CN100488913C - Reproduced energy-saving material produced by using waste raw material and usage thereof - Google Patents
Reproduced energy-saving material produced by using waste raw material and usage thereof Download PDFInfo
- Publication number
- CN100488913C CN100488913C CNB2007100177868A CN200710017786A CN100488913C CN 100488913 C CN100488913 C CN 100488913C CN B2007100177868 A CNB2007100177868 A CN B2007100177868A CN 200710017786 A CN200710017786 A CN 200710017786A CN 100488913 C CN100488913 C CN 100488913C
- Authority
- CN
- China
- Prior art keywords
- waste
- sand
- saving material
- reproduced energy
- reproduced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a regenerative energy saving material by using waste raw material, setting the mass percent at 42-52% regenerating particle mixed with waste polyvinyl chloride, waste polyethylene and waste propane polymer, 42-52% waste tailings ore, 0.5-0.8% silane cross linker, 0.2-0.5% antioxidant phosphorous acid bisphenol A or 2, 4, 6-tri- tertiary butyl phenol, 2-3% epoxide modified phenol resin or oil resin, 0.5-1% cadmium zinc heating stabilizer and 1-2% waste machine oil, the surplus is industrial alcohol. This material can be used to produce inspection cub, well cover, sewer well grate, curb, dustbin, railway sleeper or environmental material.
Description
Technical field
The present invention relates to a kind of twice-laid stuff and uses thereof, particularly relate to a kind of reproduced energy-saving material that scrap feed material makes and uses thereof that utilizes.
Background technology
In the actual life directly the harm humans environment following two big class rubbish are arranged:
(1) plastic living rubbish, the waste plastic that comprises various compositions such as polypropylene, polyethylene, polyvinyl chloride, as: mixed polymers such as Polywoven Bag, plastic hand bag, plastic packing article, waste plastic goods, waste plastic plastic sheeting for farm use, can not natural degradation because of it, environment is caused very big harm.
(2) our province Shan Nan, northern Shensi and these local frontier area rare metal mining depositses are very abundant, the large-scale stateowned enterprise and the private individual enterprise that are engaged in the mining industry exploitation are more, these mining industry master produces a large amount of slag dust ashes in the production performance history, not only without any economy, use value, also to constantly occupy large-area arable land on the contrary, and damage physical environment day by day, caused the havoc of large-area travel fatigue pollution in these surrounding areas, place, mining area and natural ecological environment.
In the street in city, the inspection chamber of some telecommunication cables, combustion gas trench and water drain well lid, well grate still use old-fashioned cast prod.The tradition existing disadvantage of urban operating mechanism and deficiency, damaged easily as the used urban operating mechanism of tradition, install heavy, seriously stolen, energy consumption, original outmoded, cost an arm and a leg, very different or the like problem.Add artificial pilferage and destruction, cause casualties and the traffic accident generation, urban construction has been formed serious harm.In addition, existing casting iron well lid cost and price are too high, Heavy Weight, and construction inconvenience makes the renewal of product be subjected to the restriction of economic condition, develops the inexorable trend that a kind of new urban operating mechanism substitute products have become society.
Summary of the invention
The objective of the invention is at above-mentioned the deficiencies in the prior art, a kind of reproduced energy-saving material that scrap feed material makes and uses thereof that utilizes is provided.
For achieving the above object, the technical solution adopted in the present invention is: a kind of reproduced energy-saving material that utilizes scrap feed material to make is characterized in that the weight percentage of this each component of reproduced energy-saving material is:
The mixed regeneration particle 42～52% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 42～52%, silane crosslinker 0.5～0.8%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.2～0.5%, epoxide modified resol or petroleum resin 2～3%, cadmium zinc heat stabilizer 0.5～1% is discarded machine oil 1～2% by the emperor himself, and all the other are industrial alcohol.
The purposes of this reproduced energy-saving material is that the product of making of this reproduced energy-saving material is inspection chamber walling crib, well lid, water drain well grate, Road isolating pillar, curb, tree wall grate, refuse container, road brick, artwork, subway sleeper, all kinds of brick and tile or environment-friendly building materials.
Described discarded tailing sand is any in iron sand, aluminium ore sand, zinc ore, galena, molybdenum ore sand, nickel minerals sand, quartz sand and the mountain range soil, or two or more mixture wherein.
