CN100516153C - Polyvinyl chloride Yingdan paint - Google Patents

Polyvinyl chloride Yingdan paint Download PDF

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Publication number
CN100516153C
CN100516153C CNB2008100607216A CN200810060721A CN100516153C CN 100516153 C CN100516153 C CN 100516153C CN B2008100607216 A CNB2008100607216 A CN B2008100607216A CN 200810060721 A CN200810060721 A CN 200810060721A CN 100516153 C CN100516153 C CN 100516153C
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China
Prior art keywords
polyvinyl chloride
paint
yingdan
component
modified compound
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CN101265381A (en
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钱计兴
钱银珠
钱建华
钱荷素
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LINHAI LONGGANG CHEMICAL FACTORY
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LINHAI LONGGANG CHEMICAL FACTORY
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Abstract

The invention discloses a polyvinyl chloride fluoric ferrophosphorus coating, which consists of components A and B. Component A can be divided into A1 and A2. A1 is a polyvinyl chloride fluoric ferrophosphorus primer; and A2 is a polyvinyl chloride fluoric ferrophosphorus finish coat. Component B is a polyurethane curing agent. Before use, a primer is prepared with A1 and B in the ratio of 12 to 1 by weight; and a finish coat is prepared with A2 and B in the ratio of 12 to 1 by weight. The temperature for the coating to be used for a long time is 120 DEG C; the coating contains 30 to 50 percent of solid; the coating film thickness is 30 Mu m per round to 40 Mu m per round, and the construction time is reduced. As fluoric ferrophosphor is added, the corrosion resistance is significantly improved. In addition, the construction cost is reduced, and the construction cycle is shortened.

