CN100478188C - Photographic paper for computerized digital spray drawing - Google Patents
Photographic paper for computerized digital spray drawing Download PDFInfo
- Publication number
- CN100478188C CN100478188C CNB021129762A CN02112976A CN100478188C CN 100478188 C CN100478188 C CN 100478188C CN B021129762 A CNB021129762 A CN B021129762A CN 02112976 A CN02112976 A CN 02112976A CN 100478188 C CN100478188 C CN 100478188C
- Authority
- CN
- China
- Prior art keywords
- base material
- photographic paper
- spray drawing
- layer
- digital spray
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007921 spray Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 229920000159 gelatin Polymers 0.000 claims abstract description 15
- 235000019322 gelatine Nutrition 0.000 claims abstract description 15
- 108010010803 Gelatin Proteins 0.000 claims abstract description 11
- 239000008273 gelatin Substances 0.000 claims abstract description 11
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 230000001464 adherent effect Effects 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000001828 Gelatine Substances 0.000 claims description 4
- -1 alkyl phosphoric acid diethanol ammonium salt Chemical compound 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 239000004923 Acrylic lacquer Substances 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 11
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000003068 static effect Effects 0.000 abstract description 3
- 238000009825 accumulation Methods 0.000 abstract 1
- 238000004873 anchoring Methods 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 239000002274 desiccant Substances 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
Images
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- Paper (AREA)
Abstract
The photographic paper for computerized digital spray drawing consists of main base material and subsidiary base material. Its main base material has painted intermediate layer and ink absorbing layer, and its subsidiary base material is stuck via adhesive to the main base material. Into the said ink absorbing layer, are added anchoring agent in 1-3%, color fixing agent in 2-6%, quick drying agent in 2-3 % and gelatin in 1-5% to raise the printing resolution and shorten ink absorbing period. In addition, one antistatic skidproof coatign comprising polyacrylic varnish, dulling powder and antistatic agent is painted to the subsidiary base material to prevent accumulation of static electricity and sliding.
Description
Technical field:
The present invention relates to a kind of printing paper, refer more particularly to a kind of high-resolution photographic paper for computerized digital spray drawing.
Background technology:
Fast development along with electronic information technology, traditional photograph and ad production adopt the numerial code spray drawing technology more and more, promptly adopt digital camera to take a picture, then digital information is input in the computer, and to the image of photograph carry out Creation Through Computer, drive ink-jet printer again, image is printed on the photographic paper for computerized digital spray drawing, the image fabric width that adopts this mode to print can reach 36 ", 50 ", 60 ", 72 " even can reach 6m, the length maximum can reach 30m, is used in widely in outdoor advertising and the photographic image.At present, domestic production numerial code spray drawing printing paper generally only is applicable to the heat sublimation type ink-jet printer, the printing paper ink that this machine uses requires low, the print image precision low (≤1440dpi), the printing and making pattern can only be used for advertisement, panel and picture and text to be handled, can not adapt to the image requirement, its basic reason is that printing precision is that resolution ratio is too low; In addition, in print procedure, the high-pressure electrostatic 〉=1200V that produces on the PET film, easily the ink gun with printer breaks, and also can be forbidden because of electrostatic interaction causes image to print; Because the printing paper two sides is very smooth, causes and print the luck walking partially, image fault simultaneously.
Summary of the invention:
Photographic paper for computerized digital spray drawing of the present invention is made up of main base material and secondary base material, and main base material generally adopts PH stationery, PP synthetic paper or PET polyester film; Secondary base material is to add the antiadhesion barrier that is coated with silicone oil, and material generally adopts papery or plastic sheeting.In process, at first main base material is coated with last layer silane coupling agent (Primer) intermediary layer, and then is coated with last layer ink-absorbed coated layer PVA polyvinyl alcohol, the secondary base material that scribbles silicone oil is coated with the last layer adhesive sticker; At last secondary base material is sticked on the main base material by adhesive sticker, just can form the photographic paper for computerized digital spray drawing of back of the body spray formula.One deck is antistatic, the anti-slip coating if be coated with at secondary base material another side, just can generate air brushing printing paper antistatic, anti-slip.Comprise crucial industrial chemicals in the ink-absorbed coated layer PVA polyvinyl alcohol: the gelatin of the anchor fixing agent of 1-3%, the color-fixing agent of 2-6%, 2-30% quick dry agent and 1-5%.Described anchor fixing agent can adopt DOW CORNING-297; Described color-fixing agent can adopt color fixing agent Y, also can adopt cotton with color-fixing agent or anion color-fixing agent; Described quick dry agent adopts aerosil 405, or adopts precipitated silica 401, also can adopt silica gel series (P703, AS-30) etc.; Described gelatin generally adopts photographic gelatin or industrial gelatine.Form because of ink-absorbed coated layer PVA comprises anchor fixing agent, color-fixing agent, quick dry agent and gelatin mixing, its ink-absorbed coated layer blotting time obviously accelerates, and drying time is short, and the print resolution height, and ink dot is difficult for oozing expansion.
