CN100569929C - Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof - Google Patents
Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof Download PDFInfo
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- CN100569929C CN100569929C CNB2007100705977A CN200710070597A CN100569929C CN 100569929 C CN100569929 C CN 100569929C CN B2007100705977 A CNB2007100705977 A CN B2007100705977A CN 200710070597 A CN200710070597 A CN 200710070597A CN 100569929 C CN100569929 C CN 100569929C
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Abstract
The invention discloses a kind of automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof.It with weight percent earlier the synthetic pipeline of coal-based methanol input of 15-50%, be the emulsifying agent of 1.5-10% again with weight percent, the interpolation properties-correcting agent of 1.5-10%, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 5-20 minute, adding weight percent is the gasoline of 45-80%, and the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 15-30 minute.Clean environment firendly synthetic gasoline of the present invention, combustionvelocity is fast, heat release is rapid, contain oxygen rate height, burning is clean fully, the heat release rate height, can not cause burn into keyword to engine fuel system, the pollutent that motor vehicle exhaust goes out also reduces greatly, is a kind of new environment-friend substitution energy of China's national situation, has not only cleaned but also environmental protection.
Description
Technical field
The present invention relates to substitute energy, relate in particular to a kind of automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof.
Background technology
Since the reform and opening-up, Chinese national economy constantly develops, automotive industry and other, industry is the same, the production and marketing excellent situation, more and more prosperous, year consumption gasoline reaches more than 200,000,000 tons at present, and a year input reaches 7,000 ten thousand tons, processed oil, year import volume, more than more than 3,000 ten thousand tons, under the huge pressure of demand consumption, Chinese energy safety has become a serious difficult problem, and everything urgent need will be sought new substitute energy, the end of last year, State Council's meeting, point out in the working conference of researchdevelopment substitute energy: currently will give priority to fuel oil for vehicles and alternative petroleum products, do well, coal, liquefaction, coal system methyl alcohol, products such as dme are to imitate good outlet with coal system methyl alcohol.
Summary of the invention
The purpose of this invention is to provide a kind of automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof.
Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline is characterized in that component by weight percentage is:
Gasoline 45-80%,
Coal-based methanol 15-50%,
Emulsifying agent 1.5-10%,
Add auxiliary agent 1.5-10%.
The preparation method of automobile-used environmental protection, low emission, coal-based alcohol ether gasoline is to be earlier the synthetic pipeline of coal-based methanol input of 15-50% with weight percent, be the emulsifying agent of 1.5-10% again with weight percent, the interpolation properties-correcting agent of 1.5-10%, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 5-20 minute, adding weight percent is the gasoline of 45-80%, the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 15-30 minute.
The present invention with coal-based methanol and additive micro-emulsifier by modification, mix synthetic by a certain percentage with gasoline, coal-based methanol gasoline, it can directly replace, regular gasoline, the nervous situation of alleviation gasoline, coal-based methanol gasoline combustion safety simultaneously, good environment protection emission effect is arranged, and its application prospect is very good.Do not change at the vehicle motor that travels under the situation of any parts in addition, the synthetic coal-based methanol gasoline of the present invention of annotating can mix use immediately, can obtain huge social benefit and economic benefit.
Clean environment firendly synthetic gasoline of the present invention, combustionvelocity is fast, heat release is rapid, contain oxygen rate height, burning is clean fully, the heat release rate height, can not cause burn into keyword to engine fuel system, motor vehicle exhaust (hydrocarbon polymer, carbon monoxide, carbonic acid gas, oxynitride, sulfide etc.) is poisonous, objectionable impurities is significantly less than emission standard, has reached European standard in the detection of aromatic hydrocarbons, alkene, near the standard of Europe VI.Be a kind of new environment-friend substitution energy of China's national situation, promptly clean and environmental protection.
