CN100595239C - Coating composition for crude tyre - Google Patents
Coating composition for crude tyre Download PDFInfo
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- CN100595239C CN100595239C CN200610087680A CN200610087680A CN100595239C CN 100595239 C CN100595239 C CN 100595239C CN 200610087680 A CN200610087680 A CN 200610087680A CN 200610087680 A CN200610087680 A CN 200610087680A CN 100595239 C CN100595239 C CN 100595239C
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Abstract
The present invention discloses one kind of paint composition to be coated onto tyre before vulcanizing for preventing faults formed in the vulcanizing process and raising the antifouling property ofthe produced tyre. The paint composition consists of filming solid components including glass bead or polymer bead in 0.001-500 micro size and in 100 weight portions, adhesive up to 2000 weight portions and surfactant in 2-2000 weight portions, and dispersing medium for dilute the solid components. Coating the paint composition to tyre before vulcanizing can minimize faults formed in the vulcanizing process, result in lubricating effect and releasing effect, and minimize the contamination on the tyre during its transportation, assembling and use.
Description
Technical field
The present invention relates to a kind of coating composition that is used for crude tyre, and more specifically, relate to a kind of coating composition that is used for crude tyre, it is being coated to before sulfidizing on the crude tyre, with anti-the staining property after preventing the defective in the sulfidation of tire and being implemented in tire production.
Background technology
When being inserted into, crude tyre is used for sulfuration and during forming mould, because following purpose and on crude tyre, apply anti-defective or anti-exposed paint:
1. lubricity, this can make tire easily be inserted in the mould, and after forming processes reposefully from wherein discharging.
2. by revising the defective that produces when the crude tyre moulding or exposed, as folding, projection, space, crackle etc. in the sulfurized process, obtain slick outward appearance in mould.
3. make the folding or crackle that is caused by the overflow of rubber or unfilled space (so-called " lights ") minimized, described unfilled space is to be caused by the insufficient flow of rubber in the sulfidation in mould.
4. air bubble of catching between crude tyre and mould or small steam bubbles are discharged easily, form the space owing to existing of this bubble with prevention when not filling mould with rubber.
In order to prevent defective, what mainly use is carbon black, rubber, inorganic particulate and/or silicone compounds solution or the dispersion liquid in solvent or water.
But it is opaque or colored being used for improving main ingredient such as the organic-inorganic particulate that anti-defective paint that the present commercially available crude tyre of gas leakage uses uses, and has therefore limited their application.Paint can be sheltered, decolours or stain and be used for annular colour or white wire (" wheel rim ") or literal that the type and the size of tire are classified on the sidewall of tire.Recently, although the barcode of indication tire history is provided on tire, because the use of anti-defective paint will be difficult to discern barcode.
In the process of the storage of the tire of the final manufacturing by forming processes and processing, blooming may take place, promptly low-molecular-weight material such as amine-based stabilizer, antioxidant, perfume oil and wax cause the deterioration of tire outward appearance to the transmission on the surface of tire.In addition, in transportation, loading, storage and the use of the tire of tire, because external factor such as dust, friction, sunlight and rainwater may be damaged or stain.Particularly under the situation of black tire, color is the mark beyond the black on sidewall, stains as observing significantly on the annular white line etc., and this transmission by low molecular weight material causes.Little black or brown point or agglomerate are typical.Therefore, nearly all tire product all additionally is coated with the anti-paint of staining, to protect the surface after their sulfurations and the moulding.For this reason, main use is wax or dispersion liquid or the solution of siloxane polymer in water.
For the deterioration that makes the tire outward appearance that sulfuration back causes owing to the blooming of low molecular weight material minimizes, or in order to make in transportation, loading, storage and the use of the tire of producing since the damage that external factor causes as the scraping that is produced by dust, friction, sunlight and rainwater or stain minimize, need to apply the anti-extra process of paint that stains, thereby increase production cost.
Summary of the invention
Technical problem
One object of the present invention is to provide a kind of coating composition that is used for crude tyre, and it prevents the defective of tire in the sulfidizing process.
Another object of the present invention is to provide a kind of coating composition that is used for crude tyre, and it is neither sheltered, decolours in the prevention defective, does not also stain annular colour or white wire or literal.
Another object of the present invention is to provide a kind of coating composition that is used for crude tyre, its in the prevention defective, anti-the staining property of demonstration in the processing of the sulfuration and the tire of moulding and storage process.
