CN100460136C - Filling metal particle for welding and manufacturing method therefor - Google Patents
Filling metal particle for welding and manufacturing method therefor Download PDFInfo
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- CN100460136C CN100460136C CNB2007100134203A CN200710013420A CN100460136C CN 100460136 C CN100460136 C CN 100460136C CN B2007100134203 A CNB2007100134203 A CN B2007100134203A CN 200710013420 A CN200710013420 A CN 200710013420A CN 100460136 C CN100460136 C CN 100460136C
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Abstract
A stuffing metal grain for soldering with diameter of 0.1-5.0mm, with the mass percentage of C less than 0.15%, S less than 0.035%, P less than 0.035%, oxygen less than 50ppm, nitrogen less than 50ppm, with other alloy elements like Mn being 0.1%-2.0%, Si 0.02%-1.8%, Mo less than 2.5%, Cr less than 3.5%, Ni less than 6.0%, Ti less than 0.5%, V less than 0.5%, Nb less than 0.5%, Cu less than 0.5%, and B less than 0.09%. It is simple in process, with greatly reduced cost.
Description
Technical field
The present invention relates to a kind of welding material and production method thereof, relate in particular to filling metallic particles for overlay of a kind of novel welding usefulness and preparation method thereof.
Background technology
Along with the development of Welding Structure to maximization, high parameter direction, the above welding structural element quantity of middle thickness increases severely.And the welding procedure that adopts at present generally is submerged-arc welding, gas shielded arc welding, SMAW, electro-gas (enclosed) welding etc.At the prefabricated groove in steel plate edge, add backing plate (or liner) overleaf or adopt less sweating heat input during welding, carry out multi-pass welding then and connect at groove bottom weldering backing weld seam.SMAW otherwise the replacing welding rod that stops, this has not only reduced production efficiency, but also produces weld defect in the joint of weld seam easily.The heat input that multi-pass welding connects technology is bigger, makes the welding heat affected zone broad, and overheated more serious, the performance of heat affected area reduces, and also easily causes big welding stress and distortion simultaneously.Multi-pass welding not only workload and working strength of workers is bigger, and wastes energy and welding material.Therefore, the welding material of exploitation high efficiency and welding procedure are the raising welding productivities, reduce cost, and improve the important channel of welding quality.
In the welding material, iron powder electrode and metal powder core solder wire belong to the welding material of high deposition efficiency, as Chinese patent CN1056454 " low-hydrogen efficient alkaline iron-powder welding electrode ", CN1055893 " reduced ilmenite type of high efficient iron powder electrode ", CN1657224 disclosed iron powder electrodes such as " ultralow-hydrogen type high efficiency iron powder welding rod for low alloy high streagth steel ", the metal powder core solder wire of CN1249980 " a kind of metallic core type flux-cored wire " patent disclosure etc.But this class iron powder electrode and metal powder core solder wire have just improved deposition rate, still need bevel to carry out multi-pass welding for cut deal and connect.
China utility model patent CN2426397Y, patent of invention CN1273900A have proposed a kind of broken welding wires, before the weldering this broken welding wires are dispersed evenly in the groove, form weld seam by arc-melting, have reached the purpose of efficient welding.The production technology of above-mentioned broken welding wires is, the hot rolling wire of the welding usefulness of producing with iron and steel enterprise is a raw material, make the filament of certain diameter after the cold-drawn by multi-pass, and then the broken welding wires that cylindrical shape is made in chopping (is seen " installation " magazine, 2003 the 5th phase articles " large oil tank base plate welding-broken welding wires submerged-arc welding "), its manufacturing process is comparatively complicated.Described broken welding wires and production technology thereof have the following disadvantages: the alloying component that at first is broken welding wires can not independently be adjusted, and its kind is subjected to the restriction that iron and steel enterprise produces the hot rolling wire kind; Next is that the higher metal material of high strength, alloying element content is difficult to make wire rod, particularly prepare the following wire rod of diameter 0.8mm difficulty more, make this broken welding wires be difficult to use in the welding of high strength, metal such as heat-resisting, cause its application to be subjected to very big restriction; The 3rd is the complex manufacturing of broken welding wires, and raw material derive from the special type welding of iron and steel enterprise again and use hot rolling wire, make its production cost high.
Along with increasing gradually that large welded structures is used, and harsh day by day (as low temperature, big load, the high temperature etc.) of structure operating condition, also more urgent to the demand of the high efficiency welding material of low-cost, easy to use, excellent performance.
Summary of the invention
At the deficiencies in the prior art, the deficiency of broken welding wires technology particularly, the problem to be solved in the present invention are filling metallic particles for overlay and the production methods thereof that proposes a kind of novel welding usefulness.
