CN100558467C - A kind of beneficiation method that improves brown iron ore grade - Google Patents
A kind of beneficiation method that improves brown iron ore grade Download PDFInfo
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- CN100558467C CN100558467C CNB2007100267578A CN200710026757A CN100558467C CN 100558467 C CN100558467 C CN 100558467C CN B2007100267578 A CNB2007100267578 A CN B2007100267578A CN 200710026757 A CN200710026757 A CN 200710026757A CN 100558467 C CN100558467 C CN 100558467C
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Abstract
The present invention relates to the beneficiation method of ferrous metal, relate in particular to the beneficiation method that a kind of difficulty is selected limonite, it comprises the following steps: that a. uses ball mill, spiral classifier and high frequency shale shaker in conjunction with ore grinding; B. gravity treatment: roughly select, selected, recleaning; C. reverse flotation obtains high-grade limonite concentrate.The present invention adopts gravity treatment to add reverse floatation process, and flow process is simple, and power consumption is less, and cost is low, is applicable to the ore dressing plant of producing 100000 tons of left and right sides limonite concentrate per year; In the ore grinding step, in traditional ball mill and spiral classifier combination, add high frequency shale shaker, it is simple to operate, but can effectively improve classification efficiency, makes classification efficiency improve more than 30%; Increased recleaning in addition, the clay content of ore pulp can have been dropped to below 5%, the iron ore grade improves 2～3 degree; And, first desliming before reverse flotation, thus the influence of sludge eliminated, reduced reagent consumption.
Description
[technical field]
The present invention relates to the beneficiation method of ferrous metal, relate in particular to the beneficiation method that a kind of difficulty is selected limonite.
[background technology]
Limonite is oxidizing aqueous iron ore, and by generating after other ore weathering, it is very extensive to distribute in Northern Guangdong Province, but big actually rare of mineral deposit reserve.Its chemical formula is nFe
2O
3MH
2O (n=1～3, m=1～4).Limonite is actually by goethite (Fe
2O
3H
2O), liquid drugs injection iron ore (2Fe
2O
3H
2O) form with the mixture of iron oxide that contains the different crystallizations water and shale material.Most iron-bearing minerals are with 2Fe in the limonite
2O
3H
2The O form exists.
The limonite clay content is big, disseminated grain size is thin, easy argillization, main gangue part is the silica of easy collecting, is weak magnetic mineral, and sorting with general magnetic separator does not have effect substantially, rely on present high gradient intensity magnetic separator can carry out enrichment, but adsorbed in the lump owing to often contain iron content silicate mineral (as garnet, aegirine etc.) in the gangue, cause concentrate grade on the low side, must be use up the processing in a step.Because the characteristic of limonite easy argillization in grinding process causes mineral particles all to be difficult for being adsorbed in high-intensity magnetic field, and quite a few metal is drained with mine tailing, cause choosing than high again, the rate of recovery is low.
At present, the most frequently used high intensity magnetic separation method in the beneficiation method of limonite, the ore dressing effect is not ideal, and reason mainly contains the following aspects:
1, grinding particle size control is bad
Limonite this as easy argillization mineral, argillization very easily in grinding process, and the limonite particulate after the argillization is not high with various beneficiation methods recovery productive rates.Part gangue in the ore combines closely with the limonite particulate on the other hand, is not ground into corresponding particle size fraction and is difficult to realize monomer separation.
The present traditional grinding grading technique that uses ball mill to combine with spiral classifier, it is simple ripe and effective using in the production process of magnetic iron ore and part bloodstone, but in the ore grinding of limonite and classification process because the restriction of classification efficiency, be very easy to produce mineral and cross and pulverize and pulverize two kinds of situations not in place, be necessary to match and form new grind grading flow process and improve with other classifying equipoments.