Description

Polyvinyl chloride Yingdan paint
Technical field
The present invention relates to the industrial antisepsis technical field of coatings, especially relate to a kind of pair of solvent type polyvinyl chloride Yingdan paint of component.
Technical background
In industrial antisepsis coating prior art, to be with single polyvinyl chloride (PVC) RESINS be the coating of main film forming substance to this kind coating of institute's production and supply on the market.This kind solids coatings is low, has only about 17%: paint film is thin, and per pass brushing thickness is about 18 μ m; Workability is poor, comes and goes the easy plucking of brushing; Levelling property is poor, and decorate properties is poor, the construction cost height.In addition, because of solids content in the coating is low, volatile matter solvent height, environmental pollution is bigger.
Summary of the invention
The objective of the invention is to solve existing problem in the prior art, the polyvinyl chloride Yingdan paint that provide a kind of paint film thickness, Corrosion Protection height, have good workability, construction cost is low.
The object of the present invention is achieved like this: a kind of polyvinyl chloride Yingdan paint, it is combined by the two components of A, B, wherein the A component is divided into two kinds of A1 and A2 again, A1 is that polyvinyl chloride Yingdan paint priming paint, A2 are the polyvinyl chloride Yingdan paint finish paint, the B component is a polyurethane curing agent, it is characterized in that: the prescription of A1 component polyvinyl chloride Yingdan paint priming paint weight percent (%) is
PVC modified compound resin is expected 55-65 clearly
The red 2-10 of firefly
Anti-sedimentation agent 0.5-1.5
Red iron oxide 2-10
Pigment extender 1-4
Clorafin v 0.1-2.0
Flow agent 0.3-1.0
Ultraviolet-resistant absorbent 0.05-0.15
Dimethylbenzene 20-30
Defoamer 0.05-0.15
The prescription of A2 component polyvinyl chloride Yingdan paint finish paint weight percent (%) is,
PVC modified compound resin is expected 55-65 clearly
Titanium dioxide 8-13
The red 0.1-3 of firefly
Clorafin 0.1-2.0
Anti-sedimentation agent 0.5-1.5
Flow agent 0.3-1.0
Ultraviolet-resistant absorbent 0.05-0.15
Dimethylbenzene 20-30
Defoamer 0.05-0.15
Use preceding: 1 preparation, A2: B=12: 1 preparation by weight A1: B=12;
Above-mentioned PVC modified compound resin expects that clearly the prescription of weight percent (%) is,
Polyvinyl chloride (PVC) RESINS 4-9
Supervinyi chloride resin 5-11
Pimelinketone 50-65
Resins, epoxy 5-10
Acrylic resin 5-12
Dibutylester 5-9
At first polyvinyl chloride (PVC) RESINS and supervinyi chloride resin are added the pimelinketone dissolving respectively, the three mixes then, stirs, add Resins, epoxy and acrylic resin again, after fully stirring, add dibutylester, after fully stirring even matter, PVC modified compound resin expect clearly.
One preferred embodiment in, the prescription of A1 component polyvinyl chloride Yingdan paint priming paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Firefly pellet 5
Anti-sedimentation agent 0.9
Red iron oxide 4
Pigment extender 3
Clorafin 1
Flow agent 0.9
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 25
Defoamer 0.1
One preferred embodiment in, the prescription of A2 component polyvinyl chloride Yingdan paint finish paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Titanium dioxide 11
Firefly pellet 0.2
Clorafin 1
Anti-sedimentation agent 0.8
Flow agent 0.8
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 26
Defoamer 0.1
One preferred embodiment in, PVC modified compound resin expects that clearly the prescription of weight percent (%) is,
Polyvinyl chloride (PVC) RESINS 6.6
Supervinyi chloride resin 8.2
Pimelinketone 62.3
Resins, epoxy 8.2
Acrylic resin 8.2
Dibutylester 6.5
Life-time service temperature of the present invention is 120 ℃, surpasses the use temperature of 90 ℃ of general industry protective systems; Solids content is increased to 30-50% by about 17%, and film thickness is increased to 30 μ m/ roads by 18 μ m/ roads--40 μ m/ roads, reduced the engineering time, and reduced construction cost; Add the firefly pellet, steel surface is had the phosphatization passivation, increased sticking power, improved Corrosion Protection greatly, the corrosion of media such as anti-sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, methyl alcohol, formaldehyde, caustic soda, soda ash and various salts.Be widely used in Industrial buildings, oil, chemical industry, medicine, process pipe, equipment, steel component, bridge, shipbuilding anticorrosion engineering field.
Below in conjunction with embodiment the present invention is elaborated.
Embodiment
