
By disclosed method, because the strong self-compression mechanism of micro air bubble, oxygen and hydrogen can be dissolved in the space between hydrone respectively, thus the oxidation reaction of producing and hydrogenation are less, breaking-in period is long hydrogen water or oxygen water.
7, with hydrate form stored-gas
Hydrate is that a kind of gas molecule is enclosed in the synthetic in the hydrone.Cause the gas of global warming,, when mixing, can form hydrate with water as carbon dioxide, nitride, methane, CFC, HCFC, HFC or the like.
The part characteristics of micro air bubble are that because the effect that the total body surface area of its increase and internal pressure strengthen, they can dissolve the gas in the liquid, disappear in liquid until these gases.Because the compressibility of micro air bubble has produced gas hydrate, that is, the internal pressure of bubble is than the height of periphery.When gas dissolved in liquid, bubble diminished.But along with reducing of bubble diameter, pressure can increase, and this is owing to the surface tension with respect to bubble diameter increases, and reaches at peripheral liquid to produce the nuclear crucial pressure of hydrate.In case hydrate begins to form, it can continue to increase.The storage of gas of warming need not to use large-scale equipment and investment, and only according to disclosed method, just can finish with simple equipment.
It is lower than the saturation vapour pressure of heating material to produce the necessary pressure of hydrate, thereby the invention provides the low energy consumption economic means of separating hydrate from liquid.
8, purify by the water environment of polychlorostyrene phenylbenzene (PCB) and/or dioxin contamination, remove the method for stink and decompose volatile organic compound
When sewage, muddy water flow in magnetic field randomly, can give out metal ion in the magnetic field, son and the heat energy that can absorb the metal ion of hydrone moisturize.By this synergy, the regional area of micro air bubble border surface can form higher temperature.High-temperature area can distribute and contact with PCB.Then, PCB at high temperature is decomposed.
In the machine based on revealing method of the present invention, liquid forcefully, is promptly stirred, and constantly obtains the energy that produces from compression, expansion and rotation.
Because flowing water and effect of electric field, PCB shifts to the border surface of bubble, and the energy that is produced by borderline molecule swing decomposes.Even PCB is absorbed in one group of hydrone, electromagnetic field and metal ion have quickened the molecular motion of contaminated water, so, isolate PCB in the water and become easily.Because metal ion such as Mg, Na and K have the performance of chlorine among the good removal PCB, when chlorine is met one of them ion, can come off from object.Under these effects, the phenyl ring of PCB is destroyed, decomposes in carbon dioxide and the chloride.
Frowzy and volatile material is introduced based in the equipment of the present invention, be dissolved in water and be decomposed by oxidation and hydrogenization, simultaneously, identical with PCB, at random, the energy of the regional area molecule swing Cheng Sheng of institute that produces of water movement also plays decomposition apace.
Two, the using method of " liquid "
1, eliminates the method for bubble
By using " liquid ", the present invention proposes the new cost effective method of eliminating bubble, this method need not to use additive, and uses additive can bring harm in process of production, as the chemical plant, produce the factory of polymer, chemical fertilizer etc.
The big quantity of fluid that traditional physics one mechanical technique requires to use equipment expensive, high energy consumption needs to eliminate bubble pressurizes, heats or shakes.In chemistry is eliminated, must use additive, thereby increase cost.Can not then can not use with under the situation of additive.
Find in the experiment that when the equipment of making " liquid " during in operation, one group of obstinate bubble that exists has just disappeared in a short period of time in polymerization emulsion.Although this phenomenon is not understood as yet fully, but the surface tension that may be their peripheral liquid according to estimates is owing to the influence that is subjected to " liquid " weakens, liquid than the minute bubbles periphery becomes more viscous, makes can not to keep when the stabilise bubbles collision that produces with equipment and break than air pocket.What do is exactly to turn round after liquid is put into equipment, very simple.Any diameter that can produce can both be used for doing this bubble less than the equipment of 10 micron bubbles and eliminates.
