CN100591748C - Thickening composition - Google Patents
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- CN100591748C CN100591748C CN200580004683A CN200580004683A CN100591748C CN 100591748 C CN100591748 C CN 100591748C CN 200580004683 A CN200580004683 A CN 200580004683A CN 200580004683 A CN200580004683 A CN 200580004683A CN 100591748 C CN100591748 C CN 100591748C
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Abstract
A thickening composition simultaneously ensuring an appropriate thickening performance and an excellent feeling of use, which thickening composition comprises as essential components an N-long chain acyl acidic amino acid and/or its salt, an amphiphilic substance, an inorganic salt and water and has a viscosity of >=200 mPa.s. A cleaner and cosmetic simultaneously ensuring an appropriate thickening performance and an excellent feeling of use while containing an N-long chain acyl acidic amino acid and/or its salt can be provided by mixing of this thickening composition.
Description
Technical field
The present invention relates to contain the thickening property that has both appropriateness of N-long acyl acidic amino acid and/or its salt, amphiphilic species, inorganic salt, 4 kinds of compositions of water and the thickening composition of good usability, and the washing composition and the makeup that contain it.
Background technology
Known very early and general use show that with negatively charged ion such as alkyl-sulphate, alkylsulfonates promoting agent compares as the washing composition that is used for skin or hair of principal constituent, N-long acyl acidic amino acid and/or its salt are useful as bland material.
But, if for abirritate, to being to cooperate N-long acyl glutamic acid and/or its salt, the problem that then has viscosity to reduce in the skin of host and the hair washing composition with alkyl-sulphate, alkylsulfonate, polyoxyethylene alkyl ether sulfate salt etc.
In order to address this problem; the treatment process of viscosity that contains the washing composition of N-long acyl acidic amino acid as increase; so far have to cooperate and have the ester class of polyoxyethylene chain or the example of ethers macromolecule tackifer (spy opens flat 6-158089 communique); the example (spy opens flat 6-264090 communique) that cooperates the polyose tackifier; the example (spy opens the 2003-55690 communique) that cooperates cellulose family natural polymer derivative; but as cooperated macromolecule tackifer for the sufficient quantity that obtains viscosity, then can aspect usability, produce the whipability variation; when flushing, have new problems such as the distinctive stick-slip sense of polymer.
In addition; the method of viscosity that contains the detergent composition of N-long acyl acidic amino acid as increase; the also known example that in the N-long acyl acidic amino acid aqueous solution, cooperates colloidal silicate, but the problem (spy opens flat 7-11288 communique) that can not get enough viscosity is arranged as liquid washing agent.
On the other hand; as the gel-form composition that uses N-long acyl acidic amino acid and/or its salt; reported and had thixotropic gel-form composition (spy opens flat 6-057290 communique); water-based tackify gel-form composition and liquid oil-in-water type emulsified composition (spy opens flat 9-301846 communique); these are the beauty liquids that use N-long acyl acidic amino acid and/or its salt as modulation; matrix during external composition for skin such as frost utilize method; but, therefore can not get as the enough functions that are used for the detergent composition of skin and hair because these water-based tackify gel-form compositions and liquid oil-in-water type emulsified composition do not have foaming power and washing force.
For this reason, the urgent thickening composition of wishing to have the thickening property with appropriateness of the whipability that do not hinder N-long acyl acidic amino acid and/or its salt, usability and containing N-long acyl acidic amino acid and/or its salt.
Summary of the invention
The inventor is in order to solve above-mentioned problem; further investigate; found that; by with N-long acyl acidic amino acid and/or its salt, amphiphilic species, inorganic salt, water as must composition; can obtain having both the thickening property of appropriateness and the thickening composition of good usability, and, by using this thickening composition; when can obtain containing N-long acyl acidic amino acid and/or its salt, washing composition, makeup that thickening property and usability all satisfy.
That is, the present invention includes following scheme:
[1]. thickening composition, it is characterized in that 4 kinds of compositions that contain (A) N-long acyl acidic amino acid and/or its salt, (B) amphiphilic species, (C) inorganic salt, (D) water are as necessary composition, viscosity is more than the 200mPas.
[2] .[1] described thickening composition, it is characterized in that, should (B) composition be the amphiphilic species of organic value inorganic value in order to following relational expression 1 expression,
(inorganic value)≤-5* (organic value)+2500 [1].
[3] .[1] or [2] described thickening composition, it is characterized in that, (A) composition is 90: 10～30: 70 with (B) weight ratio of composition, (A) composition and (C) weight ratio of composition be 99.5: 0.5～50: 50, and (A) composition, (B) composition and (C) gross weight of composition be 2: 98～70: 30 with (D) weight ratio of composition.
