Three, summary of the invention:
Purpose of the present invention: torpedo jar novel refractory---aluminum-silicon carbide brick and the torpedo tank lining structure therewith of producing longer service life.
Technical scheme of the present invention is:
A kind of alumina-silicon carbide-carbon brick for torpedo tank, represent with weight percent, contain alumina 10~60% in the raw material, fused corundom 10~50%, silicon carbide 3~20%, graphite 2~20%, chromic oxide 0.5~5%, metallic aluminium 0.2-3%, Pure Silicon Metal 0.2-3%, wedding agent 3~5%, andaluzite or sillimanite or kyanite 3~10%.
Wherein alumina 20~50%, fused corundom 20~40%, silicon carbide 5~15%, graphite 5~15%, chromic oxide 1~4%, metallic aluminium 0.5-2%, Pure Silicon Metal 0.5-2%, andaluzite or sillimanite or kyanite 5~8%.
The granularity of described alumina is two kinds of 8~3mm and 3~1mm, wherein granularity is that the alumina of 8~3mm accounts for 5~15% of raw material total amount, granularity be the alumina of 3~1mm account for the raw material total amount 5~45%, the fused corundom granularity is 1~0.1mm, and carborundum granularity is-200 orders, and graphite is the natural graphite of L-190, the granularity of andaluzite or sillimanite or kyanite is-200 orders, the granularity of chromic oxide is-180 orders, and metallic aluminium is-200 orders, and Pure Silicon Metal is-200 orders.
Described fused corundom is a fused white corundum, or is the electric smelting sub-white corundum, or is fused brown corundum, or is the electric smelting compact alumina, or is the arbitrary combination of above-mentioned different sorts fused corundom.
Described wedding agent is a resol.
A kind of torpedo tank lining structure therewith, the spray material (2) that contains the tank body inner side-wall, tank body intermediary jar mouth (1), the refractory brick work layer that spray material (2) is inboard, this refractory brick work layer comprises cylindrical shell inside lining building section (51,52), truncated cone shell inside lining building section (53) and headwall inside lining building section (54), wherein cylindrical shell inside lining building section comprises impact zone (51) and the non-impact zone (52) under jar mouthful (1), described impact zone (51) is built by laying bricks or stones by torpedo jar special brick first (3) and is formed, a longitudinal cross-section of this brick is a rectangle, and another longitudinal cross-section is an isosceles trapezoid; Non-impact zone (52) is built by laying bricks or stones by torpedo jar special brick second (4,5) and is formed, and longitudinal cross-section of this brick is a rectangle, and another longitudinal cross-section is an isosceles trapezoid, and wherein the height of unit Zhuan Jia (3) is greater than the height of unit brick second (4,5); Truncated cone shell inside lining building section (53) is built by laying bricks or stones by torpedo jar special brick third (6,7,8) and is formed, and a longitudinal cross-section of this brick is a right-angled trapezium, and another longitudinal cross-section is an isosceles trapezoid; Headwall inside lining building section (54) is built by laying bricks or stones by torpedo jar special brick fourth (9) and is formed, and this brick is a rectangular parallelepiped.
Be provided with one section cambered surface end liner and build layer by laying bricks or stones between the bottom of described cylindrical shell inside lining building section (51,52) and spray material (2), this end liner is built layer by laying bricks or stones and is built by laying bricks or stones by torpedo jar special brick penta (10) and form; Perhaps described cylindrical shell inside lining building section (51,52) directly contacts with spray material (2), does not establish end liner in the middle of it and builds layer by laying bricks or stones.
Described torpedo jar special brick brick second (4,5) comprises two (5) of one of unit brick second (4) and unit brick second; Two (5) isosceles trapezoid cross section of one of this unit brick second (4) and unit brick second, the waist of its isosceles trapezoid is different with the base corner dimension, waist of one of unit brick second (4) and end angle (α
1) less than two (5) waist and the end angle of cut (α of unit brick second
2); One of torpedo jar special brick second (4) for regulating brick, this brick is built by laying bricks or stones at impact zone (51) center or non-impact zone (52) center as required.