Fig. 9 is about eliminating the schematic diagram of bubble method basic conception.As long as equipment 10 and bracing or strutting arrangement thereof are put into the container bottom that need elimination bubble liquid is housed, flexible pipe (12) is connected with air intlet (29), with the end of flexible pipe as on the liquid surface, connect liquid line and liquid-inlet (27), the liquid line end is placed in the pending liquid, move machine then.
2, " liquid " otherwise application
The method that the present invention relates to fine droplet and how to produce fine droplet by using " liquid ", can be used for sterilizing, the exchangeable cations of humidification, fire extinguishing, fertilising, improvement crumb structure and soil or the like.
The magnetic treatment of liquid (especially water) receives a large amount of concerns.Although do not find reason as yet comprehensively, can find that processed water has presented unique characteristic, as the enhancing of penetrating power, protection or remove because of the iron rust that contacts generation with non-ferrous metal and prevent that calcium carbonate is attached on the tube wall.
On the other hand, along with the technology that bubble is dwindled is improved widely, the method that the present invention discloses can be created in the liquid (especially in the water) diameter only several microns or littler bubble.Experience according to the inventor, obviously, the characteristic of micro air bubble has obviously different with characteristic than air pocket, as previously mentioned, concrete manifestation comprises that micro air bubble is very stable, can in water, keep the long period and can not drift about or scatter, and the water of oxygenous bubble has more activity for bacterium or microorganism.
At present, " liquid " application aspect improvement mainly is that the spray pattern that still is difficult drop or spraying is so far used micro-bubble by previously described liquid operation.
Therefore, the present invention proposes the novel method of use " liquid ", and the novel using method of the micro-bubble that method or other similar approach produced that discloses with Japanese Laid-Open Patent Application P2003-53373.
According to the long-time investigation result and to the generation micro air bubble, by the experience that magnetic treatment is purified waste water, concrete manifestation of the present invention is as follows:
(1) contains the using method of liquid under drop or Sprayable of the small or micro air bubble of special gas.
(2) by magnetoelectricity activation, contain the using method of liquid under drop or Sprayable of the small or micro air bubble of special gas.
(3) method (1) and (2), in these two kinds of methods, the equipment that is mixed by the liquids and gases that will add import or produce the equipment of small or micro air bubble or more excellent selection is used disclosed method manufacturing " liquid ".
(4) method (1) and (2), in these two kinds of methods, by the equipment that liquids and gases are mixed or produce the equipment of small or micro air bubble or more excellent selection, use disclosed method manufacturing " liquid ", and be loaded into suitable sprayer.
(5) method (1) and (2), in these two kinds of methods, gas is air, oxygen, nitrogen, carbon dioxide or hydrogen, or the mixture of these gases.
(6) method (1) and (2), in these two kinds of methods, described dropping liquid is water and the water that contains dissolved material.
(7) method (1) is to (6), and in these methods, " liquid " is loaded into the import of at least one sprayer.
According to Xin Fangming, produced drop and/or spraying with new features, contain micro-bubble and/or be subjected to the liquid of magnetic treatment to be used for sterilization, cleaning, fire extinguishing and industrial production by sprinkling.
Spendable gas liquid blender or the equipment that produces micro-bubble (as the preamble definition, diameter is less than 50 microns bubble) comprise and any liquid, gas feed are housed, can make and meet bubble that diameter requires and/or other has the equipment of magnetic treatment function among the present invention.The micro-bubble manufacturing equipment that Japanese Laid-Open Patent Application P2003-53373 discloses and in Fig. 1 shown micro-bubble manufacture process be particularly useful for the present invention.
Any liquids and gases all are adapted to disclosed method.From actual angle, the gas that the present invention mainly uses may be air, oxygen, ozone, nitrogen, carbon dioxide and hydrogen.
As for spraying, Fig. 1,8 can transform as and at least one sealing chamber that has the sprayer of nozzle to link to each other with the junction chamber shown in 10 (31), can use after transforming.If necessary, nozzle can be loaded onto the device that utilizes ultrasonic wave and/or other ways to come accelerating liquid to disperse.
