CN100494559C - Adjuvant for cation dye and acidic dye co-bathing dyeing - Google Patents
Adjuvant for cation dye and acidic dye co-bathing dyeing Download PDFInfo
- Publication number
- CN100494559C CN100494559C CNB2007100409634A CN200710040963A CN100494559C CN 100494559 C CN100494559 C CN 100494559C CN B2007100409634 A CNB2007100409634 A CN B2007100409634A CN 200710040963 A CN200710040963 A CN 200710040963A CN 100494559 C CN100494559 C CN 100494559C
- Authority
- CN
- China
- Prior art keywords
- dye
- dyeing
- positive ion
- cation
- acid dyes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
This invention discloses a kind assistant using in the positive ion dye and the acid dyes. Its component and the quality percentage is: the polyether quaternary ammonium salt positive ion surface active agent 5-30%, the non-ionic surface active agent 10-40%, the inorganic salt 2-10%, other is the water. Because of using new structure polyether quaternary ammonium salt positive ion surface active agent, in its structure besides quaternary ammonium salt positive ion groups and bases, also includes the water affinity polyether chain and the hydroxyl. The positive ion groups and bases may through compete with the dye the place to has slow effect on the positive ion. Simultaneously, but may also with the acid dyes through the electrostatic coupling, slow down the acid dyes ; Because also in its molecular structure includes the water affinity polyether segment and the hydroxyl, reduced the possibility of producing deposit greatly after the acid dyes, improve the dyeing uniformity, and reduce improves the product quality.
Description
Technical field
The present invention relates to a kind of auxiliaries for textile dyeing and printing, particularly a kind of auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing as retarding agents and antiprecipitant, belongs to the textile dyeing and finishing technical field.
Background technology
In the textile dyeing process, because the fiber of different structure has the coloured differently performance, dyestuff used during dyeing is different.Press the ionic nature classification, dyestuff commonly used can be divided three classes: a class is positive lotus property in water dyestuff mainly contains cation dyes, is used for the dyeing of acrylic fibers and cation dyeable modified polyster fibre; The another kind of anionic species dye species that is cloudy lotus property in water is more, ACID DYES is mainly used in the dyeing of wool, silk, nylon fibre, direct dyes and REACTIVE DYES are mainly used in the dyeing of cellulose fibres such as cotton, fiber crops, bamboo, viscose glue and regenerated celulose fibre, also can be used for the dyeing of wool and silk; Also having a class is the nonionic dyestuff, mainly contains DISPERSE DYES, is used to dye terylene or nylon fibre.
For different, the colourful weaving face fabric of obtained performance, in textile development, often adopt two or more to carry out blending or interweave, just need two or more dyestuff of employing to dye.Comprise and to use the anionic dyestuff, use the situation of cationic dyes simultaneously again.In the blended yarn or coloration of textile materials of wool and acrylic fibers or cation dyeable modified polyster fibre, need to adopt ACID DYES dyeing wool, cation dyes to dye acrylic fibers or cation dyeable modified polyster fibre.Meeting generation gathering in dye bath deposits owing to ACID DYES and cation dyes mixing back, causes the inhomogeneous of color spot and dyeing.Therefore, adopt two baths to dye, dye acrylic fibers or cation dyeable modified terylene with cation dyes earlier, on the basis of fully cleaning, renew bath in addition then, adopt the ACID DYES dyeing wool.
Because two bathe the method time consumption and energy consumption, production cost is higher, and people explore single bath process and dye, and assembles in order to prevent ACID DYES and cation dyes from interacting, and needs to add non-ionic surface active agent as antiprecipitant.In addition, because cationic dyeing speed is very fast, cause dyeing inhomogeneous easily, usually need to add levelling agent such as cationic surfactant such as cationic surfactant 1227 (dodecyl benzyl dimethyl ammonium chloride), cationic surfactant 1231 (DTAB) etc. as cation dyes, and these cationic surfactants also can take place to assemble and deposit with ACID DYES, in order to prevent the generation of this deposition, must increase the consumption of antiprecipitant.In addition, owing to need to add multiple auxiliary agent, thereby increased the factor that influences final Color, the reappearance of dyeing product is descended.