[4] .[1]～[3] any described thickening composition, it is characterized in that the amino acid that is somebody's turn to do (A) composition is L-glutamic acid.
[5] .[1]～[4] any described thickening composition; it is characterized in that acyl group that should (A) composition is to derive from the acyl group more than a kind or 2 kinds that is selected from sad, capric acid, lauric acid, tetradecanoic acid, stearic acid, palmitinic acid, oleic acid, linolic acid, mountain Yu acid, fatty acid distribution of coconut oil, PALM FATTY ACID and sclerosis tallow fatty acids.
[6] .[1]～[5] any described thickening composition, it is characterized in that, should (B) composition be to be selected from monoglyceride, mono fatty acid propylene glycol ester, mono fatty acid butanediol ester, mono fatty acid glycol ether ester, mono fatty acid N-methyl ethanol acid amides, Propylene glycol laurate hydroxypropyl ether, single more than a kind or 2 kinds of isopropanol amide of polyoxypropylene (1) fatty acid distribution of coconut oil.
[7] .[1]～[6] any described thickening composition, it is characterized in that, should (B) composition be that carbonatoms is the mono fatty acid glycidol more than 8, below 18.
[8] .[1]～[7] any described thickening composition, it is characterized in that, should (C) composition be the alkaline-earth metal inorganic salt.
[9] .[1]～[8] any described thickening composition, it is characterized in that, contain (E) polyvalent alcohol.
[10] .[1]～[9] any described thickening composition, it is characterized in that, contain (F) sequestrant.
[11]. washing composition, it is characterized in that, contain any described thickening composition of claim 1～10.
[12]. makeup, it is characterized in that, contain any described thickening composition of claim 1～10.
Embodiment
Composition (A) N-long acyl acidic amino acid and/or its salt that the present invention uses can obtain by known method.For example, the Xiao of acidic amino acid and fatty carboxylic acid halides-Bao Shi reaction is known method.
As the acidic amino acid of composition (A), can use L-glutamic acid, aspartic acid etc.These amino acid whose L bodies, D body or DL body all can, in addition, also can be the mixture more than 2 kinds that is selected from these.The viewpoint that the usability of material after stability and acidylate is good considers, preferably L-glutamic acid.
As the acyl group of composition (A), can use by carbonatoms is the acyl group of 8～22 saturated or unsaturated fatty acids deutero-straight or branched.For example, as lipid acid, can enumerate sad, capric acid, lauric acid, tetradecanoic acid, stearic acid, Unimac 5680, palmitinic acid, oleic acid, linolic acid, mountain Yu acid, fatty acid distribution of coconut oil, PALM FATTY ACID and sclerosis tallow fatty acids etc.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Particularly, consider preferred fatty acid distribution of coconut oil, lauric acid, tetradecanoic acid from the viewpoint that whipability, alveolar substance are good.
Salt for composition (A) is not particularly limited, and for example can enumerate basic metal such as sodium, potassium; Alkaline-earth metal such as calcium, magnesium; The inorganic salt of aluminium, zinc etc.; Or organic amine such as ammonia, monoethanolamine, diethanolamine, trolamine; The organic salt of basic aminoacids such as arginine, Methionin etc.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Consider preferred as alkali salt or organic amine salt, basic aminoacids, preferred especially sodium, potassium, trolamine, arginine from the viewpoint of the easiness that obtains, the property handled etc.
The composition (B) that the present invention uses if amphiphilic species have surfactivity because wetting ability and hydrophobicity balance with composition (A) N-long acyl acidic amino acid and/or its salt formation aggregate, have the tackify effect, then its structure is not particularly limited.
Wetting ability and hydrophobicity balance are meant that the relation of its organic value and inorganic value is selected from the scope of following relational expression 1,
(inorganic value)≤-5* (organic value)+2500 [1].
If inorganic value is greater than-5* (organic value)+2500, then to form the balance of aggregate destroyed with composition (A) N-long acyl acidic amino acid, and the tackify effect reduces.Be noted that, inorganic value, organic value are by organic conceptional diagram-basis and use (have Machine notion figure-basic Foundation と ying with) (1984) people such as (, three publish altogether) first Tian Shansheng, utilize the emulsification prescription design (Machine notion figure To I Ru emulsification place side Let Meter is arranged) (1997) (Japanese エ マ Le ヅ ヨ Application is compiled) of organic conceptional diagram to calculate.Inorganic value and organic value are 0 or positive number.