When very little very little drop of needs or more powerful injection, produce through magnetic treatment and the equipment that contains micro-bubble water and must be equipped with suitable sprayer thereby produce small or micro air bubble.
According to the present invention, contain the water of small ozone bubbles by injection, can be used for disinfecting air space, metope, vessel and other objects.The object of sterilization must be isolated in the space of a sealing generally speaking, introduce ozone gas then.According to the present invention, ozone is retained in the drop with the form of micro-bubble, and then, at leisure from attached to discharging the drop on the sterilised object, disinfecting process only takes place near drop.When water droplet when open space sprays, do not have ozone and be released in the air.Therefore, spray the water droplet that contains ozone bubbles and can not bring harm to human body.
When bubble diameter during less than 1 micron, it can be very stable, can keep for a long time in drop." liquid " can be used to stored-gas safely.
" liquid " (water) that contains nitrogen and carbon dioxide can be used to spray to burning things which may cause a fire disaster, thereby can put out a fire.Compare with the fire extinguisher of common generation larger bubbles, " liquid " more concentrated area sprays to burning things which may cause a fire disaster, brings littler pollution.Simultaneously, the barrier action of the cooling effect of water and inert gas also clearly.
Although to the present invention's description of specializing very much,, this does not limit the scope of the invention and only limits to the description mentioned.

Claims (20)

1. make the method that contains the micro air bubble active liquid: drive the rotor rotation that is installed in the stationary pipes with motor, have 1 liquid-inlet and 1 gas feed on the tube wall that stationary pipes is a section at least, have at least a junction chamber to be connected to the other end of stationary pipes, drive a pump formula device with motor, the liquids and gases of outside are pumped in the above-mentioned stationary pipes by above-mentioned import, liquids and gases are mixed, activation also is converted into the active liquid stream that is rich in micro air bubble, this process is to work as liquid, when gas flows through the shear route that is formed by said fixing pipe and rotor, one group of linear tubercle is housed on the inner surface of stationary pipes and the outer surface of rotor, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with a group permanent-magnet, and the groove that the top of above-mentioned tubercle or two adjacent nubs form is embedded with another group permanent-magnet, and wherein a group permanent-magnet of at least 30% has identical magnetic pole facing to the space between said fixing pipe and the rotor with another permanent magnet of organizing facing to above-mentioned space.
2. make the method that contains the micro air bubble active liquid: drive the rotor rotation that is installed in the stationary pipes with motor, have 1 liquid-inlet and 1 gas feed on the tube wall that stationary pipes is a section at least, have at least a junction chamber to be connected to the other end of stationary pipes, drive a pump formula device with motor, the liquids and gases of outside are pumped in the above-mentioned stationary pipes by above-mentioned import, liquids and gases are mixed, activation also is converted into the active liquid stream that is rich in micro air bubble, this process is to work as liquid, when gas flows through the shear route that is formed by said fixing pipe and rotor, one group of linear tubercle is housed on the inner surface of stationary pipes and the outer surface of rotor, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with a group permanent-magnet, and the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with another group permanent-magnet, and before above-mentioned shear route, place an annular activator that mainly constitutes by the far infrared irradiation material, to activate the molecule swing of fluid molecule.
3. make the method that contains the micro air bubble active liquid: drive the rotor rotation that is installed in the stationary pipes with motor, have 1 liquid-inlet and 1 gas feed on the tube wall that stationary pipes is a section at least, have at least a junction chamber to be connected to the other end of stationary pipes, drive a pump formula device with motor, the liquids and gases of outside are pumped in the above-mentioned stationary pipes by above-mentioned import, liquids and gases are mixed, activation also is converted into the active liquid stream that is rich in micro air bubble, this process is to work as liquid, when gas flows through the shear route that is formed by said fixing pipe and rotor, one group of linear tubercle is housed on the inner surface of stationary pipes and the outer surface of rotor, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with a group permanent-magnet, and the groove that the top of above-mentioned tubercle or two adjacent nubs form is embedded with another group permanent-magnet, and wherein a group permanent-magnet of at least 30% has identical magnetic pole facing to the space between said fixing pipe and the rotor with another permanent magnet of organizing facing to above-mentioned space.And before above-mentioned shear route, place an annular activator that mainly constitutes by the far infrared irradiation material, to activate the molecule swing of fluid molecule.
