CN100477871C - Organic electroluminescent assembly and manufacturing method thereof - Google Patents
Organic electroluminescent assembly and manufacturing method thereof Download PDFInfo
- Publication number
- CN100477871C CN100477871C CNB2005100632708A CN200510063270A CN100477871C CN 100477871 C CN100477871 C CN 100477871C CN B2005100632708 A CNB2005100632708 A CN B2005100632708A CN 200510063270 A CN200510063270 A CN 200510063270A CN 100477871 C CN100477871 C CN 100477871C
- Authority
- CN
- China
- Prior art keywords
- organic
- layer
- electron transfer
- transfer layer
- chelate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000010410 layer Substances 0.000 claims abstract description 73
- 239000012044 organic layer Substances 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 230000005540 biological transmission Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 37
- 230000027756 respiratory electron transport chain Effects 0.000 claims description 36
- 238000000576 coating method Methods 0.000 claims description 24
- 239000013522 chelant Substances 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 21
- 238000002347 injection Methods 0.000 claims description 21
- 239000007924 injection Substances 0.000 claims description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- -1 fluoro-cesium compound Chemical class 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000005749 Copper compound Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- HHFOOWPWAXNJNY-UHFFFAOYSA-N promoxolane Chemical compound CC(C)C1(C(C)C)OCC(CO)O1 HHFOOWPWAXNJNY-UHFFFAOYSA-N 0.000 claims description 2
- 229950008352 promoxolane Drugs 0.000 claims description 2
- 238000012545 processing Methods 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 238000000151 deposition Methods 0.000 description 7
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000004064 dysfunction Effects 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- TVIVIEFSHFOWTE-UHFFFAOYSA-K tri(quinolin-8-yloxy)alumane Chemical compound [Al+3].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 TVIVIEFSHFOWTE-UHFFFAOYSA-K 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- VQGHOUODWALEFC-UHFFFAOYSA-N 2-phenylpyridine Chemical compound C1=CC=CC=C1C1=CC=CC=N1 VQGHOUODWALEFC-UHFFFAOYSA-N 0.000 description 1
- HXWWMGJBPGRWRS-CMDGGOBGSA-N 4- -2-tert-butyl-6- -4h-pyran Chemical compound O1C(C(C)(C)C)=CC(=C(C#N)C#N)C=C1\C=C\C1=CC(C(CCN2CCC3(C)C)(C)C)=C2C3=C1 HXWWMGJBPGRWRS-CMDGGOBGSA-N 0.000 description 1
- VFUDMQLBKNMONU-UHFFFAOYSA-N 9-[4-(4-carbazol-9-ylphenyl)phenyl]carbazole Chemical compound C12=CC=CC=C2C2=CC=CC=C2N1C1=CC=C(C=2C=CC(=CC=2)N2C3=CC=CC=C3C3=CC=CC=C32)C=C1 VFUDMQLBKNMONU-UHFFFAOYSA-N 0.000 description 1
- 229920001621 AMOLED Polymers 0.000 description 1
- MSDMPJCOOXURQD-UHFFFAOYSA-N C545T Chemical compound C1=CC=C2SC(C3=CC=4C=C5C6=C(C=4OC3=O)C(C)(C)CCN6CCC5(C)C)=NC2=C1 MSDMPJCOOXURQD-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Images
Landscapes
- Electroluminescent Light Sources (AREA)
Abstract
The organic electroluminescent assembly comprises an electron injecting electrode, a buffer layer, an organic layer with at least one luminous layer and an electron transmission layer included CsF, an electric injecting electrode, and a substrate in turn.
Description
Technical field
The present invention is relevant a kind of organic EL component, particularly about a kind of organic EL component and manufacture method thereof of pushing up luminous (topemission) pattern.
Background technology
Organic EL component is by research and discussion ardently recently in Display Technique, it can be in order to make the display of slimming, and display-LCD compared to another kind of slimming, organic EL component is a kind of self luminous assembly, LCD then needs backlight, so organic EL component is the easier full color rendition degree that closes of reaching.