Can enumerate monoglyceride, difatty acid glyceryl ester, triglyceride, mono fatty acid propylene glycol ester, mono fatty acid butanediol ester, mono fatty acid glycol ether ester, mono fatty acid N-methyl ethanol acid amides, Propylene glycol laurate hydroxypropyl ether, the single isopropanol amide of polyoxypropylene (1) fatty acid distribution of coconut oil etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Wherein, consider preferred especially monoglyceride, mono fatty acid propylene glycol ester, mono fatty acid butanediol ester, mono fatty acid glycol ether ester, mono fatty acid N-methyl ethanol acid amides, Propylene glycol laurate hydroxypropyl ether, the single isopropanol amide of polyoxypropylene (1) fatty acid distribution of coconut oil from low molecule, viewpoint that usability is good.
As mono fatty acid glycidol, can enumerate single caprylin, single caprin, glyceryl monolaurate, single tetradecanoic acid glyceryl ester, monopalmitin, glyceryl monostearate, single Tegin ISO etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Wherein, the viewpoint that forms aggregate easily from composition (A) N-long acyl acidic amino acid and/or its salt and composition (C) salt is considered preferred single caprylin, single caprin, glyceryl monolaurate, single tetradecanoic acid glyceryl ester.It is 8～18 saturated or unsaturated fatty acids that lipid acid can use carbonatoms, also can contain the substituting group that does not hinder effect degree of the present invention.As carbonatoms is below 8, and then the tackify effect is low, is that then solvability is low more than 18, separates out easily.From stable and keep the viewpoint of the thickening property that continues to consider, be preferably 8～14, consider more preferably 10～12 from the viewpoint that can keep lathering property.
As the mono fatty acid propylene glycol ester, can enumerate single sad propylene glycol ester, single capric acid propylene glycol ester, mono laurate propylene glycol ester, single tetradecanoic acid propylene glycol ester, single palmitinic acid propylene glycol ester, propylene glycolmonostearate, single Unimac 5680 propylene glycol ester etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.The viewpoint that forms aggregate from composition (A) N-long acyl acidic amino acid and/or its salt and composition (C) salt is easily considered preferred single sad propylene glycol ester, single capric acid propylene glycol ester, mono laurate propylene glycol ester, single tetradecanoic acid propylene glycol ester.It is 8～18 saturated or unsaturated fatty acids that lipid acid can use carbonatoms, also can contain the substituting group that does not hinder effect degree of the present invention.As carbonatoms is below 8, and then the tackify effect is low, is that then solvability is low more than 18, separates out easily.From stable and keep the viewpoint of the thickening property that continues to consider, be preferably 8～14, consider more preferably 10～12 from the viewpoint that can keep lathering property.
As the mono fatty acid butanediol ester, can enumerate single sad butanediol ester, single capric acid butanediol ester, mono laurate butanediol ester, single tetradecanoic acid butanediol ester, single palmitinic acid butanediol ester, Stearinsaeure butanediol ester, single Unimac 5680 butanediol ester etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.The viewpoint that forms aggregate from composition (A) N-long acyl acidic amino acid and/or its salt and composition (C) salt is easily considered preferred single sad butanediol ester, single capric acid butanediol ester, mono laurate butanediol ester, single tetradecanoic acid butanediol ester.It is 8～18 saturated or unsaturated fatty acids that lipid acid can use carbonatoms, also can contain the substituting group that does not hinder effect degree of the present invention.As carbonatoms is below 8, and then the tackify effect is low, is that then solvability is low more than 18, separates out easily.From stable and keep the viewpoint of the thickening property that continues to consider, be preferably 8～14, consider more preferably 10～12 from the viewpoint that can keep lathering property.
As mono fatty acid glycol ether ester, can enumerate single sad glycol ether ester, single capric acid glycol ether ester, mono laurate glycol ether ester, single diethylene glycol myristate, single diethylene glycol palmitate, Stearinsaeure glycol ether ester, single Unimac 5680 glycol ether ester etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.The viewpoint that forms aggregate from composition (A) N-long acyl acidic amino acid and/or its salt and composition (C) salt is easily considered preferred single sad glycol ether ester, single capric acid glycol ether ester, mono laurate glycol ether ester, single diethylene glycol myristate.It is 8～18 saturated or unsaturated fatty acids that lipid acid can use carbonatoms, also can contain the substituting group that does not hinder effect degree of the present invention.As carbonatoms is below 8, and then the tackify effect is low, is that then solvability is low more than 18, separates out easily.From stable and keep the viewpoint of the thickening property that continues to consider, be preferably 8～14, consider more preferably 10～12 from the viewpoint that can keep lathering property.
