CN100429194C - Method for utilizing reaction heat in process of producing methane chloride and purifying mixture - Google Patents
Method for utilizing reaction heat in process of producing methane chloride and purifying mixture Download PDFInfo
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- CN100429194C CN100429194C CNB2006100964801A CN200610096480A CN100429194C CN 100429194 C CN100429194 C CN 100429194C CN B2006100964801 A CNB2006100964801 A CN B2006100964801A CN 200610096480 A CN200610096480 A CN 200610096480A CN 100429194 C CN100429194 C CN 100429194C
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- 238000000034 method Methods 0.000 title claims abstract description 29
- FBBDOOHMGLLEGJ-UHFFFAOYSA-N methane;hydrochloride Chemical compound C.Cl FBBDOOHMGLLEGJ-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 75
- 238000003860 storage Methods 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000006228 supernatant Substances 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 50
- 238000010791 quenching Methods 0.000 claims description 40
- 230000000171 quenching effect Effects 0.000 claims description 40
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 239000007921 spray Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 16
- 239000002918 waste heat Substances 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000005587 bubbling Effects 0.000 claims description 11
- 241000282326 Felis catus Species 0.000 claims description 8
- 230000000630 rising effect Effects 0.000 claims description 7
- 238000000746 purification Methods 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 230000007423 decrease Effects 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 230000000153 supplemental effect Effects 0.000 claims description 3
- 239000000571 coke Substances 0.000 abstract 2
- 239000000110 cooling liquid Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 6
- 229960001701 chloroform Drugs 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 3
- 239000008247 solid mixture Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229950005499 carbon tetrachloride Drugs 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000013526 supercooled liquid Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 210000000689 upper leg Anatomy 0.000 description 2
- 230000001174 ascending effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
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Abstract
The process of utilizing reaction afterheat and purifying produced mixture in producing methane chloride. The process includes the following steps: introducing the high temperature and high pressure methane chloride gas mixture produced into cooling liquid in the reactor into the chilling tower to deposit carbon coke grains, passing the gas mixture through the heat exchange plate inside the tower to countercurrent contact with the tower top sprayed liquid for further eliminating carbon coke grains, leading the gas mixture from the tower bottom to one storage tank via pipeline while depositing and exhausting the solid grains, feeding partial supernatant through the upper part of the storage tank to the downstream rectification section while spraying the rest supernatant in the top of the chilling tower, feeding most of the high temperature and high pressure gas mixture to afterheat boiler to recover heat while condensing into liquid, and leading the liquid into the storage tank.
Description
Technical field
The present invention relates to the method for comprehensive utilization of the reaction heat energy in a kind of methane chloride production process.
Background technology
In production processes such as chemical industry, petrochemical industry, run into by certain high temperature, high pressure or have the gas-liquid-solid mixture of certain pressure or the mixed flow thigh that vapour-solid mixture is formed through regular meeting.Self containing high-grade heat energy can support recycling on the one hand for they, and on the other hand, processing requirement also often need be condensed into vapour phase wherein cryogenic liquid, and removes small amount of solid impurity wherein simultaneously, so that enter downstream unit operations.
For example, producing with the methyl alcohol method in the process of methane chloride, degree of depth chlorination reaction is a strong exothermal reaction, the reaction product of reactor outlet is that one has 1.2MPa pressure and 400 ℃ of high temperature, and contain tens kinds of components gas-solid mixture of (comprising the trace impurity component), this mixture flow thigh wherein contains the higher-grade heat energy that can support recycling in a large number because flow is bigger; On the other hand, it also contains the burnt particulate matter of carbon below 3%, must be removed, and just can enter the operation of downstream rectifying workshop section and does not cause the obstruction of this workshop section's equipment.Therefore, design performance is good has novel method necessity extremely of removing solid effect and heat recuperation effect concurrently.
Summary of the invention
The present invention is directed to the methyl alcohol method and produce the technological process of methane chloride (monochloro methane, methylene dichloride, chloroform and tetracol phenixin), propose a kind of wherein higher-grade heat energy that both can reclaim, can remove the method for other solid impurities such as carbon black granules in the mixture again.
Technical scheme of the present invention is as follows.