Before the present invention makes, at " the polyoxyethylene-type cationic surfactant synthesizes the research with surface nature " ([J], daily chemical industry, 2002, Vol.32 (5): 8-10) in the literary composition, disclosing a kind of is the synthetic technology that contains the novel cation surfactant of polyether group and hydroxypropyl of raw material with fatty alcohol-polyoxyethylene ether, epoxychloropropane, trimethylamine, but its application in textile printing and dyeing processing does not appear in the newspapers.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists, a kind of dyeing uniformity can effectively improve cation dyes and acidic dye co-bathing dyeing the time is provided, reduce the dyeing defect that causes because dyestuff interacts, takes place to assemble, improve the dyeing assistant of the quality of dyeing product.
The technical solution used in the present invention is: a kind of auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing is provided, its constituent and mass percent are: contain polyethers quaternary cationics 5～30%, non-ionic surface active agent 10～40%, inorganic salts 2～10%, all the other are water; The described polyethers quaternary cationics that contains has following structure:
Wherein: m=7～17; N=3～15; X=Br or Cl.
Described non-ionic surface active agent is one or more the mixture among peregal 0-25, dispersant IW, the dispersant WA.
Described inorganic salts compound is glauber salt, salt or their mixture.
The present invention has adopted the new structure polyether quaternary cationics, except the quaternary ammonium salt cationic group, also contains hydrophilic polyether chain and hydroxyl in this class surfactant molecule structure.On the one hand, have cation group in its molecule, can dye seat by contention with cation dyes and cation dyes are played slow dye effect, play the level dyeing effect; Simultaneously, also can combine by static, slow down the dyeing rate of ACID DYES, play the level dyeing effect with ACID DYES; Different with common quaternary ammonium salt cationic surfactant is, owing to also contain hydrophilic polyether segment and hydroxyl in its molecular structure, greatly reduce the possibility that combines generation precipitation in back with ACID DYES, make the uniformity of dyeing obtain significantly to improve, reduced the defect that produces because produce dye precipitated in the dyeing course simultaneously.
Compared with prior art, advantage of the present invention is:
(1) adopted the new structure polyether quaternary cationics, when cation dyes and acidic dye co-bathing dyeing, can play the slow effect of dying to cation dyes and acid dyeing, can preventing again interacts between ACID DYES and the cation dyes and produce precipitates, effectively improved dyeing uniformity, reduce the dyeing defect that causes because dyestuff interacts, takes place to assemble, improve the quality of dyeing product.
(2) in the assistant composition of the present invention, add non-ionic surface active agent, issuable precipitation is played peptizaiton, guarantee that dyeing course carries out smoothly; The inorganic salts compound produces certain slow effect of dying to two kinds of dyestuff uniformities.Unite two into one by the composition that obtains after composite function, only need in the dyeing course to add a kind of auxiliary agent, help reducing between the different batches because the difference of the Color that the reinforced error of auxiliary agent causes improves dyeing reproducibility with level dyeing and antisolvent precipitation.
The specific embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment 1:
The auxiliary formula that is used for cation dyes and acidic dye co-bathing dyeing is composed as follows by weight:
Polyethers quaternary cationics A 16%
Dispersant IW 20%
Glauber salt 5%
Water 59%
Wherein, described dispersant IW can be referring to " dyeing and finishing auxiliaries for textile handbook, China Light Industry Press's nineteen ninety-five front page.
Method for making: the polyethers quaternary cationics A and the non-ionic surface active agent dispersant IW of amount of calculation are dissolved under heating condition with a certain amount of water respectively, mix then, stir, the glauber salt that adds amount of calculation, stirring makes its dissolving, supply the remaining water yield, mix the back discharging.