As mono fatty acid N-methyl ethanol acid amides, can enumerate single sad N-methyl ethanol acid amides, single capric acid N-methyl ethanol acid amides, mono laurate N-methyl ethanol acid amides, single tetradecanoic acid N-methyl ethanol acid amides, single palmitinic acid N-methyl ethanol acid amides, Stearinsaeure N-methyl ethanol acid amides, single Unimac 5680 N-methyl ethanol acid amides etc. particularly.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.The viewpoint that forms aggregate from composition (A) N-long acyl acidic amino acid and/or its salt and composition (C) salt is easily considered preferred single sad N-methyl ethanol acid amides, single capric acid N-methyl ethanol acid amides, mono laurate N-methyl ethanol acid amides, single tetradecanoic acid N-methyl ethanol acid amides.It is 8～18 saturated or unsaturated fatty acids that lipid acid can use carbonatoms, also can contain the substituting group that does not hinder effect degree of the present invention.As carbonatoms is below 8, and then the tackify effect is low, is that then solvability is low more than 18, separates out easily.From stable and keep the viewpoint of the thickening property that continues to consider, be preferably 8～14, consider more preferably 10～12 from the viewpoint that can keep lathering property.
As the Propylene glycol laurate hydroxypropyl ether, can enumerate commercially available PVC ス コ セ one Off LPE (river is ground Off ア イ Application ケ ミ カ Le company and produced) particularly.
As the single isopropanol amide of polyoxypropylene (1) fatty acid distribution of coconut oil, can enumerate commercially available ア ミ ゼ Star ト 1PC (river is ground Off ア イ Application ケ ミ カ Le company and produced) particularly.
(C) composition inorganic salt that use among the present invention are not particularly limited, can enumerate the salt of ore deposit acid such as sulfuric acid, hydrochloric acid, phosphoric acid or carbonic acid and basic metal or alkaline-earth metal.Particularly, can enumerate sodium-chlor, Repone K, magnesium chloride, calcium chloride, sodium sulfate, sodium pyrosulfate, vitriolate of tartar, sal enixum, sal epsom, calcium sulfate, SODIUM PHOSPHATE, MONOBASIC, Sodium phosphate dibasic, potassium dihydrogen sulfate, dipotassium hydrogen phosphate, yellow soda ash, sodium bicarbonate, salt of wormwood, saleratus, magnesiumcarbonate, lime carbonate etc.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Particularly, consider preferred bases earth metal salt, more preferably calcium salt or magnesium salts, further preferred magnesium salts from the high viewpoint of tackify effect.
Consider from tackify and the viewpoint that obtains high transparent, as the preferred chlorion of gegenion.As concrete compound, especially preferably calcium chloride or magnesium chloride, preferred especially magnesium chloride.
The water of (D) composition that the present invention uses so long as the purity of the degree that general washing composition or makeup use then be not particularly limited.Particularly, can use ion exchanged water, well water, natural water, underground water, public water (city's water), hard water, soft water etc.Can use a kind of in these, or also can be selected from above-mentioned mixing more than 2 kinds and use.Consider the preferred ion exchanged water from storage stability, the health aspect of the present invention's product.
(A) composition that the present invention uses and (B) weight ratio of composition be generally 90: 10～30: 70.Less than 10, then a little less than the tackify effect, greater than 70, the problem of separating out is easily arranged then as (B) composition as (B) composition.Composition forms aggregate easily, viewpoint with persistence considers from (A) composition with (B), preferred 85: 15～35: 65, considers more preferably 85: 15～50: 50 from the viewpoint that obtains sufficient whipability and fluid composition.
(A) composition that the present invention uses and (C) weight ratio of composition be generally 99.5: 0.5～50: 50.Less than 0.5, then a little less than the tackify effect, as greater than 50, problem such as then separate out as (C) composition.From stable and can expect that the viewpoint of the tackify effect that continues considers preferred 99: 1～55: 45.
(A) composition that the present invention uses, (B) composition and (C) gross weight of composition be generally 2: 98 with (D) weight ratio of composition～70: 30.As (A) composition, (B) composition and (C) gross weight of composition less than 2, then insufficient, and the tackify effect is low as functions such as the foaming of washing composition, alveolar substances, as the problem of the usability variation such as separating out greater than 70.Consider preferred 2.5: 97.5～50: 50 from usability with the viewpoint that stable and lasting tackify effect is arranged as washing composition.
