CN100427630C - Production method of high-strength atmospheric corrosion resistant section steel - Google Patents

Production method of high-strength atmospheric corrosion resistant section steel Download PDF

Info

Publication number
CN100427630C
CN100427630C CNB2005100224412A CN200510022441A CN100427630C CN 100427630 C CN100427630 C CN 100427630C CN B2005100224412 A CNB2005100224412 A CN B2005100224412A CN 200510022441 A CN200510022441 A CN 200510022441A CN 100427630 C CN100427630 C CN 100427630C
Authority
CN
China
Prior art keywords
steel
alloy
molten steel
vacuum
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CNB2005100224412A
Other languages
Chinese (zh)
Other versions
CN1793404A (en
Inventor
刘明
周一平
方淑芳
唐历
刘建华
陶功明
王亚东
李纪仁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pangang Group Co Ltd
Original Assignee
Panzhihua Iron and Steel Group Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panzhihua Iron and Steel Group Corp filed Critical Panzhihua Iron and Steel Group Corp
Priority to CNB2005100224412A priority Critical patent/CN100427630C/en
Publication of CN1793404A publication Critical patent/CN1793404A/en
Application granted granted Critical
Publication of CN100427630C publication Critical patent/CN100427630C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention provides a production method of high-strength atmospheric corrosion resistant section steel, which comprises the following steps: 1) smelting molten steel, 2) adding a pre-deoxidizer into a steel ladle, then adding an alloy of Si, Mn and Cr and a slag charge, 3) heating the molten steel and blowing argon, adding an alloy of C powder, Si and Mn, stopping heating when the temperature of the molten steel is 1600-1630 ℃, and continuing blowing argon for 15-30 min; or heating the molten steel and blowing argon, stopping heating when the temperature of the molten steel is 1600-1630 ℃, performing vacuum treatment, adding C powder, Si and Mn alloy at the later stage of the vacuum treatment, 4) casting, 5) heating the casting blank to 1100-1250 ℃, preserving heat, rolling the section steel, and cooling after rolling. R of the section Steel of the present inventioneLThe production method of the invention does not need a cold bending process, does not need to control a cooling method after rolling, and only adopts natural cooling.

Description

The production method of high strength atmospheric corrorsion resistant section steel
Technical field
The present invention relates to a kind of shape steel producing method, particularly relate to a kind of production method of high strength atmospheric corrorsion resistant section steel.
Background technology
Development along with China Railway Freight train heavy loading, the manufacturing of railway freight train is developing to the high strength direction with steel always, in order to satisfy the requirement of joist steel in China's heavy haul train, Tiedaobu Transportation Bureau has issued rail freight high-strength weather-resistant hot rolling 310 second font steel technical qualification in 2004, high-strength weather-resistant hot rolling 310 second font steel are proposed yield strength (ReL) be not less than 450MPa, tensile strength (Rm) is not less than 550MPa,-40 ℃ of ballistic works (AkV) are not less than the performance requriements of 24J, require steel to have good weldability and atmospheric corrosion resistance simultaneously.
" steel vanadium titanium " magazine (the 23rd~26 page of the 23rd the 4th phase of volume in December, 2002, the VN12 alloying technology is to 09V steel Effect on Performance, Liu Mingzhu) reported that climbing steel adopts VN12 alloy replacing ferro-vanadiumization, can improve the report of the intensity 30MPa of second font steel." Baogang's science and technology " magazine (the 35th~37 page of the 30th the 4th phase of volume in August, 2004, high weather-proof 310 second font steel trial-production, works such as Cheng Defu) reported that Baogang produces the situation of high weather-proof (atmospheric corrosion resistance) Q345GNHL310 second font steel, the ReL of this steel can reach 420~435MPa, and has good weather resistance." rare earth information " magazine (o. 11th was the 10th page in 2003) has reported that Baogang successfully develops the situation of high-strength weather-resistant B450NbRE310 second font steel, but this magazine is not seen the report that detailed performance index and scale operation information are arranged.The application number of Hankow Steel Mill be 03125344.X public announcement of a patent application a kind ofly be used for the clod wash central sill that rail vehicle is made, adopt the big hat shape steel of the method production yield strength ReL 〉=450MPa of roll formed shape, replace second font steel to make the rail freight central sill.