A kind of production methane chloride reaction workshop section's utilization of Heat of Reaction and purifying mixture method, it is made up of the following step basically:
Step 1. will be produced the high temperature of the reactor generation of methane chloride, highly compressed methane chloride mixed gas, wherein comprise monochloro methane, methylene dichloride, trichloromethane (chloroform), tetrachloromethane and a spot of oxygen, the burnt particle of chlorine and carbon, enter quenching column 2 by pipeline 1-2 from quenching column 2 bottoms, gas distributor 2-1 is arranged at quenching column 2 bottoms, gas distributor 2-1 is immersed among the cold liquid of quenching column 2 bottoms, the cold liquid of bottom is the phlegma of methane chloride gas, the methane chloride mixed gas of High Temperature High Pressure enters quenching column 2, just by gas distributor 2-1 bubbling in cold liquid, by the bubbling effect, reduced temperature on the one hand, on the other hand the burnt particle of carbon is scrubbed, deposit to cold liquid bottom, the mixed gas that purifies through the supercooled liquid bubbling still has higher temperature and pressure, they flow to the low pressure area at quenching column 2 tops, during the polylith flow through type heat exchange column plate that in passing tower, is provided with (2-3 is one of them), spray the cryogenic liquid counter current contact of getting off with the overhead liquid sparger 2-2 of quenching column 2, temperature further reduces, the burnt particle of the trace carbon of being carried secretly in the gas is further washed away purification by liquid simultaneously, taken the bottom of tower to
Enter the methane chloride mist of quenching column 2 through the cold liquid bubbling of tower reactor of quenching column 2 and step by step cooling and the purification of cat head spray liquid; Temperature slightly has decline; The burnt particle of carbon has not wherein existed substantially; There is the fraction hot gas to be condensed into liquid and is back to quenching column 2 tower reactors with spray liquid; Remaining most high temperature and high pressure gas enters waste heat boiler 5 by pipeline 2-5 and carries out heat recovery; Air release goes out a large amount of heat energy; Self is condensed into liquid; Enter storage tank 3 by pipeline 5-1; Become the at the middle and upper levels part of clear liquid of storage tank 3
The cold liquid of the burnt particulate of a large amount of carbon is contained under the effect of the impact of cat head spray liquid and gravity in step 2. quenching column 2 tower stills bottoms, enter solid-liquid separation storage tank 3 by pipeline 2-4, the ingress of storage tank 3 is provided with baffle plate 3-1, it makes the burnt particles settling of carbon in the incoming mixture get off, enter solid particles sediment groove 3-2, again from subsider 3-2 bottom discharge system, supernatant liquid is then under the effect of law of connected vessels, the top of swarming storage tank 3 from the slit of baffle plate 3-1 bottom, a small amount of gas of wherein carrying secretly is from storage tank 3 tops, by pipeline 3-3, come back in the quenching column 2
A large amount of clear liquids then enters transferpump 3-4 by pipeline in step 3. storage tank 3, flows to two pipeline 3-5 and 3-6, and pipeline 3-6 directly sends into the part clear liquid rectifying workshop section 6 in downstream; Pipeline 3-5 then sends into clear liquid interchanger 4, and interchanger 4 slightly descends the temperature of clear liquid, delivers to quenching column 2 tops by pipeline 4-1 again, descend through liquid distributor 2-2 spray, with rising high temperature gas flow counter current contact, temperature has rising slightly, arrive the tower still at last, begin new one and take turns circulation.
Above-mentioned utilization of Heat of Reaction and purifying mixture method, described heat exchange column plate 2-3 can be sieve plate, valve tray, bubble cap plate or slant-hole tray.
Above-mentioned utilization of Heat of Reaction and purifying mixture method, the high pressure steam that described waste heat boiler 5 produces then can be used as the supplemental heat source of downstream rectifying workshop section 6, at first, by pipeline 5-2 is reboiler 7 heat supplies of rectifying workshop section 6, and the water of condensation that forms after the heat exchange is transported to waste heat boiler 5 by pipeline 7-1 and recycles.
Above-mentioned utilization of Heat of Reaction and purifying mixture method, the hot water that the overhead condenser 8 at described interchanger 4 and rectifying workshop section rectifying tower top is produced can be used for the raw material hydrogenchloride and the methyl alcohol of pre-thermal reactor 1.