(A) composition in the thickening composition and (D) weight ratio of composition be generally 0.5: 99.5～68: 32.From obtaining viewpoint consideration, be preferably 1: 99～46: 54, more preferably 5: 95～40: 60 as the usability of washing composition.As (A) composition less than 0.5, then can not get sufficient washing effect, the washing after the sense of preserving moisture, greater than 68, the problem of usability variation is arranged then as (A) composition.
The preparation method of thickening composition of the present invention is as follows: will stipulate composition (A) and the composition (B) and composition (D) mixing of ratio, and after 60～80 ℃ scope heating for dissolving, add composition (C) again, and make the solution of homogeneous.Be cooled to room temperature then, obtain thickening composition.
The viscosity of thickening composition of the present invention is generally 200mPas～50000mPas.Can adjust arbitrarily by the ratio that changes composition (A), (B), (C), (D), but consider from viewpoint as the use easness of washing composition, be preferably 250mPas～40000mPas, more preferably 300mPas～25000mPas, more preferably 350mPas～10000mPas.
Thickening composition of the present invention can be matched with in makeup and the washing composition, and (A) is not particularly limited to the composition in whole makeup and the washing composition, can select 0.2～60% scope usually.Composition (A) is less than 0.2% o'clock, and effect as the thickening composition inapparent tendency that becomes is arranged, and greater than 60% o'clock, might damage the sufficient usability as makeup, washing composition under a lot of situations.Consider that from the viewpoint of bringing into play significant tackify effect its lower value is preferably more than 0.3%, more preferably more than 0.5%, more preferably more than 1%, especially more preferably more than 2%, is preferably more than 3% especially.Consider that from the viewpoint that good makeup of usability and washing composition can be provided its higher limit is preferably below 55%, more preferably below 50%, more preferably below 45%, especially more preferably below 40%, is preferably below 35% especially.
The makeup of thickening composition of the present invention and the desirable viscosity that washing composition also presents 200mPas～50000mPas have usually been cooperated.Consider from viewpoint, be preferably 250mPas～40000mPas, more preferably 300mPas～25000mPas, more preferably 350mPas～10000mPas as the use easness of washing composition and makeup.
For thickening composition of the present invention, consider from the viewpoint of further performance tackify effect, preferably make the composition that has cooperated (E) polyvalent alcohol in the thickening composition of the invention described above.As polyvalent alcohol, can enumerate glycerine, Glycerol dimer, Sorbitol Powder, propylene glycol, dipropylene glycol, butyleneglycol, polyoxyethylene glycol etc.Consider preferred polyvalent alcohol more than 3 yuan, more preferably glycerine, Glycerol dimer, Sorbitol Powder, especially preferably Sorbitol Powder from the viewpoint of bringing into play excellent tackify effect.
The polyvalent alcohol of this composition (E) can use a kind, also can will also use more than 2 kinds.In addition, its use level is not particularly limited, but, is preferably 0.2～50 weight %, more preferably 1～20 weight with respect to composition in its entirety.The use level of E composition can not get sufficient tackify effect during less than 0.2 weight %, can not fully obtain the sense of preserving moisture as polyvalent alcohol effect itself.And during greater than 50 weight %, the then foaming minimizing of composition, feel reduce.
For thickening composition of the present invention, consider from the viewpoint of further performance tackify effect, preferably make in the thickening composition of the invention described above and cooperated (F) combination of chelating agents thing.As sequestrant, can enumerate ethylenediamine tetraacetic acid (EDTA) and/or its salt (EDTA), hydroxyethylethylene diamine tri-acetic acid and/or its salt (HEDTA), dihydroxy ethyl ethylenediamine-N,N'-diacetic acid(EDDA) and/or its salt (DHEDTA), 1,3-trimethylenedinitrilo-tertraacetic acid and/or its salt (PDTA), diethylene triaminepentaacetic acid(DTPA) and/or its salt (DTPA), triethylenetetraaminehexaacetic acid and/or its salt (TTHA), nitrilotriacetic acid(NTA) and/or its salt (NTA), hydroxyethyliminodiacetic acid and/or its salt (HIMDA) etc.Consider from bringing into play excellent tackify effect, especially preferably there is not neutral, preferred ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, dihydroxy ethyl ethylenediamine-N,N'-diacetic acid(EDDA), 1,3-trimethylenedinitrilo-tertraacetic acid, diethylene triaminepentaacetic acid(DTPA), preferred especially ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate.
