CN100582331C - High shrinkage acrylic fiber tow making method - Google Patents

High shrinkage acrylic fiber tow making method Download PDF

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CN100582331C
CN100582331C CN200610076295A CN200610076295A CN100582331C CN 100582331 C CN100582331 C CN 100582331C CN 200610076295 A CN200610076295 A CN 200610076295A CN 200610076295 A CN200610076295 A CN 200610076295A CN 100582331 C CN100582331 C CN 100582331C
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唐振波
许贵成
白艳
尚印烽
曲彦书
杨丽华
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Petrochina Co Ltd
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Abstract

本发明涉及一种高收缩腈纶丝束制条方法,高收缩拉断条生产工艺:电热板温度℃:现场温度;热延伸区牵伸倍数:1.25倍;后再割区隔距:130mm;前再割区隔距:115mm;喂给区牵伸倍数:1.05倍;预拉区牵伸倍数1.31倍;主拉区牵伸倍数1.88倍;后再割区牵伸倍数1.30倍;前再割区牵伸倍数1.58倍;正规拉断条生产工艺:电热板温度℃:现场温度;热延伸区牵伸倍数:1.25倍;后再割区隔距:130mm;前再割区隔距:115mm;喂给区牵伸倍数1.05倍;预拉区牵伸倍数1.31倍;主拉区牵伸倍数1.80倍;后再割区牵伸倍数1.25倍;前再割区牵伸倍数1.58倍;延长了设备寿命,保证了纤维质量,降低了能耗,改善了环境温度。

Figure 200610076295

The invention relates to a method for making high-shrinkage acrylic fiber tow strips. The production process of high-shrinkage stretched strips: electric heating plate temperature ℃: site temperature; drafting multiple in the thermal extension zone: 1.25 times; re-cut zone spacing: 130mm; Gauge of re-cutting area: 115mm; draft ratio of feeding area: 1.05 times; draft ratio of pre-drawing area 1.31 times; draft ratio of main drawing area 1.88 times; draft ratio of re-cutting area 1.30 times; front re-cutting area The drafting ratio is 1.58 times; the normal production process of the broken strip: the temperature of the electric heating plate ℃: the site temperature; the drafting ratio in the thermal extension zone: 1.25 times; the distance between the re-cut area: 130mm; The drafting ratio in the feeding area is 1.05 times; the drafting ratio in the pre-drawing area is 1.31 times; the drafting ratio in the main drawing area is 1.80 times; the drafting ratio in the re-cutting area is 1.25 times; , to ensure the fiber quality, reduce energy consumption and improve the ambient temperature.

Figure 200610076295

Description

高收缩腈纶丝束制条方法 High shrinkage acrylic fiber tow making method

技术领域 technical field

本发明涉及一种应用于腈纶丝束的拉断法工艺制条中高收缩腈纶丝束的制条方法,可以用此方法生产腈纶正规毛条。The invention relates to a sliver-making method of high-shrinkage acrylic fiber tow applied in the drawing-breaking process of acrylic fiber tow, which can be used to produce regular acrylic wool tops.