The physical process that is prepared as no chemical reaction of product of the present invention, basic identical with the production technique of other coating.In following formulation for coating material, firefly pellet (F.P.Fe) is produced by Linhai Longgang Chemical Factory, at the standard GB50046-95 of the People's Republic of China (PRC) " Industrial buildings corrosion protection design standard " and " all on the books in 309 page of the 12 joint of building anti-corrosion corrosion material design and construction handbook.
Embodiment one
1, PVC modified compound resin is expected preparation clearly: at first, by weight percentage polyvinyl chloride (PVC) RESINS 4-9% and supervinyi chloride resin 5-11% are added pimelinketone 50-65% dissolving respectively, the two mixing then, stir, add Resins, epoxy 5-10% and acrylic resin 5-12% again, after fully stirring, add dibutylester 5-9%, after fully stirring even matter, promptly become hybrid resin and expect clearly.
2, A1 component preparation: PVC modified compound resin is expected 55-65% clearly, the red 2-10% of firefly, anti-sedimentation agent 0.5-1.5%, red iron oxide 2-10%, pigment extender 1-4%, clorafin 0.1-2.0%, flow agent 0.3-1.0%, ultraviolet-resistant absorbent 0.05-0.15%, dimethylbenzene 20-30%, defoamer 0.05-0.15%.Above-mentioned raw materials is counted by weight percentage, mix even matter.
3, A2 component preparation: PVC modified compound resin is expected 55-65% clearly, titanium dioxide 8-13%, the red 0.1-3% of firefly, clorafin 0.1-2.0%, anti-sedimentation agent 0.5-1.5%, flow agent 0.3-1.0%, ultraviolet-resistant absorbent 0.05-0.15%, dimethylbenzene 20-30%, defoamer 0.05-0.15%.Above-mentioned raw materials is counted by weight percentage, mix even matter.
4, the B component is a polyurethane curing agent.
5, coating preparation:
(1) A1, the preparation in 12: 1 by weight percentage of B component are become priming paint after stirring, grind, filtering.
(2) A2, the preparation in 12: 1 by weight percentage of B component are become finish paint after stirring, grind, filtering.
Embodiment two
1, PVC modified compound resin is expected preparation clearly: at first, by weight percentage polyvinyl chloride (PVC) RESINS 6.6% and supervinyi chloride resin 8.2% are added pimelinketone 62.3% dissolving respectively, the two mixing then, stir, add Resins, epoxy 8.2% and acrylic resin 8.2% again, after fully stirring, add dibutylester 6.5%, after fully stirring even matter, promptly become hybrid resin and expect clearly.
2, A1 component preparation: the clear material 60% of PVC modified compound resin, firefly pellet 5%, anti-sedimentation agent 0.9%, red iron oxide 4%, pigment extender 3%, clorafin 1%, flow agent 0.9%, ultraviolet-resistant absorbent 0.1%, dimethylbenzene 25%, defoamer 0.13%.Above-mentioned raw materials is counted by weight percentage, mix even matter.
3, A2 component: the clear material 60% of PVC modified compound resin, titanium dioxide 11%, firefly pellet 0.2%, clorafin 1%, anti-sedimentation agent 0.8%, flow agent 0.8%, ultraviolet-resistant absorbent 0.1%, dimethylbenzene 26%, defoamer 0.1%.Above-mentioned raw materials is counted by weight percentage, mix even matter.
4, the B component is a polyurethane curing agent.
5, coating preparation:
(1) A1, the preparation in 12: 1 by weight percentage of B component are become priming paint after stirring, grind, filtering.
(2) A2, the preparation in 12: 1 by weight percentage of B component are become finish paint after stirring, grind, filtering.
Embodiment three
1, PVC modified compound resin is expected preparation clearly: with embodiment two.
2, A1 component preparation: with embodiment two.
3, A2 component preparation: with embodiment one.
4, the B component is a polyurethane curing agent.
5, coating preparation: with embodiment one.
Embodiment four
1, PVC modified compound resin is expected preparation clearly: with embodiment two.
2, A1 component preparation: with embodiment one.
3, A2 component preparation: with embodiment two.
4, the B component is a polyurethane curing agent.
5, coating preparation: with embodiment one.
Embodiment five
1, PVC modified compound resin is expected preparation clearly: with embodiment two.
2, A1 component preparation: with embodiment one.
4, A2 component preparation: with embodiment one.
4, the B component is a polyurethane curing agent.
5, coating preparation: with embodiment one.
The finish paint prescription is as the criterion with white in the foregoing description, can require to add various tinting pigment adjustment according to difference.
The key technical indexes of coating of the present invention:
(1) the life-time service temperature is 120 ℃.
(2) solids content 30-50%.
(3) priming paint sticking power is 1 grade.
(4) corrosion of media such as anti-sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, methyl alcohol, formaldehyde, caustic soda, soda ash and various salts.