4. as claim 1,2 or 3 described methods, wherein two groups of magnet is embedded in accordingly in the groove group that is formed by two adjacent linear tubercles, from above-mentioned epitrochanterian linear tubercle top to the degree of depth at respective magnets top and the linear tubercle top on the said fixing pipe different to the degree of depth at respective magnets top.
5. eliminate the method for bubble: in containing the liquid of waiting to eliminate bubble, place, at least one cover of operation can be enough as method as described in the claim 1,2,3 or utilize the equivalent processes manufacturing of mechanical shear, mixing and magnetoelectricity effect to contain the equipment of micro air bubble active liquid at least.
6. the sterilization and the method for food fresh keeping: use is as method as described in the claim 1,2,3 or utilize the micro air bubble active liquid that contains of the equivalent processes manufacturing of mechanical shear, mixing and magnetoelectricity effect that food is cleaned and/or stores at least.
7. produce the method contain gas molecular function water: use as method as described in the claim 1,2,3 or utilize at least mechanical shear, mixing and magnetoelectricity effect the equivalent processes manufacturing contain the micro air bubble active liquid, wherein need join special gas in the equipment according to described method.
8. produce the method for hydrogeneous molecular function water: use as method as described in the claim 1,2,3 or utilize at least mechanical shear, mixing and magnetoelectricity effect the equivalent processes manufacturing contain the micro air bubble active liquid, wherein need join hydrogen in the equipment according to described method.
9. the method that gas is stored with the form of hydrate: use as method as described in the claim 1,2,3 or utilize the micro air bubble of the equivalent processes manufacturing of mechanical shear, mixing and magnetoelectricity effect at least, be added in the equipment water is gentle according to described method.
10. the method that methane is stored with the form of hydrate: use as method as described in the claim 1,2,3 or utilize the micro air bubble of the equivalent processes manufacturing of mechanical shear, mixing and magnetoelectricity effect at least, water and above-mentioned gas are added in the equipment according to described method.
11. the method for decomposing pollutant matter: utilize the effect that metal ion disperses and/or hydrone heat energy increases that in making the micro air bubble process, forms, pollutant is put into equipment based on claim 1,2 or 3 described methods.
12. use the method contain the small molecule liquid of special gas (one or more): by method as described in claim 1,2,3 or utilize the equivalent processes of mechanical shear, mixing and magnetoelectricity effect to make these micro-bubbles at least.
13. use contain the small molecule of special gas (one or more), by the magnetoelectricity activation and utilize sprayer to make it to be the method for drop or spray form liquid: by with claim 1,2,3 described methods or utilize the equivalent processes of mechanical shear, mixing and magnetoelectricity effect to make these micro-bubbles at least.
14. comprise diameter less than 1 micron, contain the fine droplet that gas bubbles is crossed in special and/or magnetic treatment.
15. make method, in this method, used and to have put into liquids and gases, also can discharge equipment that contains micro-bubble liquids and gases mixture or the equipment of making micro-bubble as the fine droplet in the claim 14.
16. spray the method for the fine droplet described in claim 14, in this method, used and can put into liquids and gases, also can discharge equipment that contains micro-bubble liquids and gases mixture or the equipment of making micro-bubble, the material that is discharged from is put in the suitable sprayer.