In addition, at static that occurs in the print procedure and printing paper skidding, the present invention adds antistatic, an anti-slip coating on the surface of secondary base material PET antiadhesion barrier, this coating mainly is made up of flatting silica and the 10-15% antistatic additive of 78-88% acrylic lacquer, 4-11%, described flatting silica adopts precipitated silica 401, or adopt aerosil 405, also can adopt SYLOJE and SYLOLD silica gel; Described antistatic additive can adopt octadecyl dimethyl ethoxy quaternary ammonium nitrate, also can adopt trihydroxyethyl methyl quaternary ammonium sulfate, perhaps adopts alkyl phosphoric acid diethanol ammonium salt.
The present invention compared with prior art has following advantage:
1, have the print resolution height, blotting is fast, drying time is short, ink dot does not ooze characteristics such as expansion.
2, have antistatic and the anti-slip function.
Description of drawings:
Fig. 1 is the structural representation of photographic paper for computerized digital spray drawing of the present invention.
1. ink-absorbed coated layer 2. silane coupling agent intermediary layers 3. main base material 4. non-drying glue layers
5. adherent layer 6. secondary base material 7. antistatic, anti-slip coatings
The specific embodiment:
As can be seen from Figure 1, high-resolution photographic paper for computerized digital spray drawing of the present invention is made up of ink-absorbed coated layer (1), silane coupling agent intermediary layer (2), main base material (3), non-drying glue layer (4), adherent layer (5), secondary base material (6).Main base material (3) adopts the PP polypropylene, and main base material (3) surface scribbles one deck silane coupling agent (Primer) intermediary layer (2), scribbles the ink-absorbed coated layer (1) that one deck is made up of polyvinyl alcohol then on silane coupling agent (Primer) intermediary layer (2); Scribble one deck organic silicone oil adherent layer (5) on secondary base material (6) surface of forming by antiadhesion barrier, and scribble one deck non-drying glue layer (4) on adherent layer (5) surface, secondary base material (6) sticks on the main base material (3) by non-drying glue layer (4), comprises 2% anchor fixing agent, 4% color-fixing agent, 6% quick dry agent and 3% gelatin in described ink-absorbed coated layer (1).Described anchor fixing agent is to adopt DOW CORNING-297, and described color-fixing agent is the anion color-fixing agent, and described quick dry agent is an aerosil 405, and described gelatin generally adopts industrial gelatine.Effect by these anchor fixing agents, color-fixing agent, quick dry agent and gelatin can make the photographic paper for computerized digital spray drawing print resolution be greatly improved, and its blotting is fast, and drying time is short, and ink dot is difficult for oozing expansion.In addition, in order to prevent that the printing paper surface from producing static and skidding, scribble on the surface of secondary base material (6) that one deck is antistatic, the anti-slip coating, this coating is made up of 82% acrylic lacquer, 5.5% aerosil 405 and 12.5% alkyl phosphoric acid diethanol ammonium salt.Its printing colour of the photographic paper for computerized digital spray drawing precision 〉=2000dpi that adopts this method to make prints drying time≤5min, electrostatic charge≤350V on the printed photographic paper, paper feeding error≤5 ‰.
