CN100464828C - Lignin parents amphoteric surface active agent - Google Patents
Lignin parents amphoteric surface active agent Download PDFInfo
- Publication number
- CN100464828C CN100464828C CNB200610012471XA CN200610012471A CN100464828C CN 100464828 C CN100464828 C CN 100464828C CN B200610012471X A CNB200610012471X A CN B200610012471XA CN 200610012471 A CN200610012471 A CN 200610012471A CN 100464828 C CN100464828 C CN 100464828C
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- CN
- China
- Prior art keywords
- lignin
- present
- parents
- active agent
- surface active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920005610 lignin Polymers 0.000 title claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000005660 chlorination reaction Methods 0.000 claims description 7
- -1 ether carboxylates Chemical class 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 150000001450 anions Chemical class 0.000 abstract description 2
- 150000001768 cations Chemical class 0.000 abstract description 2
- 239000003208 petroleum Substances 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 abstract 2
- 239000003921 oil Substances 0.000 description 11
- 238000004945 emulsification Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
Abstract
The amphiphilic lignin surfactant consists of lignin 85-105 weight portions, cation 1-2 weight portions, anion 5- 10 weight portions, and water 3-10 weight portions. It has excellent surfactant property, capacity of lowering the interfacial tension between water and oil to 10<-4> dyne.cm, capacity of emulsifying superheavy petroleum of (2.7-5.0)x10<5> centipoise to 27-50 centipoise in the emulsifying solubility of 98-99 %, and consumption within 0.01-1.5 %.
Description
Technical field
The present invention relates to industrial surfactant, be specially adapted to hydrophilic, the oleophylic amphoteric surfactant of oil exploitation and emulsification specifically.
Background technology
Surfactant has important effect in the emulsification of mink cell focus exploitation and petroleum product.For example, surfactant can effectively reduce the viscosity of viscous crude, reduces oil water interfacial tension, improves the flowability of crude oil, so surfactant usually can be used as heavy crude thinner, oil displacement agent uses; Surfactant also can be used for the cut oil goods, as pitch, coal tar are carried out emulsification.Surfactant mainly is divided into cationic surfactant, anion surfactant, amphoteric surfactant and non-ionic surface active agent.At present, the surfactant that is used for oil exploitation and emulsification has a lot, for example alkyl polyoxyethylene based quaternary ammonium salt, NPE series of products or the like, and these surfactant costs of material are higher, are not suitable for a large amount of uses.US5035288 discloses a kind of oil exploitation auxiliary agent of Texaco Oil's development, and it is by benzene sulfonic acid sodium salt and caustic alkali, carboxymethyl cellulose, forms through high temperature, high pressure, hydrogenation, oxygenation cracking.Though these auxiliary agent raw material sources are extensive, its complex manufacturing, poor stability when producing, and narrow between cost height, application area, application is narrow (specified volume is 0.3%-0.5% and only can be used as the additive of exploitation heavy crude).
Summary of the invention
It is extensive that purpose of the present invention just provides a kind of raw material sources, cheap for manufacturing cost, the lignin parents amphoteric surface active agent that has wide range of applications.
The object of the present invention is achieved like this:
It is that primary raw material is added with the two dodecyl dimethyl ammoniums of chlorination, C simultaneously that the present invention adopts lignin
12-C
14Aliphatic alcohol polyethenoxy ether carboxylate and water.The weight part ratio of its each raw material is:
85-105 parts in lignin, 1-2 parts of the two dodecyl dimethyl ammoniums of chlorination, C
12-C
145-10 parts of aliphatic alcohol polyethenoxy ether carboxylates, 3-10 parts in water.
Lignin wherein can adopt black liquid to extract lignin, lignin resin, alkali lignin.
Preparation method of the present invention is very simple, is about to lignin, the two dodecyl dimethyl ammoniums of chlorination, C
12-C
14After aliphatic alcohol polyethenoxy ether carboxylate takes by weighing according to described weight part ratio, add water its dissolving, mixing are got final product.
Lignin among the present invention contain active hydrogen hydroxyl and can be by two keys of addition.It is introduced, and cation and anion are compound to become the amphoteric surfactant that existing cationic hydrophilic group has anionic hydrophilic radical again, and it introduces non-ionic group again simultaneously, makes it form the surfactant that has the hydrophobic unit structure simultaneously.
The present invention has the surface of good activity function, and it can drop to 10 to the interfacial tension of water and oil
-4Dyne centimetre.Can be with overweight petroleum emulsification to the 27-50 centipoise degree of 270,000～500,000 centipoise degree, the emulsification dissolution rate can reach 98-99%.Consumption is defined as 0.01%-1.5%.
Applied range of the present invention can be used as oil displacement agent, thinner in heavy crude exploitation, also can be used for, the emulsification of pitch, coal tar, also can be used as efficient cleaning agent.Simultaneously also can be stifled at Xie Jing, well logging is dark and tertiary oil recovery in be applied.
When the present invention uses, the present invention can be mixed with 1-5% the aqueous solution (being the aqueous solution of the present invention) earlier.
The present invention is when being used for the heavy crude exploitation, and consumption is that the heavy crude and the aqueous solution of the present invention carry out according to the proportioning of 85-105:15-25.Concrete grammar is that the aqueous solution of the present invention is added oilbearing stratum, and feeds steam, is emulsified into solution to heavy crude, can carry and taking out.
Adopt the present invention to carry out the heavy crude exploitation and compare, can improve 80% recovery ratio with independent steam exploitation.
The present invention can be ejected into the aqueous solution of the present invention in the pipe-line equipment when being used to clean oil equipment and car, ship pipeline greasy dirt, gets final product.
Experiment shows that the present invention is as cleaning agent, and is higher 30 times than its cleaning efficiency of the disclosed auxiliary agent of US503522.And can prolong service life of equipment more than 1 times.
