CN100460355C - Method for producing ceramic granule from oil sludge sand - Google Patents
Method for producing ceramic granule from oil sludge sand Download PDFInfo
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- CN100460355C CN100460355C CNB2006100911838A CN200610091183A CN100460355C CN 100460355 C CN100460355 C CN 100460355C CN B2006100911838 A CNB2006100911838 A CN B2006100911838A CN 200610091183 A CN200610091183 A CN 200610091183A CN 100460355 C CN100460355 C CN 100460355C
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
This invention relates to a method for producing ceramicite by using oily sands as raw material. The procedures are: (a), raw material oily sands are fed into a vessel with its agitator; adding water for dilution and agitating for ten minites, so the sands are treated into sand-slurry; (b), said sand-slurry is pumped, by using first sand-slurry pump, into slurry sieve to obtain fine sand slurry; (c), the fine sand slurry is pumped into a solid/liquid separator, and separated into oily dirt, waste-water and deoiled sand mud; (d), said mud is then fed into ceramicite formation machine to produce semifinished products: (e), the same is then fed into a rotary kiln and sintered under temperature of 800-1450deg.C for 50-60 minites, after natural cooling to obtain the final products with the volume-weight of 300-1500kg/m3.
Description
Technical field
The present invention relates to a kind of is the method for raw material production haydite with oil sludge and sand; described method is that de-oiling sand mud (or add auxiliary material such as clay in de-oiling sand mud make compound pottery mud) is carried out granulated processed; make particulate state haydite blank, through high temperature sintering process for producing ceramic product.
Background technology
Oil sludge and sand also is oily sludge, produces in the oil production activity, is mainly derived from each link of Oil extraction, transportation and treating processes, by crude oil and other Organic pollutants oil, silt particle, the mixture of water.General oil length is 10-50% in the mud, and water ratio in the China's oil chemistry industry, produces 800,000 tons of oil sludge and sand 25-50% every year on average; Shengli Oil Field produces oil sludge and sand more than 100,000 tons every year, the about 50,000 tons of oil sludge and sand of the annual generation of Henan Oil Field.Contain cacodorous toxic substances such as a large amount of benzene series things, phenols, anthracene, pyrene in the oil sludge and sand, if do not handled, contaminate environment not only, and cause the waste of resource.Because the oil sludge and sand solid load is low, the water ratio height presents the suspended dispersed state again, thereby bulky, the different oil sludge and sand of originating simultaneously is as fresh and aged oil sludge and sand, it is formed and physical properties all may have than big difference, as viscosity, water ratio, dehydration property, oily water separation etc.; The complicated component of oil sludge and sand own contains a large amount of aging crude oil, cured matter, bituminous matter, colloid and suspended solid, bacterium, salt, sour gas, corrosion product and a small amount of mechanical impurity etc.About 25-50% is water in the oil sludge and sand, 5% inorganic sediment such as silt particle, and about 70% is hydrocarbon polymer, and wherein, bituminous matter accounts for 7.8%, and paraffin accounts for 6%, mud ash oontent 4.8%.At these different character, adopted different method for innocent treatment, as landfill method, re-injection method, drying bed facture, burning method, carbonizing treatment method, biological treatment etc., aforesaid method or exist harmless treatment thoroughly not pollute environmental problem or exist oil contained in the oil sludge and sand, silt particle can not recycle and waste resource also takies a large amount of soils and carries out problems such as landfill.The annual oil sludge and sand that produces in oil field, unprocessed, pay effluent charge and reach more than one hundred million units, also need to bear a large amount of expenses such as permanent fees paid for taking rural land, well site maintenance cost, administrative fine simultaneously.
Chinese patent 200410082899.2 has been announced a kind of treatment process of oil sludge and sand, adopt the method for oil, water, silt particle solid-liquid separation, be the oil sludge and sand → homogenize → chemical separation of the heating → separation → mechanical dehydration of heating → curing → microbiological treatment → mummification landfill, separating of oilly come out to recycle contained in the oil sludge and sand.But the silt particle that adopts this method to separate generally all adopt landfill after the burning disposal or directly landfill reach the purpose of oil sludge and sand harmless treatment, promptly spent processing costs and wasted sediment resource again, also taken a large amount of soils simultaneously.
