CN100582037C - Continuous andesite fiber, its production method and uses of the fiber - Google Patents

Continuous andesite fiber, its production method and uses of the fiber Download PDF

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CN100582037C
CN100582037C CN200610145748A CN200610145748A CN100582037C CN 100582037 C CN100582037 C CN 100582037C CN 200610145748 A CN200610145748 A CN 200610145748A CN 200610145748 A CN200610145748 A CN 200610145748A CN 100582037 C CN100582037 C CN 100582037C
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阎崇光
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Abstract

The invention relates to a kind of successive an mountain rock fiber, the transverse section diameter of which is 3-15 um. The specific ruining intensity of the crude yarn whose primitive biber has a diameter of 11.0 mum is 400-500mN/tex. The invention also relates to the preparing method and preparing device of the fiber. The preparing method includes the following steps: adding material; melting the ore and uniformizing the quality of the melting body; shaping the fiber; coating the wetting agent and elongating the fiber. The device contains feed; melting pool, melting pool dreg-blocking board, bottom tapping opening, heating device, drawing-off leaking board, wetting agent coating device and twister. The mentioned heating device is air-fuel gas device and the electrode. The successive an mountain fiber is a kind of excellent strengthening fiber material which can be used as insulant, cleaning material, filtering material, structure-strengthening material, anti-corrosion material, heat insulation material and deadener.

Description

The purposes of continuous andesite fiber, its production method and continuous andesite fiber
Technical field
The present invention relates to the purposes of a kind of ore fiber and production method thereof and equipment and ore fiber, the purposes of particularly a kind of continuous andesite fiber and production method and andesite fiber.
Background technology
The andesite ore is a kind of main ore of volcanics slurry, and the Chinese patent application " application of andesite plagioclase in sour contact arrangement " (application number is 200510127533.7) of the applicant's application and Chinese patent application " application of andesite in architectural coating " (application number is 200610103562.4) have disclosed andesite and had extraordinary mechanical characteristics, chemical stability, erosion resistance and thermostability.
Continuous fibre by andesite production is that continuous andesite fiber (Continuous AndesiteFibre is called for short CAF) has higher intensity, good corrosion-resistant stability and thermostability and electrical insulation capability preferably, long service life.The ore of andesite fiber is abundant, be widely used, but the widespread use of continuous andesite fiber is subjected to the restriction of factors such as production technology complexity to a certain extent, have only Russia, georgia to grasp production technology at present in the world, developing and improving the Technology that continuous andesite fiber is produced so press for.
Summary of the invention
The technical problem to be solved in the present invention is intended to overcome the deficiency of above-mentioned prior art, and a kind of continuous andesite fiber is provided, and this continuous andesite fiber intensity height, resistance toheat are good, are suitable for using as the structural strengthening material.
Technical scheme of the present invention is:
A kind of continuous andesite fiber, described continuous andesite fiber are to adopt with plagioclase K (AlSi 3O 8) be that main andesite ore materials is made, described andesite contains the essential mineral composition of following mass ratio: SiO 2-57~63, Fe 2O 3-4~5, TiO 2-0.6~1, CaO-5~8, MgO-1~2, Al 2O 3-15~16, Na 2O-3~4, K 2O-1~2, the cross-sectional diameter of described continuous andesite fiber are 3~15 microns, and the ratio strength at break of its pristine fibre when being the roving of diameter 11.0 μ m is 400~500mN/tex.
Further, the continuous andesite fiber that the present invention relates to is got by the following steps preparation:
1) reinforced: as, make after last batch of material melts fully, to add second batch of material again, and molten mass to be stablized the setting level that remains in the melting pool with adding in the melting pool with feed way in batches of fragmentation based on the andesite ore of plagioclase;
2) ore fusing and molten mass quality homogenizing: the heating rock makes it be converted into the non-type attitude from crystal form, and the control Heating temperature is 1420~1490 ℃, makes the ore quality of non-type attitude even simultaneously;
3) fiber-forming: the molten mass that aforesaid operations obtains flows to bushing by the top of dreg-blocking board, carries out fiber-forming and makes it become primary filament, and the forming temperature of control bushing is 1210~1280 ℃;
4) treating compound coating: carry out coating with the treating compound coating apparatus;
5) stretching is twined: the above-mentioned fiber that obtains is wound on the wrapping machine.