The present invention can add the aqueous solution of the present invention in the pitch when being used for emulsified asphalt, heats first then about 60 ℃, carries out emulsification.Pitch after the emulsification can be exempted from heating and be paved the way or carry out building coats, and places 1 year not stratified or caking.
The specific embodiment
Embodiment 1
Get lignin 85kg, the two dodecyl dimethyl ammonium 1kg of chlorination.C
12AEO carboxylic acid sodium 10kg, water 10kg.Mix, get final product.
Embodiment 2
Alkali lignin 100kg, the two dodecyl dimethyl ammonium 2kg of chlorination.C
14AEO carboxylic acid potassium 10kg, water 3kg.Mix, get final product.
Embodiment 3
Get lignin resin 100kg, the two dodecyl dimethyl ammonium 1.5kg of chlorination.C
12AEO carboxylic acid sodium 8kg, water 10kg mixes, and gets final product.
Claims (1)
1, a kind of lignin parents amphoteric surface active agent is characterized in that it is to be made by the raw material of following weight ratio:
85-105 parts in lignin, 1-2 parts of the two dodecyl dimethylammoniums of chlorination, C
12-C
145-10 parts of aliphatic alcohol polyethenoxy ether carboxylates, 3-10 parts in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610012471XA CN100464828C (en) | 2006-03-09 | 2006-03-09 | Lignin parents amphoteric surface active agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610012471XA CN100464828C (en) | 2006-03-09 | 2006-03-09 | Lignin parents amphoteric surface active agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101032682A CN101032682A (en) | 2007-09-12 |
| CN100464828C true CN100464828C (en) | 2009-03-04 |
Family
ID=38729540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200610012471XA Expired - Fee Related CN100464828C (en) | 2006-03-09 | 2006-03-09 | Lignin parents amphoteric surface active agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100464828C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540305B (en) * | 2012-07-12 | 2016-02-10 | 中国石油化工股份有限公司 | Surfactant composition for chemical displacement of reservoir oil and preparation method thereof |
| CN103666430B (en) * | 2012-09-05 | 2016-04-13 | 中国石油化工股份有限公司 | For the surfactant composition and preparation method thereof of intensified oil reduction |
| CN103756537A (en) * | 2014-02-10 | 2014-04-30 | 广东华兹卜化学工业有限公司 | Light-smell wood varnish |
| CN105295881A (en) * | 2015-06-29 | 2016-02-03 | 戴文洁 | Thick oil molecule dispersion and emulsification composite viscosity reducer as well as preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091333A (en) * | 1993-02-27 | 1994-08-31 | 刘东升 | A kind of method of making hydrocarbon surfactants |
| CN1458222A (en) * | 2003-05-21 | 2003-11-26 | 中国海洋石油总公司 | Viscosity reducing and drag reducing agent for high viscosity well |
| CN1616627A (en) * | 2004-09-30 | 2005-05-18 | 霍纪功 | Dirt detergent |
-
2006
- 2006-03-09 CN CNB200610012471XA patent/CN100464828C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091333A (en) * | 1993-02-27 | 1994-08-31 | 刘东升 | A kind of method of making hydrocarbon surfactants |
| CN1458222A (en) * | 2003-05-21 | 2003-11-26 | 中国海洋石油总公司 | Viscosity reducing and drag reducing agent for high viscosity well |
| CN1616627A (en) * | 2004-09-30 | 2005-05-18 | 霍纪功 | Dirt detergent |
Non-Patent Citations (2)
| Title |
|---|
| PS-木素基两性表面活性剂在溶化沥青修筑公路方面的应用. 刘东升.资源节约和综合利用，第2期. 1994 |
| PS-木素基两性表面活性剂在溶化沥青修筑公路方面的应用. 刘东升.资源节约和综合利用，第2期. 1994 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101032682A (en) | 2007-09-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: BEIJING HUAXIA RONGYOU TECHNOLOGY DEVELOPMENT CO., Free format text: FORMER OWNER: GUAN XUEMEI Effective date: 20110713 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 050000 1/F, AREA A + B, JINSHI INDUSTRIAL PARK, HIGH-TECH. DEVELOPMENT ZONE, SHIJIAZHUANG CITY, HEBEI PROVINCE TO: 100025 NO. 802, BUILDING 15, CHINA CENTRAL PLACE, NO. 89, JIANGUO ROAD, CHAOYANG DISTRICT, BEIJING |
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| TR01 | Transfer of patent right |
Effective date of registration: 20110713 Address after: 100025, No. 802, building 15, Huamao center, No. 89 Jianguo Road, Beijing, Chaoyang District Patentee after: Beijing Huaxia melt Oil Technology Development Co., Ltd. Address before: 050000, B District, A Industrial Zone, Shijiazhuang hi tech Development Zone, Hebei, china. Patentee before: Guan Xuemei |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Beijing Huaxia melt Oil Technology Development Co., Ltd. Assignor: Guan Xuemei Contract record no.: 2011110000129 Denomination of invention: Lignin parents amphoteric surface active agent Granted publication date: 20090304 License type: Exclusive License Open date: 20070912 Record date: 20110809 |
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| ASS | Succession or assignment of patent right |
Owner name: LI MEIFANG Free format text: FORMER OWNER: GUAN XUEMEI Effective date: 20111116 Owner name: QIN YISONG |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20111116 Address after: 2, building 33, No. 050000, cooperation Road, Xinhua District, Hebei, Shijiazhuang 2-201 Co-patentee after: Qin Yisong Patentee after: Li Meifang Address before: 050000, B District, A Industrial Zone, Shijiazhuang hi tech Development Zone, Hebei, China Patentee before: Guan Xuemei |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090304 Termination date: 20140309 |