2, desliming flow process metal loss is big
The many desliming technologies that adopt are directly used in limonite production at present many drawbacks, as goes into the log washer desliming operation before the mill, in flush away part sludge, also makes many limonite particle loss in thin mud.Through actual sample examination, the iron grade of sludge is substantially all at more than 80% of raw ore iron grade, some sludge sample ore iron grade even identical with raw ore iron grade, and metal loss is very big.
Desliming behind the ore grinding such as hydrocyclone desliming technology can remove most of sludge, but compare with log washer desliming operation identical shortcoming is arranged: the limonite metal particle after the argillization is too thin because of granularity, is discharged by overfall with sludge basically.
3, concentrate grade is low
High gradient magnetic separator has very high recovery ability to the limonite of weak magnetic, but in the limonite often symbiosis the iron content silicate mineral is arranged, strong magnetic machine also adsorbs recovery with the iron content silicate mineral in the lump when reclaiming limonite, cause the grade of iron ore concentrate on the low side.
[summary of the invention]
In order to overcome the prior art deficiency, a kind of beneficiation method that improves brown iron ore grade is provided, can effectively control grinding particle size, reduce the desliming metal loss, improve concentrate and tailings grade, and flow process is simple, with low cost, being suitable on a small scale, ore deposit factory selects for use.
A kind of beneficiation method that improves brown iron ore grade of the present invention may further comprise the steps:
(1), ore grinding
The limonite crushing raw ore to-3mm, is gone into that ball mill is levigate to account for 96%～99% to-200 orders, and pulp density is 50%～60%, then through spiral classifier classification overflow, enters-200 purpose high frequency shale shakers, and the pulp density after sieving is adjusted into 20%～25%; Unsifted ore particle returns to be regrinded;
(2), gravity treatment
Above-mentioned ore pulp sent into spiral chute is roughly selected, selected and recleaning;
A, roughly select: ore pulp is carried out desliming, and it is 15%～25% that the ore pulp that concentrate mouth and middle mine mouth are discharged is adjusted concentration, preferred 20%, enters selectedly, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
B, selected: ore pulp is carried out desliming and selected, and from concentrate mouth intercepting concentrate, it is 15%～25% that the middle ore pulp that middle mine mouth is discharged is adjusted concentration once more, preferred 20%, enters recleaning, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
C, recleaning: ore pulp is carried out desliming once more and selected, from concentrate mouth intercepting concentrate, it is 15%～25% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, preferred 20%, enter reverse flotation, the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
Wherein, spiral chute is selected the BL1500 spiral chute that the Beijing Mine and Metallurgy General Inst produces (Chinese patent, Granted publication number: CN2495615) for use.
Helicla flute first three circle from the top down installed vertical bar with the groove face adhered shape additional, the upper end of vertical bar (a) is that 60mm, lower end (b) are 260mm with the distance b of groove cross section outer rim with groove cross section outer rim apart from a, and the angle δ between vertical bar and the helicla flute radius is 45 °; The length of vertical bar is 480mm, highly is 4mm, and width is 4mm.
In the refining process, the width of concentrate mouth is 15～25mm, and the concentrate weight of intercepting is 8%～15% of raw ore total amount;
In the recleaning process, the width of concentrate mouth is 20～30mm, and the concentrate weight of intercepting is 10%～15% of raw ore total amount.
(3), reverse flotation
Add the inhibitor of 100g～200g/ ton in the middle ore pulp after adjusting concentration, the collecting agent of 100g～150g/ ton stirred 2-3 minute, and reverse flotation is 10～12 minutes under the condition of normal temperature, pH=7, promptly obtains high-grade limonite concentrate.
Wherein, inhibitor is selected the industrial starch aqueous solution that is mixed with 1% mass concentration for use, and collecting agent is selected the surfactant salt amine acid salt aqueous solution of 1% mass concentration for use, and wherein the composition of surfactant is octadecyl primary amine and ether amine, and mass ratio is 6: 4; The BF series flotation device that mining and metallurgy total institute in reverse flotation equipment choosing Beijing produces according to the difference of designed productive capacity, disposes different groove numbers.