The performance of the continuous andesite fiber that the present invention relates to is as shown in table 1 below with the comparing result of the basalt fibre of using always both at home and abroad, glass fibre:
Table 1
Figure C20061014574800061
Figure C20061014574800071
As seen from the above table, the andesite fiber that the present invention relates to is compared with basalt fibre, glass fibre commonly used, has the following advantages:
(1), Young's modulus exceeds expensive S glass fibre; Be used for Woven fabric weight at 150~210g/m 2Product the time, weaving performance is good; Can make insulating product and matrix material in order to replace the S glass fibre, make hard armor, various GFRP product and portion C FRP product.For example, utilize the E glass fibre to produce Glass Steel Tube, can only anti-25 normal atmosphere, caliber is 2 meters to the maximum, and makees Glass Steel Tube with andesite fiber, then can anti-60 normal atmosphere, caliber can reach 3.5 meters.Under some Working environment, andesite fiber can partly replace carbon fiber or aramid fiber.
(2), because water resistance is good, even surpass the E glass fibre that water tolerance has reached the I level, the cotton plate made from the andesite fiber of diameter 17~25 μ m has enough water-permeables and flexibility during as agriculture substratum.Through repeatedly freezing and thawing, soak and dry recycle, the cotton plate of andesite shows enough stability.Because its anti-atmospheric action can be in order to reinforce building near water such as dash slope earth dam, fending groin and irrigation canals and ditches.
(3), thermotolerance is better than mineral wool and E glass fibre, the high resistant to elevated temperatures quartz glass fibre of price near output is little.When working under 400 ℃ of temperature, its breaking tenacity still can keep 96%; When working under 600 ℃ of temperature, its breaking tenacity still can keep 90% green strength, even and also can only keep good mineral wool at this moment 50~60% intensity, glass wool is completely destroy then.If andesite fiber is handled under 880~920 ℃ in advance, fiber can also be worked under 960 ℃ and can not occurred shrinking.If the short yarn cutting of andesite fiber is bonded into felt with sodium~montomorillonite~bentonite slurry, handled 5 minutes down at 550 ℃, can improve its water tolerance, and can bring up to working temperature on 1000 ℃ of quartz glass fibre.Sometimes fiber also will stand vibration except standing heat effect.The heat of andesite fiber under the 500 ℃ of temperature stability of shaking is still constant, and original weight loses less than 1.3%; In the time of 900 ℃, only 2%.The andesite fiber of low unit weight, low heat conductivity, low rate of moisture absorption and high chemical stability also can be used as the most effective very low temperature thermal insulation material of liquid nitrogen containers such as (196 ℃) or equipment except can be used for high temperature thermal insulation material, and the E glass fibre can only be anti--60 ℃.There is not the carcinogenic problem that may cause when making lagging material with asbestos in andesite fiber when the lagging material.
(4), since sound absorption coefficient than E glass fibre height, andesite fiber also is efficient sound-proof material, and fire prevention, can be used for kino and other saloons with the form of baffle blanket or plate.
(5), because the filter factor height, andesite fiber also successfully purify air or the equipment of flue gas in, as high-temperature-resistant filtering material.
(6), the tensile strength of andesite fiber under 200~300 ℃ of temperature will improve 30%, and general glass fibre descends 23%.Andesite fiber also can keep higher-strength under the hot water effect.For example, the intensity of basalt fibre can keep 1000 hours under 80 ℃ of water effects, and general glass fibre is less than just losing intensity in 200 hours.Andesite fiber is exposed to the sun 47 ℃ of strong sunlight still can keep intensity in 2000 hours.
(7), andesite contains the conductive oxide less than 20%, the glass fibre that contains conductive oxide generally can not be used to prepare insulating material, but the tangent of the dielectric loss angle of andesite fiber is close with the E glass fibre, the andesite fiber that the application specific treating compound was handled, its tangent of the dielectric loss angle also hangs down 60% than general glass fibre, thereby can be used as heat-resistant insulation material, can be widely used in the fields such as printed-wiring board (PWB) manufacturing of electronic industry.