Embodiment
The present invention is with coal-based methanol, the component of single molecular structure and interpolation auxiliary agent micro-emulsifier, organic synthesis modification, the performance of higly branched chain is more comprehensively arranged, the material of characteristics isomery alcohol ether, acid amides, alkylphenol, fully in conjunction with, microemulsified and infiltration and dissolve, at high temperature have very wide boiling point (in case vapour lock) at low temperatures, be difficult for layering, bigger molten water-based arranged meeting moisture content, under the effect of microemulsified, surface tension is all practised and is reached standard-required, so characteristics clearly, combination is optimized very much.Be a kind of octane value rich oxygen content foot, surface tension, all practise, burn fully, make engine strengthen power.
In-engine combustion processes all is that aerobic participates in, and (molecule has paramagnetic, character to oxygen, produces the inducedmagnetic field consistent with field direction under the effect in magnetic field.
The energy level generation transition of oxygen molecule, be in higher energy state, and its reactive behavior is strengthened, nucleus in some fuel molecule is rotating, have specific spin states, under the effect of externally-applied magnetic field, the nucleus of spin just has certain stable orientations, and these nucleus that are orientated spin in magnetic field can resonate under specific absorption frequency after being subjected to electromagnetic radiation.Be energized into high energy state orientation from the low-energy state orientation.
Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline is characterized in that component by weight percentage is:
Gasoline 45-80%,
Coal-based methanol 15-50%,
Emulsifying agent 1.5-10%,
Add auxiliary agent 1.5-10%.
Component by weight percentage is preferably:
Gasoline 65-80%,
Coal-based methanol 15-30%,
Emulsifying agent 1.5-8%,
Add auxiliary agent 1.0-10%.
The component of described interpolation auxiliary agent weight percent meter is:
Tert amyl methyl ether(TAME) 30-45%
Diisopropyl ether 15-35%
Cyclopentadiene tricarbonyl manganese 0.1-0.01%
Iso-pentane 5-30%
Benzotriazole 0.5-8%
2,6---ditertbutylparacresol 0.1-1.0%
Described emulsifying agent component by weight percentage is:
Dimethyl formamide 20-40%
Fatty alcohol-polyoxyethylene ether 15-35%
Isomery alcohol and ethylene oxide condensate 10-30%
Alkylphenol and ethylene oxide condensate 5-30%.
The preparation method of automobile-used environmental protection, low emission, coal-based alcohol ether gasoline is to be earlier the synthetic pipeline of coal-based methanol input of 15-50% with weight percent, be the emulsifying agent of 1.5-10% again with weight percent, the interpolation auxiliary agent of 1.5-10%, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 5-20 minute, adding weight percent is the base gasoline of 45-80%, the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 15-30 minute.Enter the proofing unit jar, to be detectedly enter the finished product jar after qualified.
Embodiment 1
Elder generation is 15% the synthetic pipeline of coal-based methanol input with weight percent, be 1.5% emulsifying agent again with weight percent, 1.5% interpolation auxiliary agent, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 5 minutes, the adding weight percent is 45% gasoline, and the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 15 minutes.
By weight percentage, add 30% tert amyl methyl ether(TAME), 15% diisopropyl ether, 0.1% cyclopentadiene tricarbonyl manganese, 5% iso-pentane, 0.5% benzotriazole, 0.1% 2,6---ditertbutylparacresol stirs the companion evenly, makes the interpolation auxiliary agent.
By weight percentage, add 20% dimethyl formamide, 15% fatty alcohol-polyoxyethylene ether, 10% isomery alcohol and ethylene oxide condensate, 5% alkylphenol stirs the companion evenly with ethylene oxide condensate, the big emulsifying agent that gets
Embodiment 2
Elder generation is 50% the synthetic pipeline of coal-based methanol input with weight percent, be 10% emulsifying agent again with weight percent, 10% interpolation auxiliary agent, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 20 minutes, the adding weight percent is 80% gasoline, and the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 30 minutes.