Another purpose of the present invention is to provide a kind of coating composition that is used for crude tyre, and it plays following effect: prevent that in the use of tire pollutent from adhering to easily, or pollutent is removed easily in the prevention defective.
Technical scheme
According to the present invention, a kind of coating composition that is used for crude tyre is provided, it comprises and is used for film forming solid ingredient, described solid ingredient comprises: (a) 100 weight parts are of a size of 0.001～500 micron glass beads or polymer beads, (b) 2000 weight parts or still less tire is had the tackiness agent of high adhesion and (c) tensio-active agent of 2～2000 weight parts; (d) be used to dilute the dispersion medium of described solid ingredient.(a) glass beads or polymer beads play following effect: form thin projection to show the gas leakage performance on the film that solidifies or be coated with; help easily being inserted into crude tyre in the mould and rubber is flowed in mould in sulfidation reposefully; be implemented in after the sulfuration with anti-the staining property on the surface of tyre of its coating, and keeping the transparency film.(b) tackiness agent, itself and tire have high bounding force, play a part coating composition of the present invention is bonded to tire.Dispersion medium is preferably water, and is used for the solid ingredient that film forming is used is diluted to the concentration of 1～70 weight %.Coating composition in invention is used for film forming solid ingredient and can also comprises (e) 1000 weight parts or softening agent still less.In addition, solid ingredient can also comprise (f) 1000 weight parts or still less be of a size of 1000nm or littler particulate that described particulate is less than described bead.In addition, coating composition of the present invention can also comprise (g) softening agent, (h) stablizer, (i) neutralizing agent of significant quantity and/or (j) sequestrant, as additive.In addition, if desired, coating composition of the present invention can comprise the various additives of significant quantity, as defoamer, sanitas, sterilizing agent, antioxidant, pigment and dyestuff.
Below, will specifically describe one composition.In the present invention, proportion of composing is based on glass beads or the polymer beads of 100 weight parts in the solid ingredient that film forming is used and calculates.
(a) glass beads or polymer beads
Be of a size of 0.001～500 micron granulated glass sphere or polymeric beads, it is the main component of coating composition of the present invention, play following effect: on filming, form thin projection to show the gas leakage performance, can easily be inserted into crude tyre in the mould and rubber is flowed in mould in sulfidation reposefully, be implemented in after the sulfuration with anti-the staining property on the surface of tyre of its coating, and the transparency to keep filming.Bead is preferably dimensioned to be 0.01～300 micron, and more preferably 0.1～100 micron.This bead has different shape, as spherical form, and planeform, fiber shape or other shape, and be preferably spherical form.The size of the bead of spherical form or fiber shape is based on its diameter, and the size of the bead of planeform is based on its thickness.If bead is too big, then be difficult to this bead is dispersed in the water.On the other hand, if bead is too little, mis-behave then leaks gas.But this bead should be a highly transparent, not shelter, to decolour or to stain annular colour or white wire, literal and the barcode of tire.
The examples of materials that is used for the transparent polymer bead comprises: vinyl monomer such as vinylbenzene or Polymerization of Methyl thing, polycondensate such as polycarbonate or urethane and cross-linked polymer such as Resins, epoxy.
The preferably transparent glass beads of bead that is used for coating composition of the present invention, wherein glass is defined as physically full-bodied rigidity, supercooled liquid amorphous material, to prevent crystallization, and in the set that chemically is defined as non-volatile inorganic oxide, its decomposition and fusing by alkali and alkaline earth compound, sand and other glass ingredient obtains, and finally has the product of unordered atomic structure.Glass is by will be as the silicon-dioxide in the sand of main component, and lime and/or soda-lime, and if desired, and various trace constituents fusings are cooled off them and the amorphous material that obtains then.The material that the glass beads of using among the present invention is used comprises all types of glass, and is not particularly limited.For example, the material used of glass beads comprises fused silica glass, soda-lime glass, lead glass, borosilicate glass or alumina silicate glass.In coating composition of the present invention, when the usage quantity of bead very hour, the gas leakage mis-behave.On the other hand, the excessive use of bead cause in water bad dispersibility and film flexible poor.
(b) tackiness agent
Tackiness agent (" bonding composition "), it has high bounding force to tire, plays a part coating composition of the present invention is bonded to tire.Preferred this tackiness agent is made up of flexible adhesive.The content of tackiness agent is 2000 weight parts or lower, is preferably 5～1000 weight parts, and 10～100 weight parts more preferably.