(8), andesite fiber has good reinforcing effect.The hot candied test of ultimate fibre shows that the adhesive capacity of andesite fiber and epoxy polymer is higher than the E glass fibre, and also can further improve after adopting silane coupling agent to handle.Therefore, andesite fiber can replace being about to the strongthener of the asbestos of forbidding as high-temperature-resistant structure matrix material, rubber technology goods etc., also can be used for making the strongthener of the wearing piece of stopper, clutch coupling etc.
(9), the ECR glass fibre that the acid resistance of andesite fiber is higher than the valency through being commonly used for acid-resistant glass steel strongthener is not bad; Its alkali resistance is suitable with AR alkali resistant glass fibre commonly used in the market, can replace the AR glass fibre, fields such as fiber reinforced concrete member (GRC) that is applied to be in great demand or road surface geo-grid.
In a word, andesite fiber almost can replace glass fibre or special glass fibre commonly used at present, is a kind of reinforcing fiber materials of excellence.
The invention still further relates to a kind of preparation method of continuous andesite fiber, may further comprise the steps:
1) reinforced: as, make after last batch of material melts fully, to add second batch of material again, and molten mass to be stablized the setting level that remains in the melting pool with adding in the melting pool with feed way in batches of fragmentation based on the andesite ore of plagioclase;
2) ore fusing and molten mass quality homogenizing: the heating rock makes it be converted into the non-type attitude from crystal form, and the control Heating temperature is 1420~1490 ℃, makes the ore quality of non-type attitude even simultaneously;
3) fiber-forming: the molten mass that aforesaid operations obtains flows to bushing by the top of dreg-blocking board, carries out fiber-forming and makes it become primary filament, and the forming temperature of control bushing is 1210~1280 ℃;
4) treating compound coating: carry out coating with the treating compound coating apparatus;
5) stretching is twined: the above-mentioned fiber that obtains is wound on the wrapping machine.
The present invention will be based on reinforced, fusing, molten mass quality homogenizing, the bushing moulding of the andesite ore of plagioclase, carry out the treating compound coating and processes one such as windings that stretch go on foot and finish, " single stage method " for the andesite continuous fibre is produced guarantees the production of continuous andesite fiber (CAF).
The molten mass that utilizes method of the present invention to produce can be used for making the fine-fibered that 3~15 microns continuous andesite fiber (CAF), 1~3 micron weak point are cut ultra-fine fibre and 4~10 microns.
The invention still further relates to the employed equipment of a kind of preparation continuous andesite fiber, include feeding device, ore fusing tank furnace 4, ore melting pool 5, melting pool dreg-blocking board 6, bottom slag notch 18, heating unit 11, bushing 8, treating compound coating apparatus 14 and wrapping machine 15, described heating unit is combustion gas~air gas mixture mixing device and electrode.
To be the contriver design according to the characteristic of andesite the employed equipment of preparation continuous andesite fiber that the present invention relates to, and this equipment makes the industrialization of continuous andesite fiber become possibility.
The present invention also provides the application of multiple continuous andesite fiber, and promptly andesite fiber is as the application of structural strengthening material; Application as heat-insulating and sound-proof material; Application as purification filtering material; Application as insulating material; As the application of corrosion resistant material, this paper has disclosed multiple physics, the chemical parameters of continuous andesite fiber, and has proposed to expand the various uses of andesite Application Areas according to the excellent properties of the shown andesite of these parameters.
Description of drawings
Fig. 1 represents the structural representation of the preparation specific equipment of the continuous andesite fiber that the present invention relates to;
Fig. 2 represents the top surface structure synoptic diagram of the preparation specific equipment of the continuous andesite fiber that the present invention relates to.
Embodiment
With reference to accompanying drawing, below will be described in detail the specific embodiment of the present invention.
Among the preparation method of the continuous andesite fiber that the present invention relates to, the andesite ore should select to have the characteristic that is suitable for fiber-forming and the ore of processing characteristics.Wherein, the preferred andesite that adopts the essential mineral composition that contains following mass ratio: SiO 2-57~63, Fe 2O 3-4~5, TiO 2-0.6~1, CaO-5~8, MgO-1~2, Al 2O 3-15~16, Na 2O-3~4, K 2O-1~2, the mineral composition of the described andesite of further preferred employing is with plagioclase [K (AlSi 3O 8)] be main.