Technical conceive of the present invention is: select impurity (S, P, N, the O etc.) steel scrap that content is lower; adopt induction melting furnace or electric arc furnaces that it is fused into molten steel; in fusion process, adopt slag or atmosphere protection; and add or do not add alloying element according to the filling metallic particles for overlay composition needs of desire system welding usefulness; by high pressure liquid stream (as water, wet goods) or high pressure draught (as air, nitrogen, inert gas etc.) the above-mentioned molten steel of impact grinding; make it solidify the back and form ball or oval spherical metallic particles, make the filling metallic particles for overlay of welding usefulness.
Welding filling metallic particles for overlay of the present invention, make by steel scrap and ferroalloy, it is characterized in that, described metallic particles is a ball or oval spherical, particle diameter is 0.1～5.0mm, its chemical composition by percentage to the quality, must satisfy C less than 0.15%, S less than 0.035%, P less than 0.035%, oxygen is no more than the content that 50ppm, nitrogen are no more than 50ppm; Other alloying elements Mn should be 0.1%～2.0%, Si should be 0.02%～1.8%, Mo is no more than 2.5%, Cr is no more than 3.5%, Ni is no more than 6.0%, Ti is no more than 0.5%, V is no more than 0.5%, Nb is no more than 0.5%, Cu is no more than 0.5%, B is no more than 0.09%.
Wherein, described steel scrap is wrench, edges of boards, leftover pieces discarded in iron and steel enterprise or the steel user production process.
Impurity (S, P, N, O etc.) content is lower, and useful alloying element content is more and stable, meets the steel scrap of welding material with the desired characteristic of steel, should preferentially select for use.Wrench, edges of boards, the leftover pieces discarded as the DB590 steel announced among the patent CN1152767C or X70 steel etc.
The chemical composition of DB590 steel (mass percent) is: C 0.067, Si 0.305, Mn 1.439, P 0.019, S 0.008, Nb 0.041, Cu 0.108, Ti 0.021, B 0.0010; The chemical composition of X70 steel (mass percent) is: C 0.06, Si 0.25, Mn 1.46, P 0.012, S 0.003, Mo 0.22, Ni 0.20, Cu 0.22.
Therefore, comparatively preferred mode is:
Metallic particles is a ball or oval spherical, particle diameter is 0.5～3mm, its chemical composition is C0.067%, Si0.305%, Mn1.439%, P0.019%, S0.008%, Nb0.041%, Cu0.108%, Ti0.021%, B0.0010% by percentage to the quality.
Perhaps, metallic particles is a ball or oval spherical, and particle diameter is 0.5～3mm, and its chemical composition is C 0.06%, Si 0.25%, Mn 1.46%, P 0.012%, S 0.003%, Mo 0.22%, Ni 0.20%, Cu 0.22% by percentage to the quality.
Above-mentioned welding comprises the steps: with the preparation method of filling metallic particles for overlay
(1) selection of steel scrap: C, S, P, O, N in the chemical composition of described steel scrap, by percentage to the quality, must satisfy C less than 0.15%, S less than 0.035%, P less than 0.035%, oxygen is no more than the content that 50ppm, nitrogen are no more than 50ppm; Other alloying elements Mn should be 0.1%～2.0%, Si should be 0.02%～1.8%, Mo is no more than 2.5%, Cr is no more than 3.5%, Ni is no more than 6.0%, Ti is no more than 0.5%, V is no more than 0.5%, Nb is no more than 0.5%, Cu is no more than 0.5%, B is no more than 0.09%;
Impurity (S, P, N, the O etc.) content of some wrench of discarding in iron and steel enterprise or the steel user production process, edges of boards, leftover pieces is lower, useful alloying element content is more and stable, it is lower that phosphorus content is controlled, and meets welding material with the desired characteristic of steel, should preferentially select for use.DB590 steel of announcing among the patent CN1152767C or X70 steel should be first-selected.
