CN100457622C - Prepn. of small-grain Ti-Si molecular sieve in cheap hydrothermal system and its application - Google Patents
Prepn. of small-grain Ti-Si molecular sieve in cheap hydrothermal system and its application Download PDFInfo
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- 239000002808 molecular sieve Substances 0.000 title claims abstract description 27
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910004339 Ti-Si Inorganic materials 0.000 title 1
- 229910010978 Ti—Si Inorganic materials 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003513 alkali Substances 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 13
- 239000010936 titanium Substances 0.000 claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002425 crystallisation Methods 0.000 claims abstract description 11
- 230000008025 crystallization Effects 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 150000001412 amines Chemical class 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 6
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 230000001476 alcoholic effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N mono-methylamine Natural products NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 238000003483 aging Methods 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 15
- 238000006735 epoxidation reaction Methods 0.000 abstract description 12
- 230000003197 catalytic effect Effects 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 239000003054 catalyst Substances 0.000 abstract description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000012847 fine chemical Substances 0.000 abstract description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 239000010457 zeolite Substances 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005805 hydroxylation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- -1 pure oxidation Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The present invention provides a preparation method of small grain titan-silicon molecular sieve catalyst. This titan-silicon molecular sieve is a catalyst synthesized by adopting ammonium bromide tetraalkyl as template agent, organic amine as alkali source, silicon sol as silicon source and alcohol solution of titanium tetrachloride as titanium source through the process of temp.-changing crystallization in hydrothermal synthesis system. The grain size of said molecular sieve is 0.85 micrometer X0.4 micrometer X 0.15 micrometer. Said molecular sieve can be used in propylene epoxidation and styrene epoxidation reaction, and possesses high catalytic activity, it also can be used for synthesizing other fine chemical products.
Description
Technical field
The present invention relates to a kind of hydrothermal synthesis method and application of molecular sieve catalyst.
Background technology
Since the titanium-silicon molecular sieve TS-1 with MFI topological structure that US Patent 4410501 discloses synthesizes successfully first, because its excellent catalytic selective oxidation performance has caused that people pay attention to widely.In the synthetic method of classics, expensive template and harsh synthetic technological condition are the principal elements that hinders its industrial applications always, develop cheap synthetic system and prepare HTS and become a focus.In the preparation research of HTS, StudSurfSci Catal, 1994,84,203 have reported that with 4-propyl bromide (TPABr) be template, with the strong aqua is alkali source, synthesize titanium-silicon molecular sieve TS-1, crystallization temperature is 185 ℃, and crystallization time is 168h, thereby reduced synthetic cost of HTS and Operating Complexity, but the grain-size of its synthetic sieve sample is 15 μ m * 3 μ m * 1.5 μ m.EP Appl.0,543,247 description is a template with the 4-propyl bromide, and ammoniacal liquor is done alkali source, and colloid silica is the silicon source, and butyl (tetra) titanate is the titanium source after using the hydrogen peroxide complexing, synthesizes through hydro-thermal to obtain the TS-1 that grain-size is 10 μ m.Zeolite16 (1996) 108 has reported the method for a kind of synthetic TS-1, is template with cheap 4-propyl bromide, and hexanediamine is an alkali source, and tetraethyl silicane acid esters and tetraethyl-titanic acid ester are respectively silicon source and titanium source, and the mole of reaction mixture consists of: SiO
2: TiO
2: C
6DN: TPABr: H