The present invention has realized the combination of each machining process such as fusing, molten mass quality homogenizing and fiber-forming of andesite ore by to the fusing of andesite ore and the control of complete processing, thereby improves the fusing and the Economics of Processing of andesite ore.
The inventive method comprises following processing step: reinforced → ore fusing → molten mass quality homogenizing → bushing moulding → as to carry out treating compound coating → stretching to twine.
The present invention with reinforced, fusing, molten mass quality homogenizing, the bushing moulding of andesite ore, carry out the treating compound coating and one step of processes such as windings that stretch finishes, be " single stage method " of andesite continuous fibre production.
In order to realize " single stage method " production technique, the present invention to reinforced, ore fusing, molten mass quality homogenizing, bushing moulding, carry out treating compound coating and stretching winding process require as follows:
1, reinforced: with setting-up time at interval, the mode of continuous charging directly is added in the ore fusing tank furnace in batches with the andesite ore of fragmentation, (1) add second batch of material again after last batch of material melts fully, the molten mass in (2) tank furnace stably remains on the horizontal plane of setting.
Wherein, the preferred employing by the reinforced industry control funnel 3 of ore fusing tank furnace with continuous charging or quantitatively and equably carry out reinforced in batches mode and directly be added in the ore melting pool 5 by the timed interval of setting, requirement according to fiber-forming, the setting level of this molten mass in ore melting pool 5 is 200~250mm, and the setting level in fusing tank furnace feeder 7 is 50~80mm.In implementing the reinforced process of andesite ore, in order to guarantee that the molten mass in the molten bath stably remains on the setting level, when adopting continuous charging, feed rate can be set at 1~2 Grams Per Second, adopt when feeding in raw material in batches, every batch of feeding quantity can be set at 100~300 grams, and reinforced interval can be set at 50~200 seconds.
2, ore fusing and molten mass quality homogenizing: andesite is a kind of single constituent element ore, finished the quality homogenizing and the melting process of chemical composition under the vulcanism in time immemorial, volcano magma melts body and is changing into crystal form from the non-type attitude in the condensation process slowly.Therefore, the andesite ore must change into the non-type attitude of the non-type degree with setting from crystal form in melting process.
Concrete operations are: the andesite ore is molten into the molten mass of good fluidity and meets the requirement of wire drawing viscosity in tank furnace, and the control Heating temperature is 1420~1490 ℃; Simultaneously can make rock, before the bushing moulding, molten mass be flowed and reach the quality homogenizing by heat power from the solid-state molten mass that changes into amorphous liquid state.
Wherein, temperature of fusion is controlled by the flow of the combustion gas~air gas mixture of intelligent temperature controller adjusting tank furnace top and sidewall; In ore melting pool 5 or 2. can be 1. in ore melting pool 5 and fusing tank furnace feeder 7, merge by the molten mass quality homogenizing process of non-type degree requirement and to carry out.
Wherein, preferably adopt combustion gas~air gas mixture and heated by electrodes rock.Further, preferably adopt to be provided with in combustion gas~air mixing device to increase the turbo-supercharger that combustion gas~air gas mixture enters the air input of tank furnace, promptly the thermo-efficiency that is arranged so that combustion gas~air of turbo-supercharger strengthens.
3, bushing moulding: in tank furnace, carry out the fusing of ore, after carrying out the quality homogenizing molten mass directly flow to above by dreg-blocking board the platinum rhodium bushing above, carry out fiber-forming by the hole on the bushing and become primary filament 13 (Fig. 1), the forming temperature of control bushing is 1210~1280 ℃.
The andesite molten mass is in the flame space temperature of determining to depend on ore fusing tank furnace, the horizontal plane that melts molten mass in the tank furnace feeder 7 and the temperature of bushing 8 of the processing temperature at fusing tank furnace feeder 7 and bushing 8 places.For thermal radiation, the mutual relationship between andesite melt temperature and the horizontal plane changes the opaqueness that depends on its molten mass.The regulation and control of bushing temperature rely on the current value of regulating by bushing, arrange and connect the bushing intelligent temperature controller at the bushing two ends by soft copper, the energising amount of control bushing.The forming temperature of andesite fiber is 1210~1280 ° on bushing, and this depends on the aperture of the fibre-forming performance and the bushing of the molten mass that need obtain.