Please refer to Fig. 1, it is an existing organic EL component side generalized section.Organic EL component 100 comprises a substrate 102, a hole injecting electrode 104, a hole transmission layer 110, a luminescent layer 120, an electron transfer layer 140 and an electron injection electrode 150 usually in regular turn.Wherein, hole transmission layer 110, luminescent layer 120 are generally organic material with electron transfer layer 140 and prepare with organic processing procedure.
Electronics can make that combining of luminescent layer 120 electric energy is converted into luminous energy with the hole, if towards below outgoing organic EL component 100, then this kind organic EL component 100 is to belong to the end luminous (bottom emission) pattern to the light that discharges via substrate 102.The organic EL component 100 of the luminous pattern in the end is comparatively common, hole injecting electrode 104 wherein can adopt transparent indium tin oxide (ITO) material, electron injection electrode 150 then utilizes the metal material of low work function, and for example materials such as aluminium, calcium, magnesium and silver are made.And utilize the characteristic that this type of electron injection electrode 150 can be reflective, make light via substrate 102 by organic EL component 100 bottom outgoing.
Yet, because when making display, some necessary leads (for example signal line and scanning linear) are to be made on the substrate 102, if and desire is made active organic electroluminescent assembly (AMOLEDs), then more need make the thin-film transistor array on substrate 102, these leads or thin-film transistor can hinder light penetration.Therefore, the organic EL component 100 of the luminous pattern in the end is the problem with aperture opening ratio.
As shown in Figure 2, it is to be provided that another kind is called the organic EL component 100 that pushes up luminous (top emission) pattern, and it is to make light by the top outgoing, can make then that light has better utilization rate via electron injection electrode 150.
When the organic EL component 100 of the luminous pattern in development top, what at first need is transparent electron injection electrode 150, but when the indium tin oxide material that utilizes transparent and electrically conductive is implemented, the problem that at first suffers from is: when the sputter indium tin oxide, destroy the organic material of its below easily.Therefore, please refer to Fig. 2, people such as G.Parthasaraty have proposed to be used as with benzene dimethylan-copper compound (CuPc) technology of resilient coating 145, and this technology is before forming electron injection electrode 150, one deck resilient coating 145 at first is provided, then can keeps out the destruction of sputter program thus.But this case the inventor point out, according to the electric current injection properties extreme difference of the organic EL component 100a that the people provided such as G.Parhasaraty, so this technology and be not suitable for further commercial applications.Through experiment,, when operating voltage 6V, has only 3.7mA/cm approximately according to the prepared EL component 100a of people's such as G.Parthasaraty technology
2The electric current injection efficiency, and energy efficiency is less than 11m/W.
Please refer to Fig. 3, Fig. 3 shows another prior art.The another kinds that the people provided such as Hung Liang-sun are about the prior art of organic EL component 100b, wherein, resilient coating 145 still adopts benzene dimethylan-copper compound (CuPc), yet it is before forming resilient coating 145, plated the thin metal of one deck, be to carry out it in the document with fluoro-lithium compound (LiF) interface layer 143 in advance.This technology is to diffuse in the organic material of its below by the lithium among the fluoro-lithium compound interface layer 143, so that Jie's dysfunction of the aluminium chelate compound of electron transfer layer 140 (energy barrier) reduces, injects in order to electronics.As if therefore people such as Hung Liang-sun have solved the shortcoming of prior art shown in Figure 2.
Yet this case the inventor point out, among the prior art shown in Figure 3, because lithium diffuses to luminescent layer 120 inside easily further, so the assembly life-span of meeting loss organic EL component 100b.In addition, luminescent layer 120, electron transfer layer 140 all can utilize organic process apparatus (organic chamber) to make with resilient coating 145, yet 143 needs of fluoro-lithium compound interface layer utilize metal procedure equipment (metal chamber) to make, therefore the prior art of Fig. 3 is forming luminescent layer 120 and electron transfer layer 140 organic materials such as grade (in organic process apparatus) afterwards, at least need to move to metal procedure equipment, move to organic process apparatus again, move to sputter process equipment (sputtering chamber) at last again to form electron injection electrode 150, at least need three times processing procedure to shift, so the processing procedure complexity is a shortcoming of this kind prior art.
In view of this, how a kind of organic EL component that pushes up luminous pattern is provided, and can solve in the prior art simultaneously, the destruction of sputter program, electric current injection efficiency low, assembly life-span is too short and processing procedure is complicated ... etc. various shortcoming, be that current techniques lacks and the direction of needs development.