2O=1: 0.01: 0.3: 0.1: 50, the hydrothermal crystallizing temperature is 180 ℃, and crystallization time is 5 days, and the HTS grain-size of preparation is 7 μ m * 2.5 μ m * 0.5 μ m.In recent years, the exploitation of cheap system obtains a very large progress, but in the synthetic system of TS-1 that with TPABr is template, all has the bigger phenomenon of zeolite grain always.With TPAOH is template, TPAOH itself is exactly very strong alkali source, do not need to add again the alkalescence that alkali source is regulated glue, institute synthetic HTS crystal grain less (Zeolites, 1992,12,943), be difficult for producing the extra-framework titanium species, to epoxidation of propylene, the phenol hydroxylation reaction all has good catalytic performance; And need add alkali source in addition to regulate the basicity of synthetic glue with TPABr synthetic HTS, be easy to generate the extra-framework titanium species, and crystal grain is bigger, at phenol hydroxylation, catalytic performance relatively poor (Stud Surf SciCatal, 1994 in the epoxidation of styrene, 84,203).The catalytic property of zeolite molecular sieve, particularly selectivity are relevant with mass transfer and diffusional limitation with inactivation character.The zeolite grain size then is the important factor that influences the catalyzer scattering nature, along with reducing of zeolite grain, helps molecular diffusion, improves the accessibility in active centre, helps the performance of catalyst catalytic performance.The shortening of the evolving path, and the porous surface degree of lip-rounding improved product selectivity one time, reduces the chance of secondary reaction, reduces the possibility that generates carbon distribution, increased the activity stabilized time.Therefore, in cheap hydrothermal system, reduce HTS grain-size size, synthesize small-crystallite titanium-silicon molecular sieve TS-1 with respect to other cheap system HTS.And be applied to have in the reaction of obvious diffusional effect, the small-crystallite titanium-silicon molecular sieve that obtains highly active catalytic performance has important significance for theories and actual application value.
Summary of the invention
The catalyzer of the present invention's preparation is a kind of HTS that contains of MFI structure, it is to adopt cheap 4-propyl bromide (TPABr) to be template, organic amine is an alkali source, silicon sol is the silicon source, the alcoholic solution of titanium tetrachloride is done the titanium source, alcoholic solution comprises methyl alcohol, ethanol, propyl alcohol, Virahol, propyl carbinol etc., and organic amine comprises methylamine, ethamine, Tri N-Propyl Amine, n-Butyl Amine 99, hexanediamine, quadrol, diethylamine etc., and the mole of reactant consists of: SiO
2: TiO
2Amine: TPABr: H
2O=1: 0.01-0.03: 0.1-3.0: 0.1-0.3: 30-60.Adopt hydro-thermal variable temperature crystallization process, crystallization condition is: under the agitation condition (100rpm-400rpm), low temperature maturation (80-100 ℃, 2-9 days), low temperature crystallized (100-130 ℃, 2-10 days), after filtration, washing, drying, 540 ℃ of roastings 6 hours, making average crystal grain directly is the HTS of 0.84 μ m.
The HTS of the present invention's preparation shows that by the X diffraction spectrogram it is the MFI topological structure; By measuring the titanium active centre that IR spectrogram explanation molecular sieve has four-coordination; Mainly exist by the titanium elements in the UV-Vis spectrogram explanation HTS with skeleton four-coordination form; By measuring the brilliant looks feature of HTS, the grain-size that molecular sieve is described is 0.85 μ m * 0.4 μ m * 0.15 μ m; And the laser particle size of having measured HTS distributes, and the narrower particle size distribution of molecular sieve is described, median size is 0.84 μ m.
The HTS of the present invention's preparation has following advantage and effect:
(1) adopts titanium tetrachloride to do the titanium source, synthesized titanium-silicon molecular sieve TS-1, further simplified the hydro-thermal synthesis process of HTS.
(2) adopted organic amine to do alkali source, 170 ℃ of following generated times have been reduced to 24h by 96h, improved the resultant velocity of HTS, further reduced the synthetic cost of molecular sieve, and the low temperature crystallized possibility that provides has been provided.
(3) use 4-propyl bromide to do template, in the hydro-thermal synthetic system, adopt extraordinary synthetic route, zeolite crystal is reduced to below the 1 μ m.
(4) the synthetic small-crystallite titanium-silicon molecular sieve is used in the reactions such as epoxidation of propylene and epoxidation of styrene, catalytic activity is good.