The example that tire is had high bounding force and the flexible of filming (b-1) flexible adhesive comprises natural or synthetic rubber latex, for example natural rubber latex, chloroprene rubber latex, content of polybutadiene rubber latex, styrene butadiene rubbers latex and acrylonitrile-butadiene rubber latex etc.
In addition, if desired, partly (b-1) flexible adhesive can be that crystalline or second-order transition temperature are-40 ℃ or the replacement of higher (b-2) tackiness agent, with the transmission of the low molecular weight material in the obstruction tire to surface of tyre.As for (b-2) tackiness agent that becomes the composition that solidified films, operable is that second-order transition temperature is-40 ℃ or higher, and the preferred glass transition temperature is room temperature or higher polymer materials, or the crystalline material that at room temperature has low chain flexibility, make low molecular material be difficult to therebetween from passing through.For example, urethane resin with water dispersible or water-soluble is arranged, the saponification variant such as the polyvinyl alcohol of vinylite or polyvinyl acetate, acrylic resin, vinyl acetate copolymer such as vinyl-vinyl acetate copolymer or its saponification variant, Resins, epoxy, or multipolymer such as the styrene-maleic anhydride copolymer or the methyl vinyl ether-maleic acid copolymer of maleic anhydride, toxilic acid, fumaric acid, acrylic or methacrylic acid.Binding agent based gross weight, (b-2) usage quantity of tackiness agent is 100 weight % or still less, is preferably 0～50 weight %, and more preferably 0～25 weight %.When using tackiness agent aptly, low molecular weight material is hindered to the transmission on surface.But the excessive use of tackiness agent causes reducing with the bounding force of tire, reduces film flexible unfavourably.
(c) tensio-active agent
For the water dispersible of the stable components that improves said composition and the wetting properties of filming, use (c) tensio-active agent.Can use nonionogenic tenside, anion surfactant and cats product separately, or can use with the form of its combination.The example of nonionogenic tenside comprises: the partial condensate of the condenses of the condenses of the condenses of the condenses of high fatty alcohol such as oleyl alcohol and oxyethane, alkylphenol and oxyethane, oxyethane and high fatty acid amide, higher fatty acid and polyoxyethylene glycol and polyvalent alcohol such as Sorbitol Powder triacetate and lipid acid, or the addition condensation thing of this partial condensate and oxyethane.The example of anion surfactant comprises an alkali metal salt of following material: the part phosphoric acid hydrochlorate of lipid acid, alkylbenzene sulfonate, alkylsulfonate, alkyl aryl polyether sulfonate, alkylether sulfonate, amine dodecylbenzene sulfonate, condensed alkylphenol and oxyethane, etc.The content of tensio-active agent in the solid ingredient that film forming is used is 2～2000 weight parts, preferred 5～1000 weight parts, and more preferably 10～100 weight parts.
(d) dispersion medium
(d) dispersion medium that uses in the coating composition of the present invention is organic solvent or water, preferred alcohol or water, and water more preferably.Thereby, consider working conditions, make water aptly.Dispersion medium or solvent can be added when the preparation of paint, also can be used for diluting and only use film forming with solid ingredient or the paint that uses the film forming of high density to prepare with solid ingredient.In addition, under the situation of spraying, can use dispersion medium or solvent like this, the feasible film forming that is used for handling remains in 1～70 weight % scope with the concentration of solid ingredient.
(e) softening agent
In coating composition of the present invention, (e) softening agent is used for improving film flexible and is used for improving flowing and rubber-rubber adhesion power of in mould rubber, so that the generation of the exposed part of tire outward appearance is minimized.The example of softening agent that can be compatible with rubber comprises alkane, naphthenic hydrocarbon, aromatics petroleum oil or its sex change variant, low molecular weight polyethylene or wax, animal or plant oil, oil ﹠ fat or its modifier, lipid acid or its metal-salt, lower molecular weight or high-molecular weight ester or ether compound, as bialkyl ortho phthalate (dibutyl phthalate, dioctyl phthalate (DOP) etc.), Tritolyl Phosphate or polycaprolactone, and wood extractive such as Stockholm tar.In being used to form the solid ingredient of filming, the content of softening agent can be 1000 weight parts or lower, is preferably 5～500 weight parts, and 10～100 weight parts more preferably.Although softening agent plays the prevention defective in the sulfidation of tire, its excessive use causes being used to hinder the reduction of the low molecular weight material of cured coating film to anti-the staining property of the transmission of surface of tyre.