Summary of the invention
Main purpose of the present invention is to be to provide a kind of organic EL component with luminous pattern in top of high electric current injection efficiency.
Another object of the present invention is to be to improve the too short shortcoming of the assembly life-span of organic EL component in the prior art.
Another object of the present invention is to be to provide a kind of processing procedure easy organic EL component manufacture method.
The present invention provides a kind of organic EL component and its manufacture method, organic EL component comprises that a substrate, a hole injecting electrode are formed on this substrate, an organic layer is formed on this hole injection layer, a resilient coating is formed on this organic layer, and an electron injection electrode is on this resilient coating.Wherein, the organic layer below resilient coating can be protected in the high-energy plated film program that forms this electron injection electrode.Organic layer of the present invention comprises that at least a luminescent layer and an electron transfer layer are formed on this luminescent layer.This electron transfer layer comprises fluoro-caesium (CsF) compound at least, can reduce Jie's dysfunction (energybarrier), injects in order to electronics.
Description of drawings
Fig. 1 is an existing organic EL component side generalized section;
Fig. 2 is the organic EL component of the luminous pattern in an existing top;
Fig. 3 is the organic EL component of another luminous pattern in existing top; And
Fig. 4 is an organic EL component side generalized section of the present invention.
Symbol description:
Organic EL component 100,100a, 100b, 200 substrates 102,202
Hole injecting electrode 104,204 hole transmission layers 110,210
Luminescent layer 120,220 electron transfer layers 140,240
Fluoro-lithium compound interface layer 143 resilient coatings 145,245
Electron injection electrode 150,250 organic layers 23
First electron transfer layer, 241 second electron transfer layers 242
Embodiment
Please refer to Fig. 4, Fig. 4 is an organic EL component side generalized section of the present invention.When making organic EL component 200, be that a substrate 202 at first is provided.Then then hole injecting electrode 204 is formed on the substrate 202.Substrate 202 optional self-induced transparencys or opaque but have the material of reflectivity properties.And the conductive material of hole injecting electrode 204 optional self-induced transparencys, for example indium tin oxide (Indium TinOxide, ITO), (Indium Zinc Oxide IZO) waits material to indium-zinc oxide, and makes with sputtering method; If hole injecting electrode 204 adopts metal material, then can select the preferable magnesium of conductivity, lithium metal or alloy, and be made on the substrate 202 with evaporation or sputtering way.
Then, then form organic layer 23 on hole injecting electrode 204.Organic layer 23 can be a sandwich construction, and it comprises a luminescent layer 220 and an electron transfer layer 240 at least, and electron transfer layer 240 is formed on the luminescent layer 220, and electron transfer layer 240 is to comprise fluoro-caesium (CsF) compound.Wherein, organic layer 23 can have a hole transmission layer 210 between luminescent layer 220 and hole injecting electrode 204.
Wherein, luminescent layer 220 materials can use fluorescent or phosphorescence pigment or chelate materials such as Alq3, NPB, CuPc, C545T, DCJTB, CBP, Balq, Ir (ppy) 3.The formation method is that the vacuum vapour deposition, ionization vapour deposition method, organic molecular line vapour deposition method, electric slurry polymerization, vacuum evaporation polymerization, organic molecular line vapour deposition method, the electricity that are selected from vacuum vapour deposition, electron beam heating are starched polymerization, vacuum evaporation polymerization, soak the lining method, rotated coating method, Langmuir-Blodgett (LB) membrane process, Sol-Gel method, electrolysis polymerization method .... etc.
Afterwards, then form electron transfer layer 240 on luminescent layer 220.The formation method of electron transfer layer 240 is to comprise: 1) deposition one metallo-chelate is on this luminescent layer; And 2) fluoro-cesium compound (CsF) is doped in the above-mentioned metallo-chelate.Wherein, metallo-chelate is aluminium chelate compound (Alq3) for example, and the mode of mixing up of fluoro-cesium compound (CsF) then can be for example hot vapour deposition method.