The sequestrant of this composition (F) can use a kind, also can will also use more than 2 kinds.In addition, its use level is not particularly limited, but, is preferably 0.01～1.0 weight %, more preferably 0.05～0.5 weight % with respect to composition in its entirety.The use level of E composition can not get sufficient tackify effect during less than 0.01 weight %, can not fully obtain the sequestering power as sequestrant effect itself.
Except above-mentioned necessary composition, thickening composition of the present invention also can suitably cooperate the common makeup that do not hinder effect degree of the present invention, accurate medicine employed various any compositions such as (medicine part outer articles), is in particular finish (chain polysiloxane such as Camellia oil, Semen Maydis oil, sweet oil, rapeseed oil, cocounut oil, plam oil, hardened castor oil, beeswax, liquid lanolin, whiteruss, squalene, Vaseline, polydimethylsiloxane; Cyclic polysiloxanes such as octamethylcyclotetrasiloxane; Amino-modified silicone oil etc.), tensio-active agent (alkyl-sulphate, alkyl ether sulphate salts, soap, sulfosuccinate, sulfonated, N-acyl sarcosinate, N-acyl methyl taurine salt, alkyl ether carboxy acid salt, phosphate ester salt plasma type tensio-active agent; The imidazolines amphoterics; Betaines amphoterics etc.), compositions such as tackifier (polymer tackifier such as guar gum, starch, carrageenin, xanthan gum, ethyl cellulose, methyl hydroxypropylated starch, carboxymethyl cellulose, carboxyvinyl polymer, wilkinite, hectorite), sanitas, spices, UV light absorber, wetting Agent for Printing Inks, physiologically active ingredient, antioxidant, anti-inflammatory agent, antiseptic-germicide, antiperspirant, neutralizing agent, pH regulator agent, can cooperate according to the concrete purposes and the formulation of washing composition, makeup.
Purposes to thickening composition of the present invention is not particularly limited, and various washing composition and makeup can be provided.For example, Clean-makeup such as cosmetic perfumed soap, the agent of washing one's face (using emulsion, paste, liquid gel shape, aerosol etc.), shampoo; Hair-care agent (comprising emulsion form, vaporific, oily, gel, other forms and the coating pronged hair (branch hair コ one ト drug)), hairspray Hair grooming makeup such as (hair oil, style keeping liquid, wave set, brilliantine, clavate brilliantine, hair on the temple oil, hairdressing spray, ヘ ア ミ ス ト, hair style dressing liquid, ヘ ア Off オ one system, hair gel, ウ オ one タ one グ リ one ス); Basic cosmetics such as common white emulsion (cleansing cream, cold cream, vanishing cream, hand lotion etc.), shaving cream (back protective skin cream, shaving cream etc. shave), astringent (hand lotion, common astringent etc.), the liquid that shaves (the back skin-care liquid that shaves, liquid shaves), greasepaint, facial mask; Foundation cream (paste, aqueous etc.), eye cream, eye shadow, eyelashes wet goods cosmetics; Perfume classes such as common perfume, Practice り perfume, powder perfume; Tanned sunscreen, tanned sun screen, the tanned sun care preparations of tanned sun-proof wet goods; Manicure preparationss such as profit first frost, nail varnish, nail varnish remover; Lip makeup such as informer's makeup, lipstick, lipstick; Oral cavity makeup such as toothpaste, bath salt, bath wet goods are bathed and are applied some make up etc.Consider from the viewpoint of usability excellence, preferably as the application of Clean-makeup, Hair grooming makeup, basic cosmetics.
Embodiment
Below, describe the present invention in detail by embodiment, but the invention is not restricted to following embodiment.
Embodiment 1～embodiment 10
Form thickening composition and the detergent composition that constitutes shown in the modulation following table 1, its viscosity is by following method evaluation.
(mensuration of viscosity) with Brookfield viscometer (TOKIMC company produce, DVL-B type), is measured with the condition of No. 3 or No. 4 rotors, rotating speed 30rpm and is carried out viscosity after 30 seconds under 25 ℃.
[table 1-1]
[table 1-2]
[table 1-3]
[table 1-4]
By the result who shows 1-1～4 as can be known; in order to obtain containing the N-long acyl acidic amino acid of composition (A) and/or the thickening composition of the present invention of its salt; the water of the inorganic salt of the amphiphilic species of composition (B), composition (C), composition (D) is necessary composition, lacks any composition and all can not get thickening composition.And, also as can be known with do not satisfy [formula 1] (inorganic value)≤-amphiphilic species of 5* (organic value)+2500 can not get thickening composition (comparative example 11～14).