The beneficiation method of raising brown iron ore grade of the present invention adopts gravity treatment to add reverse floatation process, and flow process is simple, and power consumption is less, and it is low to have reduced cost significantly, is applicable to the ore dressing plant of producing 100000 tons of left and right sides limonite concentrate per year; Add high frequency shale shaker in the ore grinding step in traditional ball mill and spiral classifier combination, it is simple to operate, but can effectively control grinding particle size, improves classification efficiency, makes classification efficiency improve more than 30%; The present invention has increased the recleaning step, is the process of repetition primary cleaning, and it can drop to the clay content of ore pulp below 5%, and the iron ore grade improves 2～3 degree; First desliming before reverse flotation, thus the influence of sludge eliminated, reduced reagent consumption; The tailings grade that produces all between 30%～35%, reach the technical standard requirement in cement plant fully, but outright selling need not to store up; Whole process does not all produce environmental pollution.
In addition, when gravity treatment, select for use microfine ore dressing accommodation can reach the BL1500 spiral chute that-400 purpose Beijing Mine and Metallurgy General Inst produce, in desliming, directly intercept qualified concentrate containing, reduce the chats amount that enters flotation step, directly reduced medicament and power consumption from the concentrate mouth.By in spiral chute, installing vertical bar additional, to strengthen the stirring action of turbulent flow, accelerate the sinking speed of thin mud, improve the efficiency of separation of little density contrast mineral.
In flotation, select the starch inhibitor for use, the one, suppress the oxide ore come-up, the 2nd, produce flocculation, make the microfine breeze quicken sedimentation because of flocculation, improve the concentrate rate of recovery; The surfactant of selecting for use octadecyl primary amine and ether amine to mix can effectively reduce the foam volume in the reverse flotation process, overcome low temperature flow poor, run the serious disadvantage of groove.
[description of drawings]
Fig. 1 is the structural representation of the BL1500 spiral chute of Beijing Mine and Metallurgy General Inst's production.
Fig. 2 is the spiral fluted structure chart.
Fig. 3 is the spiral fluted vertical view that has installed vertical bar additional.
1-mine distributor, 2-upper bracket, 3-feed launder, 4-groove pillar, 5-helicla flute, 6-mine cut groove, 7-connect ore bucket, 8-vertical bar;
[specific embodiment]
Embodiment one:
(1), ore grinding: raw ore is gone into levigate extremely-200 orders of ball mill account for 98%, pulp density is 55%, then through spiral classifier classification overflow, enters-200 purpose high frequency shale shakers, and the pulp density after sieving is adjusted into 25%, and unsifted ore particle returns to be regrinded;
(2), gravity treatment: above-mentioned ore pulp sent into spiral chute is roughly selected, selected and recleaning;
A, roughly select: ore pulp is carried out desliming, and it is 20% that the ore pulp that concentrate mouth and middle mine mouth are discharged is adjusted concentration, enters selectedly, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
B, selected: ore pulp is carried out desliming and selected, the width adjustment of concentrate mouth is 15mm and intercepts concentrate, it is 20% that the middle ore pulp that middle mine mouth is discharged is adjusted concentration once more, enters recleaning, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
C, recleaning: ore pulp is carried out desliming once more and selected, the width adjustment of concentrate mouth is 20mm and intercepts concentrate, it is 20% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, enters reverse flotation, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
(3), reverse flotation: the industrial starch aqueous solution of the mass concentration 1% of adding 160g/ ton is as inhibitor in the middle ore pulp after adjusting concentration, (the octadecyl primary amine: salt amine acid salt aqueous solution ether amine=6: 4) is as collecting agent for the surfactant of the mass concentration 1% of 125g/ ton, stirred 2 minutes, reverse flotation is 10 minutes under the condition of normal temperature, pH=7, obtains high-grade limonite concentrate.