背景技术 Background technique

腈纶纤维的结构是腈纶大分子呈不规则的螺旋构象,不具有真正的结晶结构,因此,没有严格的结晶区和无定形区,只有高序区和低序区之分,腈纶的这一结构特点,不如真正的晶状结构稳定,受热即表现出热弹性,腈纶膨体毛条就是利用这种热弹性来加工制造的。腈纶膨体毛条的制造原理是腈纶纤维先在拉断机加热下拉伸,然后在张力下冷却,这时纤维内部便潜伏着一种应变——潜在收缩,处于这种状态的纤维,称“高收缩纤维”。把高收缩纤维经过超过拉伸温度处理后,潜在收缩就消失了,消失了应变的纤维叫“正规纤维”。把高收缩纤维与正规纤维按一定的比例混合,再经过梳理牵伸等工艺过程,最后制成膨体毛条,如果把这种膨体毛条制成膨体纱后,这种纱或线经蒸汽或热水处理,其中高收缩纤维回缩,位于纱的中心,而混合在一起的正规纤维,由于不再回缩,被拉缩成卷曲状,处于纱的表面,使纱的体积膨大,形成了具有膨松性的膨体纱,这就是腈纶膨体毛条的制造原理。目前,生产膨体毛条的方法,大多采用拉断法制条。此法工艺流程短、占地面积小,可节省人力、物力及能源,自动化程度高,速度快,便于管理。但由于这种方法是使丝束在拉断机上强制性被拉断,而在每个区域拉断都是随机性的,所以生产出的产品短毛率较高。拉断法制条是利用多区拉断机把长丝束拉断,在这个过程中,经过加热、冷却或汽蒸处理,制成具有一定卷曲的高缩条或正规条,再把高缩条和正规条按4∶6的重量比例混合梳理,制成腈纶膨体毛条,其工艺流程如下图1。The structure of acrylic fibers is that the acrylic macromolecules are in an irregular helical conformation and do not have a real crystalline structure. Therefore, there are no strict crystalline regions and amorphous regions, only high-order regions and low-order regions. The structure of acrylic fibers It is not as stable as the real crystalline structure, and it shows thermoelasticity when heated. Acrylic puffed tops are processed and manufactured by using this thermoelasticity. The manufacturing principle of acrylic puffy wool top is that acrylic fiber is first stretched under the heating of the breaking machine, and then cooled under the tension. At this time, there is a kind of strain hidden inside the fiber - potential shrinkage. The fiber in this state is called " High Shrinkage Fiber". After the high-shrinkage fiber is processed beyond the stretching temperature, the potential shrinkage disappears, and the fiber that has lost the strain is called "regular fiber". Mix high-shrinkage fibers and regular fibers in a certain proportion, and then go through processes such as carding and drawing, and finally make bulky tops. If the bulky tops are made into bulky yarns, the yarn or thread is steamed. Or hot water treatment, in which the high-shrinkage fiber retracts and is located in the center of the yarn, while the normal fibers mixed together are pulled into a curled shape because they are no longer retracted, and are on the surface of the yarn, which makes the volume of the yarn expand and form The bulky yarn is obtained, which is the manufacturing principle of the acrylic bulked top. At present, the methods for producing bulky wool tops mostly adopt the breaking method to make strips. This method has a short process flow and a small footprint, which can save manpower, material resources and energy. It has a high degree of automation, high speed and is easy to manage. But because this method is to make the tow be broken forcibly on the breaking machine, and the breaking in each area is random, so the short hair rate of the produced product is higher. The stretch-breaking method is to use a multi-zone stretch-breaking machine to break the filament bundle. In this process, after heating, cooling or steaming, it is made into a high-shrinkage strip or regular strip with a certain curl, and then the high-shrinkage strip And regular strips are mixed and carded at a weight ratio of 4:6 to make acrylic bulked tops. The process flow is shown in Figure 1.

对于普通腈纶丝束来说,电热板加热是提高腈纶毛条缩率的必要工艺,也是生产膨体毛条的必要保证。但对于采用高收缩腈纶丝束生产膨体毛条就是不必要的条件,从而可以降低能源消耗。而且对于生产普通腈纶丝束来说,如果生产正规毛条就没必要将电热板设定为135℃,使拉断纤维提高缩率后又采用汽蒸方法消除缩率。所以,采用同样工艺方法,取消生产正规毛条的拉断机热板温度。经实践应用,也满足设备的使用要求。For ordinary acrylic tow, heating by electric heating plate is a necessary process to improve the shrinkage of acrylic tops, and it is also a necessary guarantee for the production of bulky tops. However, it is an unnecessary condition for the production of bulky tops by using high-shrinkage acrylic fiber tow, so that energy consumption can be reduced. And for the production of ordinary acrylic fiber tow, it is not necessary to set the electric heating plate to 135°C if producing regular tops, so that the broken fibers can increase the shrinkage and then use steaming to eliminate the shrinkage. Therefore, the same process method is adopted to cancel the hot plate temperature of the breaking machine for producing regular tops. After practical application, it also meets the requirements of the equipment.