But no matter adopt VN12 alloy replacing ferro-vanadium production second font steel, or Q345GNHL310 second font steel, ReL does not all reach 450MPa.Adopt the clod wash method to produce big hat shape steel and replace second font steel to make railway freight train central sill, needing increases the clod wash operation, has increased production cost.
Summary of the invention
Technical problem to be solved by this invention provides a kind of production method of high strength atmospheric corrorsion resistant section steel, and the ReL of this steel reaches more than the 450MPa, and Akv and has good atmospheric corrosion resistance ability more than 24J, and this method does not need the clod wash operation.
The technical scheme that technical solution problem of the present invention is adopted is: the production method of high strength atmospheric corrorsion resistant section steel, may further comprise the steps: 1) smelting molten steel, make P in the molten steel≤0.35%, S≤0.15%, V≤0.15%, add Cu plate and Ni plate again, make Cu:0.20 in the molten steel~0.40%, Ni:0.15~0.35%, when C content in the molten steel less than 0.05% the time, tap in the ladle, 2) in ladle, add pre-deoxidant, make that oxygen concn drops to below 0.01% in the molten steel, add Si again, the alloy of Mn and Cr, make Si:0.30 in the molten steel~0.45%, Mn:1.20~1.40%, Cr:0.20~0.40%, add the slag charge that contains Al2O3,3 again) to molten steel heating and Argon, add the C powder, the alloy of Si and Mn, make C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, CEN:0.25~0.34%, after liquid steel temperature is 1600~1630 ℃, stop heating, continue Argon 15~30min; Or to molten steel heating and Argon, after liquid steel temperature is 1600~1630 ℃, stop heating, carry out vacuum-treat, the vacuum-treat later stage adds the C powder, the alloy of Si and Mn, make C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, CEN:0.25~0.34%, 4) casting, temperature is 1548 ± 10 ℃, 5) with the speed of 8~14 ℃/min heating strand to 1100~1250 ℃, be incubated after 1.5~2.0 hours, rolled section steel, finishing temperature is 700~900 ℃, cools off after rolling, obtain high strength atmospheric corrorsion resistant section steel, its Chemical Composition comprises by weight percentage: C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, Cu:0.20~0.40%, Ni:0.15~0.35%, Cr:0.20~0.40%, P≤0.35%, S≤0.15%, V≤0.15%.
The invention has the beneficial effects as follows: the ReL of shaped steel of the present invention reaches more than the 450MPa; Rm reaches more than the 550MPa; AkV is greater than 26J, and the maximum value of carbon equivalent (CEN) is no more than 0.34%, carries out CO2 shielded welding, union-melt weld and manual welding and all crackle can not occur under 0 ℃ of condition.When carrying out corrosion test, shaped steel of the present invention is with respect to corrosion rate≤55% of Q345B (weight percent content of Chemical Composition is: C:0.12~0.18%, Si≤0.40%, Mn:0.12~0.18%, P≤0.030%, S≤0.020%, Cu≤0.070%, Cr≤0.10%, Ni≤0.10%) (degree that occurs below is weight percent content) to adopt TB/T2375-1993 " railway soaks into the corrosion test method with the weathering steel cycle ".Production method of the present invention does not need the clod wash operation, does not need the controlled chilling method after rolling, and only adopts naturally cooling to get final product.
Description of drawings
The 310 second font steel sectional views that Fig. 1 adopts the inventive method to produce.
The clod wash central sill sectional view that Fig. 2 number of patent application 03125344.X produces.
Fig. 3 310 second font steel of the present invention to postwelding again with the welding synoptic diagram of railway freight railway car.
The clod wash central sill that Fig. 4 number of patent application 03125344.X produces and the welding synoptic diagram of railway freight railway car.
Embodiment
The invention will be further described below by drawings and Examples.
C is by increasing the intensity that steel Medium pearlite quantity improves steel, Si, Mn are solid-solubilized in the steel can significantly improve intensity equally, but increase along with C, Si, Mn component in the steel, the toughness and the weldability of steel descend thereupon, so C content is 0.10~0.15%, Si content is 0.30~0.50%, Mn content is 1.20~1.45%.
Add Cu, Ni and Cr element and can improve the atmospheric corrosion resistance ability of steel, but these elements also can reduce the toughness and the weldability of steel, therefore, Cu content is 0.20~0.40%, Ni content is 0.15~0.35%, Cr content is 0.20~0.40%.
P also can improve the atmospheric corrosion resistance ability of steel, but P can improve the low temperature brittleness transition temperature again, is unfavorable for the low temperature impact properties of steel, so P content is not more than 0.35%.