Summary of the invention
It is the method for raw material production haydite with oil sludge and sand that order of the present invention is to provide a kind of, described method is that de-oiling sand mud (or add auxiliary material such as clay in de-oiling sand mud make compound pottery mud) is carried out granulated processed, make particulate state haydite blank, through high temperature sintering process for producing ceramic product; This method can reach the purpose of oil sludge and sand harmless treatment, the silt particle resource in the oil sludge and sand can be carried out recycling again.
The objective of the invention is to be achieved through the following technical solutions: a kind of is the method for raw material production haydite with oil sludge and sand,
A, the oil sludge and sand of collecting is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank;
B, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
A kind of is the method for raw material production haydite with oil sludge and sand,
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes; This oil sludge and sand is processed into oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively;
D, described de-oiling sand mud is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank;
E, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
A kind of is the method for raw material production haydite with oil sludge and sand,
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes; Oil sludge and sand is processed into oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively;
D, described de-oiling sand mud is sent into the secondary agitator, make auxiliary material and de-oiling sand mud carries out combination treatment, make compound pottery mud with clay, magnesium oxide, water glass, dioctyl maleate sodium sulfonate; The weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 60~96
Clay 3~40
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2;
E, described compound pottery mud is sent into the haydite shaper carry out granulated processed, make particulate state haydite blank;
F, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
The present invention compared with prior art has following advantage:
1, method of the present invention is utilized the de-oiling sand mud production haydite after separating again utilizing simple oil, water, silt solid-liquid isolation method to reclaim on wherein the oil and the basis of water resources, has improved the comprehensive utilization effect of oil sludge and sand greatly.The product that the present invention produces is a kind of artificial particle of ceramic, have functions such as comprehensive strength height, fire resistance are good, weather resistance, it is good light building material, can solve the difficult problem on the engineerings such as weight, fire prevention, heat insulation, sound insulation, insulation, have advantages such as good and cheap, environmental protection, can be widely used in prefabricated panel, a wall, light weight concrete, roof heat insulation, concrete precast element, small, light building block, brick etc., also can be used for fields such as gardening, flowers, municipal administration and soilless culture;
2, method of the present invention is handled by high temperature sintering, makes a large amount of objectionable impurities combustion decomposition in the oil sludge and sand, has reached purpose innoxious, environmental protection;
3, method of the present invention does not need the landfill waste material, has both saved land resources, helps again preserving the ecological environment;
4, method applicability of the present invention is strong, and oleaginousness, water content, the sand content of oil sludge and sand do not had strict restriction, and is easy and simple to handle, technology is simple, with low cost, realized the utilization again of limited resources, have tangible economic benefit, environmental benefit and social benefit.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is the process flow sheet of the embodiment of the invention two;
Fig. 2 is the process flow sheet of the embodiment of the invention three.
Embodiment
Below in conjunction with drawings and Examples the present invention is made a detailed description.
Embodiment one: a kind of is the method for raw material production haydite with oil sludge and sand, said method comprising the steps of:
A, the oil sludge and sand of collecting is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank; Oleaginousness in the oil sludge and sand raw material is less than 3%, but water content is not more than 10% o'clock straight forming in the mud, is about to described oil sludge and sand and directly delivers to the haydite shaper without any pre-treatment and carry out granulated processed, makes particulate state haydite blank.
With conveying belt the oil sludge and sand of collecting is transported in the haydite shaper, requires plastic bulk, spherical, ellipticity product according to different ceramic products; Present embodiment uses conventional haydite shaper, can select B18-003 lytag shaper for use.
B, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
Present embodiment uses the rotary kiln of conventional sintering ceramsite, also can select the disclosed sintering oven of Chinese patent CN93230032.4 for use.