发明内容 Contents of the invention

本发明的目的是在高收缩腈纶丝束生产膨体毛条的过程中,“取消电热板加热”这一道工艺控制程序,并调整拉断机的牵伸倍数和再割区的隔距参数,生产的膨体毛条各项指标均达到原工艺生产的水平,对纤维的可纺性没有影响,并能满足生产设备的正常要求。The purpose of the present invention is to "cancel the electric heating plate heating" process control program in the process of producing bulky tops from high-shrinkage acrylic fiber tow, and adjust the drafting ratio of the stretching machine and the gauge parameters of the re-cutting area to produce All the indicators of the bulked wool top have reached the level of the original process, and have no effect on the spinnability of the fiber, and can meet the normal requirements of the production equipment.

经过研究在使用高收缩腈纶丝束生产膨体毛条的过程中,拉断机的电热板温度对毛条缩率没有影响。为了应用这一发现,关键是如何保证产品质量,并降低生产消耗。采用“取消电热板加热”这一新工艺制条方法后,通过调整拉断机的牵伸倍数以及再割区隔距的工艺参数,生产的膨体毛条各项指标均达到原工艺生产水平。在此研究基础上,取消生产正规毛条的拉断机电热板温度,即在室温环境下进行生产。其生产主要工艺参数如下表:After research, in the process of using high-shrinkage acrylic fiber tow to produce bulky tops, the temperature of the electric heating plate of the stretching machine has no effect on the shrinkage of the tops. In order to apply this discovery, the key is how to ensure product quality and reduce production consumption. After adopting the new sliver making method of "cancelling electric heating plate heating", by adjusting the drafting ratio of the stretching machine and the process parameters of the re-cutting interval, all the indicators of the produced bulky wool tops have reached the original process production level. On the basis of this research, the temperature of the electromechanical heating plate of the breaking machine for the production of regular wool tops is canceled, that is, the production is carried out at room temperature. The main process parameters of its production are as follows:

表一拉断工序主要生产工艺参数Table 1 The main production process parameters of the pull-off process

  拉断区域 Pull off area   新工艺方法 New process method   原工艺方法 The original process method   改进的作用 Improved effect   电热板温度℃ Heating plate temperature ℃   现场温度 Site temperature   135 135   降低生产成本,改进工作环境。 Reduce production costs and improve the working environment.   热延伸区牵伸倍数 Draft multiple in thermal elongation zone   1.23-1.27 1.23-1.27   1.27-1.31 1.27-1.31   降低该区的运转负荷 Reduce the operating load in the area   后再割区隔距mm Re-cut area interval mm   130-135 130-135   120-125 120-125   减轻该区负荷 Lighten the load in the area   前再割区隔距mm Front re-cut area spacing mm   110-115 110-115   105-110 105-110   减轻该区负荷 Lighten the load in the area

高收缩丝束制条采用新工艺方法后,对纤维的可纺性没有影响;并能满足生产设备的使用要求;通过工艺调整,生产产品的质量符合要求,指标达到原工艺生产状态。The high-shrinkage tow sliver making adopts the new process method, which has no effect on the spinnability of the fiber; and can meet the requirements of the production equipment; through process adjustment, the quality of the produced products meets the requirements, and the indicators reach the original process production status.

经济效益计算:Economic benefit calculation:

(1)取消电热板加热,高收缩丝束生产高收缩毛条的电耗成本每吨下降5.54元;正规毛条的成本每吨下降3.72元,所以生产的膨体毛条吨成本下降了9.26元。(1) The electric heating plate heating is canceled, and the cost of electricity consumption for producing high-shrinkage wool tops with high-shrinkage tow is reduced by 5.54 yuan per ton; the cost of regular wool tops is reduced by 3.72 yuan per ton, so the cost per ton of bulked wool tops produced is reduced by 9.26 yuan.

