CN100579919C - Method and apparatus for generating hydrogen-enriched water - Google Patents
Method and apparatus for generating hydrogen-enriched water Download PDFInfo
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- CN100579919C CN100579919C CN200510068852A CN200510068852A CN100579919C CN 100579919 C CN100579919 C CN 100579919C CN 200510068852 A CN200510068852 A CN 200510068852A CN 200510068852 A CN200510068852 A CN 200510068852A CN 100579919 C CN100579919 C CN 100579919C
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- Prior art keywords
- water
- rich hydrogen
- hydrogen
- box
- hydrogen water
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 106
- 239000001257 hydrogen Substances 0.000 title claims abstract description 68
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 68
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims description 25
- 239000011777 magnesium Substances 0.000 claims abstract description 41
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 239000000919 ceramic Substances 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 6
- 239000004332 silver Substances 0.000 claims abstract description 6
- 239000008187 granular material Substances 0.000 claims description 30
- 235000009508 confectionery Nutrition 0.000 claims description 29
- 238000005245 sintering Methods 0.000 claims description 20
- 239000011796 hollow space material Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003651 drinking water Substances 0.000 abstract 5
- 235000020188 drinking water Nutrition 0.000 abstract 5
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 230000004913 activation Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 4
- 239000000347 magnesium hydroxide Substances 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 208000030961 allergic reaction Diseases 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003292 diminished effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000036783 anaphylactic response Effects 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 238000004814 ceramic processing Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000002008 hemorrhagic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
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- Water Treatment By Sorption (AREA)
- Physical Water Treatments (AREA)
Abstract
The present invention purposes to enable efficient conversion of drinking water to hydrogen-rich water containing plenty of hydrogen without using an electrolysis device. Magnesium particles 4 and silver particles 3 which have been subjected beforehand to burning treatment under the condition of a burning time of 10+-1 minutes and a burning temperature of 110+-2[deg.]C, and react with drinking water 6 to generate hydrogen gas are packed in a water-permeable porous ceramic case 1 to form a hydrogen-rich water generator 2. The hydrogen-rich water generator 2 is put in a container 5 together with the drinking water 6, and the drinking water 6, magnesium particles 4, ceramic, and silver particles 3 are made to react with generate hydrogen gas. The drinking water 6 in the container 5 is purified by the action of the silver particles 3 and converted to the hydrogen-rich water containing plenty of hydrogen and having an antibacterial action.
Description
Technical field
The present invention relates to by drinking or coat skin, to removing intravital active oxygen or improvement aging effective rich hydrogen water generation method of color spot, wrinkle and the rich hydrogen Water generator that produces because of skin.
Background technology
In recent years to have delivered the many water of hydrogen richness be effective theory for the active oxygen of removing the cause of disease that becomes cancer and other various diseases to medical circle, caused gazing at of people.Existing known device as the so rich hydrogenous sweet water of generation is to utilize electrolytic device.In addition, be following consideration about magnesium in the past." MAGNESIUM METAL is not at room temperature reacted with water, if micropowder is heated in water, generates magnesium hydroxide and hydrogen with the water reaction.... " (for example with reference to non-patent literature 1) or " magnesium Mg... and high-temperature vapor reaction generate hydrogen ... " (for example with reference to non-patent literature 2).
In addition, the inventor has developed and has made sweet water and magnesium granules react generation hydrogen at normal temperatures, sweet water is become the rich hydrogen water generation method and the rich hydrogen Water generator (for example with reference to patent documentation 1) of hydrogeneous abundant rich hydrogen water.
The great work of (non-patent literature 1) Sakurai [new knowledge of element 111] talk society publishes the 82nd page
(non-patent literature 2) 2002 Japanese publication association volume Japan that broadcast of annual Education seminar lecture chemistry NHKs of NHK senior middle school of Educational TV Service broadcast the 64th page of publication association
(patent documentation 1) spy opens the 2004-41949 communique
Summary of the invention
Existingly utilize electrolytic rich hydrogen Water generator, must use power supply and complex structure, thereby the cost height, can not simply and cheaply provide rich hydrogen water to the human consumer.
In addition, in existing rich hydrogen Water generator, make sweet water and magnesium granules react generation hydrogen at normal temperatures, sweet water is become hydrogeneous abundant rich hydrogen water, have the advantage that can generate hydrogeneous abundant sweet water at normal temperatures simply, but the hydrogeneous abundant sweet water that generates is through producing muddy phenomenon after a few days.
In addition, knownly have a following problem: the water of generation exhales an offensive odor with the stench of similar acetylene or Nicotine.In addition, the box that magnesium granules is housed put into container that sweet water is housed during be more than one month mid-term or when long-term, the throw out that has compounds such as magnesium hydroxide in the container of sweet water is housed more.
The objective of the invention is to address the above problem.