Compare with traditional method, present method has three big advantages: 1. the abundant high-quality heat energy (the methane chloride heat energy that mixed gas is with of High Temperature High Pressure) of recycling system self.Take a broad view of system, the measure of three place's heat recovery and utilizations is arranged: at first be waste heat boiler 5, a large amount of heat energy recycle; Next is that pipeline 3-6 directly sends the part supernatant liquid in the storage tank 3 into rectifying workshop section 6, has utilized the heat energy that this part clear liquid had; Moreover be that interchanger 4 and overhead condenser 8 can will be used for the reaction mass of pre-thermal reactor 1 from the heat energy that system obtained; 2. saving great lot of water resources.Do not use waste heat boiler in the traditional method, utilize interchanger to come cooling down high-temperature highly compressed methane chloride mixed gas fully, need to consume a large amount of water coolants and electric energy, in present method, 4 need of interchanger slightly reduce the clear liquid temperature, water seldom, most of heat energy is by waste heat boiler 5 recyclings, efficient is very high.And in total system, water all is to recycle in an airtight pipeline, does not almost have loss; 3. efficiently solve the burnt particulate purifying problem of carbon in the methane chloride gas that reactor 1 produces.The step by step tray counter current contact of spray liquid in bubbling effect by gas distributor 2-1 and the quenching column 2, the air-flow that arrives quenching column 2 tops substantially no longer contains the burnt particle of carbon, and this has cleared away obstacle for material enters downstream separation workshop section smoothly.
Description of drawings
Fig. 1 is the schematic flow sheet of the inventive method, wherein:
1 is reactor, and 1-1 is a pipeline, and 1-2 is a pipeline;
2 is quenching column, and 2-1 is a gas distributor, and 2-2 is a liquid distributor, and 2-3 is the heat exchange column plate, and 2-4 is a pipeline, and 2-5 is a pipeline;
3 is storage tank, and 3-1 is a baffle plate, and 3-2 is a subsider, and 3-3 is a pipeline, and 3-4 is a transferpump, and 3-5 is a pipeline, and 3-6 is a pipeline;
4 is interchanger, and 4-1 is a pipeline;
5 is waste heat boiler, and 5-1 is a pipeline, and 5-2 is a pipeline;
6 are rectifying workshop section;
7 is reboiler, and 7-1 is a pipeline;
8 is the rectifying tower overhead condenser.
Embodiment
Embodiment
Certain factory's methane chlorination biological production system, the pressure of the methane chloride mixed gas that its reactor 1 produces is 1.2MPa, temperature is 450 ℃, (37 tons/hour of the amounts of gas) adopts the mixed gas of this High Temperature High Pressure of conventional process, not only consume a large amount of power and water energy, and wasted the high-quality heat energy that mixed gas had, after using method of the present invention instead, cold liquid temp is 190 ℃ at the bottom of quenching column 2 towers, 180 ℃ of cat head spray liquids, arrive overhead gas pressure 0.8MPa, temperature is 220 ℃, producing vapor pressure in waste heat boiler is 200 ℃ of 0.6MPa temperature, supplies with downstream rectifying workshop section rectifying tower and uses, and add up 500 ten thousand yuan for factory saves general expenses every year.Its method is as follows:
Raw material hydrogenchloride and the methyl alcohol of producing methane chloride enter reactor 1 by pipeline 1-1, in reactor 1, violent thermopositive reaction takes place under the effect of catalyzer, (temperature is 450 ℃ to produce High Temperature High Pressure, pressure is 1.2MPa) the methane chloride mixed gas: monochloro methane, methylene dichloride, trichloromethane (chloroform), the burnt particle of tetrachloromethane and a spot of oxygen, chlorine and carbon, ultimate production is 37 tons/hour.This mixed gas enters quenching column 2 by pipeline 1-2, and quenching column 2 diameters are that 12 flow through type heat exchange column plate 2-3 are arranged in the high 10500mm of 2000mm, and heat exchange column plate 2-3 is a valve tray, and percentage of open area is 30%.Gas distributor 2-1 is arranged at the bottom of quenching