(2)由于电热板及仪表每年的工作时间大幅下降了65%,不但延长了其使用寿命,而且年降低了备件损耗1.4万元。(2) Since the annual working time of the electric heating plate and the instrument has been greatly reduced by 65%, it not only prolongs its service life, but also reduces the loss of spare parts by 14,000 yuan per year.

(3)电热板温度过高,可使丝束泛黄;所以取消电热板加热,能保证纤维的质量。(3) If the temperature of the electric heating plate is too high, the tow will turn yellow; therefore, canceling the heating of the electric heating plate can ensure the quality of the fiber.

(4)取消电热板加热后,腈纶丝束不必在热延伸区加热,因此大大降低了冷却循环水的降温能耗,减轻了冰机系统的工作负荷。(4) After canceling the heating of the electric heating plate, the acrylic tow does not need to be heated in the thermal extension zone, thus greatly reducing the cooling energy consumption of the cooling circulating water and reducing the workload of the ice machine system.

(5)特别在夏季,取消电热板加热有利于改善室内工作环境温度。(5) Especially in summer, canceling the electric heating plate heating is conducive to improving the indoor working environment temperature.

附图说明 Description of drawings

图1拉断法制条工艺流程Figure 1 The process flow of strip making by pulling off method

图2本发明拉断法制条工艺流程Fig. 2 the present invention draws off the strip making technological process

具体实施方式 Detailed ways

采用高收缩腈纶丝束制条新法在大庆石化公司腈纶厂毛条二车间进行了生产,收到了预想的效果,生产成本下降,电热板及仪表配件消耗降低,拉断机设备备件保持原来水平。在整个生产工艺流程,只针对拉断机生产工艺进行了改进,其它生产工艺仍保持原工艺。拉断工序生产工艺细节如下表:The new method of high-shrinkage acrylic fiber tow sliver production was carried out in the second workshop of the acrylic fiber factory of Daqing Petrochemical Company, and the expected effect was received. The production cost decreased, the consumption of electric heating plates and instrument accessories was reduced, and the spare parts of the breaking machine equipment remained at the original level. In the entire production process, only the production process of the stretching machine has been improved, and other production processes remain the original process. The production process details of the breaking process are as follows:

表二高收缩拉断条生产工艺Table 2 Production process of high shrinkage broken strip

  拉断区域 Pull off area   新工艺方法 New process method   原工艺方法 The original process method   改进的作用 Improved effect   电热板温度℃ Heating plate temperature ℃   现场温度 Site temperature   135 135   降低生产成本,改进工作环境。 Reduce production costs and improve the working environment.   喂给区牵伸倍数 Draft multiple in feeding zone   1.05 1.05   1.05 1.05   热延伸区牵伸倍数 Draft multiple in thermal elongation zone   1.25 1.25   1.31 1.31   降低该区的运转负荷 Reduce the operating load in the area   预拉区牵伸倍数 Drafting ratio in pre-drawing zone   1.31 1.31   1.29 1.29   稍微增加该区的负荷 Slightly increase the load of the area   主拉区牵伸倍数 Draft multiple in main draw zone   1.88 1.88   1.77 1.77   增大该区的负荷,减轻再割区的负荷。 Increase the load in this area and reduce the load in the recut area.   后再割区牵伸倍数 Draft multiple of recut area   1.30 1.30   1.20 1.20   控制纤维长度分布 Control fiber length distribution   前再割区牵伸倍数 Draft multiple of front recutting area   1.58 1.58   1.58 1.58   后再割区隔距mm Re-cut area interval mm   130 130   125 125   减轻该区负荷 Lighten the load in the area   前再割区隔距mm Front re-cut area spacing mm   115 115   110 110   减轻该区负荷 Lighten the load in the area