To achieve these goals, the present invention is rich hydrogen water generation method, and this method is to make sweet water and the magnesium granules of having implemented the presintering processing react generation hydrogen at normal temperatures in container, makes sweet water become hydrogeneous abundant rich hydrogen water.
The present invention is rich hydrogen water generation method, and this method is that above-mentioned sintering processes is 10 ± 1 minutes at sintering time, and sintering temperature is to carry out under 110 ± 2 conditions of spending.
The present invention is rich hydrogen water generation method, and this method is that above-mentioned magnesium granules is put into the box that comprises the porous ceramics that inside can water leaking-in.
The present invention is rich hydrogen water generation method, and this method is reacted sweet water and above-mentioned magnesium granules simultaneously with silver-colored particle, by the rich hydrogen water of this silver particulate burning purifying.
The present invention is rich hydrogen Water generator, and this maker can be put into sweet water with in the container, and it possesses the box that inside can water leaking-in and puts into the hollow space of this box, generates hydrogen with the sweet water reaction at normal temperatures and implemented the magnesium granules that presintering is handled.
The present invention is rich hydrogen Water generator, and wherein above-mentioned sintering processes is to be 10 ± 1 minutes at sintering time, and sintering temperature is to carry out under the conditions of 110 ± 2 degree.
The present invention is rich hydrogen Water generator, it is characterized in that: above-mentioned box is a porous ceramics.
The present invention is rich hydrogen Water generator, and this maker is that above-mentioned magnesium granules is housed in above-mentioned box, and the silver-colored particle or other materials with same effect that are used to purify sweet water are housed simultaneously.
The present invention can be simply and effectively common sweet water is become rich hydrogen water, and magnesium granules so can improve or prevent the rich hydrogen water in the container muddiness, stench, throw out takes place through sintering processes.
Description of drawings
[Fig. 1] is the sectional view of rich hydrogen Water generator of the present invention.
[Fig. 2] is general description figure of the present invention.
Nomenclature
1 box
2 rich hydrogen Water generators
3 silver medal particles
4 magnesium granules
5 containers
6 sweet waters
Embodiment
Followingly embodiments of the present invention are elaborated with reference to accompanying drawing.
Among the figure, symbol 1 is bullet (BULLET) the shape box of rich hydrogen Water generator 2, and the cross-sectional shape of its shell is made of elongated tubular porous ceramics.Owing on above-mentioned box 1, be formed with countless apertures, the inside and outside connection of box 1, the liquid box 1 of can freely coming in and going out.The little particle of aperture by than box 1 shell of filling specified amount constitutes in box 1 silver-colored particle 3 or other materials and magnesium granules 4 with identical decontamination effect improving.
The magnesium granules 4 of filling in above-mentioned box 1 is 10 ± 1 minutes at sintering time, and sintering temperature is to implement presintering under 110 ± 2 conditions of spending to handle.
In above-mentioned formation, as shown in Figure 2, will in box 1, fill the rich hydrogen Water generator 2 of silver-colored particle 3 and magnesium granules 4 and put in the container 5 that normal temperature or refrigerative sweet water 6 are housed.After dropping into rich hydrogen Water generator 2, through about 10 minutes, the sweet water 6 in the container 1 purifies with silver-colored particle 5 reactions.Sweet water 6 reacts with magnesium granules 4 simultaneously in addition, generates hydrogen by following reaction formula.
Mg+2H
2O→Mg(OH
2)+
2H→Mg(OH)
2+H
2
It becomes rich hydrogen water when sweet water 6 such as normal temperature in the container 1 or refrigerative tap water is cleaned as a result.Present chemical boundary is consistent to be thought when MAGNESIUM METAL heats and water reaction generation hydrogen, or magnesium and high-temperature vapor reaction generation hydrogen.But, when using simple and easy hydrogen sensor to detect the reaction of magnesium granules of above-mentioned embodiment, confirmed that magnesium all reacts easily at normal temperature (about 25 degree Celsius) or refrigerative water (about 5 degree Celsius), generates the new fact of magnesium hydroxide and hydrogen.
In view of the above, do not use the electrolyzer just can be really and prepare rich hydrogen water cheaply.
By the phenomenon of above-mentioned magnesium granules and water reaction generation hydrogen, the constitute pottery of box spreads out water molecules by ejected electron and far infrared rays effect simultaneously, makes the water activation.This activation capacity to water molecules is the very important fundamental property that pottery has.This performance test judges how many water or oil molecules diminished, and judges bulk of molecule by the frequency shown in the collection of illustrative plates of nuclear magnetic resonance device resonance.