| Head grade | Concentrate grade | Tailings grade | The rate of recovery |
| 48％ | 60％ | 32％ | 68％ |
Embodiment two:
(1), ore grinding: raw ore is gone into levigate extremely-200 orders of ball mill account for 96%, pulp density is 60%, then through spiral classifier classification overflow, enters-200 purpose high frequency shale shakers, and the pulp density after sieving is adjusted into 20%, and unsifted ore particle returns to be regrinded;
(2), gravity treatment: above-mentioned ore pulp sent into spiral chute is roughly selected, selected and recleaning;
A, roughly select: ore pulp is carried out desliming, and it is 20% that the ore pulp that concentrate mouth and middle mine mouth are discharged is adjusted concentration, enters selectedly, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
B, selected: ore pulp is carried out desliming and selected, the width adjustment of concentrate mouth is 25mm and intercepts concentrate, it is 20% that the middle ore pulp that middle mine mouth is discharged is adjusted concentration once more, enters recleaning, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
C, recleaning: ore pulp is carried out desliming once more and selected, the width adjustment of concentrate mouth is 30mm and intercepts concentrate, it is 20% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, enters reverse flotation, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
(3), reverse flotation: the industrial starch aqueous solution of the mass concentration 1% of adding 200g/ ton is as inhibitor in the middle ore pulp after adjusting concentration, (the octadecyl primary amine: salt amine acid salt aqueous solution ether amine=6: 4) is as collecting agent for the surfactant of the mass concentration 1% of 100g/ ton, stirred 3 minutes, reverse flotation is 12 minutes under the condition of normal temperature, pH=7, obtains high-grade limonite concentrate.
| Head grade | Concentrate grade | Tailings grade | The rate of recovery |
| 46％ | 58％ | 35％ | 66％ |
Embodiment three:
(1), ore grinding: raw ore is gone into levigate extremely-200 orders of ball mill account for 99%, pulp density is 50%, then through spiral classifier classification overflow, enters-200 purpose high frequency shale shakers, and the pulp density after sieving is adjusted into 20%, and unsifted ore particle returns to be regrinded;
(2), gravity treatment: above-mentioned ore pulp sent into spiral chute is roughly selected, selected and recleaning;
A, roughly select: ore pulp is carried out desliming, and it is 20% that the ore pulp that concentrate mouth and middle mine mouth are discharged is adjusted concentration, enters selectedly, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
B, selected: ore pulp is carried out desliming and selected, the width adjustment of concentrate mouth is 20mm and intercepts concentrate, it is 20% that the middle ore pulp that middle mine mouth is discharged is adjusted concentration once more, enters recleaning, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
C, recleaning: ore pulp is carried out desliming once more and selected, the width adjustment of concentrate mouth is 25mm and intercepts concentrate, it is 20% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, enters reverse flotation, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
(3), reverse flotation: the concentration of recleaning concentrate pulp is adjusted into 20%, the industrial starch aqueous solution of the mass concentration 1% of adding 100g/ ton is as inhibitor, (the octadecyl primary amine: salt amine acid salt aqueous solution ether amine=6: 4) is as collecting agent for the surfactant of the mass concentration 1% of 150g/ ton, stirred 2 minutes, reverse flotation is 10 minutes under the condition of normal temperature, pH=7, obtains high-grade limonite concentrate.