When mixing up fluoro-cesium compound (CsF), can make the fluoro-cesium compound only be doped to the metallo-chelate of part, and make electron transfer layer 240 become the pair of lamina structure, as shown in Figure 4, it is to comprise that one first electron transfer layer 241 and one second electron transfer layer, 242, the second electron transfer layers 242 are positioned on first electron transfer layer 241.Wherein second electron transfer layer 242 comprises above-mentioned fluoro-cesium compound and metallo-chelate; And first electron transfer layer 241 only comprises metallo-chelate, for example aluminium chelate compound.
Follow-up, then form resilient coating 245 on organic layer 23, in the enforcement, resilient coating 245 comprises benzene dimethylan material (phthalocyanine material), for example a benzene dimethylan-copper compound (CuPc).Step about above-mentioned formation organic layer 23, step until the resilient coating 245 that forms its top, all can in organic process apparatus (organic chamber), finish, also need not carry out the transfer of processing procedure or equipment even if form the step of electron transfer layer 240 therebetween, can directly in organic process apparatus, carry out.
At last; 250 of electron injection electrodes are formed on the resilient coating 245; but electron injection electrode 250 is to select transparent electric conducting material for example indium tin oxide (ITO) or indium-zinc oxide (IZO) for use; it is with high-octane coating method; sputter for example; with film forming on resilient coating 245, each layer structure below resilient coating 245 can be protected when sputter.
Method for making explanation by the invention described above organic EL component 200 can find out that compared to prior art, the present invention has the easy advantage of processing procedure.In the DESCRIPTION OF THE PRIOR ART that Fig. 3 is correlated with, reach, the technology that the people provided such as HungLiang-sun, after forming luminescent layer, at least the processing procedure of needs three times shifts (organic process apparatus → metal procedure equipment → organic process apparatus → sputter process equipment), and the spontaneous photosphere 120 of the present invention all can be made in organic process apparatus until resilient coating 245, only need when forming electron injection electrode 250, to move in the sputter process equipment, only transfer once is the efficient that promotes processing procedure significantly.
Further according to technology provided by the present invention, organic EL component 200 of the present invention is carried out the actual measurement of electric current injection and current efficiency, under the situation of operating voltage 6V, organic EL component 200 of the present invention is 52mA/cm
2, not only the prior art that the people provided such as G.Parthasaraty more shown in Figure 2 exceeds ten several times, and also is higher than the prior aries that the people provided such as Hung Liang-sun shown in Figure 3.And energy efficiency of the present invention is about 11.6lm/W, also is higher than above-mentioned two kinds of prior aries (being about respectively less than 1lm/W, with 9lm/W).In addition, the brightness of organic EL component 200 of the present invention is when 2000nits, its assembly life-span is can reach more than 1,500 hours, in the prior art, lithium diffuses to luminescent layer inside easily further, and the existing shortcoming of the assembly life-span of loss organic EL component is improved effectively.
Though the present invention illustrates as above with preferred embodiments, so it is not only to terminate in the foregoing description that in order to limit the present invention's spirit with the invention entity.To being familiar with this operator, when understanding and utilize other assembly or mode to produce identical effect easily.Be with, the modification of being done in not breaking away from spirit of the present invention and scope all should be included in the described claim.
Claims (11)
1. organic EL component comprises at least:
One substrate;
One hole injecting electrode is formed on this substrate;
One organic layer is formed on this hole injecting electrode, and this organic layer comprises a luminescent layer at least, and an electron transfer layer is formed on this luminescent layer, and this electron transfer layer is to comprise a fluoro-cesium compound;
One resilient coating is formed on this organic layer;
One electron injection electrode is formed on this resilient coating; And
Described electron transfer layer more comprises a metallo-chelate.
2. organic EL component according to claim 1, wherein this metallo-chelate is an aluminium chelate compound.
3. organic EL component according to claim 1, wherein this electron transfer layer is the pair of lamina structure, comprise that one first electron transfer layer and one second electron transfer layer are positioned on this first electron transfer layer, wherein this second electron transfer layer comprises this fluoro-cesium compound.
4. organic EL component according to claim 3, wherein this second electron transfer layer comprises a metallo-chelate.
5. organic EL component according to claim 4, wherein this metallo-chelate is an aluminium chelate compound.
6. organic EL component according to claim 3, wherein this first electron transfer layer comprises a metallo-chelate.