The present invention compared with prior art has the following advantages:
1, become useless and be usefulness, economize on resources, can save a large amount of metallic substance, energy-saving effect is remarkable;
2, environment purification reduces the environmental pollution that causes because of the waste stacking;
3, substitute traditional high energy consumption product as novel regenerated construction material, and can be widely used in the municipal public use auxiliary facility;
4, the raw material production cost is low, and price is low, and maintenance cost is low, can save municipal funds, produces remarkable economic efficiency;
5, material source is extensive, anticorrosion antiwear, and long service life, good insulation preformance, in light weight, be easy to construction, be easy to large scale application;
Embodiment
Below in conjunction with embodiment technology contents of the present invention is elaborated.
Embodiment 1
The raw material of this reproduced energy-saving material is formed and weight percentage is:
The mixed regeneration particle 52% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 42%, silane crosslinker 0.5%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.2%, epoxide modified resol or petroleum resin 2%, the cadmium zinc heat stabilizer 0.5% of admiring, discarded machine oil 1%, all the other are industrial alcohol, and each component concentration sum equals 100%.
Its preparation technology is: for guaranteeing reinforced filling and additives thorough mixing, by above-mentioned formula ratio material is pressed the mixed regeneration particle of discarded tailing sand, waste polyvinyl chloride, waste polyethylene and waste polypropylene, epoxide modified resol or petroleum resin, silane crosslinker, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4, the order of 6-tri-butyl-phenol, the cadmium zinc heat stabilizer of admiring, discarded machine oil and industrial alcohol adds under whipped state in the dry type cylinder mixer successively, thorough mixing under room temperature state, stand-by behind the mixing; Under 130 ℃～140 ℃ temperature, in screw extrusion press, carry out fully mixing to compound, obtain the thick matrix material of crosslinked adherent, under hot state, send in the design mode timber die, compression moulding under 300 tons of pressure, get final product high strength reproduced energy-saving material-type material products.
Embodiment 2
The raw material of this reproduced energy-saving material is formed and weight percentage is:
The mixed regeneration particle 42% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 52%, silane crosslinker 0.8%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.5%, epoxide modified resol or petroleum resin 2%, the cadmium zinc heat stabilizer 0.5% of admiring, discarded machine oil 1.5%, all the other are industrial alcohol, and each component concentration sum equals 100%.
Its preparation technology is with embodiment 1.
Embodiment 3
The raw material of this reproduced energy-saving material is formed and weight percentage is:
The mixed regeneration particle 47% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 47%, silane crosslinker 0.6%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.4%, epoxide modified resol or petroleum resin 2%, the cadmium zinc heat stabilizer 1% of admiring, discarded machine oil 1%, all the other are industrial alcohol, and each component concentration sum equals 100%.
Its preparation technology is with embodiment 1.
Embodiment 4
The raw material of this reproduced energy-saving material is formed and weight percentage is:
The mixed regeneration particle 45% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 45%, silane crosslinker 0.8%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.5%, epoxide modified resol or petroleum resin 3%, the cadmium zinc heat stabilizer 1% of admiring, discarded machine oil 2%, all the other are industrial alcohol, and each component concentration sum equals 100%.
Its preparation technology is with embodiment 1.
Embodiment 5
The raw material of this reproduced energy-saving material is formed and weight percentage is:
The mixed regeneration particle 46% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 46%, silane crosslinker 0.7%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.4%, epoxide modified resol or petroleum resin 2.5%, the cadmium zinc heat stabilizer 0.8% of admiring, discarded machine oil 1.5%, all the other are industrial alcohol, and each component concentration sum equals 100%.
Its preparation technology is with embodiment 1.