Described torpedo jar special brick third (6,7,8) comprise one of unit brick third (6), unit brick third two (7), unit brick third three (8); One of this unit brick third (6), unit brick third two (7), three (8) isosceles trapezoid cross section of unit brick third, the waist of its isosceles trapezoid is different with the base corner dimension, waist of one of unit brick third (6) and end angle (β
1) greater than two (7) waist and end angle (β of unit brick third
2), two (7) waist and end angle (β of unit brick third
2) greater than three (8) waist and end angle (β of unit brick third
3); In the big end section of described truncated cone shell inside lining building section (53) based on one of torpedo jar special brick third (6), torpedo jar special brick third two (7) for regulating brick; In the stage casing of truncated cone shell inside lining building section (53) based on two (7) of torpedo jar special brick third, torpedo jar special brick third three (8) for regulating brick; In the small end section of truncated cone shell inside lining building section (53) based on three (8) of torpedo jar special brick third.
The right-angled trapezium cross section of brick third (6,7,8) is built in the torpedo jar special use of described truncated cone shell inside lining building section (53) by laying bricks or stones, and the right angle waist of this right-angled trapezium is built by laying bricks or stones in torpedo jar inboard, and the inclination waist contacts with spray material builds (2) by laying bricks or stones.
Positive beneficial effect of the present invention:
1, alumina-silicon carbide-carbon brick for torpedo tank of the present invention and torpedo tank lining structure therewith, on probation at Shoudu Iron and Steel Co and resettlement factory thereof in April, 2006, furnace life obviously improves, and is increased to more than 900 stoves by original less than 300 stoves, furnace life has surpassed original 3 times, has obtained remarkable economic efficiency.
2, to adopt extraordinary alumina, fused corundom, silicon carbide, graphite be that main raw material and wedding agent are made to alumina-silicon carbide-carbon brick for torpedo tank of the present invention, be applicable to torpedo pot bottom impact zone, conical ring and two ends position, also be applicable to position beyond the torpedo jar band of column impact zone, this brick has good anti-slag iron aggressiveness, characteristics such as resistance of oxidation and good thermal shock stability preferably.
3, torpedo tank lining structure therewith of the present invention adopts minimum brick type as far as possible, conveniently joins brick and builds by laying bricks or stones, reduces the brick envelope simultaneously, effectively avoids phenomenons such as brick, dross, sticking iron.
4, alumina-silicon carbide-carbon brick for torpedo tank of the present invention, production technique is simple, do not need high temperature to burn till during moulding, thereby production cost is lower, less investment, instant effect.
Five, embodiment:
Embodiment one: alumina-silicon carbide-carbon brick for torpedo tank
1, raw material:
(1) composition of raw materials: alumina 10%, fused corundom 50%, silicon carbide 3%, graphite 12%, andaluzite 10%, chromic oxide 5%, metallic aluminium 3%, Pure Silicon Metal 3%, resol 4%.
(2) raw material physical and chemical index:
The alumina specification is GAL-88
Fused corundom is Al wherein
2O
3〉=95%
Silicon carbide is SiC 〉=97% wherein, Fe
2O
3≤ 1.2%
Metallic aluminium is Al 〉=98% wherein
Pure Silicon Metal is Si 〉=97% wherein
Chromic oxide is Cr wherein
2O
3〉=98.5%
Graphite is C 〉=95% wherein, moisture content≤0.5%, volatile matter<2.0%
Andaluzite is Al wherein
2O
3〉=55%
Resol solid content 〉=75%, fixed carbon 〉=45%
Each raw material moisture can not be greater than 0.5%, otherwise, must be used further to after the raw material stoving produce.
2, production technique:
Take by weighing alumina, fused corundom, fused corundom as aggregate, aggregate is done mixed 1min, add resol, mixed grind 3-5min again; Add fines mixed grind 10min such as silicon carbide, graphite, andaluzite, chromic oxide, metallic aluminium, Pure Silicon Metal, blowing; Moulding then, drying are burnt till.
(1) mixed grind requires:
Total mixed grind time of every biscuit must not be less than 15 minutes, and winter, raw material should suitably be heated to 45 ± 5 ℃.
(2) moulding requires:
A) this operation should strictly be controlled, and calculates substance by the physical size of goods, and the decision cycle, should guarantee that per kilogram material cycle must not be lower than 1.5 times.
B) during moulding, it is heavy to abide by light earlier back, forbids cold principle of beating, and avoids and eliminate the slabbing phenomenon.