(2) according to desire system welding chemical composition index with filling metallic particles for overlay, determine whether to need to add alloying constituent according to the chemical composition of the selected steel scrap of step (1), and the kind and the quantity of adding alloying constituent;
(3) step (1) is selected steel scrap is divided into two parts of A, B, A part is put into induction melting furnace earlier with the shortest time it is melted, and the quantity of A part determines that according to the size of burner hearth with molten steel after melting 10mm～20mm can be arranged is principle deeply; Add slag former then, and with its fusing (set up the molten slag protective layer, secluding air contacts with molten steel), the addition of slag former is a principle to form the thick molten slag of 3mm～4mm at molten steel surface; After treating that molten slag forms, B part steel scrap is added in the induction melting furnace, add and fashionablely can not destroy the molten slag layer that molten steel is shielded, treat to continue melting 10～15 minutes behind B part scrap melting;
(4) according to step (2) determine add alloying constituent kind and quantity add alloying constituent successively, treat its melt fully after refining 5～12 minutes again;
(5) melted molten steel (overheated 150～200 ℃) and its surperficial slag are poured in the insulation crucible that the bottom is provided with mozzle;
Wherein: the mozzle of described insulation crucible links to each other with leting slip a remark, and the diameter of leting slip a remark is changed selection according to the grain diameter of desire preparation in 6～20mm; Be provided with nozzle around the exit same level height of leting slip a remark, nozzle is a circular seam type, is square and arranges, and the described foursquare length of side is 200～500mm, and the described outlet of leting slip a remark is positioned at described square intersection of diagonal place; Nozzle inlet and high pressure liquid stream or high pressure draught pipe join, the high pressure liquid stream or the air-flow of jet expansion ejection and the molten steel that flows out of leting slip a remark are 30 °～60 ° angles, and high pressure liquid stream or high pressure draught that jet expansion sprays focus on the vertical steel flow that flows out of the outlet of leting slip a remark; Let slip a remark below with nozzle is provided with the bottom aslope (angle of slope and horizontal plane is 30～60 °, little steel during the slope can make and solidify drips along the slope and moves, prevent its too fast deposition and mutual weldering knot) collecting pit, the dark liquid cooling medium of 1.5～2m is housed in the pond, dielectric fluid identity distance nozzle focus point is that (distance of nozzle and collecting pit liquid level is as far as possible little for 200～500mm, entry fast after making molten steel be granulated into little steel to drip reduces the oxidation of air to it);
(6) replace with leting slip a remark of selected diameter, flow with 10～50kg/min makes the molten steel that is sunken to the bottom in the crucible by the outflow of leting slip a remark, open the nozzle of high pressure liquid stream or high pressure draught simultaneously, (pressure is big more with the pressure of 0.8～10MPa, metallic particles is tiny more) molten steel that spray to flow out, after treating that molten steel all flows out, molten slag discards, molten steel is under the percussion of high pressure liquid stream or high pressure draught, become little steel and drip, and cooled off fast, fall into the collecting pit that liquid cooling medium is housed, after little steel drips and solidifies, promptly become metallic particles;
(7) metallic particles in the taking-up collecting pit water is used oven for drying, and bake out temperature is 120～180 ℃, and temperature retention time is 20～40 minutes;
(8) metallic particles after the conventional vibrosieve equipment screening of employing is dried selects for use the metallic particles of different-grain diameter to mix use according to the requirement of welding procedure in proportion; Perhaps, behind the metallic particles mixing after the oven dry, directly use.
Above-mentioned welding is with among the preparation method of filling metallic particles for overlay, and step (2) or (4) described alloying constituent are one of ferrosilicon, molybdenum-iron, ferrochrome, ferro-niobium, metallic nickel, copper, ferromanganese, ferrotianium, vanadium iron, ferro-boron or part or all of.
Above-mentioned welding is used among the preparation method of filling metallic particles for overlay, the solder flux 431 that the preferred submerged-arc welding of the described slag former of step (3) is commonly used.
Above-mentioned welding is used among the preparation method of filling metallic particles for overlay, step (5) or the preferred water under high pressure of (6) described high pressure liquid stream, the preferred high pressure argon gas of high pressure draught; Liquid cooling medium preferred water in the described collecting pit.
Above-mentioned welding is with among the preparation method of filling metallic particles for overlay, when the described diameter of leting slip a remark of step (6) is chosen to be 6mm, the molten steel that is sunken to the crucible bottom with the flow of 18～22kg/min by the outflow of leting slip a remark; When the diameter of leting slip a remark is chosen to be 8mm, the molten steel that is sunken to the crucible bottom with the flow of 42～46kg/min by the outflow of leting slip a remark.
General diameter decision flow, the diameter of leting slip a remark is more little, and molten steel flow is slow more, and the liquid stream of jet expansion ejection or the pressure of air-flow are big more, and metallic particles is tiny more.
When the diameter of leting slip a remark was chosen to be 6mm, during molten steel flow 18kg/min, the water under high pressure pressure of jet expansion ejection was 10MPa, and the size of metallic particles can reach 100～200 μ m, and is tiny of powder.
The filling metal of welding usefulness is mainly used in the connection of metal material, requires weld seam to have certain mechanical property, and has good cracking resistance etc.
The quality of above-mentioned metal and ferroalloy is carried out with following country and industry standard:
Ferromanganese GB/T3795-2006, ferrosilicon GB2272-1987, ferrochrome GB5683-1987, vanadium iron GB4139-2004, ferro-niobium GB7737-1997, molybdenum-iron GB3649-1987, ferrotungsten GB/T3648-1996, ferrotianium GB3282-1987, ferro-boron GB/T5682-1995, nickel and nickel alloy plate GB/T2054-2005, blister copper YS/T 70-93 (China YouSe metal industry standard) does not have the country and the execution manufacturing enterprise standard of industry standard.
When using filling metallic particles for overlay of the present invention to weld; at first determine to fill metal components according to the performance requirement of butt welded seam; preferably selecting for use simultaneously varigrained filling metallic particles for overlay to mix uses; can reduce the gap between the particle like this; increase the volume quality, increase the loading of unit volume.