The present invention adopts the rejected material regenerated granule material as the inborn nature matrix material in the prescription, and the discarded ore in sand form that uses the metal mining industry is as reinforcement (degree) stopping composition.These two kinds of raw materials cooperate the shape need that had both satisfied finished product, have guaranteed that again finished product have enough working strengths.In order to guarantee effective mortise of inorganic solid filler and polymkeric substance, so adding proper amount of cross-linking agent in prescription is coupling agent, the present invention selects silane coupling agent for use, be because silane molecule has dual-use function, its molecule part can form the covalent linkage bridge with figuration matrix polymer molecule, molecule another part can with reinforcement (degree) inorganic solid filling surface bonding, be good binding agent between inorganic fillers and the polymkeric substance, can increase substantially physical strength, thermotolerance and the work-ing life of finished product.Consider that the finished product polymkeric substance may cause wearing out in the medium-term and long-term use of complicated severe environment, also be anti-aging agent-phosphorous acid dihydroxyphenyl propane so in prescription, add proper quantity of antioxidant, antioxidant 246 is 2,4, the 6-tri-butyl-phenol all has good anti-oxidant (anti-old) performance to plastics such as polyolefine, polyvinyl chloride, resin.In prescription, add a certain amount of epoxide modified resol or petroleum resin simultaneously, can increase the binding property between filler and the polymkeric substance on the one hand, help the intensity stopping composition to be soaked into again, lubricated, and in polymkeric substance, evenly disperse fully, also can improve the processing characteristics of matrix material.Consider that the high strength composite preparation is to carry out under comparatively high temps, in adding hot procedure, degrade, so in prescription, add an amount of cadmium zinc heat stabilizer 104-1 that admires for preventing polymkeric substance.Add a certain amount of discarded machine oil when above-mentioned mixing of materials is disperseed, because the infiltration of machine oil self, lubricity not only can improve the dispersiveness of mixture in the blend process, and flowability also has demoulding effect.In addition, as linking agent, the dispersion medium of antioxidant, industrial alcohol be should give consideration in prescription.
KH-550 silane crosslinker, its molecular formula are C
9H
23O
3NSi, structural formula H
2NCH
2CH
2Si (C
2H
5)
3, the molecular formula of antioxidant phosphorous acid dihydroxyphenyl propane is C
45H
45O
6P, its structural formula is:
Antioxidant 2,4, the molecular formula of 6-tri-butyl-phenol are C
18H
30O, structural formula is:
The phenolic aldehyde molecular structural formula is:
See the following form with the survey report of reproduced energy-saving material of the present invention as material of construction:
Claims (3)
1, a kind of reproduced energy-saving material that utilizes scrap feed material to make is characterized in that the weight percentage of this each component of reproduced energy-saving material is:
The mixed regeneration particle 42～52% of waste polyvinyl chloride, waste polyethylene and waste polypropylene, discarded tailing sand 42～52%, silane crosslinker 0.5～0.8%, antioxidant phosphorous acid dihydroxyphenyl propane or 2,4,6-tri-butyl-phenol 0.2～0.5%, epoxide modified resol or petroleum resin 2～3%, barium cadmium zinc heat stabilizer 0.5～1%, discarded machine oil 1～2%, all the other are industrial alcohol.
2, the reproduced energy-saving material that utilizes scrap feed material to make according to claim 1, it is characterized in that described discarded tailing sand is a kind of in iron sand, aluminium ore sand, zinc ore, galena, molybdenum ore sand, nickel minerals sand and the quartz sand, or two or more mixtures.
3, the purposes of reproduced energy-saving material according to claim 1 is characterized in that the product of making of this reproduced energy-saving material is inspection chamber walling crib, well lid, water drain well grate, Road isolating pillar, curb, tree wall grate, refuse container, road brick, artwork or subway sleeper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100177868A CN100488913C (en) | 2007-04-30 | 2007-04-30 | Reproduced energy-saving material produced by using waste raw material and usage thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100177868A CN100488913C (en) | 2007-04-30 | 2007-04-30 | Reproduced energy-saving material produced by using waste raw material and usage thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101041573A CN101041573A (en) | 2007-09-26 |
| CN100488913C true CN100488913C (en) | 2009-05-20 |
Family
ID=38807391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100177868A Expired - Fee Related CN100488913C (en) | 2007-04-30 | 2007-04-30 | Reproduced energy-saving material produced by using waste raw material and usage thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100488913C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292613A (en) * | 2014-09-15 | 2015-01-21 | 合肥瑞瑶环保建材科技有限公司 | Corrosion-resistant plastic manhole |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168610B (en) * | 2007-10-12 | 2010-10-20 | 唐山金三顺装饰材料有限公司 | Producing method of special-purpose board for building |