By weight percentage, add 45% tert amyl methyl ether(TAME), 35% diisopropyl ether, 0.01% cyclopentadiene tricarbonyl manganese, 30% iso-pentane, 8% benzotriazole, 1.0% 2,6---ditertbutylparacresol stirs the companion evenly, makes the interpolation auxiliary agent.
By weight percentage, adding 40% dimethyl formamide, 35% fatty alcohol-polyoxyethylene ether, 30% isomery alcohol and ethylene oxide condensate, 30% alkylphenol and ethylene oxide condensate, to stir the companion even, makes emulsifying agent.
Embodiment 3
Elder generation is 15% the synthetic pipeline of coal-based methanol input with weight percent, be 1.5% emulsifying agent again with weight percent, 1.0% interpolation auxiliary agent, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 10 minutes, the adding weight percent is 65% gasoline, and the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 20 minutes.
Embodiment 4
Elder generation is 30% the synthetic pipeline of coal-based methanol input with weight percent, be 8% emulsifying agent again with weight percent, 10% interpolation auxiliary agent, the synthetic pipeline of input simultaneously, pass through static mixer, magnetic resonance gatherer synthesis modification again after 15 minutes, the adding weight percent is 80% gasoline, and the synthetic pipeline of input simultaneously is again through mixing clipper, the mixing of magnetic resonance gatherer 25 minutes.
Embodiment 5
Get 150 kilograms of coal-based methanols, 850 kilograms in 90# gasoline, 6 kilograms of synthetic emulsifiers, the synthetic auxiliary agent that adds passes through method for preparing for 9 kilograms.
Implementation column 6
Get 300 kilograms of coal-based methanols, 700 kilograms in 90# gasoline, synthetic emulsifier, 15 kilograms, the synthetic auxiliary agent that adds passes through method for preparing for 25 kilograms.
Embodiment 7
Get 500 kilograms of coal-based methanols, 90# gasoline, 500 kilograms, 25 kilograms of synthetic emulsifiers, the synthetic auxiliary agent that adds passes through method for preparing for 35 kilograms.
Embodiment 8
Get coal-based methanol, 650 kilograms, 350 kilograms in 90# gasoline, 30 kilograms of synthetic emulsifiers synthetic add auxiliary agent and pass through method for preparing for 45 kilograms.
Embodiment 9
Get 800 kilograms of coal-based methanols, 200 kilograms in 900# gasoline, 45 kilograms of synthetic emulsifiers, the synthetic auxiliary agent that adds passes through method for preparing for 55 kilograms.
The present invention uses by the longer-term industrialization, in practice, adjusts production technique and prescription repeatedly.Develop the practical technique scheme of science; many advantages are arranged; industrialization is produced the back public vehicles in batches and is used coal-based environment friendly fuel; become the fuel of automobile, pollution emission is compared with gasoline during gasoline, reduces about 50%; the title that green energy resource is arranged; fully develop talents to preserving the ecological environment,, significantly reduce atmospheric greenhouse effect.Also be to the mankind, the problem of ozonosphere is made huge contribution.
Use synthetic gasoline and regular gasoline exhaust emissions feelings synopsis as follows
| CO％ | HC(PPM) | |
| Present standard GB 14761.5-93 | 3.5 | 900 |
| Use coal-based alcohol ether synthetic gasoline test result | 0.57 | 68 |
| With national standard contrast (%) | Descend 98.4 | Descend 98.2 |
| Same automotive test contrast (%) | Descend 55.2 | Descend 45.2 |
The alkene aromaticity content detects and European motor spirit standard
| Automobile emissions standards | Europe III number | Europe VI number | Synthetic oil |
| Aromaticity content % | 42 | 35 | 36 |
| Olefin(e) centent % | 20 | 18 | 10 |
From correlation data with near Europe IV standard, so reached international advanced emission standard.
