From Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system
Technical field
The invention belongs to the evaporation separation technology field of inorganic salt mixing solutions, refer to a kind of especially from NaCl-Na
2SO
4-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system.
Background technology
Known from Na
2SO
4--NaCl-H
2Produce the method for sodium sulfate and sodium-chlor in the O system, have the salt-making mother liquor of evaporation absorption method and evaporation system nitre mother liquor to discharge method, require Na in the raw material but wherein evaporate the existence of salt-making mother liquor absorption method
2SO
4Content less than the content of NaCl, and wherein evaporation system nitre mother liquor discharge method exists and requires Na in the raw material
2SO
4Content low and influence problem of environment more than content, the raw material rate of recovery of NaCl, therefore, above-mentioned two methods are difficult to adapt to Na
2SO
4--NaCl-H
2O system sodium sulfate and sodium chloride content change situation greatly.
Summary of the invention
The present invention is directed to the problems referred to above, change Na
2SO
4--NaCl-H
2The O system is produced the technology of sodium sulfate and sodium-chlor, proposes one and can adapt to Na
2SO
4--NaCl-H
2The variation of O system sodium sulfate and sodium chloride content cuts down the consumption of energy and cost, solves the sodium sulfate and the sodium-chlor production technique of environment protection.
For achieving the above object, the present invention takes following design: a kind of from Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system, it is characterized in that it comprises the following steps:
One, gets Na
2SO
4--NaCl-H
2O system raw material, wherein concentration of component is: NaCl 5-320g/l, Na
2SO
45-350g/l evaporates above-mentioned system raw material, and vaporization temperature 60-130 ℃, carry out solid-liquid separation then and obtain sodium sulfate or sodium-chlor and mother liquid evaporation in the raw material, the mother liquid evaporation concentration of component is: NaCl 305-290g/l, Na
2SO
450-60g/l;
Two, the above-mentioned mother liquid evaporation of low-temperature evaporation and carry out solid-liquid separation and obtain salt-making mother liquor and sodium-chlor, vaporization temperature 40-60 ℃, the salt-making mother liquor concentration of component is: NaCl 295-285g/l, Na
2SO
460-70g/l;
Three, the above-mentioned salt-making mother liquor of evaporation and carry out solid-liquid separation and obtain making nitre mother liquor and sodium sulfate, vaporization temperature is 5-15 ℃ or 70-100 ℃, system nitre mother liquor concentration of component is: NaCl 290-320g/l, Na
2SO
420-60g/l;
Four, this system nitre mother liquor participates in the above-mentioned low-temperature evaporation salt manufacturing operation of circulation down.
Na
2SO
4--NaCl-H
2Can contain concentration in the O system for greater than 0 calcium sulfate and/or the sal epsom that is less than or equal to 5g/l.
Advantage of the present invention is: the present invention be one from Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system, at first take Na
2SO
4--NaCl-H
2O system raw material, wherein component concentration is: NaCl5-320g/l, Na
2SO
45-350g/l evaporates above-mentioned raw materials, and vaporization temperature 60-130 ℃, the mother liquid evaporation concentration of component is: NaCl 305-290g/l, Na
2SO
450-60g/l carries out solid-liquid separation then and obtains sodium sulfate or sodium-chlor and mother liquid evaporation in the raw material, and the above-mentioned mother liquid evaporation of low-temperature evaporation is NaCl 295-285g/l, Na up to the salt-making mother liquor concentration of component then
2SO
460-70g/l carries out solid-liquid separation again and obtains salt-making mother liquor and sodium-chlor, vaporization temperature 40-60 ℃; The above-mentioned salt-making mother liquor of revaporization up to system nitre mother liquor concentration of component is: NaCl290-320g/l, Na
2SO
451.6-60g/l, to carry out solid-liquid separation again and obtain making nitre mother liquor and sodium sulfate, vaporization temperature is 5-15 ℃ or 70-100 ℃; At last, this system nitre mother liquor participates in the low-temperature evaporation salt manufacturing operation in above-mentioned second step of circulation down.In the above-mentioned technological process, the theoretical rate of recovery of sodium sulfate and sodium-chlor is 100%, and the rate of recovery of discharging method 50-90% than known technology evaporation system nitre mother liquor has significantly raising, and the acceptable end product standard that the product sodium sulfate quality reaches country's promulgation (contains Na
2SO
4〉=99%, Cl
-≤ 0.35%), the product sodium-chlor quality premium grads standard that reaches country promulgation (contains NaCl 〉=99.1%, SO
4 2-≤ 0.30%).Technological process does not have waste liquid and discharges, and has the high and quality product height of raw material availability, and energy consumption is low, production cost is low and characteristics such as three-waste free discharge.
