CN100536764C - Silver/silver chloride powder solid electrode and preparation method - Google Patents
Silver/silver chloride powder solid electrode and preparation method Download PDFInfo
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- CN100536764C CN100536764C CNB200710052564XA CN200710052564A CN100536764C CN 100536764 C CN100536764 C CN 100536764C CN B200710052564X A CNB200710052564X A CN B200710052564XA CN 200710052564 A CN200710052564 A CN 200710052564A CN 100536764 C CN100536764 C CN 100536764C
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- silver
- electrode
- chloride
- electrode material
- aqueous solution
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- 239000004332 silver Substances 0.000 title claims abstract description 76
- 229910021607 Silver chloride Inorganic materials 0.000 title claims abstract description 62
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 title claims abstract description 56
- 239000000843 powder Substances 0.000 title claims abstract description 50
- 239000007787 solid Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 88
- 229910052709 silver Inorganic materials 0.000 claims abstract description 72
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000000034 method Methods 0.000 claims abstract description 28
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 11
- 238000005245 sintering Methods 0.000 claims abstract description 10
- 238000011282 treatment Methods 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract description 3
- 239000007772 electrode material Substances 0.000 claims description 36
- 239000007864 aqueous solution Substances 0.000 claims description 21
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 9
- 230000004888 barrier function Effects 0.000 claims description 9
- 238000005259 measurement Methods 0.000 claims description 8
- 239000001103 potassium chloride Substances 0.000 claims description 8
- 235000011164 potassium chloride Nutrition 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 235000002639 sodium chloride Nutrition 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 230000010287 polarization Effects 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 229940075397 calomel Drugs 0.000 claims description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 230000000638 stimulation Effects 0.000 abstract description 4
- 239000010946 fine silver Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 9
- 101710134784 Agnoprotein Proteins 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005660 chlorination reaction Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 230000005518 electrochemistry Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000004936 stimulating effect Effects 0.000 description 2
- 208000006096 Attention Deficit Disorder with Hyperactivity Diseases 0.000 description 1
- 208000036864 Attention deficit/hyperactivity disease Diseases 0.000 description 1
- 206010008190 Cerebrovascular accident Diseases 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 208000006011 Stroke Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000000763 evoking effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 210000001138 tear Anatomy 0.000 description 1
- 238000003325 tomography Methods 0.000 description 1
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Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200710052564XA CN100536764C (en) | 2007-06-27 | 2007-06-27 | Silver/silver chloride powder solid electrode and preparation method |
Applications Claiming Priority (1)
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CNB200710052564XA CN100536764C (en) | 2007-06-27 | 2007-06-27 | Silver/silver chloride powder solid electrode and preparation method |
Publications (2)
Publication Number | Publication Date |
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CN101084829A CN101084829A (en) | 2007-12-12 |
CN100536764C true CN100536764C (en) | 2009-09-09 |
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Family Applications (1)
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CNB200710052564XA Active CN100536764C (en) | 2007-06-27 | 2007-06-27 | Silver/silver chloride powder solid electrode and preparation method |
