CN100575464C - Coal-saving synergist dedicated for shaft kiln - Google Patents

Coal-saving synergist dedicated for shaft kiln Download PDF

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Publication number
CN100575464C
CN100575464C CN200610137000A CN200610137000A CN100575464C CN 100575464 C CN100575464 C CN 100575464C CN 200610137000 A CN200610137000 A CN 200610137000A CN 200610137000 A CN200610137000 A CN 200610137000A CN 100575464 C CN100575464 C CN 100575464C
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China
Prior art keywords
coal
shaft kiln
saving
improve
synergist
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Expired - Fee Related
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CN200610137000A
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Chinese (zh)
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CN1995298A (en
Inventor
王秀贵
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Individual
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Individual
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Priority to CN200610137000A priority Critical patent/CN100575464C/en
Publication of CN1995298A publication Critical patent/CN1995298A/en
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Publication of CN100575464C publication Critical patent/CN100575464C/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses a kind of coal-saving synergist dedicated for shaft kiln, it adopts following component and consumption (weight %): potassium permanganate 2.5-4.5%; Saltpetre 1.5-3.5%; Ammonium nitrate 0.5-2.0%; Sodium-chlor 90.0-95.0%.After in cement slurry, adding coal-saving synergist of the present invention, can improve the coal calorific value more than 20%, coal saving rate 10-25%; Make 28 days ultimate compression strength of shaft kiln clinker improve 2-3MPa; Improve shaft kiln unit-hour output 8-10%; Reduce obnoxious flavour and smoke discharge amount 60-80%; Improve the grindability of grog.

Description

Coal-saving synergist dedicated for shaft kiln
Technical field
The invention belongs to additive for solid fuel, be specifically related to a kind of coal-saving synergist that is used for cement in vertical kiln.
Background technology
At present China's cement production enterprise mostly adopts and add composite mineralizer (fluorite adds gypsum) in raw material aspect energy-conservation, and effect of coal saving is not obvious, only plays mineralization.The producer that has adopts yellow phosphorus slag phosphogypsum, and effect of coal saving is also not obvious.The producer that also has adopts simple coal-saving agent (the ripe burning agent of so-called raw material)----potassium permanganate to add sodium-chlor and join fluorite etc. again, and their effect of coal saving is undesirable equally. and be considered to cost height (raw material per ton increase about 4 yuan cost) always.
Summary of the invention
The objective of the invention is problem, provide a kind of effect of coal saving good coal-saving synergist at the prior art existence.
The present invention seeks to be achieved through the following technical solutions:
Coal-saving synergist adopts following main ingredient and consumption (weight %):
Potassium permanganate 2.5-4.5%;
Saltpetre 1.5-3.5%;
Ammonium nitrate 0.5-2.0%;
Sodium-chlor 90.0-95.0%.
The effect of coal-saving synergist mainly is the combustion-supporting of coal.It is added to when burning in the raw material, and potassium permanganate, saltpetre and ammonium nitrate all can discharge oxygen, impel coal fully to burn, to reach the purpose of economizing on coal.Different components discharges stage of oxygen in coal combustion process different, begins to decompose at 200 ℃ as ammonium nitrate, and saltpetre begins to decompose at 350-450 ℃, and potassium permanganate then begins to decompose at 200-300 ℃.Each stage in the time of so just can making coal combustion all has additive to discharge oxygen, guarantees the abundant burning of coal to greatest extent.Sodium-chlor mainly as carrier, is made swelling agent and properties-correcting agent simultaneously.
Coal-saving synergist of the present invention can also increase some accessory constituents and become another prescription on the basis of said components, to obtain better effect of coal saving.This prescription adopts following component and consumption (weight %):
Potassium permanganate 2.5-3%;
Saltpetre 1.5-2.5%;
Ammonium nitrate 0.5-1.0%;
Sodium-chlor 80.0-85.0%;
Unslaked lime 2.0-6.5%;
Potassium perchlorate 1.5-2.5%;
Red iron oxide 1.0-2.5%;
Potcrate 1.0-2.0%.
In the said components, unslaked lime is used for solid sulphur, and potassium perchlorate begins to decompose at 400-600 ℃, discharges comburant oxygen, and red iron oxide is used for the adjusting that component discharges amount of oxygen, and Potcrate is used as swelling agent, and discharges comburant oxygens at 400 ℃.
The making of coal-saving synergist is very simple, and a need is determined concrete prescription according to the user's with the coal situation, and various components are mixed, and packing gets final product.
Can be during use according to the difference of coal, add coal-saving synergist of the present invention by the 0.02-0.05% of raw material.
The characteristics of coal-saving synergist of the present invention comprise:
1). can change the combustion system of original raw material, by peel off formula burning become inside and outside burning together;
2). improve the after-flame degree of fugitive constituent in the coal;
3). reduce the thermosteresis of interior chemical incomplete combustion of shaft kiln kiln and mechanical incomplete combustion;
4). the heat energy component in the perfect combustion raw material;
5) Gu. sulphur, reduce the influence of pollution substance to environment.
Result of use: after in raw material, adding coal-saving synergist of the present invention, can improve the coal calorific value more than 20%, coal saving rate 10-25%; Make 28 days ultimate compression strength of shaft kiln clinker improve 2-3MPa; Improve shaft kiln unit-hour output 8-10%; Reduce obnoxious flavour and smoke discharge amount 60-80%; Improve the grindability of grog.
Embodiment
Embodiment 1
A prescription: potassium permanganate 3.0kg+ saltpetre 2.5kg+ ammonium nitrate 1kg+ unslaked lime 6.5kg+ oxidation iron oxide red 2kg+ sodium-chlor 83kg+ Potcrate 2kg=100kg
Embodiment 2
B prescription: potassium permanganate 3.5kg+ saltpetre 2.5kg+ ammonium nitrate 1kg+ sodium-chlor 93kg=100kg
Application example
1). Sichuan wyls company: (A prescription addition press cement slurry 0.02%)
Raw material are joined heat: 560*4.18KJ/kg drops to 450*4.18KJ/kg
Output: 9.5 tons/hour are raised to 11.7 tons/hour
Intensity: 3d 21MPa-25MPa is increased to 28MPa-32MPa.,
28d 48MPa-52MPa is increased to 55MPa-58MPa.
2). Gansu jqqfjh company: (A prescription addition press cement slurry 0.04%)
Raw material are joined heat: 850*4.18KJ/kg drops to 650*4.18KJ/kg
Output: 11 tons/hour are raised to 13.7 tons/hour.
Intensity: 3d 20MPa-22MPa is increased to 26MPa-29MPa.,
28d 48MPa-50MPa is increased to 53MPa-56MPa.
3). Longyan, Fujian ty factory (A prescription addition press cement slurry 0.03%)
Raw material are joined heat: 528*4.18KJ/kg drops to 444*4.18KJ/kg
Output: 8.5 tons/hour are raised to 11.2 tons/hour.
Intensity: 3d 20MPa-22MPa is increased to 24MPa-28MPa.
28d 48MPa-50MPa is increased to 55MPa-58MPa.
4). Guangdong sgsj factory (A prescription addition is pressed the 0.03-0.05% of cement slurry)
Raw material are joined heat: 600*4.18KJ/kg drops to 520*4.18KJ/kg
Output: 13 tons/hour are raised to 14.7 tons/hour.
Intensity: 3d 22MPa-25MPa is increased to 228MPa-30MPa.
28d 48MPa-50MPa is increased to 56MPa-58MPa.
Above situation explanation coal-saving synergist of the present invention can be used for low grade coal, bone coal at the shaft kiln calcination of cement clinker, and cost is low, is worth high.