Embodiment
Embodiment 1: a kind of from Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system, comprise the following steps:
One, gets 100m
3Na
2SO
4--NaCl-H
2O system raw material, wherein concentration of component is: NaCl 300g/l, Na
2SO
420g/l evaporates above-mentioned bittern, and 68 ℃ of vaporization temperatures are carried out solid-liquid separation then and obtained 19.3 tons in sodium-chlor and mother liquid evaporation 36.4m
3, the mother liquid evaporation concentration of component is: NaCl 294g/l, Na
2SO
455g/l;
Two, above-mentioned mother liquid evaporation of low-temperature evaporation and circulation system nitre mother liquor and carry out solid-liquid separation and obtain salt-making mother liquor 156.3m
3With 10.7 tons in sodium-chlor, 48 ℃ of vaporization temperatures, the salt-making mother liquor concentration of component is: NaCl 290g/l, Na
2SO
464g/l;
Three, the above-mentioned salt-making mother liquor of evaporation and carry out solid-liquid separation and obtain making nitre mother liquor 148.1m
3With 2.0 tons in sodium sulfate, 95 ℃ of vaporization temperatures, system nitre mother liquor concentration of component is: NaCl 306g/l, Na
2SO
454g/l, this system nitre mother liquor participates in the low-temperature evaporation salt manufacturing operation in above-mentioned second step of circulation down.
Embodiment 2: a kind of from Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system, comprise the following steps:
One, gets 100m
3NaCl-Na
2SO
4-H
2O system raw material, wherein concentration of component is: NaCl 179g/l, Na
2SO
4181g/l evaporates above-mentioned raw materials, and 63 ℃ of vaporization temperatures are carried out solid-liquid separation then and obtained 14.5 tons in sodium sulfate and mother liquid evaporation 62.1m in the raw material
3, the mother liquid evaporation concentration of component is: NaCl 290g/l, Na
2SO
456g/l;
Two, above-mentioned mother liquid evaporation of low-temperature evaporation and circulation system nitre mother liquor and carry out solid-liquid separation and obtain salt-making mother liquor 247.5m
3With 18 tons in sodium-chlor, 45 ℃ of vaporization temperatures, the salt-making mother liquor concentration of component is: NaCl 286g/l, Na
2SO
468g/l;
Three, the above-mentioned salt-making mother liquor of evaporation and carry out solid-liquid separation and obtain making nitre mother liquor 185.4m
3With 3.5 tons in sodium sulfate, 100 ℃ of vaporization temperatures, system nitre mother liquor concentration of component is: NaCl 310g/l, Na
2SO
455g/l, this system nitre mother liquor participates in the low-temperature evaporation salt manufacturing operation in above-mentioned second step of circulation down.
Embodiment 3: a kind of from Na
2SO
4--NaCl-H
2Produce the technology of sodium sulfate and sodium-chlor in the O system, comprise the following steps:
One, gets 100m
3Na
2SO
4--NaCl-H
2O system raw material, wherein component concentration is: NaCl 20g/l, Na
2SO
4340g/l evaporates above-mentioned raw materials, and 62 ℃ of vaporization temperatures are carried out solid-liquid separation then and obtained 33.6 tons in sodium sulfate and mother liquid evaporation 6.9m in the raw material
3, the mother liquid evaporation concentration of component is: NaCl 291g/l, Na
2SO
457g/l):
Two, above-mentioned mother liquid evaporation of low-temperature evaporation and circulation system nitre mother liquor and carry out solid-liquid separation and obtain salt-making mother liquor 38.5m
3With 2 tons in sodium-chlor, 50 ℃ of vaporization temperatures, the salt-making mother liquor concentration of component is: NaCl 292g/l, Na
2SO
462g/l;
Three, the above-mentioned salt-making mother liquor of evaporation and carry out solid-liquid separation and obtain making nitre mother liquor 32.2m
3With 0.4 ton in sodium sulfate, 5 ℃ of vaporization temperatures, system nitre mother liquor concentration of component is: NaCl 290g/l, Na
2SO
420g/l, this system nitre mother liquor participates in the low-temperature evaporation salt manufacturing operation in above-mentioned second step of circulation down.