Adopt titanium-silicon molecular sieve TS-1 provided by the invention when the reduction Preparation of Catalyst expends, reduced the grain-size size of HTS, the active centre is effectively utilized.Can be used for the reaction such as synthetic of oxidation, the ammoxidation of cyclohexanone of alkene epoxidation, stable hydrocarbon, pure oxidation, fine chemicals, particularly can be used for doing in the propylene ring oxidation reaction and epoxidation of styrene reaction of oxygenant with hydrogen peroxide.In reaction process, mild condition, controllability is strong, non-pollution discharge.Therefore, in today that environmental problem comes into one's own day by day, molecular sieve provided by the present invention will have very strong using value.
Embodiment
Embodiment 1
Getting 10 gram deionized waters is added in 15 gram 30% (wt) silicon sol, stir after 30 minutes, be added dropwise to the alcoholic solution of 1.4 gram titanium tetrachlorides, continue to stir 30 minutes, then with 3 gram 4-propyl bromides, 10 gram 65% (wt) ethylamine solutions, be added in the glue, stir after 60 minutes, add 30 ml deionized water, the gained glue is joined in 100 milliliters of stainless steel autoclaves; 100 ℃ of ageings 9 days, then the temperature journey is risen to 120 ℃ earlier, continued crystallization 9 days, filter through conventional method, washing, drying in 540 ℃ of roastings 6 hours, is removed organic formwork agent, obtains sieve sample A, and crystal grain is 0.85 μ m * 0.4 μ m.
Embodiment 2
Blending process is with embodiment 1, and crystallization process is: after glue joined in the stainless steel autoclave, 170 ℃ of crystallization 1 day obtained sieve sample B, and crystal grain is 2.96 μ m * 1.6 μ m..
The comparative example
According to EP Appl.0,543,247 disclosed methods are template with the 4-propyl bromide, and ammoniacal liquor is done alkali source, and colloid silica is done the silicon source, and butyl (tetra) titanate be the titanium source after with the hydrogen peroxide complexing, synthesizes 5 days in 175 ℃ of hydro-thermals, and the glue proportioning is: SiO
2: TiO
2: NH
4OH: TPABr: H
2O=1: 0.01: 0.3: 0.1: 50, obtain production code member C, crystal grain is 10 μ m * 4 μ m.
Embodiment 3
In 205ml stainless steel high pressure batch reactor, add 0.4 gram catalyzer C, 32 ml methanol, 2 milliliter 30% hydrogen peroxide stirs and feeds propylene, propylene pressure 0.4MPa down, 60 ℃ of temperature of reaction, the sampling when reaction times is 30,60,90 minutes, the transformation efficiency of iodometric determination hydrogen peroxide, gas chromatograph is analyzed the selectivity and the productive rate of propylene oxide.The results are shown in Table 1.
Substitute C with catalyst A, carry out above-mentioned reaction, reaction result is listed in table 1.
The epoxidation of propylene catalytic performance of table 1 molecular sieve
As can be seen, the activity of small-crystallite titanium-silicon molecular sieve provided by the invention in propylene ring oxidation reaction surpassed the HTS of big crystal grain.
Embodiment 4
Present embodiment illustrates the application and the activity in the epoxidation of styrene reaction of molecular sieve provided by the invention.
Reactor is 250 milliliters of stainless steel chuck autoclaves, water bath with thermostatic control heating, magnetic stirrer.In reactor, add 20 milliliters in acetone, 10 milliliters of vinylbenzene, 1 gram catalyzer C, 4 milliliters in hydrogen peroxide, with the reactor sealing, heating up begins reaction.Get material analysis after 60,120,180 minutes reaction times.Using branch 1102 type gas chromatographic analysis products forms.Use the iodometric titrationiodimetry titration hydrogen peroxide content.The results are shown in Table 2.Substitute C with catalyst A, carry out above-mentioned reaction, reaction result is listed in table 2.
The epoxidation of styrene catalytic performance of table 2 molecular sieve.
As can be seen, the activity of small-crystallite titanium-silicon molecular sieve provided by the invention in the epoxidation of styrene reaction is better than the HTS of big crystal grain.