(f) particulate
Be of a size of 1000nm or littler (f) particulate is organic and inorganic or organic/inorganic heterozygosis particle, preferred size is 500nm or littler, and 100nm or littler more preferably.When particulate was disperseed, the flexible reduction of chain and obstruction effect were greatly improved.Because the surface-area of these particulates is big, they can adsorb low-molecular-weight material, have therefore reduced the pollution on tire that causes owing to low molecular weight material, and help the formation of film.Inorganic or organic filler can have different shape, as spherical form, and planeform, fiber shape or other shape.These particles comprise and are of a size of 1000nm or littler nanoparticle, and can use separately or with the form of its combination.The size of the bead of spherical form or fiber shape is based on its diameter, and the size of the bead of planeform is based on its thickness.Specific examples synthetic or the natural inorganic particle comprises silicate such as silicon-dioxide, glass, and Gao Ling, talcum, synthetic mica, montmorillonite, saponite, vermiculite etc., or use organic reagent (organizationagent) those particles to above-mentioned modification.When this nanoparticle of excessive use, reduced film flexible.Therefore, the particle usage quantity is 1000 weight parts or littler, is preferably 5～500 weight parts, and 10～100 weight parts more preferably.Can be when tackiness agent synthetic, after tackiness agent synthetic, or mixing oil paints timesharing, adds particulate.Particularly consider stability, preferably particle is added when tackiness agent synthetic.
(g) lubricant
For the lubricity of filming, as (g) lubricant, can be with 1000 weight parts or lower, preferred 100 weight parts or lower, and more preferably 10 weight parts or lower amount are used lipid acid, soap, silicone resin and wax separately, or use with the form of its combination.Under the situation of transparency that do not need to film, can use carbon black.In addition because silicone oil or silicone resin may cause problem that rubber in the process of sulfidizing-rubber adhesion power descends and in the driving process owing to undue lubricity makes tire and the isolating problem of wheel, must be with minimum use.
(h) stablizer
In order stably to disperse inorganic materials and being formed uniformly to film, as (h) stablizer, can be with 1000 weight parts or lower, preferred 100 weight parts or lower, and more preferably 10 weight parts or lower amount are used water soluble polymer material.Water soluble polymer material is by following example: polyvinylpyrrolidone or its partial hydrolysate, polyvinylpyridine, polyacrylamide, PMAm, poly-(N,N-DMAA), poly-(N-N-isopropylacrylamide), poly-(N-acetamido acrylamide) and polyvinyl acetate or its part or all of saponification variant, polyacrylic acid, polymethyl acrylic acid, polyethylene oxide, PEP-101, casein, white protein, xanthan gum, carboxymethyl cellulose, Natvosol etc.
(i) neutralizing agent
In order to realize dispersion stabilization, can (i) neutralizing agent be added in the solid ingredient with 500 weight parts or lower amount.The example of neutralizing agent comprises ammoniacal liquor, Monoethanolamine MEA BASF, diethanolamine, trolamine etc.
(j) sequestrant
In order to remove unnecessary ion, can chelate compound be added in the solid ingredient that film forming uses with 100 weight parts or lower amount.Typically, this chelate compound is by ethylenediamine triacetic acid sodium, and EDTA and polyacrylic mixture example.
Other additive
Can also add various additives with significant quantity, as defoamer, sanitas, sterilizing agent and antioxidant.In addition, can add pigment or dyestuff, to realize needed color.
Embodiment
The present invention may be better understood by the following examples, and described embodiment illustrates for example and lists, and not will be understood that it is limitation of the present invention.
1) preparation of polyurethane rubber latex
In the presence of dibutyltin dilaurate catalyst (solid content of about 0.03 weight %), making the 0.25mo1 molecular weight is that 2000 polybutadiene diol (PBD), 0.75mo1 molecular weight are that the dimethylol propionic acid (DMPA) of the isophorone diisocyanate (IPDI) of 2000 pcl-diol acid lactone, 1.75mol and 0.45mol was 80 ℃ of reactions 1 hour, use 1 of 0.02mol then, 4-butyleneglycol (BD) makes it react 1 hour at 80 ℃ again, the synthetic thus prepolymer that contains isocyanate end.This prepolymer is cooled to 50 ℃, adds the triethylamine (TEA) of 0.45mol, stirred then 1 hour, thus in and the dimethylol propionic acid segment.Subsequently, when adding entry, this prepolymer is dispersed in the water, and adds the aqueous solution of Triethylenetetramine (TETA) (TETA) with the amount of about 3 weight % solids contents with predetermined speed, react to produce chain extension, thereby preparation contains the polyurethane rubber latex of 25 weight % solids contents.