C) work in-process of producing are wanted strict and are checked by the technology block-by-block, accomplish that overall dimensions are accurate, flawless, slabbing, arrisdefect, fall defectives such as rib, overlap, pitted skin.
(3) burn till requirement:
When burning till, intensification will be carried out in accordance with regulations operation, and paying special attention to can not be on fire too fast, and heat-up rate is as follows:
Temperature (℃) temperature rise rate (℃/10min)
Normal temperature~60 ℃ 4
60 ℃ of insulation 1h
60~100℃ 2
100 ℃ of insulation 1h
100~150℃ 3
150~200℃ 4
200~220℃ 4
Kiln discharge behind insulation 12h under 220 ℃.
Embodiment two: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: alumina 60%, fused corundom 10%, silicon carbide 20%, graphite 2%, andaluzite 3%, chromic oxide 0.5%, metallic aluminium 0.2%, Pure Silicon Metal 0.3%, resol 4%.
Embodiment three: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: alumina 20%, fused corundom 40%, silicon carbide 18%, graphite 12%, andaluzite 5%, chromic oxide 1%, metallic aluminium 0.5%, Pure Silicon Metal 0.5%, resol 3%.
Embodiment four: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: superfine Shanxi bauxite clinker 50%, fused white corundum 20%, silicon carbide 5%, graphite 5%, andaluzite 8%, chromic oxide 4%, metallic aluminium 2%, Pure Silicon Metal 1%, resol 5%.
Embodiment five: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials is: superfine Shanxi bauxite clinker 30%, electric smelting sub-white corundum 35%, silicon carbide 10%, graphite 10%, andaluzite 5%, chromic oxide 3%, metallic aluminium 1%, Pure Silicon Metal 2%, novolac resin 4%.
Embodiment six: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: granularity is that the alumina of 5~3mm accounts for 5%, granularity is that the alumina of 3~1mm accounts for 30%, granularity is the fused brown corundum 40% of 1~0.1mm,-200 purpose silicon carbide 5%, graphite 5% ,-200 purpose andaluzites 5% of L-190,-180 purpose chromic oxide 1%,-200 purpose metallic aluminiums 2% ,-200 purpose Pure Silicon Metals 3%, novolac resin 4%.
Embodiment seven: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: granularity is that the alumina of 5~3mm accounts for 15%, granularity is that the alumina of 3~1mm accounts for 20%, granularity is the electric smelting compact alumina 20% of 1~0.1mm,-200 purpose silicon carbide 15%, graphite 15% ,-200 purpose andaluzites 8% of L-190,-180 purpose chromic oxide 1%,-200 purpose metallic aluminiums 1% ,-200 purpose Pure Silicon Metals 1%, heat-reactive phenolic resin 4%.
Embodiment eight: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: granularity is that the alumina of 5~3mm accounts for 10%, granularity is that the alumina of 3~1mm accounts for 25%, granularity is the electric smelting compact alumina 30% of 1~0.1mm,-200 purpose silicon carbide 10%, graphite 10% ,-200 purpose andaluzites 6% of L-190,-180 purpose chromic oxide 3%,-200 purpose metallic aluminiums 1.5% ,-200 purpose Pure Silicon Metals 0.5%, heat-reactive phenolic resin 4%.
Used alumina is a superfine Shanxi bauxite clinker, and specification is with embodiment one.
Embodiment nine: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: granularity is that the alumina of 5~3mm accounts for 8%, granularity is that the alumina of 3~1mm accounts for 22%, granularity is the electric smelting compact alumina 15% of 1~0.1mm, and granularity is fused white corundum 15% ,-200 purpose silicon carbide 13% of 1~0.1mm, the graphite 12% of L-190,-200 purpose sillimanites 6% ,-180 purpose chromic oxide 3% ,-200 purpose metallic aluminiums 1.5%,-200 purpose Pure Silicon Metals 0.5%, heat-reactive phenolic resin 4%.
Used alumina is a superfine Shanxi bauxite clinker, and specification is with embodiment one.