| CN101698312B (en) * | 2009-10-16 | 2011-05-04 | 中国铝业股份有限公司 | Method for preparing composite porcelain imitation wood prepared by bauxite tailings |
| CN101736864B (en) * | 2009-11-25 | 2011-06-15 | 南京林业大学 | Rigid polyvinyl chloride pantile and preparation method thereof |
| CN102399401B (en) * | 2011-10-18 | 2013-08-07 | 池州灵芝化建材料科技有限公司 | Environment-friendly cable filler and its preparation method |
| CN103044801B (en) * | 2012-11-29 | 2015-06-24 | 重庆市帅之盾门业有限公司 | Method for preparing solid wood imitated building material by using waterborne floating object |
| CN105198280A (en) * | 2015-08-24 | 2015-12-30 | 泉州市路通管业科技有限公司 | Overall resin inspection well and preparation method thereof |
| CN105602107B (en) * | 2016-01-05 | 2018-03-13 | 安徽瑞瑶环保科技有限公司 | A kind of processing technology of three way type reinforced plastics inspection shaft |
| JP2019516031A (en) * | 2016-04-22 | 2019-06-13 | フォスロー−ベルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング | Manufacturing method of makarigi for railway track superstructure |
| ES2885069T3 (en) * | 2016-04-22 | 2021-12-13 | Vossloh Fastening Systems Gmbh | Procedure for fabricating a sleeper for use in the track superstructure |
| CN108358517A (en) * | 2018-05-11 | 2018-08-03 | 安徽砼宇特构科技有限公司 | A kind of antibacterial preventing water leakage inspection shaft and preparation method thereof |
| CN110511468A (en) * | 2019-08-13 | 2019-11-29 | 北京国达恒泰科贸有限责任公司 | Waste polymer is the preparation method of the railing of substrate |
| CN111171476A (en) * | 2020-02-21 | 2020-05-19 | 苏州绿萃筑新材料科技有限公司 | Composite heat insulation material for green building and preparation method thereof |
| CN111410800A (en) * | 2020-02-24 | 2020-07-14 | 苏州绿萃筑新材料科技有限公司 | Wood-grain-like decorative line and preparation method thereof |
| CN111484274B (en) * | 2020-04-24 | 2021-11-05 | 位赛厦 | Preparation method of highway repair material |
-
2007
- 2007-04-30 CN CNB2007100177868A patent/CN100488913C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292613A (en) * | 2014-09-15 | 2015-01-21 | 合肥瑞瑶环保建材科技有限公司 | Corrosion-resistant plastic manhole |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101041573A (en) | 2007-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100488913C (en) | Reproduced energy-saving material produced by using waste raw material and usage thereof | |
| CN102030942B (en) | Cold-resistant and high temperature-resistant composite material and preparation method thereof | |
| CN102268190B (en) | Recycling method of garbage plastic | |
| CN1712637A (en) | Wholly coated rail sleeper and manufacture thereof | |
| CN101831101B (en) | Preparation method for producing automobile awning special material by using waste plastics | |
| CN105753389A (en) | Baking-free bricks produced by waste bottom slag and production method of baking-free bricks | |
| CN105481272A (en) | Manufacturing methods of geopolymer and precursor thereof, product and application | |
| CN111718172A (en) | Preparation method for producing baking-free bricks by using domestic garbage incinerator slag and waste plastic particles in synergy mode | |
| CN106906691B (en) | Light biomass material and preparation method thereof | |
| CN109320978A (en) | A kind of asphalt mixed material modifier and preparation method thereof | |
| CN102382369B (en) | Luminescent material special for street manhole cover and preparation method thereof | |
| CN101629000B (en) | Asphalt modified product and preparation method thereof | |
| CN1229105A (en) | Modified asphalt compounded with waste plastic and waste rubber | |
| Yaro et al. | Effect of palm oil clinker powder-based geopolymer on bitumen and asphalt mixture properties | |
| CN106145883A (en) | A kind of slag building waste is non-burning brick and preparation method thereof | |
| CN106242513A (en) | A kind of environment-friendly type building brick utilizing waste material to produce and production technology thereof | |
| CN109912253A (en) | A kind of method that plastic garbage prepares water-permeable brick with porous aggregate consolute | |
| CN1163547C (en) | Compound material made from old and waste material and use thereof | |
| CN102260396A (en) | Gull rock polyvinyl chloride-flyash composite material | |
| CN105131392A (en) | Method for processing draining corrugated pipe using waste and old mulch film | |
| CN102167545B (en) | Low-temperature smokeless flame-retardant pavement material for tunnel and preparation method thereof | |
| CN113716913A (en) | Regenerated fiber concrete joggle joint luminous kerb and preparation method thereof | |
| CN102020863B (en) | Filling body dedicated material for hollow floor system prepared from waste plastics by modification and preparation method | |
| CN104278609A (en) | Road pavement material prepared by compounding residue soil and steel slag and method for preparing road pavement material | |
| CN1174815C (en) | Permanent manhole cover made of garbage |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090520 Termination date: 20150430 |
|
| EXPY | Termination of patent right or utility model |