Used polyethers quaternary cationics A structure is:
Embodiment 2:
The auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing, its prescription is composed as follows by weight:
Polyethers quaternary cationics B 12%
Dispersant WA 20%
Salt 6%
Water 62%
Wherein, described dispersant WA can be referring to " dyeing and finishing auxiliaries for textile handbook, China Light Industry Press's nineteen ninety-five front page.
Method for making: the cationic surfactant B and the non-ionic surface active agent peregal 0-25 of amount of calculation are dissolved under heating condition with a certain amount of water respectively, mix then, stir, the salt that adds amount of calculation, stirring makes its dissolving, supplies the remaining water yield, mixes the back discharging.
Used polyethers quaternary cationics B structure is:
In the dye liquor when auxiliary agent that the foregoing description 1,2 is provided joins cation dyes and acidic dye co-bathing dyeing, owing to adopted the new structure polyether quaternary cationics, except the quaternary ammonium salt cationic group, also contain hydrophilic polyether chain and hydroxyl in its structure.Cation group can dye seat by contention with cation dyes and cation dyes be played slow dye effect, simultaneously, also can combine by static with ACID DYES, slows down the dyeing rate of ACID DYES; Also owing to contain hydrophilic polyether segment and hydroxyl in its molecular structure, greatly reduce the possibility that combines generation precipitation in back with ACID DYES, make the uniformity of dyeing obtain significantly to improve, reduced the defect that produces because of dye precipitated in the dyeing course simultaneously, improve the quality of products.
Claims (3)
1. auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing, it is characterized in that: its constituent and mass percent are: contain polyethers quaternary cationics 5～30%, non-ionic surface active agent 10～40%, inorganic salts 2～10%, all the other are water; The described polyethers quaternary cationics that contains has following structure:
Wherein: m=7～17n=3～15; X=Br or Cl.
2. a kind of auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing according to claim 1 is characterized in that: described non-ionic surface active agent is one or more the mixture among peregal 0-25, dispersant IW, the dispersant WA.
3. a kind of auxiliary agent that is used for cation dyes and acidic dye co-bathing dyeing according to claim 1 is characterized in that: described inorganic salts are glauber salt, salt or their mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100409634A CN100494559C (en) | 2007-05-21 | 2007-05-21 | Adjuvant for cation dye and acidic dye co-bathing dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100409634A CN100494559C (en) | 2007-05-21 | 2007-05-21 | Adjuvant for cation dye and acidic dye co-bathing dyeing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101070682A CN101070682A (en) | 2007-11-14 |
| CN100494559C true CN100494559C (en) | 2009-06-03 |
Family
ID=38898079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100409634A Expired - Fee Related CN100494559C (en) | 2007-05-21 | 2007-05-21 | Adjuvant for cation dye and acidic dye co-bathing dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100494559C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643259B (en) * | 2009-08-25 | 2011-10-19 | 苏州大学 | Additive of dyeing process for reclaimed water reusing |
| CN102628229B (en) * | 2012-02-20 | 2014-11-19 | 浙江安诺其助剂有限公司 | Anti-precipitant and its preparation method |
| CN102936859A (en) * | 2012-11-22 | 2013-02-20 | 河南工程学院 | One-bath one-step dyeing method for cotton and nitrile blended fabric |
| KR102129650B1 (en) * | 2013-04-01 | 2020-07-02 | 가부시키가이샤 아데카 | Flame-retardant agent composition, flame-retardant fiber treated with flame-retardant agent composition, and method for increasing amount of flame-retardant component adhered onto fibers using said composition |