By more untreated water or oil and water or oil, can judge what have diminished by original frequency with ceramic processing.The pottery that uses in the present embodiment obtains the good like this numerical value of 63.9HZ.Make the far infrared radiation coefficient curve of water activatory pottery have the level and smooth curve of ideal.The situation that the pottery that uses in the present embodiment departs from typical curve is few, has realized infinitely near ideal radiation curve characteristic.When the pottery that uses in the present embodiment makes the water activation, generate H
2O
2Aquae hydrogenii dioxidi.
This H
2O
2Aquae hydrogenii dioxidi is promptly so-called to be used as sterilizing agent, its present embodiment in the water that pottery is handled, growing amount is about 2 times of common tap water.This growing amount still has threat to bacterium to human or animal's not infringement fully.In the water of handling with the pottery of present embodiment, cultivate colibacillus, hemorrhagic colibacillus O157, staphylococcus aureus and flooded 48 hours, can reduce 99.6%-99.9%.Just has sterilizing ability by ceramic activatory water like this.In addition, confirmed the pottery in the sweet water also with reactive magnesium, promote to produce hydrogen by magnesium, in sweet water, generate a large amount of hydrogen.
In addition,, when using P.P to be polypropylene, cause allergic reaction sometimes from the polypropylene composition of this box stripping as the material of box 1, but as present embodiment when using pottery, pottery can not cause allergic reaction, so can eliminate anaphylaxis.As above-mentioned, pottery can make the water activation, have anti-microbial effect when promoting to generate hydrogen, can generate rich hydrogen water.
When having confirmed that magnesium granules do not implemented sintering processes, magnesium granules is dropped in the water, carry out the generation of rich hydrogen water, muddiness has taken place through water after a few days.Show that in addition the water of generation exhales an offensive odor with the stench of similar acetylene or Nicotine.And then, be contained in magnesium granules in the box put into container that water is housed during be more than one month mid-term or when long-term, can see the throw out of compound such as magnesium hydroxide more than being equipped with in the container of water.
In contrast, confirmed the following fact: when magnesium granules is implemented sintering processes, can improve water above-mentioned muddiness, foul smell, throw out take place.Confirm in addition, under these conditions, when in advance magnesium granules being implemented sintering processes, improve particular significant effect, muddiness or foul smell do not take place.Also confirm, even be contained under these conditions magnesium granules in the box put into container that water is housed during more than one month mid-term or do not have sedimentary generation for a long time the time yet.But when being implemented sintering processes, also improved between the usage period of magnesium granules magnesium granules.Confirm that especially the sintering magnesium granules that satisfies above-mentioned condition can generate competent hydrogen at least continuously more than 6 months.In addition, the not specific box that is made of porous ceramics that is defined in of the present invention can use boxes such as plastics, stainless steel.
Claims (8)
1. a rich hydrogen water generation method is characterized in that: make the magnesium granules of sweet water and enforcement presintering processing react generation hydrogen at normal temperatures in container, make sweet water become hydrogeneous abundant rich hydrogen water.
2. rich hydrogen water generation method as claimed in claim 1, it is characterized in that: above-mentioned sintering processes is 10 ± 1 minutes at sintering time, sintering temperature is to carry out under 110 ± 2 conditions of spending.
3. rich hydrogen water generation method as claimed in claim 1 or 2 is characterized in that: with above-mentioned magnesium granules put into can water leaking-in by inside the box that constitutes of porous ceramics.
4. rich hydrogen water generation method as claimed in claim 1 or 2 is characterized in that: make the reaction of sweet water and above-mentioned magnesium granules and silver-colored particle, by the rich hydrogen water of this silver particulate burning purifying.
5. rich hydrogen Water generator, it is characterized in that: this maker can be put into sweet water with in the container, and it possesses the box that inside can water leaking-in and puts into the hollow space of this box, generates hydrogen and implement the magnesium granules that presintering is handled with the sweet water reaction at normal temperatures.
6. rich hydrogen Water generator as claimed in claim 5 is characterized in that: above-mentioned sintering processes is 10 ± 1 minutes at sintering time, and sintering temperature is to carry out under 110 ± 2 conditions of spending.
7. rich hydrogen Water generator as claimed in claim 5, it is characterized in that: above-mentioned box is a porous ceramics.