表三正规拉断条生产工艺Table 3 Production process of regular stretched broken strips

  拉断区域 Pull off area   新工艺方法 New process method   原工艺方法 The original process method   改进的作用 Improved effect   电热板温度℃ Heating plate temperature ℃   现场温度 Site temperature   135 135   降低生产成本,改进工作环境。 Reduce production costs and improve the working environment.   喂给区牵伸倍数 Draft multiple in feeding zone   1.05 1.05   1.05 1.05   热延伸区牵伸倍数 Draft multiple in thermal elongation zone   1.25 1.25   1.31 1.31   降低该区的运转负荷 Reduce the operating load in the area   预拉区牵伸倍数 Drafting ratio in pre-drawing zone   1.31 1.31   1.29 1.29   稍微增加该区的负荷 Slightly increase the load of the area   主拉区牵伸倍数 Draft multiple in main draw zone   1.80 1.80   1.70 1.70   增大该区的负荷,减轻再割区的负荷。 Increase the load in this area and reduce the load in the recut area.   后再割区牵伸倍数 Draft multiple of recut area   1.25 1.25   1.20 1.20   控制纤维长度分布 Control fiber length distribution   前再割区牵伸倍数 Draft multiple of front recutting area   1.58 1.58   1.58 1.58   后再割区隔距mm Re-cut area interval mm   130 130   125 125   减轻该区负荷 Lighten the load in the area   前再割区隔距mm Front re-cut area spacing mm   115 115   110 110   减轻该区负荷 Lighten the load in the area

Claims (1)

1.一种高收缩腈纶丝束制条方法,它是使用高收缩腈纶丝束和常规腈纶丝束两种原料,分别经拉断条生产工艺拉断,将常规腈纶丝束在拉断后经蒸汽处理制成正规拉断条,再将高收缩腈纶丝束拉断的高收缩拉断条和常规腈纶丝束在拉断后经蒸汽处理制成的正规拉断条以重量40%∶60%的比例混条生产高收缩膨体毛条,其特征在于:1. A high-shrinkage acrylic fiber tow sliver-making method, it is to use high-shrinkage acrylic fiber tow and conventional acrylic fiber tow two kinds of raw materials, respectively break through the strip production process of stretching, and conventional acrylic fiber tow is steamed after being broken. Treat and make regular break strips, then the high shrinkage break strips with high-shrinkage acrylic fiber tows and the regular break strips made by steam treatment after breaking high-shrinkage acrylic tows are in the ratio of 40%: 60% by weight Mixed strips to produce high-shrinkage puffy tops, which are characterized by: 高收缩拉断条生产工艺:Production process of high shrinkage broken strip: 电热板温度℃:现场温度;热延伸区牵伸倍数:1.25倍;后再割区隔距:130mm;前再割区隔距:115mm;喂给区牵伸倍数:1.05倍;预拉区牵伸倍数1.31倍;主拉区牵伸倍数1.88倍;后再割区牵伸倍数1.30倍;前再割区牵伸倍数1.58倍;Heating plate temperature ℃: on-site temperature; draft ratio in thermal extension zone: 1.25 times; distance between recut zone: 130mm; distance between front recut zone: 115mm; draft multiple in feeding zone: 1.05 times; The drafting ratio is 1.31 times; the drafting ratio in the main drawing area is 1.88 times; the drafting ratio in the re-cutting area is 1.30 times; the drafting ratio in the front re-cutting area is 1.58 times; 和正规拉断条生产工艺:And the production process of regular broken strips: 电热板温度℃:现场温度;热延伸区牵伸倍数:1.25倍;后再割区隔距:130mm;前再割区隔距:115mm;喂给区牵伸倍数1.05倍;预拉区牵伸倍数1.31倍;主拉区牵伸倍数1.80倍;后再割区牵伸倍数1.25倍;前再割区牵伸倍数1.58倍。Heating plate temperature ℃: on-site temperature; drafting ratio in hot extension zone: 1.25 times; distance between recutting zone: 130mm; spacing in front recutting zone: 115mm; drafting multiple in feeding zone: 1.05 times; The multiple is 1.31 times; the drafting multiple in the main drawing zone is 1.80 times; the drafting multiple in the recutting zone is 1.25 times; the drafting multiple in the front recutting zone is 1.58 times.
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CN102021679B (en) * 2009-09-22 2013-02-13 中国石油天然气股份有限公司 Production method of fine denier acrylic wool top
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