Country Status (1)
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CN (1) | CN100536764C (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101308111B (en) * | 2008-04-07 | 2011-12-21 | 中国船舶重工集团公司第七二五研究所 | Hot dip silver coating /silver halides reference electrode and method for making same |
CN102169103B (en) * | 2010-12-07 | 2013-05-29 | 北京科技大学 | Solid Ag/AgCl electrode core and preparation method and applications thereof |
CN102368059A (en) * | 2011-10-26 | 2012-03-07 | 天津大学 | Method for preparing reference electrode with Ag/AgCl solid powder |
CN103192070B (en) * | 2013-04-17 | 2015-07-08 | 苏州格林泰克科技有限公司 | Silver/silver chloride electrode material, method for manufacturing same and electrode |
CN104287714A (en) * | 2014-11-10 | 2015-01-21 | 青岛柏恩鸿泰电子科技有限公司 | Silver/ silver chloride powder electrode |
CN105067673B (en) * | 2015-07-23 | 2017-12-22 | 河海大学 | Quickly generate the method for fine and close chlorination silvering and its silver chloride electrode of preparation |
CA2993837C (en) * | 2015-08-20 | 2023-08-22 | Parker-Hannifin Corporation | Silver-silver chloride compositions and electrical devices containing the same |
CN105311740A (en) * | 2015-11-17 | 2016-02-10 | 深圳市一体太糖科技有限公司 | Electrical stimulation coupling liquid and electrical stimulation electrode with coupling liquid |
CN105311739A (en) * | 2015-11-17 | 2016-02-10 | 深圳市一体太糖科技有限公司 | Electrical stimulation conduction liquid and electrical stimulation electrode with conduction liquid |
CN111936846B (en) * | 2018-06-14 | 2022-12-20 | Nok株式会社 | Method for manufacturing silver-silver chloride electrode |
CN111707723A (en) * | 2020-06-09 | 2020-09-25 | 上海三屹电子科技有限公司 | Silver/silver chloride slurry with high signal-to-noise ratio for biological detection electrode and preparation method thereof |
CN112387973A (en) * | 2020-10-29 | 2021-02-23 | 江苏集萃脑机融合智能技术研究所有限公司 | Preparation process of powder electrode |
CN112924506B (en) * | 2021-03-08 | 2023-01-10 | 湖南科技大学 | Preparation method of simple electrochemical micro sensor, product and application thereof |
-
2007
- 2007-06-27 CN CNB200710052564XA patent/CN100536764C/en active Active
Non-Patent Citations (2)
Title |
---|
Ag/Agcl高温参比电极的制备. 张清,李萍,白真权.应用科技,第32卷第6期. 2005 |
Ag/Agcl高温参比电极的制备. 张清,李萍,白真权.应用科技,第32卷第6期. 2005 * |
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CN101084829A (en) | 2007-12-12 |
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Owner name: DUAN YANWEN Free format text: FORMER OWNER: WUHAN GREEN TEK TECHNOLOGY CO., LTD. Effective date: 20110415 |
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Free format text: CORRECT: ADDRESS; FROM: 430072 ROOM 2406, BUILDING E, SILVER SEA PARK, HONGSHAN DISTRICT, WUHAN CITY, HUBEI PROVINCE TO: 430070 ROOM 2406, BUILDING E, SILVER SEA VILLAS, GUANGBA ROAD, HONGSHAN DISTRICT, WUHAN CITY, HUBEI PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20110415 Address after: Eight Yinhai road 430070 Hubei Nga Court E city of Wuhan province Hongshan District building 2406 room Patentee after: Duan Yanwen Address before: 430072 Hubei Province, Wuhan city Hongshan District Yinhai Yayuan E building 2406 room Patentee before: WUHAN GREENTEK Pty Ltd. |
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CP03 | Change of name, title or address |
Address after: Room 2406, Building E, Yinhai Yayuan, Guangba Road, Hongshan District, Wuhan City, Hubei Province, 430070 Patentee after: Duan Yanwen Country or region after: Australia Address before: Room 2406, Building E, Yinhai Yayuan, Guangba Road, Hongshan District, Wuhan City, Hubei Province, 430070 Patentee before: Duan Yanwen Country or region before: China |
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Effective date of registration: 20240527 Address after: 430074 Room 303, block B, Dingye building, phase III, international enterprise center, Guanggu Avenue, Donghu Development Zone, Wuhan City, Hubei Province Patentee after: WUHAN GREENTEK Pty Ltd. Country or region after: China Address before: Room 2406, Building E, Yinhai Yayuan, Guangba Road, Hongshan District, Wuhan City, Hubei Province, 430070 Patentee before: Duan Yanwen Country or region before: Australia |