2) be used for the preparation of the coating composition (paint) of crude tyre
(1) use homogenizer, weight ratio mixing water, particulate and tensio-active agent with 95/5/3 prepare aqueous dispersions 1 thus.
(2) use homogenizer, weight ratio mixing water, softening agent and tensio-active agent with 45/50/5 prepare aqueous dispersions 2 thus.
(3) aqueous dispersions 1, aqueous dispersions 2, glass beads and other composition are mixed aptly, preparation is used for the coating composition of crude tyre thus.In the table 1 below, control water amount, make the solid ingredient that film forming is used concentration comparative example 1 and 2 and embodiment 1 and 2 in be 10 weight %, be 15 weight % in embodiment 3 and 4, and be 20 weight % in embodiment 5 to 7.
3) coating and the assessment of composition (paint)
(1) Defect prevention: with paint application on crude tyre to form 0.03g/cm
2Film, then carry out sulfidizing, observe then and the existence of qualitative evaluation exposed part (in sulfidation by folding, crackle, the projection of rubber, the defective of not filling and caving in and causing).
(2) rubber-rubber adhesion power: the elastomeric material that crude tyre is used is shaped to sheet, then it is painted coating, to form 0.03g/cm
2Film.Then, the folding sheet rubber that is coated with paint makes that the paint that applies is overlapped, and at 100kg/cm
2The pressure lower compression, the sulfuration, assess interfacial adhesion power then qualitatively.
(3) colo(u)r streak protection: with paint application on sample, to form 0.09g/cm
2Film, then, be evaluated at the annular colour on the sidewall or the degree of sheltering, decolouring and staining of white wire, literal and barcode qualitatively.
(4) anti-staining property: will be by applying paint to form 0.03g/cm
2The sample that then its sulfuration is obtained of filming be placed on outdoor 6 months, then, assessment is because the degree that the low molecular material in the tire is stained on the tire that the transmission of surface of tyre causes qualitatively.
4) comparative example 1 and 2 and embodiment 1 to 7
The composition of the paint that is used for assessing is shown in following table 1, and the results are shown in the following table 2.In the comparative example 1, owing to lack rubber latex and softening agent, rubber-rubber adhesion power is poor.In addition, the use of opaque rubber particles cause the protection of annular colo(u)r streak poor.
In the comparative example 2, use the big opaque pyrogenic silica of taking measurements greatly, it is poor to cause the protection of annular colo(u)r streak.
Among the embodiment 1, owing to lack the particle that is used to form the thin projection that shows the gas leakage performance, Defect prevention is poor.
Among the embodiment 2, because tackiness agent and can hinder low molecular material in the tire to the shortage of the particle of the transmission of surface of tyre, anti-staining property is poor.
Among the embodiment 3 to 7, mix one functional component aptly, therefore demonstrated excellent performance.Particularly, the use of the transparent projection composition of sufficient quantity is considered to for realizing that the protection of anti-staining property and colo(u)r streak shows that by gas leakage excellent Defect prevention is important simultaneously in sulfidation.
Table 1
The composition of paint
1) amount of tackiness agent is the amount of the solid ingredient outside dewatering, 2) and available from Leetex, HI ammonia, 3) available from Korea Kumho Petrochemical Co.Ltd., KSL 100,4) available from Nitriflex S.A., L2000, its preparation method has been described, 6 5)) available from Air Products, EVA426,7) available from Eastman Chemical Company, AR110,8) soda-lime glass, spherical form, 30 microns of mean diameters, 9) available from Shinheung Silicate Co.Ltd., 2012 grades, 12 microns of mean diameters, 10) mean diameter is 70 microns, 11) available from Sigma Co.Ltd., mean diameter: 7nm, 12) available from SouthernClay
Table 2
The assessment result of paint performance
Zero: excellence, △: general, *: poor
Industrial usability
As mentioned above, the invention provides a kind of coating composition for crude tyre. According to the present invention, Provide the function that the crude tyre of anti-defective is painted, that is, can easily tire be inserted into mould The lubricating ability from wherein being removed in the tool and after forming processes is owing to revise by life fully Tire building is processed, the sulfuration in mould and the defective that causes and the smooth outward appearance that obtains, and Be emitted on easily the air bubble of catching between crude tyre and the mould, to prevent tire because this air gas Steep and the part depression. And, can prepare and apply the forming tire with anti-defective and paint function Paint, that is, and in the storage process of tire the prevention since tire in low molecular material to the tire table The transmission of face and worsen the outward appearance of tire, or in transportation, loading, the storage of tire product with used In the journey, make owing to what external factor such as dust, friction, sunlight and rainwater caused and staining or damaging Therefore littleization simplified this processing, reduced cost and the quality that has improved tire. In addition, this Bright coating composition is not sheltered, is decoloured or stains annular colour or white wire, literal, bar code etc., Therefore, can be coated to without restriction in its sidewall, have annular colour or white wire, literal or The tire of bar code.