Wherein, preferably adopting described bushing is the platinum rhodium in 400~2000 holes or those skilled in the art can learn that other are applicable to the bushing that the alloy of bushing is made.
Wherein, for improving the throughput of continuous fibre, reduce production costs, the present invention preferably adopts and be provided with a plurality of bushings (Fig. 2) below each smelting furnace, correspondingly preparation and the same number of bushing heating unit of bushing and treating compound coating apparatus and wrapping machine, the preferred employing is provided with the working group that is no less than 4 groups of said apparatus compositions, and more preferably adopting above-mentioned working group is the 4-8 group.
4, carry out the treating compound coating: carry out coating with the treating compound coating apparatus.
5, stretching is twined: the above-mentioned fiber that obtains is wound on the wrapping machine.
In sum, the production method of andesite fiber provided by the invention realizes the melting process of andesite ore from Technology, molten mass carries out quality homogenizing process before entering the bushing moulding, the molten mass horizontal plane is kept, the temperature of molten mass, stable viscosity, directly form process such as fiber by bushing, guarantees the production of continuous andesite fiber (CAF).
The molten mass that utilizes method of the present invention to produce can be used for making the fine-fibered that 3~15 microns continuous andesite fiber (CAF), 1~3 micron weak point are cut ultra-fine fibre and 4~10 microns, and the ratio strength at break of the continuous andesite fiber of its production when pristine fibre is the roving of diameter 11.0 μ m is 400~500mN/tex.
As shown in Figure 1, the invention still further relates to the employed equipment of a kind of preparation continuous andesite fiber, include feeding device, ore fusing tank furnace 4, ore melting pool 5, melting pool dreg-blocking board 6, bottom slag notch 18, heating unit, bushing 8, treating compound coating apparatus 14 and wrapping machine 15, described heating unit is electrode or combustion gas~air gas mixture mixing device.Wherein, when adopting combustion gas~air gas mixture mixed gas to heat, combustion gas enters from fuel gas inlet 16, and air enters from gas inlet 17, and above-mentioned two kinds of gases are in combustion gas~air gas mixture mixing tank 11 places mixing and flow to melting pool inside; When adopting heated by electrodes, electrode heats by the melting pool inner side-wall.The preferred burner 12 that adopts above-mentioned heating unit to be provided with heating unit on the top of ore molten pool.
Wherein, preferably adopt the turbo-supercharger 10 that in combustion gas~air mixing device, is provided with enhancing combustion gas~air thermo-efficiency.Wherein, preferably adopt described feeding device to include andesite feeder 1, hopper gauger 2 and reinforced industry control funnel 3.Also preferably be provided with fusing tank furnace feeder 7, collect and discharge the flue gas collection comb 9 that produces useless flue gas in the production process into the bushing feeding.The also preferred slag notch 18 that is located at the tank furnace bottom that adopts.
Continuous andesite fiber (CAF) is a kind of tencel.Contain special composition in the andesite, give andesite fiber some specific performance properties.For example, Al 2O 3Can improve melt viscosity and chemical stability; Fe 2O 3Can change and found parameter, influence thermal conductivity; MgO, K 2O and TiO 2Then can improve water resistance and erosion resistance.The andesite continuous fibre is because the excellent properties of itself makes it be with a wide range of applications at different industrial circles, and the present invention also provides the application of multiple continuous andesite fiber, and promptly andesite fiber is as the application of structural strengthening material; Application as heat-insulating and sound-proof material; Application as purification filtering material; Application as insulating material; Application as corrosion resistant material.Its concrete example application is as described below:
1, spacecraft: the internal part that the airship space vehicles need be strengthened, can improve ageing-resistant, the antifatigue level of airship space vehicles parts; The airship space vehicles is carried out inner body reinforce, can improve the reliability of airship space vehicles; Can alleviate the deadweight of airship space vehicles, increase useful load.
2, flyer: need the position parts strengthened on the military civilian aircraft, can improve the flight velocity of aircraft significantly; Can absorbing radar wave, reduce military spacecraft reflection of radar waves cross section; Can improve the endurance of surface metal.