8. as claim 5 or 6 described rich hydrogen Water generators, it is characterized in that: when above-mentioned magnesium granules is housed the silver-colored particle that is used to purify sweet water is housed in above-mentioned box.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP105820/05 | 2005-04-01 | ||
| JP2005105820A JP4642530B2 (en) | 2005-04-01 | 2005-04-01 | Hydrogen-rich water production method and hydrogen-rich water generator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1840487A CN1840487A (en) | 2006-10-04 |
| CN100579919C true CN100579919C (en) | 2010-01-13 |
Family
ID=37029721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200510068852A Expired - Fee Related CN100579919C (en) | 2005-04-01 | 2005-05-12 | Method and apparatus for generating hydrogen-enriched water |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4642530B2 (en) |
| CN (1) | CN100579919C (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007167696A (en) * | 2005-11-22 | 2007-07-05 | Hidemitsu Hayashi | Method and material for modifying drinking water |
| JP5664952B2 (en) * | 2010-06-11 | 2015-02-04 | 株式会社長野セラミックス | Reduced water generator |
| JP4652479B1 (en) | 2010-07-14 | 2011-03-16 | ミズ株式会社 | Selective hydrogenation device for biological fluids |
| CN102730895A (en) * | 2011-04-11 | 2012-10-17 | 吴全海 | Household hydrogen-rich water production device |
| CN102259939B (en) * | 2011-06-27 | 2013-03-06 | 张会艳 | Efficient method for generating hydrogen-rich water |
| JP4950352B1 (en) * | 2011-07-15 | 2012-06-13 | ミズ株式会社 | Selective hydrogenation device for biological fluids |
| KR101320463B1 (en) * | 2011-12-23 | 2013-10-23 | 주식회사 아루이 | Apparatus for manufacturing hydrogen water |
| CN102557227B (en) * | 2012-03-12 | 2013-10-09 | 彭振业 | Additive of calcium magnesium hydrogen-rich water and preparation method of additive |
| CN102697279A (en) * | 2012-06-14 | 2012-10-03 | 王美岭 | Drinking water bottle capable of generating hydrogen rich water |
| JP6028182B2 (en) | 2012-07-06 | 2016-11-16 | 株式会社光未来 | Hydrogen gas sealing bag and method for dissolving hydrogen gas |
| JP5914306B2 (en) * | 2012-11-30 | 2016-05-11 | 皓士 大田 | Vessel with hydrogen generation function and hydrogen addition method |
| CN103919234B (en) * | 2014-04-30 | 2016-05-18 | 苏州驰亚机电科技股份有限公司 | A kind of rich hydrogen method for preparing beverage and equipment |
| CN107001082B (en) * | 2014-10-17 | 2018-03-16 | 竹原隆 | Hydrogen injection device |
| CN104710065B (en) * | 2015-03-20 | 2017-01-18 | 许永堂 | Portable active hydrogen water machine |
| JP6551741B2 (en) * | 2015-10-19 | 2019-07-31 | 株式会社アカネ | Hydrogen generator |
| CN107758828A (en) * | 2016-08-19 | 2018-03-06 | 东莞市八佰伴百货有限公司 | Hydrogen-rich hydrogenesis machine and the method for accelerating generation |
| CN106865728B (en) * | 2017-03-14 | 2019-07-19 | 东莞市年氢态食品科技有限公司 | A kind of hydrogen-rich water manufacturing method and equipment |
| CN110872183A (en) * | 2018-09-03 | 2020-03-10 | 上海安娜奥环境科技有限公司 | Ceramic ball capable of rapidly producing hydrogen in water without external force and preparation method thereof |
| CN109806469A (en) * | 2019-02-26 | 2019-05-28 | 西安交通大学医学院第一附属医院 | A kind of medical hydrogen-rich atomising device |
| CN110357183B (en) * | 2019-08-09 | 2021-11-23 | 珠海品源绿色健康产业发展有限公司 | Synthesis method of hydrogen-rich water ceramic filter element |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11319810A (en) * | 1998-05-19 | 1999-11-24 | Kanai Hiroaki | Apparatus for improving water quality |
| JP2002360424A (en) * | 2001-06-13 | 2002-12-17 | Matsushita Electric Ind Co Ltd | Electric water heater |
| JP2004041949A (en) * | 2002-07-12 | 2004-02-12 | Hidemitsu Hayashi | Hydrogen enriched water-forming method and hydrogen enriched water maker |
| JP3973152B2 (en) * | 2002-11-25 | 2007-09-12 | 有限会社善玉倶楽部 | Structure for producing high hydrogen concentration water |
| JP2004243151A (en) * | 2003-02-10 | 2004-09-02 | Yoshiro Tanaka | Hydrogen-dissolved water making appliance |
-
2005
- 2005-04-01 JP JP2005105820A patent/JP4642530B2/en active Active
- 2005-05-12 CN CN200510068852A patent/CN100579919C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006281119A (en) | 2006-10-19 |
| CN1840487A (en) | 2006-10-04 |
| JP4642530B2 (en) | 2011-03-02 |
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Owner name: LIN XIANSI Free format text: FORMER OWNER: LIN XIUGUANG Effective date: 20131220 |
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Effective date of registration: 20131220 Address after: Hyogo Takarazuka City Patentee after: Lin Xiansi Patentee after: Daimaru Chisato Address before: Tokyo, Japan, Japan Patentee before: Lin Xiuguang Patentee before: Daimaru Chisato |
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Granted publication date: 20100113 Termination date: 20190512 |