Claims (12)
1. coating composition that is used for crude tyre, it comprises and is used for film forming solid ingredient, described solid ingredient comprises (a)～(c): (a) 100 weight parts are of a size of 0.001～500 micron glass beads or polymer beads, and (b) 5～2000 weight parts has the tackiness agent of high adhesion and (c) tensio-active agent of 2～2000 weight parts to tire; (d) be used to dilute the dispersion medium of described solid ingredient.
2. coating composition according to claim 1, wherein (d) dispersion medium is water and the concentration that is used to solid ingredient is diluted to 1～70 weight %.
3. coating composition according to claim 2, wherein said solid ingredient also comprise (e) 1000 weight parts or softening agent still less.
4. coating composition according to claim 3, wherein said tackiness agent comprises: (b-1) flexible adhesive, (b-2) polymer binder, described polymer binder is that crystalline or second-order transition temperature are-40 ℃ or higher, and described solid ingredient also comprises (f) 1000 weight parts or still less is of a size of 1000nm or littler particulate.
5. coating composition according to claim 4, wherein the usage quantity of (b) tackiness agent is 5～1000 weight parts, (c) usage quantity of tensio-active agent is 5～1000 weight parts, and (e) usage quantity of softening agent is 5～500 weight parts, and (f) usage quantity of particulate is 5～500 weight parts.
6. coating composition according to claim 5, wherein the usage quantity of (b) tackiness agent is 10～100 weight parts, (b-2) polymer binder is 25 weight % or still less based on the usage quantity of the gross weight of (b) tackiness agent, described polymer binder is that crystalline or second-order transition temperature are-40 ℃ or higher, (c) usage quantity of tensio-active agent is 10～100 weight parts, (e) usage quantity of softening agent is 10～100 weight parts, and (f) usage quantity of particulate is 10～100 weight parts.
7. coating composition according to claim 5, it also comprises at least a additive of significant quantity, and described additive is selected from: lubricant, stablizer, neutralizing agent and sequestrant.
8. coating composition according to claim 5, wherein said solid ingredient also comprise (h) 1000 weight parts or stablizer still less, and described stablizer is a water-soluble polymers.
9. coating composition according to claim 8, wherein said solid ingredient also comprise at least a additive of significant quantity, and described additive is selected from: defoamer, sanitas, sterilizing agent, antioxidant, pigment and dyestuff.
10. according to any one described coating composition of claim 1 to 9, wherein (a) glass beads or polymer beads are to be of a size of 0.01～300 micron spherical glass bead.
11. coating composition according to claim 10, wherein (a) glass beads is of a size of 0.1～100 micron.
12. coating composition according to claim 9, it is used to provide lubricity, release property, Defect prevention, and the function of sheltering or decolouring of annular colour or white wire or literal when the sulfuration of pre-protected tyre and moulding, anti-staining property after the sulfuration of tire and the moulding and prevention impurity adhesion and the function that can easily remove impurity easily in the use of tire.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610087680A CN100595239C (en) | 2006-05-31 | 2006-05-31 | Coating composition for crude tyre |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610087680A CN100595239C (en) | 2006-05-31 | 2006-05-31 | Coating composition for crude tyre |
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| CN101081948A CN101081948A (en) | 2007-12-05 |
| CN100595239C true CN100595239C (en) | 2010-03-24 |
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| CN105874044B (en) * | 2013-12-16 | 2019-08-13 | 埃肯有机硅法国简易股份公司 | Lubricating method |
| CN108367634B (en) * | 2015-12-11 | 2020-05-08 | 株式会社普利司通 | Tire and tire manufacturing method |
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