| CN103628329A (en) * | 2013-10-17 | 2014-03-12 | 上海缀菱纺织品有限公司 | Method for dyeing CDP/nylon/PU knitted fabrics |
| CN104611955A (en) * | 2015-01-23 | 2015-05-13 | 江苏金太阳纺织科技有限公司 | Dyeing and finishing method for high-warp-density three-color jacquard fabric |
| CN106198874A (en) * | 2016-07-15 | 2016-12-07 | 上海嘉麟杰纺织品股份有限公司 | A kind of method of preferred antisettling agent usage amount |
| CN107083702A (en) * | 2017-05-26 | 2017-08-22 | 东莞市博科纺织科技有限公司 | A kind of antisettling agent and its use technique |
| CN108867109A (en) * | 2018-07-26 | 2018-11-23 | 浙江雅雪染整有限公司 | A kind of viscous shuttle-woven fabric dyeing and finishing technology of hair |
-
2007
- 2007-05-21 CN CNB2007100409634A patent/CN100494559C/en not_active Expired - Fee Related
Non-Patent Citations (4)
| Title |
|---|
| 聚氧乙烯型阳离子表面活性剂合成玉表面性质的研究. 张颖，陶玉钢，毛培坤.日用化学工业，第32卷第5期. 2002 |
| 聚氧乙烯型阳离子表面活性剂合成玉表面性质的研究. 张颖，陶玉钢，毛培坤.日用化学工业，第32卷第5期. 2002 * |
| 聚氧乙烯烷基胺的性能及其应用. 李兰廷.精细与专用化学品，第12卷第15期. 2004 |
| 聚氧乙烯烷基胺的性能及其应用. 李兰廷.精细与专用化学品，第12卷第15期. 2004 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101070682A (en) | 2007-11-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100494559C (en) | Adjuvant for cation dye and acidic dye co-bathing dyeing | |
| CN100575582C (en) | A kind of preparation method of segment-colored mixed color fancy yarn | |
| CN104452283B (en) | Modified cotton fiber, cowboy's effect cloth and preparation method thereof | |
| CN100567403C (en) | A kind of composite active black dye | |
| CN100392164C (en) | Method for making pure cotton yarn without flying contamination | |
| CN102517723B (en) | Full-color yarn and its production process | |
| CN102977637B (en) | Compound active brown dye | |
| CN101245563A (en) | High-efficiency environment protection acidic color fixing agent and manufacture method thereof | |
| CN1687520A (en) | Dedicated dye for dyeing blend fabric and mixed fabric | |
| CN101046068A (en) | Dye process of mixed fabric of cuprammonium fiber and rayon | |
| CN100372980C (en) | Process of producing fancy yarn stripe cloth in tone-in-tone effect | |
| CN1730806A (en) | Production method for pure cotton color stripe | |
| CN107974103A (en) | A kind of composite reactive yellow dye | |
| CN101338523B (en) | Apposition dyeing additive for blended fabric of PTT fibre and cellulose fibre | |
| CN112301763B (en) | Pure cotton fabric and dyeing method thereof | |
| CN102926235B (en) | Liquid mixed base for activated dye high temperature dyeing and preparation method and application thereof | |
| CN104611954B (en) | One-bath dyeing method for dyeing cotton-acrylic fabric with direct dye and cationic dye | |
| CN106758408A (en) | A kind of blend polyester dyeing fabric liquid and preparation method thereof | |
| CN103952013B (en) | A kind of compound reactive brilliant blue K-GR composition and use thereof and using method | |
| CN109504125A (en) | A kind of compound crimson active dyestuff suitable for low temperature dyeing | |
| CN1099495C (en) | Process for dyeing textiles containing polyester fibers and dyeing auxiliaries | |
| CN101906257B (en) | Composite reactive brown dye | |
| CN102585549B (en) | Reactive red dye composition | |
| CN104194395B (en) | Reactive red dye composition, reactive red dye as well as preparation method and application of active red dye | |
| CN1089830C (en) | Dye adhesion preventing agent and method for treating previously dyed fibers or textile goods using the agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090603 Termination date: 20120521 |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20071114 Assignee: Foshan City Sanshui Jialida Textile Co., Ltd. Assignor: Soochow University Contract record no.: 2010440000585 Denomination of invention: Assistant for cation dye and acidic dye co-bathing dyeing Granted publication date: 20090603 License type: Exclusive License Record date: 20100602 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model |