Claims (2)

1, a kind of shaft kiln private section coal additive is characterized in that adopting following component and consumption (weight %):
Potassium permanganate 2.5-4.5%;
Saltpetre 1.5-3.5%;
Ammonium nitrate 0.5-2.0%;
Sodium-chlor 90.0-95.0%.
2, a kind of shaft kiln private section coal additive is characterized in that adopting following component and consumption (weight %):
Potassium permanganate 2.5-3%;
Saltpetre 1.5-2.5%;
Ammonium nitrate 0.5-1.0%;
Sodium-chlor 80.0-85.0%;
Unslaked lime 2.0-6.5%;
Potassium perchlorate 1.5-2.5%;
Red iron oxide 1.0-2.5%;
Potcrate 1.0-2.0%.
CN200610137000A 2006-12-30 2006-12-30 Coal-saving synergist dedicated for shaft kiln Expired - Fee Related CN100575464C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200610137000A CN100575464C (en) 2006-12-30 2006-12-30 Coal-saving synergist dedicated for shaft kiln

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200610137000A CN100575464C (en) 2006-12-30 2006-12-30 Coal-saving synergist dedicated for shaft kiln

Publications (2)

Publication Number Publication Date
CN1995298A CN1995298A (en) 2007-07-11
CN100575464C true CN100575464C (en) 2009-12-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN200610137000A Expired - Fee Related CN100575464C (en) 2006-12-30 2006-12-30 Coal-saving synergist dedicated for shaft kiln

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CN (1) CN100575464C (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805653A (en) * 2009-02-16 2010-08-18 李欣柏 XB type coal saving agent
CN105733738A (en) * 2016-04-29 2016-07-06 无锡锡能锅炉有限公司 Pulverized coal fired boiler decoking agent
CN106047433A (en) * 2016-05-27 2016-10-26 北京奥洁鼎森新能源科技有限公司 Briquette coal for food service industry and method for producing briquette coal
CN106085538A (en) * 2016-06-28 2016-11-09 天津大乘常盛新能源科技有限公司 Environment-protecting civil clean moulded coal and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
燃煤助燃剂及配方原理. 缪娟.焦作矿业学院学报,第14卷第4期. 1995
燃煤助燃剂及配方原理. 缪娟.焦作矿业学院学报,第14卷第4期. 1995 *

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GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Changsha Bao Bao building materials additives Co., Ltd.

Assignor: Wang Xiugui

Contract record no.: 2010430000081

Denomination of invention: Coal-saving synergist dedicated for shaft kiln

Granted publication date: 20091230

License type: Exclusive License

Open date: 20070711

Record date: 20100726

DD01 Delivery of document by public notice

Addressee: Wang Xiugui

Document name: Notification that Application Deemed not to be Proposed

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091230

Termination date: 20151230

EXPY Termination of patent right or utility model