column 2, and gas distributor 2-1 is immersed among the cold liquid of quenching column bottom.The temperature of cold liquid is 190 ℃, and the gas mixture of High Temperature High Pressure enters quenching column 2, just by gas distributor 2-1 bubbling in cold liquid, by the bubbling effect, has reduced temperature on the one hand, on the other hand the burnt particle of carbon is scrubbed, and deposits to cold liquid bottom.The gas that purifies through the supercooled liquid bubbling still has higher temperature and pressure, they flow to the low pressure area at quenching column 2 tops, during flow through type heat exchange column plate 2-3 in passing tower, spray cryogenic liquid (180 ℃) counter current contact of getting off with overhead liquid sparger 2-2, temperature further reduces, the burnt particle of the trace carbon of being carried secretly in the gas is further washed away purification by liquid simultaneously, has taken the bottom of tower to.The cold liquid of the burnt particulate of a large amount of carbon is contained under the effect of the impact of cat head spray liquid and gravity in tower still bottom, enter solid-liquid separation storage tank 3 by pipeline 2-4, the ingress of storage tank 3 is provided with baffle plate 3-1, it makes the burnt particles settling of carbon in the incoming mixture get off, enter solid particles sediment groove 3-2, again from subsider 3-2 bottom discharge system, supernatant liquid is then under the effect of law of connected vessels, the top of swarming storage tank 3 from the slit of baffle plate 3-1 bottom, a small amount of gas of wherein carrying secretly is from storage tank 3 tops, by pipeline 3-3, come back in the quenching column 2.A large amount of clear liquids then enters transferpump 3-4 by pipeline in the storage tank 3, flows to two pipeline 3-5 and 3-6, and pipeline 3-6 directly sends into the part clear liquid rectifying workshop section 6 in downstream; Pipeline 3-5 then sends into clear liquid interchanger 4, and interchanger 4 slightly descends the temperature of clear liquid, delivers to quenching column 2 tops by pipeline 4-1 again, descend through liquid distributor 2-2 spray, with rising high-temperature gas counter current contact, temperature has rising slightly, arrive the tower still at last, begin new one and take turns circulation.See rising gas again, ascending gas itself is a High Temperature High Pressure, cooling step by step and purification through cold liquid bubbling of tower still and cat head spray liquid, temperature has decline slightly, the burnt particle of carbon has not wherein existed substantially, there is small portion gas to be condensed into liquid and flow to the tower still with spray liquid, remaining most high temperature and high pressure gas arrives the cat head of quenching column 2, this moment, the temperature of gas was 220 ℃, and pressure is 0.8MPa, enters waste heat boiler 5 by pipeline 2-5 and carries out heat recuperation, gas release goes out a large amount of heat energy, self then is condensed into liquid, enters storage tank 3 by pipeline 5-1, becomes storage tank 3 part of clear liquid at the middle and upper levels.Then under the effect of pump, a part is behind interchanger 4, be delivered to the top of quenching column 2, recycle, rest part then enters the rectifying workshop section 6 in downstream through pipeline 3-6, and the high pressure steam (pressure is 0.6 MPa, 200 ℃ of temperature) that waste heat boiler produces then can be used as the supplemental heat source of downstream rectifying workshop section: at first, by pipeline 5-2 is reboiler 7 heat supplies of rectifying workshop section 6, and the water of condensation that forms after the heat exchange is transported to waste heat boiler 5 by pipeline 7-1 and recycles; Secondly, the hot water that the overhead condenser 8 at interchanger 4 and rectifying tower top is produced can be used for the raw material hydrogenchloride and the methyl alcohol of pre-thermal reactor 1.Like this, the fine high temperature heat of entire reaction system has just obtained abundant recycling, has saved lot of energy and process water, has also solved the burnt particulate purifying problem of carbon in the air-flow simultaneously.