Claims (3)
1, a kind of preparation method by template, alkali source, silicon source and titanium source synthesis of titanium silicon molecular sieve, it is characterized in that small-crystallite titanium-silicon molecular sieve is that the employing 4-propyl bromide is a template, organic amine is an alkali source, silicon sol is the silicon source, the alcoholic solution of titanium tetrachloride is done the titanium source, and the mole of reactant consists of: SiO
2: TiO
2: amine: TPABr: H
2O=1: 0.01-0.03: 0.1-3.0: 0.1-0.3: 30-60, under 100-400rpm stirs, carry out the hydro-thermal variable temperature crystallization, earlier low temperature 80-100 ℃ ageing 2-9 days, again at 100-130 ℃ of crystallization 2-10 days, after filtration, washing, drying, 540 ℃ of roastings 6 hours, making average crystal grain directly was the HTS of 0.84 μ m.
2, according to the preparation method of the described HTS of claim 1, when it is characterized in that doing the titanium source with the titanium tetrachloride alcoholic solution, alcoholic solution is methyl alcohol, ethanol, propyl alcohol, Virahol or propyl carbinol.
3, according to the preparation method of the described HTS of claim 1, when it is characterized in that the organic amine that adopts is alkali source, organic amine is methylamine, ethamine, Tri N-Propyl Amine, n-Butyl Amine 99, hexanediamine, quadrol or diethylamine.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100443408C (en) * | 2004-10-08 | 2008-12-17 | 大连理工大学 | Gas solid phase preparation method of high performance titanium silicon zeolite |
| CN100443177C (en) * | 2005-01-31 | 2008-12-17 | 中国石油化工股份有限公司 | Ethyl benzene oxidizing-dehydrogenation catalyst |
| CN100351176C (en) * | 2005-08-09 | 2007-11-28 | 华东理工大学 | Method of synthesizing titanium silicon molecular sieve using complexig agent to raise titanium source stability |
| CN101913620B (en) * | 2010-07-20 | 2012-05-30 | 大连理工大学 | Method for quickly synthesizing small-crystallite titanium-silicon molecular sieve in cheap system |
| TWI480100B (en) * | 2011-04-27 | 2015-04-11 | China Petrochemical Dev Corp Taipei Taiwan | Titanium-silicon molecular sieve and its preparation method and method for producing cyclohexanone oxime using the molecular sieve |
| CN102502686B (en) * | 2011-10-06 | 2013-06-19 | 大连理工大学 | Method for synthesizing titanium silicon molecular sieve |
| CN102616806B (en) * | 2012-04-20 | 2014-03-26 | 上海卓悦化工科技有限公司 | Method for preparing high-performance titanium and silicon molecular sieve |
| CN104944439B (en) * | 2014-03-28 | 2018-04-13 | 中国石油化工股份有限公司 | A kind of Titanium Sieve Molecular Sieve and preparation method thereof |
| CN112717997B (en) * | 2021-01-19 | 2022-02-15 | 中国科学院大连化学物理研究所 | Preparation method of high-activity catalytic oxidation catalyst TS-1 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1131126A (en) * | 1995-12-22 | 1996-09-18 | 吉林大学 | Titanium silicate zeolite molecular sieve crystal and preparation method thereof |
| CN1167081A (en) * | 1996-06-05 | 1997-12-10 | 中国石油化工总公司 | Method for preparing titanium-silicon molecular sieve (TS-2) |
| CN1217232A (en) * | 1997-11-13 | 1999-05-26 | 中国石油化工总公司 | Process for preparing titanium-silicon molecular sieve |
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2001
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1131126A (en) * | 1995-12-22 | 1996-09-18 | 吉林大学 | Titanium silicate zeolite molecular sieve crystal and preparation method thereof |
| CN1167081A (en) * | 1996-06-05 | 1997-12-10 | 中国石油化工总公司 | Method for preparing titanium-silicon molecular sieve (TS-2) |
| CN1217232A (en) * | 1997-11-13 | 1999-05-26 | 中国石油化工总公司 | Process for preparing titanium-silicon molecular sieve |
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