| Head grade | Concentrate grade | Tailings grade | The rate of recovery |
| 45％ | 56％ | 30％ | 65％ |
Claims (7)
1, a kind of beneficiation method that improves brown iron ore grade comprises following steps:
(1), ore grinding: raw ore is gone into levigate extremely-200 orders of ball mill account for 96%～99%, pulp density is 50%～60%, then through spiral classifier classification overflow, enters-200 purpose high frequency shale shakers, pulp density after sieving is adjusted into 20%～25%, and unsifted ore particle returns to be regrinded;
(2), gravity treatment: above-mentioned ore pulp sent into spiral chute is roughly selected, selected and recleaning;
A, roughly select: ore pulp is carried out desliming, and it is 15%～25% that the ore pulp that concentrate mouth and middle mine mouth are discharged is adjusted concentration, enters selectedly, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
B, selected: ore pulp is carried out desliming and selected, and from concentrate mouth intercepting concentrate, it is 15%～25% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, enters recleaning, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
C, recleaning: ore pulp is carried out desliming once more and selected, and from concentrate mouth intercepting concentrate, it is 15%～25% that the middle ore pulp of middle mine mouth discharge is adjusted concentration once more, enters reverse flotation, and the sludge of spiral chute outer rim and part mine tailing enter tailing pit;
(3), reverse flotation: add the inhibitor of 100g～200g/ ton in the middle ore pulp after adjusting concentration, the collecting agent of 100g～150g/ ton stirred 2-3 minute, and reverse flotation is 10～12 minutes under the condition of normal temperature, pH=7, promptly obtains high-grade limonite concentrate.
2, beneficiation method as claimed in claim 1 is characterized in that before the ore grinding earlier crushing raw ore to-3mm.
3, beneficiation method as claimed in claim 1, it is characterized in that roughly selecting, adjusting pulp density respectively behind the selected and recleaning is 20%.
4, beneficiation method as claimed in claim 1 is characterized in that in the refining process, and the width of concentrate mouth is 15～25mm.
5, beneficiation method as claimed in claim 1 is characterized in that in the recleaning process that the width of concentrate mouth is 20～30mm.
6, beneficiation method as claimed in claim 1 is characterized in that the inhibitor in the reverse flotation step is the industrial starch aqueous solution of mass concentration 1%.
7, beneficiation method as claimed in claim 1 is characterized in that the collecting agent in the reverse flotation step is the salt amine acid salt aqueous solution of the surfactant of mass concentration 1%, and wherein the composition of surfactant is octadecyl primary amine and ether amine, and mass ratio is 6: 4.
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| CN101234363B (en) * | 2008-03-04 | 2011-11-16 | 昆明理工大学 | Method for producing high-grade sulfur concentrate from low-grade pyrite mine ore |
| CN101413057B (en) * | 2008-03-05 | 2011-03-30 | 中南大学 | Method for efficiently separating low-ore grade and complicated iron ore |
| CN101898167A (en) * | 2010-07-17 | 2010-12-01 | 孙宝海 | Dressing process of gold ores |
| CN102205270A (en) * | 2011-05-26 | 2011-10-05 | 山东梁邹矿业集团有限公司 | Method for extracting molybdenum concentrate from hydrocyclone sand |
| CN103111362A (en) * | 2011-11-16 | 2013-05-22 | 核工业北京地质研究院 | Obtaining method of medium and high grade iron ore concentrate in iron pyrite cinder |
| CN103586125A (en) * | 2012-08-15 | 2014-02-19 | 临沂鲁兴钛业股份有限公司 | Tailing titanium selecting method through gravity |
| CN102921537B (en) * | 2012-11-06 | 2015-04-01 | 永利高盛（北京）环保科技有限公司 | Flotation agent, flotation method and flotation system for limonite |
| CN110394234B (en) * | 2019-08-14 | 2023-06-16 | 深圳市考拉生态科技有限公司 | Ore cutter, spiral concentrating machine and method for separating minerals |
| CN112588445B (en) * | 2020-10-09 | 2022-09-20 | 太原钢铁(集团)有限公司 | Operating method for stabilizing reverse flotation production |
| CN114029128B (en) * | 2021-11-08 | 2023-01-31 | 矿冶科技集团有限公司 | Graphite ore crushing, grinding and flotation integrated equipment and method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3782539A (en) * | 1971-11-01 | 1974-01-01 | Pm Holding Co | Beneficiation of phosphate ores |
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|---|---|---|---|---|
| US3782539A (en) * | 1971-11-01 | 1974-01-01 | Pm Holding Co | Beneficiation of phosphate ores |
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