Except that free-cutting steel, S is a harmful element, and is low more good more, so S content of the present invention is not more than 0.15%.
V can form V (C, N) particle, and part of V (C, N) particle becomes the ferrite core, promotes the ferritic generation of intracrystalline, makes the crystal grain of steel obtain refinement, and the add-on of V is not more than 0.15%.
CEN is the carbon equivalent of steel, and CEN is higher than at 0.34% o'clock, and the weldability of steel is poor, and CEN is lower than at 0.25% o'clock, and steel interalloy constituent content is low, and the yield strength of steel decreases.
CEN is calculated as follows:
CEN=C+A(C){Si/24+Mn/16+Cu/15+Ni/20+(Cr+V)/5}
A in the formula (C) is the proper-use factor of C, A (C)=0.75+0.25tgh[20 (C-0.12)].
The method that the present invention produces high strength atmospheric corrorsion resistant section steel is:
(1) the molten steel converter is just refined
The control of first refining phase of molten steel converter is difficult for the content of element Cu, Ni, Cr of oxidation in the scope that the final finished steel requires, and the content of Si, Mn is lower slightly than the scope of final finished steel, to prevent subsequent process the possibility that increases Si, Mn content is arranged.
1) the converter smelting molten steel makes P in the steel≤0.35%, S≤0.15%, V≤0.15%, 5min added Cu and Ni plate before converter smelting finished, make the content of Cu in the molten steel, Ni be respectively 0.20~0.40% and 0.15~0.35%, when C content in the molten steel less than 0.05% the time, in the ladle of tapping immediately.
2) tapping 1/3 back adds pre-deoxidant, and such as Al piece or Fe-Al-Mn alloy etc., add-on drops to below 0.01% with the oxygen concn in the molten steel and is as the criterion.After adding pre-deoxidant, add Si alloy (Fe-Si alloy or Fe-Si-Mn alloy), Mn alloy (Fe-Mn alloy or Fe-Si-Mn alloy) and Cr alloy (middle carbon Fe-Cr alloy, low-carbon (LC) Fe-Cr alloy, little carbon Fe-Cr alloy or Metal Cr) again, carry out alloying, Si content is 0.30~0.45% in the control molten steel, Mn content is 1.20~1.40%, Cr content is 0.20~0.40%.Tap and added all pre-deoxidants and alloy at 2/3 o'clock.
3) gone out in ladle, to add behind the steel and contained Al 2O 3Slag charge so that the Al of ladle slag 2O 3In 12~26% scope, the purpose that adds slag charge is in order to adsorb the impurity in the ladle.
(2) liquid steel refining
Adopt " electric heater unit " or " electrically heated+vacuum treatment installation " all can carry out the refining of molten steel.Liquid steel refining phase major control C, Si, Mn and CEN remove the SiO in the molten steel in the scope that the final finished steel requires 2, CaO, Al 2O 3Deng being mingled with, increase the purity of molten steel, improve the final performance of steel.
1) adopt electrical heating process:
Molten steel is after the electrically heated operation, begin Argon and heating immediately, and add C powder and Si, Mn alloy, the Argon intensity control is in 0.2~0.4MPa scope, when liquid steel temperature reaches 1600~1630 ℃, stop heating, stop to continue Argon 15~30min after the heating, during electrically heated, electrically heated after 5 minutes ladle slag can all melt, the ladle slag of fusing has the SiO of absorption in the steel 2, CaO, Al 2O 3Deng the ability that is mingled with.Control C, Si and Mn content during the electrically heated respectively in 0.10~0.15%, 0.30~0.50% and 1.20~1.45% scope, CEN is controlled in 0.25~0.34% the scope.Carry out Ca in the electrically heated operation later stage and handle, the purpose that Ca handles is that sulfide is carried out spheroidizing, reduces the rating level of impurity, and the add-on of Ca is steel 0.1~0.3kg per ton.