In order to remove the objectionable impurities in the oil sediment, particularly contain cacodorous toxic substances such as a large amount of benzene series things, phenols, anthracene, pyrene in the oil sludge and sand, described particulate state haydite blank is carried out high temperature sintering, and described high temperature sintering temperature is 800 ℃~1450 ℃, and sintering time is 50~60 minutes; Have certain expansion at sintering process particulate state haydite blank, objectionable impurities wherein at high temperature obtains combustion decomposition, thereby has reached purpose innoxious, environmental protection; The product that utilizes this method to make can be used for aspects such as body of wall thermal insulation of roof, concrete are expected admittedly, gardening.
Embodiment two: referring to Fig. 1, a kind of is the method for raw material production haydite with oil sludge and sand, said method comprising the steps of:
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes, and this oil sludge and sand is processed into oil loam, and water content is 60-80% in the oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock; In the present embodiment, can select for use SYZ series vibratory screening apparatus to sieve as mud, its purpose is to screen out foreign matters such as bulk sandstone, impurity and cotton yarn;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively, will detect, if the weight ratio of sand and mud is less than 4:1 through the de-oiling sand mud of separating treatment, water content is not more than 10% in the mud, but straight forming then; If the weight ratio of sand and mud is greater than 4:1, for example: the weight ratio of sand and mud is 5:1, then need to add an amount of clay and adjust, can moulding in follow-up granulated processed process to guarantee de-oiling sand mud;
In the present embodiment, the sewage in the sewage hold-up vessel can be used as diluting water, in needs, adds in the stirred vessel when promptly water content is low in the oil sludge and sand, makes it become oil-sand mud and is easy to carry out removal of impurities by the mud sieve and handles; With the secondary mortar pump oil sludge and sand screened stock that sieves is transported in the three-phase separator then, character according to oil sludge and sand, adding corresponding emulsion splitter, coagulant etc. carries out homogenizing, breakdown of emulsion and takes off steady, with the avidity and the sticking power of crude oil and silt particle in the reduction oil sludge and sand, realize the solid-liquid separation of oil, silt particle and water; Can use OX-912SDY series composite type crude oil demulsifier and L type demulsifying compound in the present embodiment.
From the two conduits output on solid-liquid separating machine top, the sump oil of separating is delivered to oil skimming tank through sump pump, delivers to refinery then and utilizes prior art that sump oil is carried out refining treatment respectively for sump oil and sewage; The sewage of separating is transported in the sewage hold-up vessel with liquid delivery pump and recycles; The employed solid-liquid separating machine of present embodiment can be selected the three-phase separator of SXFL-10 series for use.
D, described de-oiling sand mud is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank;
With conveying belt described de-oiling sand mud is transported in the haydite shaper, requires plastic bulk, spherical, ellipticity product according to different ceramic products; Present embodiment uses conventional haydite shaper, can select B18-003 lytag shaper for use.
E, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, to make its temperature reach normal temperature through agglomerating product naturally cooling then, form native pottery look hard haydite, the unit weight of ceramic product is 300~1500kg/m
3, cylindrical compress strength is 2~10MPa.
Present embodiment uses the rotary kiln of conventional sintering ceramsite, also can select the disclosed sintering oven of Chinese patent CN93230032.4 for use.
In order to remove the objectionable impurities in the oil sediment, particularly contain cacodorous toxic substances such as a large amount of benzene series things, phenols, anthracene, pyrene in the oil sludge and sand, described particulate state haydite blank is carried out high temperature sintering, and described high temperature sintering temperature is 800 ℃~1450 ℃, and sintering time is 50~60 minutes; Have certain expansion at sintering process particulate state haydite blank, objectionable impurities wherein at high temperature obtains combustion decomposition, thereby has reached purpose innoxious, environmental protection; The product that utilizes this method to make can be used for aspects such as body of wall thermal insulation of roof, concrete are expected admittedly, gardening.