When having groove on the workpiece, at first add backing plate (or liner) at the bottom of groove welding backing weld seam or at the back side of workpiece, uniformly dispersing filling metallic particles for overlay in groove then, all position welding seam can take some measures (as magnetic or use adhesive applicating) fixedly filling metallic particles for overlay is in groove, loading is definite according to welding procedure.(can adopt the SMAW, submerged-arc welding, gas metal-arc welding of consumable electrode etc. filling weld seam of metallic surface welding at last; also can adopt TIG welding, plasma welding of non-melt pole etc.); under the effect of welding heat source; filling metallic particles for overlay is because granularity is little; be very easy to fusing and form the molten bath; because the strong convection heat transfer' heat-transfer by convection in molten bath; the also very fast fusing of the remaining filling metal in bottom; and also there is the part metals fusing at the mother metal position, forms weld seam behind the part mother metal of fusing and the filling metallic particles for overlay solidification and crystallization.This technology has the following advantages: a sweating heat input part is used for fusing and fills metal, fill metal and hindered the transmission of heat to mother metal, thereby reduced the overheated of heat affected area, made fined, the performance improvement of heat affected area crystal grain, the quality of welding point improves; Owing to the heat input of filling the unit mass metal reduces, what heat was imported is evenly distributed, and the stress of welding, distortion also reduce; Smooth welding joint, attractive in appearance has been saved the energy and welding material, has reduced cost and working strength of workers; For the welding of the above material of middle thickness, because the minimizing of the welding number of plies has improved welding production efficiency greatly.By selecting the filling metal of heterogeneity for use, above-mentioned technology can be used for the welding of carbon steel, low-alloy high-strength steel, heat resisting steel, stainless steel and other metal materials.
The invention process has following positive effect:
(1) alloying component of product can independently be adjusted as required, and the big I of the metallic particles of use is selected arbitrarily by screening.
(2) the used raw material of this patent source is wide, and makes the steel scrap resource obtain more fully reasonable use.
Iron and steel enterprise is in producing the sheet material process, because the needs of scale approximately produce the wrench and the edges of boards of output of steel about 5%, the steel user also can produce a certain amount of leftover pieces.These wrench, edges of boards are many at present have been handled as steel scrap, have melt down, have be used for the widget manufacturing, do not give full play to its composition, tissue, stable performance, the superiority that impurity content is few.
(3) filling metallic particles for overlay of patent of the present invention is produced by the direct granulation of liquid metal, and production technology is simple, and alloying component can be determined arbitrarily according to demand.
(4) owing to, metal ingredient is not had special requirement, as long as can be fused into liquid metal without throwing.Therefore, be particularly suitable for preparing the filling metallic particles for overlay of alloying element content more (as heating resisting metal).
(5) raw material are taken from steel scrap, production technology utilization rate simple, alloying element is higher, and cost reduces greatly than broken welding wires.
The specific embodiment
Embodiment 1: the preparation of used for submerged arc welding filling metallic particles for overlay and application
The chemical composition of filling metallic particles for overlay is designed to (quality %), 0.08C, 0.35Si, 1.45Mn, 0.02Nb, 0.035V, 0.02Ti, 0.18Mo, 0.24Ni, and S and P are no more than 0.03.
(1) selection of steel scrap: according to the chemical composition requirement of filling metal, select for use the leftover pieces of tensile strength 610MPa level low-carbon micro steel-alloy to produce filling metallic particles for overlay, the chemical composition of leftover pieces is (quality %): 0.09C, 1.47Mn, 0.22Si, 0.26Ni, 0.18Mo, 0.042V, 0.016Ti, 0.002S, 0.007P.
(2), determine that according to the chemical composition of the selected steel scrap of step (1) kind and the quantity of interpolation alloying constituent is as follows according to the chemical composition design objective of used for submerged arc welding filling metallic particles for overlay:
The molybdenum-iron of furnace charge gross mass 0.07% (containing 55%Mo), 0.65% ferrosilicon (containing 45%Si), 0.075% ferro-niobium (containing 50%Nb), 0.35% ferromanganese (containing 79%Mn), 0.1% ferrotianium (containing 27%Ti).
(3) the selected steel scrap of step (1) is divided into two parts of A, B, A part is put into induction melting furnace earlier, power with the induction furnace maximum melted it with the shortest time, and the quantity of A part determines that according to the size of burner hearth with molten steel after melting 15mm～20mm can be arranged is principle deeply; The solder flux 431 that adds used for submerged arc welding then is as slag former, and the addition of slag former is a principle to form the thick molten slag of 3mm～4mm at molten steel surface; After treating that molten slag forms, B part steel scrap is added in the induction melting furnace, add and fashionablely can not destroy the molten slag layer that molten steel is shielded, fusing back melting 12 minutes.