Embodiment 11～embodiment 20:
In comprising the detergent composition that the cooperation shown in the following table 2 is formed, cooperate the thickening composition of the present invention (embodiment 11～embodiment 20) of arbitrary proportion, measure viscosity equally.
[table 2-1]
[table 2-2]
[table 2-3]
[table 2-4]
As shown in Table 2, to polyoxyethylene alkyl ether sulfate salt (laureth vitriol) is when cooperating the cocoyl Sodium Glutamate of (A) composition in the skin of principal constituent or the hair detergent composition (comparative example 15), along with the increase viscosity of use level significantly reduces (comparative example 16～comparative example 18).In addition, even to polyoxyethylene alkyl ether sulfate salt (laureth vitriol) is to cooperate the cocoyl Sodium Glutamate of (A) composition and (B) glyceryl monolaurate of composition in the skin of principal constituent or the hair detergent composition (comparative example 15), also can not get enough viscosity (comparative example 19～comparative example 23) as detergent composition.Relative therewith, as cooperate thickening composition of the present invention, then can obtain containing the detergent composition with appropriate viscosity (embodiment 11～embodiment 13) of N-acyl acidic amino acid and/or its salt.In addition, by in the detergent composition that has cooperated thickening composition of the present invention (embodiment 16), cooperating polyvalent alcohol, sequestrant can increase tackify effect (embodiment 17～embodiment 20).By last, the use level of thickening composition of the present invention can obtain high more viscosity more at most, makes the technology of a large amount of N-acyl acidic amino acids of the unavailable cooperation of prior art and/or its salt become possibility by the present invention.
Formulation Example 1～3
When making the liquid detergent compositions of prescription shown below, all can obtain good viscosity and usability according to well-established law.
Formulation Example 1 shampoo Compositions
Weight %
Sodium laureth sulfate (27% aqueous solution) 35.0
AMONYL 380LC (30% aqueous solution) 15.0
PCA-Na (50% aqueous solution) 2.0
PEG-7 coconut oil glyceryl ester 2.0
ポリクオタニウム-10 0.2
Coconut oleoyl amine MEA 0.2
Citric acid is an amount of
ヅ メ チ コ one Application 0.3
16/octodecyl alcohol polyoxyethylene (60) ether myristyl glycol 0.4
(セ テ ア レ ス-60 ミ リ ス チ Le グ リ コ one Le)
Sanitas is an amount of
Cocoyl L-glutamic acid TEA (30% aqueous solution) 20.0
Laurin 1.8
Magnesium chloride (6 hydrate) 0.2
Glycerine 3.0
Disodium ethylene diamine tetraacetate 0.2
Water surplus
Meter 100.0
Formulation Example 2 shampoo Compositions
(weight %)
Sodium laureth sulfate (27% aqueous solution) 30.0
AMONYL 380LC (30% aqueous solution) 15.0
PCA-Na (50% aqueous solution) 2.0
PEG-7 coconut oil glyceryl ester 2.0
ポリクオタニウム-10 0.2
Coconut oleoyl amine DEA 0.2
Citric acid is an amount of
ヅ メ チ コ one Application 0.3
16/octodecyl alcohol polyoxyethylene (60) ether myristyl glycol 0.4
Diglycol stearate 1.0
Sanitas is an amount of
Cocoyl L-glutamic acid TEA (30% aqueous solution) 25.0
Laurin 2.6
Magnesium chloride (6 hydrate) 0.3
Sorbitol Powder (70% aqueous solution) 6.0
Disodium ethylene diamine tetraacetate 0.2
Water surplus
Meter 100.0
Formulation Example 3 shower gels compositions
(weight %)
Sodium laureth sulfate (27% aqueous solution) 35.0
AMONYL 380LC (30% aqueous solution) 15.0
PCA-Na (50% aqueous solution) 2.0
PEG-7 coconut oil glyceryl ester 2.0
ポリクオタニウム-10 0.2
Coconut oleoyl amine DEA 0.2
Citric acid is an amount of
ジ メ チ コ one Application 0.3
Lauroyl L-glutamic acid two (plant sterol/octyl group dodecyl) ester 0.2
Diglycol stearate 1.0
Sanitas is an amount of
Cocoyl Sodium Glutamate 5.0
Lauric acid butanediol ester 2.0
Magnesium chloride (6 hydrate) 0.2
Sorbitol Powder (70% aqueous solution) 6.0
Disodium ethylene diamine tetraacetate 0.2
Water surplus
Meter 100.0
Industrial applicability
By to as the famous N-long acyl acidic amino acid of the material of tackify difficulty and/or The amphiphilic materials, inorganic salts, the water that cooperate the regulation ratio in its salt make to have simultaneously appropriateness Thickening property and excellent use sense become possibility. By cooperating this thickening composition, can provide When containing N-long acyl acidic amino acid and/or its salt, keep tackifying and use to feel The washing agent such as skin or hair, cosmetics.
The application is willing to 2004-37365 and the special 2004-271394 of hope based on the spy in Japanese publication, and this specification sheets comprises its full content.
Claims (10)
1. thickening composition; it is characterized in that; 4 kinds of compositions that contain (A) N-long acyl acidic amino acid and/or its salt, (B) amphiphilic species, (C) inorganic salt, (D) water are as necessary composition; viscosity is more than the 200mPas; should (B) composition be the amphiphilic species of organic value inorganic value in order to following relational expression 1 expression
(inorganic value)≤-5* (organic value)+2500 [1]
(A) composition and (B) weight ratio of composition be 90: 10～30: 70, (A) composition and (C) weight ratio of composition be 99.5: 0.5～50: 50, and (A) composition, (B) composition and (C) gross weight of composition be 2: 98～70: 30 with (D) weight ratio of composition.
2. the described thickening composition of claim 1 is characterized in that, the amino acid that is somebody's turn to do (A) composition is L-glutamic acid.
3. the described thickening composition of claim 1; it is characterized in that acyl group that should (A) composition derives from the acyl group more than a kind or 2 kinds that is selected from sad, capric acid, lauric acid, tetradecanoic acid, stearic acid, palmitinic acid, oleic acid, linolic acid, mountain Yu acid, fatty acid distribution of coconut oil, PALM FATTY ACID and sclerosis tallow fatty acids.
4. the described thickening composition of claim 1, it is characterized in that, should (B) composition be to be selected from monoglyceride, mono fatty acid propylene glycol ester, mono fatty acid butanediol ester, mono fatty acid glycol ether ester, mono fatty acid N-methyl ethanol acid amides, Propylene glycol laurate hydroxypropyl ether, single more than a kind or 2 kinds of isopropanol amide of polyoxypropylene (1) fatty acid distribution of coconut oil.
5. the described thickening composition of claim 1 is characterized in that, the carbonatoms that should (B) composition be lipid acid is more than 8～and mono fatty acid glycidol below 18.
6. the described thickening composition of claim 1 is characterized in that, should (C) composition be the alkaline-earth metal inorganic salt.
7. any described thickening composition of claim 1～6 is characterized in that, contains (E) polyvalent alcohol.
8. any described thickening composition of claim 1～6 is characterized in that, contains (F) sequestrant.
9. washing composition is characterized in that, contains any described thickening composition of claim 1～8.
10. makeup is characterized in that, contain any described thickening composition of claim 1～8.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004037365 | 2004-02-13 | ||
| JP037365/2004 | 2004-02-13 | ||
| JP271394/2004 | 2004-09-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1918258A CN1918258A (en) | 2007-02-21 |
| CN100591748C true CN100591748C (en) | 2010-02-24 |
Family
ID=37738666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580004683A Active CN100591748C (en) | 2004-02-13 | 2005-02-10 | Thickening composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100591748C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130210696A1 (en) * | 2012-02-10 | 2013-08-15 | Conopco, Inc., D/B/A Unilever | Calcium and magnesium salts as squeakiness enhancers in cleansing compositions |
| JP6648760B2 (en) * | 2015-07-09 | 2020-02-14 | 日油株式会社 | Hair shampoo composition |
| EP3390598A4 (en) | 2015-12-14 | 2019-07-10 | Sino Lion USA LLC | Thickening cleansing compositions and applications and methods of preparation thereof |
| CN114224765A (en) * | 2021-12-31 | 2022-03-25 | 上海佰太生物科技有限公司 | Amino acid shampoo and preparation method thereof |
-
2005
- 2005-02-10 CN CN200580004683A patent/CN100591748C/en active Active
Non-Patent Citations (2)
| Title |
|---|
| N-脂肪酰基谷氨酸系表面活性剂在日用化学品中的应用. 韦异，朱海洋，李华山，李青矾.日用化学品科学，第26卷第4期. 2003 |
| N-脂肪酰基谷氨酸系表面活性剂在日用化学品中的应用. 韦异，朱海洋，李华山，李青矾.日用化学品科学，第26卷第4期. 2003 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1918258A (en) | 2007-02-21 |
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