Embodiment three: referring to Fig. 2, a kind of is the method for raw material production haydite with oil sludge and sand, said method comprising the steps of:
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes, and oil sludge and sand is processed into oil loam, and water content is 60-80% in the oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock; In the present embodiment, can select for use SYZ series vibratory screening apparatus to sieve as mud, its purpose is to screen out foreign matters such as bulk sandstone, impurity and cotton yarn;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively;
In the present embodiment, the sewage in the sewage hold-up vessel can be used as diluting water, in needs, adds in the stirred vessel when promptly water content is low in the oil sludge and sand, makes it become oil-sand mud and is easy to carry out removal of impurities by the mud sieve and handles; With the secondary mortar pump oil sludge and sand screened stock that sieves is transported in the three-phase separator then, character according to oil sludge and sand, adding corresponding emulsion splitter, coagulant etc. carries out homogenizing, breakdown of emulsion and takes off steady, with the avidity and the sticking power of crude oil and silt particle in the reduction oil sludge and sand, realize the solid-liquid separation of oil, silt particle and water; Can use 0X-912SDY series composite type crude oil demulsifier and L type demulsifying compound in the present embodiment.
From the two conduits output on solid-liquid separating machine top, the sump oil of separating is delivered to oil skimming tank through sump pump, delivers to refinery then and utilizes prior art that sump oil is carried out refining treatment respectively for sump oil and sewage; The sewage of separating is transported in the sewage hold-up vessel to recycle with liquid delivery pump; The employed solid-liquid separating machine of present embodiment can be selected the three-phase separator of SXFL-10 series for use.
D, described de-oiling sand mud is sent into the secondary agitator, make auxiliary material and de-oiling sand mud carries out combination treatment, make compound pottery mud with clay, magnesium oxide, water glass, dioctyl maleate sodium sulfonate; The weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 60~96
Clay 3~40
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2;
Employed stirrer can be the planetary glue sand agitator of JT-5 type in the present embodiment, adds auxiliary materials such as clay, magnesium oxide, water glass, dioctyl maleate sodium sulfonate and stir in stirrer, makes compound pottery mud.
E, described compound pottery mud is sent into the haydite shaper carry out granulated processed, make particulate state haydite blank;
With conveying belt described de-oiling sand mud is transported in the haydite shaper, requires plastic bulk, spherical, ellipticity product according to different ceramic products; Present embodiment uses conventional haydite shaper, can select B18-003 lytag shaper for use.
F, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, to make its temperature reach normal temperature through agglomerating product naturally cooling then, form native pottery look hard haydite, the unit weight of ceramic product is 300~1500kg/m
3, cylindrical compress strength is 2~10MPa.
Present embodiment uses the rotary kiln of conventional sintering ceramsite, also can select the disclosed sintering oven of Chinese patent CN93230032.4 for use.
In order to remove the objectionable impurities in the oil sediment, particularly contain cacodorous toxic substances such as a large amount of benzene series things, phenols, anthracene, pyrene in the oil sludge and sand, described particulate state haydite blank is carried out high temperature sintering, and described high temperature sintering temperature is 800 ℃~1450 ℃, and sintering time is 50~60 minutes; Have certain expansion at sintering process particulate state haydite blank, objectionable impurities wherein at high temperature obtains combustion decomposition, thereby has reached purpose innoxious, environmental protection; The product that utilizes this method to make can be used for aspects such as body of wall thermal insulation of roof, concrete are expected admittedly, gardening.
Embodiment four: present embodiment is the improvement on the basis of embodiment three, and the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 80~96
Clay 3~10
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2;
Described de-oiling sand mud can also can be selected according to the unit weight of required ceramic product according to different adjustment of ratio of mud and sand in the de-oiling silt particle with the weight ratio of described auxiliary material; Present embodiment is the weight ratio that contains mud ratio de-oiling sand mud and auxiliary material when higher in the de-oiling silt particle, simultaneously, also is applicable to and produces the bigger ceramic product (1500kg/m of unit weight
3About).
Embodiment five: present embodiment is the improvement on the basis of embodiment three, and the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 50~66
Clay 30~40
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2;
Present embodiment is the weight ratio that contains sand ratio de-oiling sand mud and auxiliary material when higher in the de-oiling sand mud, simultaneously, also is applicable to and produces the less ceramic product (300kg/m of unit weight
3About).
Embodiment six: present embodiment is the improvement on the basis of embodiment three, and the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 75
Clay 25
Magnesium oxide 1.5
Water glass 1.8
Dioctyl maleate sodium sulfonate 1.0.
In addition, technical scheme of the present invention is equally applicable to use drilling waste mud as the raw material production haydite, and difference is that drilling waste mud need not through pre-treatment such as solid-liquid separation.