Claims (5)

1. polyvinyl chloride Yingdan paint is combined by the two components of A, B, and wherein the A component is divided into two kinds of A1 and A2 again, and A1 is that polyvinyl chloride Yingdan paint priming paint, A2 are the polyvinyl chloride Yingdan paint finish paint; The B component is a polyurethane curing agent, it is characterized in that: the prescription of A1 component polyvinyl chloride Yingdan paint priming paint weight percent (%) is,
PVC modified compound resin is expected 55-65 clearly
The red 2-10 of firefly
Anti-sedimentation agent 0.5-1.5
Red iron oxide 2-10
Pigment extender 1-4
Clorafin 0.1-2.0
Flow agent 0.3-1.0
Ultraviolet-resistant absorbent 0.05-0.15
Dimethylbenzene 20-30
Defoamer 0.05-0.15
The prescription of A2 component polyvinyl chloride Yingdan paint finish paint weight percent (%) is,
PVC modified compound resin is expected 55-65 clearly
Titanium dioxide 8-13
The red 0.1-3 of firefly
Clorafin 0.1-2.0
Anti-sedimentation agent 0.5-1.5
Flow agent 0.3-1.0
Ultraviolet-resistant absorbent 0.05-0.15
Dimethylbenzene 20-30
Defoamer 0.05-0.15
Use preceding: 1 mixed proportioning, A2: B=12: 1 mixed proportioning by weight A1: B=12;
Above-mentioned PVC modified compound resin expects that clearly the prescription of weight percent (%) is,
Polyvinyl chloride (PVC) RESINS 4-9
Supervinyi chloride resin 5-11
Pimelinketone 50-65
Resins, epoxy 5-10
Acrylic resin 5-12
Dibutylester 5-9
At first polyvinyl chloride (PVC) RESINS and supervinyi chloride resin are added the pimelinketone dissolving respectively, the three mixes then, stirs, add Resins, epoxy and acrylic resin again, after fully stirring, add dibutylester, after fully stirring even matter, PVC modified compound resin expect clearly.
2, polyvinyl chloride Yingdan paint according to claim 1 is characterized in that: the prescription of A1 component polyvinyl chloride Yingdan paint priming paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Firefly pellet 5
Anti-sedimentation agent 0.9
Red iron oxide 4
Pigment extender 3
Clorafin 1
Flow agent 0.9
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 25
Defoamer 0.1
3, polyvinyl chloride Yingdan paint according to claim 1 is characterized in that: the prescription of A2 component polyvinyl chloride Yingdan paint finish paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Titanium dioxide 11
Firefly pellet 0.2
Clorafin 1
Anti-sedimentation agent 0.8
Flow agent 0.8
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 26
Defoamer 0.1
4, polyvinyl chloride Yingdan paint according to claim 1 is characterized in that: the prescription of A1 component polyvinyl chloride Yingdan paint priming paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Firefly pellet 5
Anti-sedimentation agent 0.9
Red iron oxide 4
Pigment extender 3
Clorafin 1
Flow agent 0.9
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 25
Defoamer 0.1
The prescription of A2 component polyvinyl chloride Yingdan paint finish paint weight percent (%) is,
The clear material 60 of PVC modified compound resin
Titanium dioxide 11
Firefly pellet 0.2
Clorafin 1
Anti-sedimentation agent 0.8
Flow agent 0.8
Ultraviolet-resistant absorbent 0.1
Dimethylbenzene 26
Defoamer 0.1
5, according to claim 1,2,3 or 4 described polyvinyl chloride Yingdan paints, it is characterized in that: PVC modified compound resin expects that clearly the prescription of weight percent (%) is,
Polyvinyl chloride (PVC) RESINS 6.6
Supervinyi chloride resin 8.2
Pimelinketone 62.3
Resins, epoxy 8.2
Acrylic resin 8.2
Dibutylester 6.5
CNB2008100607216A 2008-04-25 2008-04-25 Polyvinyl chloride Yingdan paint Active CN100516153C (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CNB2008100607216A CN100516153C (en) 2008-04-25 2008-04-25 Polyvinyl chloride Yingdan paint

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CN101265381A CN101265381A (en) 2008-09-17
CN100516153C true CN100516153C (en) 2009-07-22

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101649143B (en) * 2009-09-10 2011-01-05 浙江永固为华涂料有限公司 Polytetrafluoroethylene modified polyvinyl chloride paint
CN103709874A (en) * 2014-01-14 2014-04-09 钱计兴 Fluororesin modified polyvinyl chloride clean material and priming paint and finish paint containing clean material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86101597A (en) * 1986-03-15 1987-09-23 武汉市武汉自行车电镀厂 Anti-corrosive coatings used for electroplating equipments
CN1124751A (en) * 1994-11-16 1996-06-19 中外合资北京天工表面材料技术有限公司 Interpenetration polymer network coating
CN1515636A (en) * 2003-01-09 2004-07-28 天津新技术产业园区北洋新技术工程有 Sand dust resisting protective paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86101597A (en) * 1986-03-15 1987-09-23 武汉市武汉自行车电镀厂 Anti-corrosive coatings used for electroplating equipments
CN1124751A (en) * 1994-11-16 1996-06-19 中外合资北京天工表面材料技术有限公司 Interpenetration polymer network coating
CN1515636A (en) * 2003-01-09 2004-07-28 天津新技术产业园区北洋新技术工程有 Sand dust resisting protective paint

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CP03 Change of name, title or address

Address after: Shaojiadu street, Linhai City, Taizhou City, Zhejiang Province

Patentee after: Taizhou Longhua Technology Co., Ltd

Address before: 317000 Youxi Town, Linhai City, Zhejiang Province

Patentee before: Linhai Longgang Chemical Factory

CP03 Change of name, title or address
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Polyvinyl chloride Yingdan paint

Effective date of registration: 20200110

Granted publication date: 20090722

Pledgee: Zhejiang Linhai Rural Commercial Bank Co., Ltd. shaojiadu sub branch

Pledgor: Taizhou Longhua Technology Co., Ltd

Registration number: Y2020330000029

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20200821

Granted publication date: 20090722

Pledgee: Zhejiang Linhai Rural Commercial Bank Co.,Ltd. shaojiadu sub branch

Pledgor: Taizhou Longhua Technology Co.,Ltd.

Registration number: Y2020330000029

PC01 Cancellation of the registration of the contract for pledge of patent right