(4) step (2) is selected molybdenum-iron, ferrosilicon, ferro-niobium, ferromanganese, ferrotianium add in the melted molten steel of step (3) successively, treat ferroalloy melt fully after refining 10 minutes again;
(5) molten steel (overheated 150～200 ℃) that step (4) is melted and its surperficial slag are poured in the insulation crucible that the bottom is provided with mozzle.
Wherein: the mozzle of described insulation crucible links to each other with leting slip a remark, the diameter of leting slip a remark is 8mm, around the exit same level height of leting slip a remark, be provided with nozzle, nozzle is a circular seam type, being square arranges, the described foursquare length of side is 300mm, and the described outlet of leting slip a remark is positioned at described square intersection of diagonal place; Nozzle inlet and High-Pressure Water pipe join, and the High-Pressure Water of jet expansion ejection is 40 ° of angles with the molten steel that flows out of leting slip a remark, and the High-Pressure Water of jet expansion ejection focuses on the vertical steel flow that flows out of the outlet of leting slip a remark; Leting slip a remark is provided with the collecting pit of bottom aslope (angle of slope and horizontal plane is 45 °) with the below of nozzle, the dark water of 1.8m is housed in the pond, and the water surface is 300mm apart from the nozzle focus point.
(6) the Xuan Ding diameter of leting slip a remark is 8mm, flow with 42kg/min makes the molten steel that is sunken to the bottom in the crucible by the outflow of leting slip a remark, open the nozzle of High-Pressure Water simultaneously, the molten steel that flows out with the pressure injection of 1.2MPa, after treating that molten steel all flows out, molten slag discards, molten steel under the percussion of High-Pressure Water, become little steel drip (water under high pressure of injection molten steel around can form a cascade, completely cut off air, the steam that water atomization simultaneously forms has also reduced the dividing potential drop of oxygen (oxygen derives from air) in the atmosphere, reduced the oxidation of molten steel), and cooled off fast, fall into the collecting pit that cooling water is housed, after little steel drips and solidifies, promptly become metallic particles;
(7) metallic particles in the taking-up collecting pit water is used oven for drying, and bake out temperature is 150 ℃, and temperature retention time is 30 minutes;
(8) metallic particles after the conventional vibrosieve equipment screening of employing is dried selects for use the metallic particles of different-grain diameter to mix use according to the requirement of welding procedure in proportion; Perhaps, behind the metallic particles mixing after the oven dry, directly use.
With the filling metallic particles for overlay cut-off footpath 0.6mm of preparation as stated above and diameter 0.8mm each half be mixed for submerged-arc welding.
Adopt H08A welding wire and HJ431 solder flux coupling, the steel plate of modifier treatment behind the thick controlled rolling and controlled cooling of welding 16mm, the mechanical property of steel is: yield strength 535MPa, tensile strength 630MPa, percentage elongation 24% ,-20 ℃ of side knock merit 180J.
Welding piece is opened 50 ° V-butt, and the back side adds backing plate, and the width of backing plate is that 30mm, thickness are that 5mm, length are identical with the length of test piece for welding.Filling metallic particles for overlay is filled up groove gap, weld at the upper surface of filling metallic particles for overlay, other test methods are undertaken by the pertinent regulations of JB4708-2000 " steel pressure vessel welding technology evaluation ".Appearance of weld is attractive in appearance, distortion is less.Nondestructive inspection shows, there are not defectives such as incomplete fusion, lack of penetration, pore, crackle, the tensile strength of welding point is 665MPa, percentage elongation is 21%, tensile sample breaks in mother metal, clod wash is qualified, and the ballistic work of-20 ℃ of weld seams and heat affected area is respectively 113J, 146J, and mechanical performance index satisfies requirement of engineering.By filling metallic particles for overlay transition alloy elements of the present invention, when other steel plate of welded high-strength level, can adopt solid wire, reduced construction cost, this welding for the high intensity levels steel provides a kind of new approach.
Embodiment 2: tensile strength 700MPa grade gas shielded welding filling metallic particles for overlay
The chemical composition of filling metallic particles for overlay is designed to (quality %), and 0.08%C, 0.56%Si, 1.65%Mn, 0.15%Ti, 0.28%Mo, 1.28%Ni, 0.18%Cu, S and P are no more than 0.03.
(1) selection of steel scrap: require to select steel scrap for use according to the chemical composition of filling metal, the chemical composition of steel scrap (quality %) is: 0.06%C, 0.28%Si, 1.55%Mn, 0.014%Ti, 0.22%Mo, 0.45%Ni, 0.2%Cu, 0.011%P, 0.004%S.
(2), determine that according to the chemical composition of the selected steel scrap of step (1) kind and the quantity of interpolation alloying constituent is as follows: the ferro-aluminum of furnace charge gross mass 0.25% (containing 55%Mo), 1.5% ferrosilicon (containing 45%Si), 0.95% metallic nickel, 0.6% ferromanganese (containing 79%Mn), 2% ferrotianium (containing 27%Ti) according to the chemical composition design objective of filling metallic particles for overlay.