This shows that oil sludge and sand is not a waste not only, and be the raw material of good production ceramic product, therefore, can realize " zero " discharging of oil sludge and sand fully.
Claims (6)
1. one kind is the method for raw material production haydite with oil sludge and sand, it is characterized in that:
A, the oil sludge and sand of collecting is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank;
B, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
2. one kind is the method for raw material production haydite with oil sludge and sand, it is characterized in that:
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes; This oil sludge and sand is processed into oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively;
D, described de-oiling sand mud is delivered to the haydite shaper carry out granulated processed, make particulate state haydite blank;
E, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
3. one kind is the method for raw material production haydite with oil sludge and sand, it is characterized in that:
A, stirred vessel of use place the oil sludge and sand of collecting in the described stirred vessel, add diluting water, start agitator and stir 10 minutes; Oil sludge and sand is processed into oil loam;
B, described oil loam is sent into the mud sieve through the one-level mortar pump carry out Screening Treatment, obtain the oil sludge and sand screened stock;
C, described oil sludge and sand screened stock is sent into solid-liquid separating machine carry out solid-liquid separation and handle, form sump oil, sewage and de-oiling sand mud respectively;
D, described de-oiling sand mud is sent into the secondary agitator, make auxiliary material and de-oiling sand mud carries out combination treatment, make compound pottery mud with clay, magnesium oxide, water glass, dioctyl maleate sodium sulfonate; The weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 60~96
Clay 3~40
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2;
E, described compound pottery mud is sent into the haydite shaper carry out granulated processed, make particulate state haydite blank;
F, described particulate state haydite blank is sent into rotary kiln carry out high temperature sintering and handle, treatment temp is 800 ℃~1450 ℃, treatment time is 50~60 minutes, will make its temperature reach normal temperature through agglomerating product naturally cooling then, and the unit weight of ceramic product is 300~1500kg/m
3
4. according to claim 3 is the method for raw material production haydite with oil sludge and sand, and it is characterized in that: the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 80~96
Clay 3~10
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2.
5. according to claim 3 is the method for raw material production haydite with oil sludge and sand, and it is characterized in that: the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 50~66
Clay 30~40
Magnesium oxide 0.5~3
Water glass 0.3~3
Dioctyl maleate sodium sulfonate 0.2~2.
6. according to claim 3 is the method for raw material production haydite with oil sludge and sand, and it is characterized in that: the weight ratio of described de-oiling sand mud and described auxiliary material is:
De-oiling sand mud 75
Clay 25
Magnesium oxide 1.5
Water glass 1.8
Dioctyl maleate sodium sulfonate 1.0.
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CN112919879A (en) * | 2021-04-27 | 2021-06-08 | 陕西中禾天成环保科技有限公司 | Method for preparing high-strength ceramsite from oil sludge |
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CN1149038A (en) * | 1996-08-29 | 1997-05-07 | 新疆大地墙体材料开发公司 | Mud ceramic granules and its production |
CN1184085A (en) * | 1996-11-29 | 1998-06-10 | 天津大港油田长虹实业公司协通技术开发分公司 | Composite haydite artificial rock stratum sand preventing technology haydite |
CN1264688A (en) * | 2000-02-25 | 2000-08-30 | 赵传文 | Light haydite of powdered coal ash and its preparing process |
CN1618538A (en) * | 2004-12-02 | 2005-05-25 | 辽河石油勘探局 | Oil sludge carbonization treatment method |
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CN1149038A (en) * | 1996-08-29 | 1997-05-07 | 新疆大地墙体材料开发公司 | Mud ceramic granules and its production |
CN1184085A (en) * | 1996-11-29 | 1998-06-10 | 天津大港油田长虹实业公司协通技术开发分公司 | Composite haydite artificial rock stratum sand preventing technology haydite |
CN1264688A (en) * | 2000-02-25 | 2000-08-30 | 赵传文 | Light haydite of powdered coal ash and its preparing process |
CN1618538A (en) * | 2004-12-02 | 2005-05-25 | 辽河石油勘探局 | Oil sludge carbonization treatment method |
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