17. make the method for the fine droplet described in claim 14, in this method, the equipment situation of using is: drive the rotor rotation that is installed in the stationary pipes with motor, have 1 liquid-inlet and 1 gas feed on the tube wall that stationary pipes is a section at least, have at least a junction chamber to be connected to the other end of stationary pipes, drive a pump formula device with motor, the liquids and gases of outside are pumped in the above-mentioned stationary pipes by above-mentioned import, liquids and gases are mixed, activation also is converted into the active liquid stream that is rich in micro air bubble, this process is to work as liquid, when gas flows through the shear route that is formed by said fixing pipe and rotor, one group of linear tubercle is housed on the inner surface of stationary pipes and the outer surface of rotor, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with a group permanent-magnet, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with another group permanent-magnet, and the drop that the said equipment will contain micro-bubble is discharged to the outside.
18. make the method for the fine droplet described in claim 14, in this method, the equipment situation of using is: drive the rotor rotation that is installed in the stationary pipes with motor, have 1 liquid-inlet and 1 gas feed on the tube wall that stationary pipes is a section at least, have at least a junction chamber to be connected to the other end of stationary pipes, drive a pump formula device with motor, the liquids and gases of outside are pumped in the above-mentioned stationary pipes by above-mentioned import, liquids and gases are mixed, activation also is converted into the active liquid stream that is rich in micro air bubble, this process is to work as liquid, when gas flows through the shear route that is formed by said fixing pipe and rotor, one group of linear tubercle is housed on the inner surface of stationary pipes and the outer surface of rotor, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with a group permanent-magnet, the groove of the top of above-mentioned tubercle or two adjacent nubs formation is embedded with another group permanent-magnet, the drop that the said equipment will contain micro-bubble is discharged to the outside, and the liquid that is discharged from is loaded into suitable sprayer.
19. the fine droplet described in claim 14, wherein, described special gas is air, oxygen, ozone, nitrogen, carbon dioxide or hydrogen, or the mixing of these gases (more than 2 kinds).
20. the fine droplet described in claim 14, wherein, aforesaid liquid is a water, or contains the water of soluble substance.
CNA2006100069178A 2006-01-23 2006-01-23 Preparation method of active liquid containing micro-gas and implementation method using said liquid Pending CN101007244A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103979665A (en) * 2014-04-25 2014-08-13 中国科学技术大学 Double-fluid micro-bubble spraying generating device
WO2016119087A1 (en) * 2015-01-29 2016-08-04 于小波 Gas-liquid mixing device
CN108203166A (en) * 2016-12-19 2018-06-26 深圳市国沅生态环保科技有限公司 A kind of suspending type water correction device
CN109890492A (en) * 2016-09-28 2019-06-14 夸图斯·保罗斯·博塔 Nano-bubble generator and the method for generating nano bubble
CN109936980A (en) * 2017-03-14 2019-06-25 纳米技术公司 Purification system
CN112426990A (en) * 2020-10-23 2021-03-02 大连理工大学 Device and method for promoting hydrate generation by nano bubbles
CN113615633A (en) * 2021-08-23 2021-11-09 浙江省海洋水产研究所 Floating and sinking controllable oxygenation device and control method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103979665A (en) * 2014-04-25 2014-08-13 中国科学技术大学 Double-fluid micro-bubble spraying generating device
CN103979665B (en) * 2014-04-25 2015-04-22 中国科学技术大学 Double-fluid micro-bubble spraying generating device
WO2016119087A1 (en) * 2015-01-29 2016-08-04 于小波 Gas-liquid mixing device
CN109890492A (en) * 2016-09-28 2019-06-14 夸图斯·保罗斯·博塔 Nano-bubble generator and the method for generating nano bubble
CN108203166A (en) * 2016-12-19 2018-06-26 深圳市国沅生态环保科技有限公司 A kind of suspending type water correction device
CN109936980A (en) * 2017-03-14 2019-06-25 纳米技术公司 Purification system
CN112426990A (en) * 2020-10-23 2021-03-02 大连理工大学 Device and method for promoting hydrate generation by nano bubbles
CN113615633A (en) * 2021-08-23 2021-11-09 浙江省海洋水产研究所 Floating and sinking controllable oxygenation device and control method

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