Claims (9)
1, a kind of photographic paper for computerized digital spray drawing is made up of ink-absorbed coated layer (1), intermediary layer (2), main base material (3), non-drying glue layer (4), adherent layer (5), secondary base material (6), be coated with one deck silane coupling agent intermediary layer (2) on described main base material (3) surface, on silane coupling agent intermediary layer (2), scribble the ink-absorbed coated layer (1) that one deck is made up of polyvinyl alcohol then; Scribble one deck organic silicone oil adherent layer (5) on secondary base material (6) surface of forming by antiadhesion barrier, and scribble one deck non-drying glue layer (4) on adherent layer (5) surface, secondary base material (6) sticks on the main base material (3) by non-drying glue layer (4), it is characterized in that: ink-absorbed coated layer (1) comprises the anchor fixing agent of DOW CORNING-297 composition of 1-3%, the anion color-fixing agent of 2-6%, aerosil quick dry agent and 1-5% photographic gelatin or the industrial gelatine composition of 2-30%.
2, the photographic paper for computerized digital spray drawing of explaining according to claim 1, it is characterized in that: scribble on the surface of described secondary base material (6) that one deck is antistatic, anti-slip coating (7), this coating is made up of the acrylic lacquer of 78-88%, flatting silica and the 10-15% antistatic additive that the aerosil of 4-11% is formed.
3, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described color-fixing agent is a color fixing agent Y, and this color fixing agent Y is a dicyandiamide formaldehyde initial reduced body, for cotton is used color-fixing agent.
4, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described quick dry agent is a silica gel series.
5, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described gelatin is photographic gelatin or industrial gelatine.
6, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described flatting silica is SYLOJE and SYLOLD silica gel.
7, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described antistatic additive is an octadecyl dimethyl ethoxy quaternary ammonium nitrate.
8, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described antistatic additive is a trihydroxyethyl methyl quaternary ammonium sulfate.
9, according to claim 1,2 described photographic paper for computerized digital spray drawing, it is characterized in that: described antistatic additive is an alkyl phosphoric acid diethanol ammonium salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021129762A CN100478188C (en) | 2002-04-30 | 2002-04-30 | Photographic paper for computerized digital spray drawing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021129762A CN100478188C (en) | 2002-04-30 | 2002-04-30 | Photographic paper for computerized digital spray drawing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1388007A CN1388007A (en) | 2003-01-01 |
| CN100478188C true CN100478188C (en) | 2009-04-15 |
Family
ID=4742369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021129762A Expired - Lifetime CN100478188C (en) | 2002-04-30 | 2002-04-30 | Photographic paper for computerized digital spray drawing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100478188C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN203410227U (en) * | 2013-05-17 | 2014-01-29 | 陈家桢 | Pre-cut lithographic film capable of being stuck repeatedly |
| CN104228388B (en) * | 2014-09-30 | 2017-06-06 | 江苏奥力广告材料股份有限公司 | A kind of ink-jet advertisement consumptive material and its production method |
| CN104312474B (en) * | 2014-10-23 | 2017-04-26 | 江苏奥力广告材料股份有限公司 | Synthesis back glue paper and production method |
| CN106364206B (en) * | 2016-08-31 | 2019-01-04 | 安徽奥斯博医疗仪器设备有限公司 | A kind of numerial code spray drawing printing consumables |
| CN110181915A (en) * | 2019-06-06 | 2019-08-30 | 广州万点写真新技术有限公司 | A kind of ad production paper and printing device, method |
-
2002
- 2002-04-30 CN CNB021129762A patent/CN100478188C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1388007A (en) | 2003-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EM01 | Change of recordation of patent licensing contract |
Change date: 20130715 Contract record no.: 2011320000601 Assignee after: JIANGSU NAISI DIGITAL TECHNOLOGY INCORPORATED LTD. Assignee before: Jiangsu Nisi Digital Colour Painting Material Co., Ltd. |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20030101 Assignee: JIANGSU NAISI DIGITAL TECHNOLOGY INCORPORATED LTD. Assignor: Li Jianping Contract record no.: 2011320000601 Denomination of invention: Photographic paper for computerized digital spray drawing Granted publication date: 20090415 License type: Exclusive License Record date: 20110418 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180111 Address after: 214500 Xingye Road, South City Park, Jingjiang Economic Development Zone, Taizhou City, Jiangsu Province, No. 12 Patentee after: JIANGSU NAISI DIGITAL TECHNOLOGY INCORPORATED LTD. Address before: 214500 Jiangsu Province, Jingjiang City Ring Road in Jingjiang nice Adhesive Products Co., Ltd. Patentee before: Li Jianping |
|
| TR01 | Transfer of patent right | ||
| CX01 | Expiry of patent term |
Granted publication date: 20090415 |
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| CX01 | Expiry of patent term |