Lotus characteristic simultaneous test data outside engine BJ4910E petrol motor
By above data the present invention coal-based alcohol ether gasoline being had fine promotion prospect, is the effective state basic policy of China's substitute energy.
Claims (4)
1. an automobile-used environmental protection, low emission, coal-based alcohol ether gasoline is characterized in that component by weight percentage is:
Gasoline 45-80%,
Coal-based methanol 15-50%,
Emulsifying agent 1.5-10%,
Add auxiliary agent 1.5-10%
The component of described interpolation auxiliary agent weight percent meter is:
Tert amyl methyl ether(TAME) 30-45%
Diisopropyl ether 15-35%
Cyclopentadiene tricarbonyl manganese 0.1-0.01%
Iso-pentane 5-30%
Benzotriazole 0.5-8%
26-ditertbutylparacresol 0.1-1.0%.
2. a kind of automobile-used environmental protection according to claim 1, low emission, coal-based alcohol ether gasoline is characterized in that component by weight percentage is:
Gasoline 65-80%,
Coal-based methanol 15-30%,
Emulsifying agent 1.5-8%,
Add auxiliary agent 1.0-10%
The component of described interpolation auxiliary agent weight percent meter is:
Tert amyl methyl ether(TAME) 30-45%
Diisopropyl ether 15-35%
Cyclopentadiene tricarbonyl manganese 0.1-0.01%
Iso-pentane 5-30%
Benzotriazole 0.5-8%
26-ditertbutylparacresol 0.1-1.0%.
3. a kind of automobile-used environmental protection according to claim 1, low emission, coal-based alcohol ether gasoline is characterized in that described emulsifying agent component by weight percentage is:
Dimethyl formamide 20-40%
Fatty alcohol-polyoxyethylene ether 15-35%
Isomery alcohol and ethylene oxide condensate 10-30%
Alkylphenol and ethylene oxide condensate 5-30%.
4. a kind of automobile-used environmental protection as claimed in claim 1, low emission, the preparation method of coal-based alcohol ether gasoline, it is characterized in that, it with weight percent earlier the synthetic pipeline of coal-based methanol input of 15-50%, be the emulsifying agent of 1.5-10% again with weight percent, the interpolation auxiliary agent of 1.5-10%, the synthetic pipeline of input simultaneously, pass through static mixer again, magnetic resonance gatherer synthesis modification is after 5-20 minute, adding weight percent is the base gasoline of 45-80%, the synthetic pipeline of input simultaneously is again through mixing clipper, magnetic resonance gatherer mixing 15-30 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100705977A CN100569929C (en) | 2007-09-04 | 2007-09-04 | Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100705977A CN100569929C (en) | 2007-09-04 | 2007-09-04 | Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN101113376A CN101113376A (en) | 2008-01-30 |
| CN100569929C true CN100569929C (en) | 2009-12-16 |
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| CNB2007100705977A Expired - Fee Related CN100569929C (en) | 2007-09-04 | 2007-09-04 | Automobile-used environmental protection, low emission, coal-based alcohol ether gasoline and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115681B (en) * | 2010-01-05 | 2013-08-21 | 张玉平 | Low-carbon liquefied gas and preparation method thereof |
| CN102585932B (en) * | 2011-12-29 | 2013-12-11 | 北京东方红升新能源应用技术研究院有限公司 | Compound additive for methanol gasoline, and preparation method and application thereof |
| CN105879802A (en) * | 2014-09-24 | 2016-08-24 | 深圳市中新能环保科技有限公司 | Preparation process of high-energy clean gasoline |
| CN106221823A (en) * | 2016-09-30 | 2016-12-14 | 广西东奇能源技术有限公司 | The vehicle fuel of low exhaust gas discharge capacity |
| CN108929727A (en) * | 2018-07-18 | 2018-12-04 | 宁波蒙曼生物科技有限公司 | A kind of coal-based methanol gasoline and its preparation method and application of environment-friendly type purifying |
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