7. organic EL component according to claim 6, wherein this metallo-chelate is an aluminium chelate compound.
8. organic EL component according to claim 1, wherein this resilient coating is to comprise a benzene dimethylan material.
9. organic EL component according to claim 1, wherein this resilient coating is to comprise a benzene dimethylan-copper compound.
10. organic EL component according to claim 1, wherein this organic layer more comprises a hole transmission layer, is formed under this luminescent layer.
11. the manufacture method of an organic EL component comprises in regular turn at least:
One substrate is provided;
Form a hole injecting electrode on this substrate;
Form an organic layer on this hole injecting electrode, this organic layer comprises a luminescent layer at least, and an electron transfer layer is formed on this luminescent layer, and this electron transfer layer is to comprise a fluoro-cesium compound;
Forming a resilient coating is formed on this organic layer; And
Form an electron injection electrode on this resilient coating;
Wherein the formation method of this electron transfer layer comprises:
Deposit a metallo-chelate on this luminescent layer; And
This fluoro-cesium compound is doped in this metallo-chelate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100632708A CN100477871C (en) | 2005-04-07 | 2005-04-07 | Organic electroluminescent assembly and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100632708A CN100477871C (en) | 2005-04-07 | 2005-04-07 | Organic electroluminescent assembly and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1845647A CN1845647A (en) | 2006-10-11 |
| CN100477871C true CN100477871C (en) | 2009-04-08 |
Family
ID=37064554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100632708A Expired - Fee Related CN100477871C (en) | 2005-04-07 | 2005-04-07 | Organic electroluminescent assembly and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100477871C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100879477B1 (en) | 2007-10-11 | 2009-01-20 | 삼성모바일디스플레이주식회사 | Organic light emitting device |
| CN103367653B (en) * | 2013-07-10 | 2016-02-03 | 上海和辉光电有限公司 | Inversion type organic light emitting diodde desplay device and preparation method thereof |
-
2005
- 2005-04-07 CN CNB2005100632708A patent/CN100477871C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1845647A (en) | 2006-10-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100420063C (en) | Organic light-emitting display device | |
| TWI253878B (en) | Organic electroluminescent element and display device including the same | |
| US9740073B2 (en) | Complex display device | |
| CN103855189B (en) | Oled | |
| CN107170900B (en) | Oled substrate and preparation method thereof, display device | |
| CN106784363B (en) | A kind of organic light emitting display panel, electronic equipment and production method | |
| CN104681580A (en) | Organic light emitting display and method for fabricating the same | |
| CN103137881B (en) | Organnic electroluminescent device and preparation method thereof | |
| JP2006012821A (en) | Metal compound-metal multilayer electrode for organic electron device | |
| CN101226993A (en) | Transparent electrode and organic electroluminescence device including the same | |
| CN106373989B (en) | A kind of organic light emitting display panel, electronic equipment and production method | |
| CN103346269B (en) | A kind of semitransparent electrode and there is the organic electroluminescence device of this semitransparent electrode | |
| CN102456842B (en) | Organic luminescent device and the method manufacturing this device | |
| Lu et al. | Solution-processable tandem solid-state light-emitting electrochemical cells | |
| CN103367653A (en) | Inversion type organic light emitting diode display device and manufacturing method thereof | |
| TW200308178A (en) | Organic electroluminescent device | |
| CN104518117A (en) | Organic light emitting diode device and preparation method thereof | |
| CN101916830B (en) | White organic electroluminescent device and preparation method thereof | |
| CN100477871C (en) | Organic electroluminescent assembly and manufacturing method thereof | |
| TWI321966B (en) | Organic electro-luminescence device and method of manufacturing the same | |
| CN104466010A (en) | Organic electroluminescence device and manufacturing method thereof | |
| CN104425720A (en) | Organic electroluminescent device and preparation method thereof | |
| US20070298283A1 (en) | Fabrication method and structure of an ITO anode containing nickel for improving injection efficiency of an OLED | |
| US20040217344A1 (en) | Apparatus and method of employing self-assembled molecules to function as an electron injection layer of OLED | |
| CN100544529C (en) | Organic electroluminescence display device and method of manufacturing same and manufacture method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090408 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |