Summary of the invention
The present invention aims to provide a kind of cleaning method on the throne of town regenerated water plate type heat exchanger, utilizes this method can remove schmutzband on the heat-transfer surface fast and efficiently, can guarantee the town regenerated water plate type heat exchanger safety and economic operation.
Technical scheme of the present invention is as follows:
A kind of cleaning method on the throne of town regenerated water plate type heat exchanger is characterized in that, this method is carried out as follows:
1) before adding medicament, in the wash cycles water tank, adds water and be preheated to 35~40 ℃;
2) disodium ethylene diamine tetraacetate and Sodium Polyacrylate are added in the wash cycles water tank successively, make the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reach 100~150mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20~25mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, the dosage of clorox makes the decontaminant concentration of circulating cleaning fluid reach 300~500mg/L;
3) the beginning first step is cleaned, and cleaning temperature is controlled at 35~40 ℃, clean flow be set at normal operating condition mutually
With, scavenging period is 1~2 hour, after clean finishing with the cleaning fluid emptying;
4) repeating step 1), with blue star LX-056A/B, disodium ethylene diamine tetraacetate and Sodium Polyacrylate add in the wash cycles water tank successively, make the concentration of blue star LX-056A/B in circulating cleaning fluid reach 500~700mg/L, the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reaches 200~250mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20~25mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, the dosage of clorox makes the decontaminant concentration of circulating cleaning fluid reach 100~150mg/L;
5) second step of beginning cleans, and cleaning temperature is controlled at 35~40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1~2 hour, cleans after the end the cleaning fluid emptying.
The cleaning frequency on the throne of town regenerated water plate type heat exchanger is 5~20 days.In order to obtain optimal cleaning effect, the cleaning frequency on the throne in summer is preferably 5 days, and the cleaning frequency on the throne in winter is preferably 7 days.
The present invention compared with prior art has the following advantages: 1. the cleaning method of the present invention's proposition can be applicable to town regenerated water plate type heat exchanger cleaning process on the throne, scale removal, the rust cleaning finished under the situation of not dismantling, not moving equipment and pipeline plate type heat exchanger are cleaned, and can reach the purpose of recovering plate type heat exchanger fluid interchange performance; 2. the two-step method cleaning process is shot the arrow at the target, and it is the dirt entry material that the first step is cleaned target, wherein chelating agent and dispersant have a performance that helps the oxidizing bactericide effect, the dirt detachment rate can be improved; Clean that main to clean target be dirt bottom material second step, help to slow down dirt regrowth speed, make that heat exchange efficiency can the long term maintenance higher level for the further removing of bottom material.3. the cleaning method of the present invention's proposition is based upon on dirt composition analysis, microscopic observation and the dirt growth course monitoring on the throne basis, used cleaning agent is through carefully screening and having carried out experiment test, clean weak point consuming time, scale removal efficient height, descale effect is not subject to seasonal restrictions, and above-mentioned characteristic all is better than existing cleaning method.
The specific embodiment
The cleaning method on the throne of a kind of town regenerated water plate type heat exchanger provided by the invention, this method is carried out as follows:
1) before adding medicament, in the wash cycles water tank, adds water and be preheated to 35~40 ℃;
2) disodium ethylene diamine tetraacetate and Sodium Polyacrylate are added in the wash cycles water tank successively, make the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reach 100~150mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20~25mg/L, mixes; Treat that solution-stabilized back adds clorox and is stirred to abundant mixing, the dosage of clorox makes the decontaminant concentration of circulating cleaning fluid reach 300~500mg/L;
3) the beginning first step is cleaned, and cleaning temperature is controlled at 35~40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1~2 hour, cleans after the end the cleaning fluid emptying;
4) repeating step 1), blue star LX-056A/B, disodium ethylene diamine tetraacetate and Sodium Polyacrylate are added in the wash cycles water tank successively, make the concentration of blue star LX-056A/B in circulating cleaning fluid reach 500~700mg/L, the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reaches 200~250mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20~25mg/L, mixes; Treat that solution-stabilized back adds clorox and is stirred to abundant mixing, the dosage of clorox makes the decontaminant concentration of circulating cleaning fluid reach 100~150mg/L;
5) begin the cleaning of second step, cleaning temperature is controlled at 35~40 ℃, cleans flow and is set at normally operating condition is identical, and scavenging period is 1~2 hour, with the cleaning fluid emptying, finishes cleaning process after cleaning finishes.
Cleaning frequency on the throne was generally 5~20 days, was preferably 5 days in the cleaning frequency on the throne in summer, and the cleaning frequency on the throne in winter is preferably 7 days.
Below in conjunction with specific embodiment content of the present invention is described in detail.
Embodiment 1: the cleaning example on the throne of town regenerated water plate type heat exchanger under winter heating's operating mode
One is the water source heat pump system of Cooling and Heat Source with the town B-grade water outlet, utilizes the Lowlevel thermal energy in the water outlet of plate type heat exchanger recovery town B-grade.In winter, the heat pump heating efficiency descends, and the analysis showed that it is that secondary effluent due to the fouling, determines to adopt cleaning technique on the throne that plate type heat exchanger is cleaned in plate type heat exchanger.
1. purging system overview
Wash cycles water tank capacity: 100L
Plate type heat exchanger material: stainless steel 304
The fouling situation: plate surface high temperature side schmutzband is thicker, and the low temperature side schmutzband is thinner, and the fouling degree is lighter relatively.
2. cleaning method
Plate type heat exchanger purging system on the throne as shown in Figure 1.
When plate type heat exchanger normally moved, data acquisition and control system be by real-time collecting temperature, pressure reduction, data on flows, and side pressure is fallen and two indexs of heat transfer coefficient are carried out on-line monitoring to the plate type heat exchanger recycled water.When above-mentioned two indexs arrived the cleaning limiting value of setting, control system was sent purge signal, cut off recycled water and recirculated water side water route this moment, opened cleaning fluid side valve door, constituted wash cycles on the throne loop, cleaned by following step:
1) before adding medicament, in the wash cycles water tank, add water 50L, test running clean cycle pump can not cause and find time, and liquid is arranged back, then with the water preheat to 35 in the water tank ℃;
2) disodium ethylene diamine tetraacetate of 5g and the Sodium Polyacrylate of 1g are added in the wash cycles water tank successively, make the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reach 100mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 300ml, be about 1: 160 with the volume ratio of circulating cleaning fluid, make the decontaminant concentration of circulating cleaning fluid reach 300mg/L;
3) the beginning first step is cleaned, and cleaning temperature is controlled at 35 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1 hour, cleans after the end the cleaning fluid emptying;
4) repeating step 1), blue star LX-056A/B with 25g, the disodium ethylene diamine tetraacetate of 10g and the Sodium Polyacrylate of 1g add in the wash cycles water tank successively, make the concentration of blue star LX-056A/B in circulating cleaning fluid reach 500mg/L, the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reaches 200mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 20mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 125ml, with the volume ratio of circulating cleaning fluid be 1: 400, make the decontaminant concentration of circulating cleaning fluid reach 100mg/L;
5) second step of beginning cleans, and cleaning temperature is controlled at 35 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1 hour, cleans after the end the cleaning fluid emptying.
After cleaning process finishes, cut off the controllable temperature heater power source, cut off wash cycles on the throne loop, open recycled water and recirculated water side valve door, plate type heat exchanger normally moves, and data acquisition and control system continue the plate type heat exchanger performance is carried out on-line monitoring.
In order to reach optimal cleaning effect, the cleaning frequency in winter is preferably 7 days.
3. cleaning performance
Plate type heat exchanger moves 28 days continuously, is the cleaning frequency to have carried out 4 cleanings on the throne altogether with 7 days therebetween.Plate type heat exchanger heat transfer coefficient after cleaning all can return to more than 98% of heat transfer coefficient under the clean conditions, but and long term maintenance higher level.Taking plate type heat exchanger apart observation finds: the plate surface is comparatively cleaned, and does not have tangible dirt to adhere to and evidence of corrosion.
Embodiment 2: the cleaning example on the throne of town regenerated water plate type heat exchanger under the summer cooling condition
One is the water source heat pump system of Cooling and Heat Source with the town B-grade water outlet, utilizes the Lowlevel thermal energy in the water outlet of plate type heat exchanger recovery town B-grade.In summer, the heat pump refrigerating efficiency descends fast, the analysis showed that it is that secondary effluent due to the fouling, determines to adopt cleaning technique on the throne that plate type heat exchanger is cleaned in plate type heat exchanger.
1. purging system overview
Wash cycles water tank capacity: 100L
Plate type heat exchanger material: stainless steel 316
The fouling situation: the plate surface all is attached with the mixed dirt based on microbial fouling from bottom to top, and the fouling degree is heavier.
2. cleaning method
Plate type heat exchanger purging system on the throne as shown in Figure 1.
When plate type heat exchanger normally moved, data acquisition and control system be by real-time collecting temperature, pressure reduction, data on flows, and side pressure is fallen and two indexs of heat transfer coefficient are carried out on-line monitoring to the plate type heat exchanger recycled water.When above-mentioned two indexs arrived the cleaning limiting value of setting, control system was sent purge signal, cut off recycled water and recirculated water side water route this moment, opened cleaning fluid side valve door, constituted wash cycles on the throne loop, cleaned by following step immediately:
1) before adding medicament, in the wash cycles water tank, add water 50L, test running clean cycle pump can not cause and find time, and liquid is arranged back, then with the water preheat to 40 in the water tank ℃;
2) disodium ethylene diamine tetraacetate of 6.5g and the Sodium Polyacrylate of 1.2g are added in the wash cycles water tank successively, make the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reach 125mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 24mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 330ml, with the volume ratio of circulating cleaning fluid be 1: 150, make the decontaminant concentration of circulating cleaning fluid reach 400mg/L;
3) the beginning first step is cleaned, and cleaning temperature is controlled at 40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1.5 hours, cleans after the end the cleaning fluid emptying;
4) repeating step 1), blue star LX-056A/B with 30g, the disodium ethylene diamine tetraacetate of 12g and the Sodium Polyacrylate of 1.2g add in the wash cycles water tank successively, make the concentration of blue star LX-056A/B in circulating cleaning fluid reach 600mg/L, the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reaches 230mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 24mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 125ml, with the volume ratio of circulating cleaning fluid be 1: 400, make the decontaminant concentration of circulating cleaning fluid reach 100mg/L;
5) second step of beginning cleans, and cleaning temperature is controlled at 40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 1.5 hours, cleans after the end the cleaning fluid emptying.
After cleaning process finishes, cut off the controllable temperature heater power source, cut off wash cycles on the throne loop, open recycled water and recirculated water side valve door, plate type heat exchanger normally moves, and data acquisition and control system continue the plate type heat exchanger performance is carried out on-line monitoring.
In order to reach optimal cleaning effect, the cleaning frequency in summer is preferably 5 days.
3. cleaning performance
Plate type heat exchanger moves 20 days continuously, is the cleaning frequency to have carried out 4 cleanings on the throne altogether with 5 days therebetween.Plate type heat exchanger heat transfer coefficient after cleaning all can return to more than 98% of heat transfer coefficient under the clean conditions, but and long term maintenance higher level.Taking plate type heat exchanger apart observation finds: the plate surface is comparatively cleaned, and does not have tangible dirt to adhere to and evidence of corrosion.
Embodiment 3: the serious town regenerated water plate type heat exchanger cleaning example on the throne of fouling under the summer cooling condition
One is the water source heat pump system of Cooling and Heat Source with the town B-grade water outlet, utilizes the Lowlevel thermal energy in the water outlet of plate type heat exchanger recovery town B-grade.In summer, heat pump moves one-month period continuously, and refrigerating efficiency descends very obvious, the analysis showed that it is that secondary effluent due to the fouling, determines to adopt cleaning technique on the throne that plate type heat exchanger is cleaned in plate type heat exchanger.
1. purging system overview
Wash cycles water tank capacity: 100L
Plate type heat exchanger material: stainless steel 316
The fouling situation: plate surface schmutzband is thicker, and viscosity is bigger, and adhesive force is stronger, and the fouling degree is very serious.
2. cleaning
Plate type heat exchanger purging system on the throne as shown in Figure 1.
Cut off recycled water and recirculated water side water route, open cleaning fluid side valve door, constitute wash cycles on the throne loop, clean by following step immediately:
1) before adding medicament, in the wash cycles water tank, add water 50L, test running clean cycle pump can not cause and find time, and liquid is arranged back, then with the water preheat to 40 in the water tank ℃;
2) disodium ethylene diamine tetraacetate of 7.5g and the Sodium Polyacrylate of 1.3g are added in the wash cycles water tank successively, make the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reach 150mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 25mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 360ml, with the volume ratio of circulating cleaning fluid be 1: 140, make the decontaminant concentration of circulating cleaning fluid reach 500mg/L;
3) the beginning first step is cleaned, and cleaning temperature is controlled at 40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 2 hours, cleans after the end the cleaning fluid emptying;
4) repeating step 1), blue star LX-056A/B with 35g, the disodium ethylene diamine tetraacetate of 13g and the Sodium Polyacrylate of 1.3g add in the wash cycles water tank successively, make the concentration of blue star LX-056A/B in circulating cleaning fluid reach 700mg/L, the concentration of disodium ethylene diamine tetraacetate in circulating cleaning fluid reaches 250mg/L, the concentration of Sodium Polyacrylate in circulating cleaning fluid reaches 25mg/L, mix, treat that solution-stabilized back adds clorox and is stirred to abundant mixing, here adopt available chlorine content (in Cl) greater than 10.0% liquor natrii hypochloritis, this liquor natrii hypochloritis's dosage is 170ml, with the volume ratio of circulating cleaning fluid be 1: 300, make the decontaminant concentration of circulating cleaning fluid reach 150mg/L;
5) second step of beginning cleans, and cleaning temperature is controlled at 40 ℃, cleans flow and is set at identically with normal operating condition, and scavenging period is 2 hours, cleans after the end the cleaning fluid emptying.
After cleaning process finishes, cut off the controllable temperature heater power source, cut off wash cycles on the throne loop, open recycled water and recirculated water side valve door, plate type heat exchanger normally moves, and data acquisition and control system continue the plate type heat exchanger performance is carried out on-line monitoring.
3. cleaning performance
After measured, plate type heat exchanger heat transfer coefficient after cleaning returns to 97% of heat transfer coefficient under the clean conditions.Taking plate type heat exchanger apart observation finds: the plate surface does not have tangible dirt to adhere to and evidence of corrosion, and local fragmentary visible faint yellow mucous membrane adheres to.
Table 1 has provided the cleaning method that proposes among the present invention rate of corrosion experimental data for the plate stainless steel.Experiment showed, and can guarantee that in short scavenging period cleaning process has lower rate of corrosion to stainless steels such as 304,316, reason has three: 1. do not contain the highly acid material in the cleaning agent; 2. first step cleaning process is carried out (the pH value is 9.0~9.5) under alkali condition, and stainless steel plate has corrosion resistance preferably for chlorion; Though the second step cleaning process is carried out (the pH value is 5.5~6.0) under acid condition, chloride ion content has decline largely than the first step in the cleaning fluid; 3. blue star LX-056A/B has the inhibition effect.
The cleaning method that proposes among table 1 the present invention is to the rate of corrosion of stainless steel
Material |
Rate of corrosion (g/m
2·h)
|
Temperature (℃) |
Cleaning frequency (my god)/wash number (inferior) |
304 stainless steels |
0.008 |
40 |
5/4 |
316 stainless steels |
0.003 |
40 |
5/4 |
Illustrate: according to town regenerated water water quality and recycled water source heat pump system operating condition, the material of town regenerated water plate type heat exchanger should be selected stainless steel 304 and more anti-corrosion stainless steel model for use.