(3) the selected steel scrap of step (1) is divided into two parts of A, B, A part is put into induction melting furnace earlier, power with the induction furnace maximum melted it with the shortest time, and the quantity of A part determines that according to the size of burner hearth with molten steel after melting 15mm～20mm can be arranged is principle deeply; The solder flux 431 that adds used for submerged arc welding then is as slag former, and the addition of slag former is a principle to form the thick molten slag of 3mm～4mm at molten steel surface; After treating that molten slag forms, B part steel scrap is added in the induction melting furnace, add and fashionablely can not destroy the molten slag layer that molten steel is shielded, fusing back melting 10 minutes.
(4) selected ferro-aluminum, ferrosilicon, metallic nickel, ferromanganese, the ferrotianium of step (2) adds in the melted molten steel of step (3) successively, treat ferroalloy melt fully after refining 10 minutes again;
(5) molten steel (overheated 150～200 ℃) that step (4) is melted and its surperficial slag are poured in the insulation crucible that the bottom is provided with mozzle.
Wherein: the mozzle of described insulation crucible links to each other with leting slip a remark, the diameter of leting slip a remark is 6mm, around the exit same level height of leting slip a remark, be provided with nozzle, nozzle is a circular seam type, being square arranges, the described foursquare length of side is 200mm, and the described outlet of leting slip a remark is positioned at described square intersection of diagonal place; Nozzle inlet and nozzle inlet and High-Pressure Water pipe join, and the High-Pressure Water of jet expansion ejection is 35 ° of angles with the molten steel that flows out of leting slip a remark, and the High-Pressure Water of jet expansion ejection focuses on the vertical steel flow that flows out of the outlet of leting slip a remark; Leting slip a remark is provided with the collecting pit of bottom aslope (angle of slope and horizontal plane is 40 °) with the below of nozzle, the dark water of 1.5m is housed in the pond, and the water surface is 250mm apart from the nozzle focus point.
(6) the Xuan Ding diameter of leting slip a remark is 6mm, flow with 20kg/min makes the molten steel that is sunken to the bottom in the crucible by the outflow of leting slip a remark, and opens the nozzle of High-Pressure Water simultaneously, the molten steel that flows out with the pressure injection of 1.0MPa, after treating that molten steel all flows out, molten slag discards, and molten steel becomes little steel and drips under the percussion of water under high pressure, and cooled off fast, fall into the collecting pit that cooling water is housed, after little steel drips and solidifies, promptly become metallic particles;
(7) metallic particles in the taking-up collecting pit water is used oven for drying, and bake out temperature is 130 ℃, and temperature retention time is 40 minutes;
(8) metallic particles after the conventional vibrosieve equipment screening of employing is dried selects for use the metallic particles of different-grain diameter to mix use according to the requirement of welding procedure in proportion; Perhaps, behind the metallic particles mixing after the oven dry, directly use.
Be used for the gas shielded arc welding soldering test after the filling metallic particles for overlay of producing as stated above mixed.Pertinent regulations by GB/T8110-1995 " gas shielded arc welding with carbon steel, low alloy steel welding wire " prepare test piece for welding, before the weldering in groove the above-mentioned filling metallic particles for overlay of uniformly dispersing, it is CO that the welding wire of gas shielded arc welding is selected HS-70C, protective gas for use
2, gage of wire is 1.2mm.
Nondestructive inspection shows, test piece for welding does not have defectives such as incomplete fusion, lack of penetration, pore, crackle.The preparation of mechanical property sample, test method are undertaken by the regulation of GB/T8110-1995.The mechanical property of deposited metal is as follows: tensile strength is that 710MPa, yield strength 608MPa, percentage elongation 23.5% ,-20 ℃ ballistic work are 92J.This filling metallic particles for overlay can be used for the welding of 700MPa grade high-strength steel.
Embodiment 3: tensile strength 500MPa level filling metallic particles for overlay
Select for use impurity contents such as S, P to meet the steel scrap of welding material requirement, do not add the tensile strength 500MPa level filling metallic particles for overlay that the alloying element preparation is fit to the structural steel welding.
(1) selection of steel scrap: select for use the Q345 steel scrap as producing the raw material that filling metallic particles for overlay is used, its main chemical compositions is (quality %): 0.18C, 1.48Mn, 0.39Si, 0.017S, 0.015P.
(2) the selected steel scrap of step (1) is divided into two parts of A, B, A part is put into induction melting furnace earlier, power with the induction furnace maximum melted it with the shortest time, and the quantity of A part determines that according to the size of burner hearth with molten steel after melting 13mm～17mm can be arranged is principle deeply; The solder flux 431 that adds used for submerged arc welding then is as slag former, and the addition of slag former is a principle to form the thick molten slag of 3mm～4mm at molten steel surface; After treating that molten slag forms, B part steel scrap is added in the induction melting furnace, add and fashionablely can not destroy the molten slag layer that molten steel is shielded, fusing back refining 15 minutes.