Claims (4)
1. produce methane chloride reaction workshop section's utilization of Heat of Reaction and purifying mixture method for one kind, it is characterized in that it is made up of the following step:
Step 1. will be produced the high temperature of the reactor generation of methane chloride, highly compressed methane chloride mixed gas enters quenching column (2) by pipeline (1-2) from quenching column 2 bottoms, gas distributor (2-1) is arranged at quenching column (2) bottom, gas distributor (2-1) is immersed among the cold liquid of quenching column (2) bottom, the cold liquid of bottom is the phlegma of methane chloride mixed gas, the methane chloride mixed gas of High Temperature High Pressure enters quenching column (2), just by gas distributor (2-1) bubbling in cold liquid, they flow to the low pressure area at quenching column (2) top, pass the polylith flow through type heat exchange column plate (2-3) that is provided with in the tower, the cryogenic liquid counter current contact that sprays with the overhead liquid sparger (2-2) of quenching column (2)
The methane chloride mixed gas that enters quenching column (2) is through the cold liquid bubbling of tower still of quenching column (2) and the cooling step by step and the purification of cat head spray liquid, temperature has decline slightly, the burnt particle of carbon has not wherein existed substantially, there is the small portion hot gas to be condensed into liquid and is back to quenching column (2) tower still with spray liquid, remaining most high temperature and high pressure gas enters waste heat boiler (5) by pipeline (2-5) and carries out heat recuperation, gas release goes out a large amount of heat energy, self is condensed into liquid, enter storage tank (3) by pipeline (5-1), become storage tank (3) part of clear liquid at the middle and upper levels
The cold liquid of the burnt particulate of a large amount of carbon is contained under the effect of the impact of cat head spray liquid and gravity in step 2. quenching column (2) tower still bottom, enter solid-liquid separation storage tank (3) by pipeline (2-4), the ingress of storage tank (3) is provided with baffle plate (3-1), it makes the burnt particles settling of carbon in the incoming mixture get off, enter solid particles sediment groove (3-2), again from subsider (3-2) bottom discharge system, supernatant liquid is then under the effect of law of connected vessels, the top of swarming storage tank (3) from the slit of baffle plate (3-1) bottom, a small amount of gas of wherein carrying secretly is from storage tank (3) top, by pipeline (3-3), come back in the quenching column (2)
A large amount of clear liquid then enters transferpump (3-4) by pipeline and flows to two pipelines (3-5) and (3-6), the direct rectifying workshop section (6) that the part clear liquid is sent into the downstream of pipeline (3-6) in step 3. storage tank (3); Interchanger (4) then sent into clear liquid by pipeline (3-5), interchanger (4) slightly descends the temperature of clear liquid, deliver to quenching column (2) top by pipeline (4-1) again, descend through liquid distributor (2-2) spray, with rising high temperature gas flow counter current contact, temperature has rising slightly, arrives the tower still at last, begins new one and takes turns circulation.
2. utilization of Heat of Reaction according to claim 1 and purifying mixture method is characterized in that: described heat exchange column plate (2-3) is sieve plate, valve tray, bubble cap plate or slant-hole tray.
3. utilization of Heat of Reaction according to claim 1 and purifying mixture method, it is characterized in that: the high pressure steam that described waste heat boiler (5) produces is as the supplemental heat source of downstream rectifying workshop section (6): at first, be reboiler (7) heat supply of rectifying workshop section (6) by pipeline (5-2), the water of condensation that forms after the heat exchange is transported to waste heat boiler (5) by pipeline (7-1) and recycles.
4. utilization of Heat of Reaction according to claim 3 and purifying mixture method is characterized in that: the hot water that the overhead condenser (8) at described interchanger (4) and rectifying workshop section (6) rectifying tower top is produced is used for the raw material hydrogenchloride and the methyl alcohol of pre-thermal reactor (1).
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CN102798112A (en) * | 2012-09-07 | 2012-11-28 | 中国东方电气集团有限公司 | Boiler capable of preventing scorification and dust stratification |
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WO2010102139A2 (en) | 2009-03-05 | 2010-09-10 | Dow Global Technologies, Inc. | Methods and assemblies for liquid-phase reactions |
CN101503336B (en) * | 2009-03-06 | 2013-03-13 | 刘世刚 | Improved methane chloride production process |
CN101497551B (en) * | 2009-03-06 | 2012-10-03 | 刘世刚 | Methane chlorides production process utilizing chlorination reaction heat |
CN102435079A (en) * | 2011-10-12 | 2012-05-02 | 厦门大学 | Condensation system of biomass pyrolyzed steam |
CN105457588B (en) * | 2015-12-04 | 2017-11-28 | 中国天辰工程有限公司 | A kind of gas-liquid two-phase catalyst reaction device for chloromethanes production |
CN109734553A (en) * | 2018-12-26 | 2019-05-10 | 山东东岳氟硅材料有限公司 | A kind of energy-efficient methane chloride process for refining |
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CN1686982A (en) * | 2005-04-21 | 2005-10-26 | 江苏梅兰化工股份有限公司 | Method for shock chilling gas of chloride of methane at high temperature in production of methyl chloride |
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CN1686982A (en) * | 2005-04-21 | 2005-10-26 | 江苏梅兰化工股份有限公司 | Method for shock chilling gas of chloride of methane at high temperature in production of methyl chloride |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102798112A (en) * | 2012-09-07 | 2012-11-28 | 中国东方电气集团有限公司 | Boiler capable of preventing scorification and dust stratification |
CN102798112B (en) * | 2012-09-07 | 2015-07-08 | 中国东方电气集团有限公司 | Boiler capable of preventing scorification and dust stratification |
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