3, launch vehicle and guided missile: rocket body or body matrix material and the position parts that need to strengthen, the bullet matrix material, internal structure stabilizing means material, can improve the reliability of rocket or guided missile, can improve the stealth of guided missile, rocket body or body weight be can alleviate, useful load or guided missile miniaturization increased.
4, submarine and surface ship: the vibration in (1), submarine main body cover composite, the submarine cuts off and makes external impact be difficult to be delivered to ship interior buffer structure and parts.Can block the interior mechanicalness noise of ship and outwards propagate, improve adiabatic sound insulation level, improve the anti-detecting function of submarine; Can after having an accident or attack, submarine improve submarine ship shell shock resistance; Can improve submarine ship shell seawater corrosion resistance level.(2), surface ship main body cover matrix material, aquatic building thing, fire resistant position parts.Can improve shell operation and corrosion prevention level; Can improve adiabatic sound insulation level; Can reduce the radio echo cross section.
5, tank and armored vehicle: composite armour protective material, can improve protection level, can alleviate tank and armored vehicle weight, can be used for the quick reinforcement repairing of battlefield tank and armored vehicle armour piercing shot, high explosive anti-tank cartridge, the radio echo cross section can be reduced, infrared divergence can be reduced.
6, individual soldier protection system: composite protective material is manufactured operation knapsack, fighting uniform, is made the caliga and the helmet, can improve shellproof, lightning protection, anti-stab, anti-cutting, fire prevention usefulness, can alleviate individual soldier's load, can reduce infrared divergence.
7, building reinforce material: road surface geo-grid material such as bridge, harbour, motorway, airfield runway, subway, railway; Bridge, buildings damage supporting material; Fiber reinforcement coagulation body member; Parent's concrete continuous fiber reinforced rebar substitutes reinforcing bar and is used for ultra-large type buildings such as dam, super-high buildings, tunnel, bridge.
8, engineering strongthener: engine in the automobile making and vehicle body reinforced insulation sound-proof material, friction materials, automobile component; Engine during aviation is made, the enhancing heat-insulating and sound-proof material of pneumatically operated equipment; Mast in the shipbuilding, hawser, deck, hull strengthen heat-insulating and sound-proof material; Shell in the electronic industry, support, reinforcing member and printing plate base material; Lagging material, the purification filtering material of the compressor cushion plate in the chemical industry, refrigeration or gas liquid groove jar; Air ultrapurification strainer in the medical science; Andesite fiber base enhancement engineering plastics; Pressurized vessel; Blade of wind-driven generator; Fuel cell; Refinforced cement.
9, Leisure Sport articles for use: the manufacturing of golf club, fishing gear, bike, racing boat, ski, ice stick.
10, other purposes: the offshore drilling platform of petroleum industry; Chemical industry and metallurgical industry field high-temperature filter; Heavy caliber crude oil, processed oil line of pipes can improve more than work-ing life to 80 year, can realize quick mending-leakage; Chemical industry heatproof, anticorrosion pipeline; Chemical plant installations heatproof, corrosion resistant member or parts; Alert usefulness, fire-fighting, shellproof, the explosion-proof protective clothing of special trade.

Claims (10)

1, a kind of continuous andesite fiber is characterized in that: described continuous andesite fiber is to adopt with plagioclase K (AlSi 3O 8) be that main andesite ore materials is made, described andesite contains the essential mineral composition of following mass ratio: SiO 2-57~63, Fe 2O 3-4~5, TiO 2-0.6~1, CaO-5~8, MgO-1~2, Al 2O 3-15~16, Na 2O-3~4, K 2O-1~2, the cross-sectional diameter of described continuous andesite fiber are 3~15 microns, and the ratio strength at break of its pristine fibre when being the roving of diameter 11.0 μ m is 400~500mN/tex.