(3) molten steel (overheated 150～200 ℃) that step (2) is melted and its surperficial slag are poured in the insulation crucible that the bottom is provided with mozzle.
Wherein: the mozzle of described insulation crucible links to each other with leting slip a remark, the diameter of leting slip a remark is 8mm, around the exit same level height of leting slip a remark, be provided with nozzle, nozzle is a circular seam type, being square arranges, the described foursquare length of side is 300mm, and the described outlet of leting slip a remark is positioned at described square intersection of diagonal place; Nozzle inlet and High-Pressure Water pipe join, and the High-Pressure Water of jet expansion ejection is 50 ° of angles with the molten steel that flows out of leting slip a remark, and the High-Pressure Water of jet expansion ejection focuses on the vertical steel flow that flows out of the outlet of leting slip a remark; Leting slip a remark is provided with the collecting pit of bottom aslope (angle of slope and horizontal plane is 55 °) with the below of nozzle, the dark water of 2m is housed in the pond, and the water surface is 400mm apart from the nozzle focus point.
(4) the Xuan Ding diameter of leting slip a remark is 8mm, flow with 46kg/min makes the molten steel that is sunken to the bottom in the crucible by the outflow of leting slip a remark, and opens the nozzle of High-Pressure Water simultaneously, the molten steel that flows out with the pressure injection of 3.2MPa, after treating that molten steel all flows out, molten slag discards, and molten steel becomes little steel and drips under the percussion of High-Pressure Water, and cooled off fast, fall into the collecting pit that cooling water is housed, after little steel drips and solidifies, promptly become metallic particles;
(5) metallic particles in the taking-up collecting pit water is used oven for drying, and bake out temperature is 180 ℃, and temperature retention time is 20 minutes;
(6) metallic particles after the conventional vibrosieve equipment screening of employing is dried selects for use the metallic particles of different-grain diameter to mix use according to the requirement of welding procedure in proportion; Perhaps, behind the metallic particles mixing after the oven dry, directly use.
Chemical composition (quality %) through the final filling metallic particles for overlay that obtains of chemical composition analysis is: 0.12C, 1.25Mn, 0.30Si, 0.016S, 0.013P can be used for the welding of tensile strength 500MPa level structure steel.
Claims (5)
1. welding comprises the steps: with the preparation method of filling metallic particles for overlay
(1) selection of steel scrap: C, S, P, O, N in the chemical composition of described steel scrap, by percentage to the quality, must satisfy C less than 0.15%, S less than 0.035%, P less than 0.035%, oxygen is no more than the content that 50ppm, nitrogen are no more than 50ppm; Other alloying elements Mn should be 0.1%～2.0%, Si should be 0.02%～1.8%, Mo is no more than 2.5%, Cr is no more than 3.5%, Ni is no more than 6.0%, Ti is no more than 0.5%, V is no more than 0.5%, Nb does not surpass 0.5%, Cu is no more than 0.5%, B is no more than 0.09%;
(2) according to desire system welding chemical composition index with filling metallic particles for overlay, determine whether to need to add alloying constituent according to the chemical composition of the selected steel scrap of step (1), and the kind and the quantity of adding alloying constituent;
(3) step (1) is selected steel scrap is divided into two parts of A, B, A part is put into induction melting furnace earlier with the shortest time it is melted, and the quantity of A part determines that according to the size of burner hearth with molten steel after melting 10mm～20mm can be arranged is principle deeply; Add slag former then, and with its fusing, the addition of slag former is a principle to form the thick molten slag of 3mm～4mm at molten steel surface; After treating that molten slag forms, B part steel scrap is added in the induction melting furnace, add and fashionablely can not destroy the molten slag layer that molten steel is shielded, treat to continue melting 10～15 minutes behind B part scrap melting;
(4) according to step (2) determine add alloying constituent kind and quantity add alloying constituent successively, treat its melt fully after refining 5～10 minutes again;
(5) melted molten steel and its surperficial slag are poured in the insulation crucible that the bottom is provided with mozzle;
Wherein: the mozzle of described insulation crucible links to each other with leting slip a remark, and the diameter of leting slip a remark is changed selection according to the grain diameter of desire preparation in 6～20mm; Be provided with nozzle around the exit same level height of leting slip a remark, nozzle is a circular seam type, is square and arranges, and the described foursquare length of side is 200～500mm, and the described outlet of leting slip a remark is positioned at described square intersection of diagonal place; Nozzle inlet and water under high pressure or high pressure tunger tube join, the water under high pressure or the argon gas of jet expansion ejection and the molten steel that flows out of leting slip a remark are 30 °～60 ° angles, and water under high pressure or high pressure argon gas that jet expansion sprays focus on the vertical steel flow that flows out of the outlet of leting slip a remark; Leting slip a remark is provided with the collecting pit of bottom aslope with the below of nozzle, the dark cooling water of 1.5～2m is housed in the pond, and the cooling water liquid level is 200～500mm apart from the nozzle focus point;