Embodiment ten: basic identical with embodiment one, something in common is no longer narrated, and difference is:
Composition of raw materials: granularity is that the alumina of 5~3mm accounts for 13%, granularity is that the alumina of 3~1mm accounts for 25%, granularity is the electric smelting sub-white corundum 10% of 1~0.1mm, and granularity is fused brown corundum 15% ,-200 purpose silicon carbide 8% of 1~0.1mm, the graphite 10% of L-190,-200 purpose kyanites 7% ,-180 purpose chromic oxide 3% ,-200 purpose metallic aluminiums 3%,-200 purpose Pure Silicon Metals 2%, heat-reactive phenolic resin 4%.
Used alumina is a superfine Shanxi bauxite clinker, and specification is with embodiment one.
Embodiment 11: referring to Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, Fig. 9, a kind of torpedo tank lining structure therewith, the spray material 2 that contains the tank body inner side-wall, tank body intermediary jar mouth 1, the refractory brick work layer of spray material 2 inboards, this refractory brick work layer comprises cylindrical shell inside lining building section 51,52, truncated cone shell inside lining building section 53 and headwall inside lining building section 54, and wherein cylindrical shell inside lining building section comprises jar impact zone 51 and the non-impact zone 52 under mouthful 1; Described impact zone 51 is built by laying bricks or stones by torpedo jar special brick first 3 and is formed, and a longitudinal cross-section of this brick is a rectangle, and another longitudinal cross-section is an isosceles trapezoid; Non-impact zone 52 is built by laying bricks or stones by torpedo jar special brick second 4,5 and is formed, and longitudinal cross-section of this brick is a rectangle, and another longitudinal cross-section is an isosceles trapezoid, and wherein the height of unit brick first 3 is greater than the height of unit brick second 4,5; Truncated cone shell inside lining building section 53 is built by laying bricks or stones by torpedo jar special brick the third 6,7,8 and is formed, and a longitudinal cross-section of this brick is a right-angled trapezium, and another longitudinal cross-section is an isosceles trapezoid; Headwall inside lining building section 54 is built by laying bricks or stones by torpedo jar special brick fourth 9 and is formed, and this brick is a rectangular parallelepiped.
Be provided with one section cambered surface end liner and build layer by laying bricks or stones between the bottom of described cylindrical shell inside lining building section 51,52 and spray material 2, this end liner is built layer by laying bricks or stones and is built by laying bricks or stones by torpedo jar special brick penta 10 and form.
Described torpedo jar special brick brick second 4,5 comprises unit brick second 1 and unit brick second 25; The isosceles trapezoid cross section of this unit brick second 1 and unit brick second 25, the waist of its isosceles trapezoid is different with the base corner dimension, the waist of unit brick second 1 and end angle α
1Waist and end angle of cut α less than unit brick second 25
2Torpedo jar special brick second 1 is for regulating brick, and this brick is built by laying bricks or stones at impact zone 51 centers or non-impact zone 52 centers as required.
Described torpedo jar special brick the third 6,7,8 comprises unit brick third 1, unit brick third 27, unit brick third 38; The isosceles trapezoid cross section of this unit brick third 1, unit brick third 27, unit brick third 38, the waist of its isosceles trapezoid is different with the base corner dimension, the waist of unit brick third 1 and end angle β
1Waist and end angle β greater than unit brick third 27
2, the waist of unit brick third 27 and end angle β
2Waist and end angle β greater than unit brick third 38
3Based on torpedo jar special brick third 1, torpedo jar special brick third 27 is for regulating brick in the big end section of described truncated cone shell inside lining building section 53; Based on torpedo jar special brick third 27, torpedo jar special brick third 38 is for regulating brick in the stage casing of truncated cone shell inside lining building section 53; In the small end section of truncated cone shell inside lining building section 53 based on torpedo jar special brick third 38.
The right-angled trapezium cross section of brick the third 6,7,8 is built in the torpedo jar special use of described truncated cone shell inside lining building section 53 by laying bricks or stones, and the right angle waist of this right-angled trapezium is built by laying bricks or stones in torpedo jar inboard, and the inclination waist contacts with spray material 2 and builds by laying bricks or stones.
Embodiment 12: referring to Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, Fig. 9, Figure 10, number identically with embodiment one, same meaning does not repeat, different is: cylindrical shell inside lining building section 51,52 with directly contact with spray material 2, do not establish end liner in the middle of it to build layer by laying bricks or stones.