2, continuous andesite fiber according to claim 1 is characterized in that described continuous andesite fiber is got by the following steps preparation:
1) reinforced: as, make after last batch of material melts fully, to add second batch of material again, and molten mass to be stablized the setting level that remains in the melting pool with adding in the melting pool with feed way in batches of fragmentation based on the andesite ore of plagioclase;
2) ore fusing and molten mass quality homogenizing: the heating rock makes it be converted into the non-type attitude from crystal form, and the control Heating temperature is 1420~1490 ℃, makes the ore quality of non-type attitude even simultaneously;
3) fiber-forming: the molten mass that aforesaid operations obtains flows to bushing by the top of dreg-blocking board, carries out fiber-forming and makes it become primary filament, and the forming temperature of control bushing is 1210~1280 ℃;
4) treating compound coating: carry out coating with the treating compound coating apparatus;
5) stretching is twined: the above-mentioned fiber that obtains is wound on the wrapping machine.
3, the preparation method of the described continuous andesite fiber of a kind of claim 1 may further comprise the steps:
1) reinforced: as, make after last batch of material melts fully, to add second batch of material again, and molten mass to be stablized the setting level that remains in the melting pool with adding in the melting pool with feed way in batches of fragmentation based on the andesite ore of plagioclase;
2) ore fusing and molten mass quality homogenizing: the heating rock makes it be converted into the non-type attitude from crystal form, and the control Heating temperature is 1420~1490 ℃, can make that the ore quality of non-type attitude is even simultaneously;
3) fiber-forming: the molten mass that aforesaid operations obtains flows to bushing by the top of dreg-blocking board, carries out fiber-forming and makes it become primary filament, and the forming temperature of control bushing is 1210~1280 ℃;
4) treating compound coating: carry out coating with the treating compound coating apparatus;
5) stretching is twined: the above-mentioned fiber that obtains is wound on the wrapping machine.
4, the preparation method of continuous andesite fiber according to claim 3 is characterized in that step 2) middle with combustion gas~air gas mixture and heated by electrodes rock.
5, the preparation method of continuous andesite fiber according to claim 4 is characterized in that being provided with turbo-supercharger in combustion gas~air mixing device.
6,, it is characterized in that the bushing in the described step 3) is platinum rhodium or other alloy bushing in 400~2000 holes according to the preparation method of the described continuous andesite fiber of the arbitrary claim of claim 3-5.
7, the preparation method of continuous andesite fiber according to claim 6 is characterized in that each smelting furnace below is provided with the working group that 4~8 groups or more bushing, bushing heating unit, treating compound coating apparatus and wrapping machine are formed.
8, the application of the described continuous andesite fiber of claim 1 is characterized in that: with its application as insulating material or purification filtering material or structural strengthening material or corrosion resistant material or heat-insulating and sound-proof material.
9, the application of described continuous andesite fiber according to Claim 8 is characterized in that: use it for the position parts that spacecraft, flyer, launch vehicle or guided missile need be strengthened.
10, the application of described continuous andesite fiber according to Claim 8 is characterized in that: use it for the heat-insulating and sound-proof material of making submarine, surface ship.
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* Cited by examiner, † Cited by third party
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CN101811826A (en) * 2010-05-05 2010-08-25 山西巴塞奥特科技有限公司 Raw material matching component for producing basalt fiber and preparation method thereof
CN104193164A (en) * 2014-09-05 2014-12-10 安山纤维有限公司 Equipment for producing andesite continuous fiber and method for producing continuous fiber through equipment
CN104746156A (en) * 2015-03-18 2015-07-01 宁波求新新材料科技有限公司 High-efficiency and energy-saving fiber drying device and method
CN104692645A (en) * 2015-03-26 2015-06-10 山东聚智机械科技有限公司 Furnace deslagging system used for producing basalt continuous filament
CN106082888A (en) * 2016-06-13 2016-11-09 马鞍山市金韩防水保温工程有限责任公司 Thermal insulation mortar that a kind of soundproof effect is good and preparation method thereof
CN106242305B (en) * 2016-09-05 2019-05-21 东南大学 Continuous basalt fiber production technology
CN109023166A (en) * 2017-06-12 2018-12-18 南京天淦新材料科技有限公司 A kind of aluminium the enhancing high sial magnesium material of amorphous and Preparation method and use
CN111847892A (en) * 2020-08-26 2020-10-30 康富 Low-cost superfine basalt fiber

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
三峰耐酸石的特性和应用效果. 沈永淦,南振卿.全面腐蚀控制,第12卷第3期. 1998
三峰耐酸石的特性和应用效果. 沈永淦,南振卿.全面腐蚀控制,第12卷第3期. 1998 *

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