(6) replace with leting slip a remark of selected diameter, flow with 10～50kg/min makes the molten steel that is sunken to the bottom in the crucible by the outflow of leting slip a remark, and opens the nozzle of water under high pressure or high pressure argon gas simultaneously, the molten steel that flows out with the pressure injection of 0.8～10MPa, after treating that molten steel all flows out, molten slag discards, and molten steel becomes little steel and drips under the percussion of water under high pressure or high pressure argon gas, and cooled off fast, fall into the collecting pit that cooling water is housed, after little steel drips and solidifies, promptly become metallic particles; Described metallic particles is a ball or oval spherical, and particle diameter is 0.1～5.0mm, its chemical composition by percentage to the quality, must satisfy C less than 0.15%, S less than 0.035%, P less than 0.035%, oxygen is no more than the content that 50ppm, nitrogen are no more than 50ppm; Other alloying elements Mn should be 0.1%～2.0%, Si should be 0.02%～1.8%, Mo is no more than 2.5%, Cr is no more than 3.5%, Ni is no more than 6.0%, Ti is no more than 0.5%, V is no more than 0.5%, Nb is no more than 0.5%, Cu is no more than 0.5%, B is no more than 0.09%;
(7) metallic particles in the taking-up collecting pit water is used oven for drying, and bake out temperature is 120～180 ℃, and temperature retention time is 20～40 minutes;
(8) metallic particles after the conventional vibrosieve equipment screening of employing is dried selects for use the metallic particles of different-grain diameter to mix use according to the requirement of welding procedure in proportion; Perhaps, behind the metallic particles mixing after the oven dry, directly use.
2. welding is characterized in that with the preparation method of filling metallic particles for overlay according to claim 1, and the described steel scrap of step (1) is selected wrench, edges of boards, the leftover pieces of DB590 steel or X70 steel.
3. welding is characterized in that with the preparation method of filling metallic particles for overlay according to claim 1, and described alloying constituent is that ferrosilicon, molybdenum-iron, ferrochrome, ferro-niobium, metallic nickel, copper, ferromanganese, ferrotianium, vanadium iron, ferro-boron are part or all of.
4. welding is characterized in that with the preparation method of filling metallic particles for overlay according to claim 1, and the described slag former of step (3) is a submerged-arc welding solder flux 431 commonly used.
5. welding is characterized in that with the preparation method of filling metallic particles for overlay according to claim 1, when the described diameter of leting slip a remark of step (6) is chosen to be 6mm, the molten steel that is sunken to the crucible bottom with the flow of 18～22kg/min by the outflow of leting slip a remark; When the diameter of leting slip a remark is chosen to be 8mm, the molten steel that is sunken to the crucible bottom with the flow of 42～46kg/min by the outflow of leting slip a remark.
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| CN102139423A (en) * | 2010-02-02 | 2011-08-03 | 北京赛亿科技股份有限公司 | Cover surface layer self-protecting metal core surfacing welding wire for repairing cold-rolled backup roller |
| CN102019520A (en) * | 2010-12-08 | 2011-04-20 | 燕山大学 | Special flux-cored wire for carrying out preheating-free and heat treatment-free surfacing repair and reproducing on shaft and gear parts |
| CN102489859B (en) * | 2011-12-16 | 2013-08-14 | 长春三友汽车部件制造有限公司 | Method for improving mechanical property of advanced high-strength steel spot welding joint |
| CN105479036A (en) * | 2016-01-04 | 2016-04-13 | 威县亚泰密封件有限公司 | Metal particle reinforced type flux-cored wire and preparation method thereof |
| CN107254610A (en) * | 2017-06-12 | 2017-10-17 | 吉林大学 | Raw nano-sized particles reinforced aluminium alloy material preparation method in a kind of |
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| CN1309009A (en) * | 2001-03-23 | 2001-08-22 | 重庆大学 | Alloy welding method for end face at smaller end of air valve |
| CN1328897A (en) * | 2001-08-08 | 2002-01-02 | 武汉钢铁(集团)公司 | Microtitanium-boron high-toughness gas protective welding stick |
| US20040112474A1 (en) * | 2002-10-17 | 2004-06-17 | Rikiya Kato | Lead-free solder ball |
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|---|---|---|---|---|
| CN1309009A (en) * | 2001-03-23 | 2001-08-22 | 重庆大学 | Alloy welding method for end face at smaller end of air valve |
| CN1328897A (en) * | 2001-08-08 | 2002-01-02 | 武汉钢铁(集团)公司 | Microtitanium-boron high-toughness gas protective welding stick |
| US20040112474A1 (en) * | 2002-10-17 | 2004-06-17 | Rikiya Kato | Lead-free solder ball |
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