2) adopt electrically heated+vacuum-treat operation:
Molten steel begins Argon and heating immediately after the electrically heated operation, the Argon intensity control is in 0.2~0.4MPa scope, and liquid steel temperature stops heating when reaching in 1600~1630 ℃ of scopes, send molten steel to carry out vacuum-treat to vacuum treatment installation.When adopting RH vacuum cycle treatment unit to handle molten steel, vacuum degree control is being not more than 12Kpa, and when adopting the VD vacuum treatment installation to handle molten steel, vacuum degree control is being not more than 10KPa.The molten steel vacuum processing time is controlled at 10~15min.Need add C powder and Si, Mn alloy in right amount in the vacuum-treat later stage, control C, Si and Mn content are respectively in 0.10~0.15%, 0.30~0.50% and 1.20~1.45% scope, and CEN is controlled in 0.25~0.34% the scope.After vacuum-treat is intact, carries out Ca and handle, the add-on of Ca is steel 0.1~0.3kg per ton.
(3) continuous casting steel machine
High-strength weather resisting steel liquidus temperature of the present invention is 1518 ℃, and the superheating temperature of wrapping in the control continuous caster is 30 ± 10 ℃, and therefore, the bag temperature is 1548 ± 10 ℃ in the control continuous caster.This temperature realizes by control electrically heated temperature.
(4) section rolling
Strand with the rate of heating heating of 8~14 ℃/min, after being heated to 1100~1250 ℃, is incubated 1.5~2.0 hours under this temperature in process furnace, finishing temperature is controlled at 700~900 ℃, can adopt the air cooling mode to cool off after rolling.
Fig. 1 is the hot rolling 310 second font steel of producing according to the inventive method 2,1 welding of itself and railway freight railway car as shown in Figure 3, because of the exterior angle of 310 second font steel 2 is the right angle, when connecing with railway carriage or compartment, compartment back welding, be the welding of plane and planar, can not occur the phenomenon of rosin joint in the welding process.
Fig. 2 is the clod wash central sill of producing according to number of patent application 03125344.X disclosed method 3, and the welding of itself and railway freight railway car 1 as shown in Figure 4.Because of clod wash central sill 3 exterior angles are big fillet, when connecing, be the welding of arc and planar with railway carriage or compartment, compartment back welding, the phenomenon of rosin joint may appear in welding process.
The clod wash central sill of producing according to the 310 second font steel and the number of patent application 03125344.X disclosed method of the inventive method production sees Table 1 in the relative merits contrast of others, comparing result shows, remove in the manufacturing of railway freight vehicle, second font steel of the present invention needs outside many welding once, and others all are better than the clod wash central sill according to the production of number of patent application 03125344.X disclosed method.
Table 1
Hot rolling 310 second font steel of the present invention 03125344.X the clod wash central sill Estimate
Steel mill's production cost Smelting → the hot rolling of steel The smelting of steel → be rolled into sheet material → clod wash becomes central sill The clod wash central sill need increase the clod wash process cost
Goods train It is first to postwelding, Directly and side bar Adopt the inventive method to produce 310 second
Manufactory's cost Again with side bar and the welding of bottom, compartment With the welding of bottom, compartment Font steel cost is slightly high
Cross-sectional shape The variable cross-section shape The uniform thickness cross-sectional shape The variable cross-section shape more helps bearing the weight on railway freight train casing top
Railway freight train manufacturing process Each exterior angle is rectangular Each exterior angle is the great circle arcuation Hot rolling 310 second font steel welding of the present invention and assembling are easily
Other defective No clod wash deformed region The clod wash deformed region is arranged The clod wash deformation place very easily forms formation of crack
Embodiment 1:
5min added Cu and Ni plate before the converter smelting molten steel finished, make the content of Cu in the molten steel, Ni be respectively 0.27% and 0.29%, when C content in the molten steel less than 0.05% the time, in the ladle of tapping immediately, the C content in the molten steel is 0.03%, P content is 0.016%, S content is 0.009%.Tapping 1/3 back adds 1 ton of pre-deoxidant Fe-Al-Mn alloy, Al content is 20% in the Fe-Al-Mn alloy, Mn content is 25%, oxygen concn to 0.005% in the control molten steel, add Fe-Si-Mn, Fe-Si and Fe-Cr alloy again, carry out Si, Mn, Cr is element alloyed, wherein, Si content is 12% in the Fe-Si-Mn alloy, Mn content is 62%, Si content is 74% in the Fe-Si alloy, Cr content is 63% in the Fe-Cr alloy, and Si content is 0.42% in the control molten steel, Mn content is 1.30%, Cr content is 0.24%.In ladle, add Al after having gone out steel 2O 3Content is 21% slag charge 500kg.After molten steel is delivered to electrical heater, heating molten steel to 1615 ℃, in the RH vacuum treatment installation, carry out vacuum-treat immediately, vacuum degree control is at 10KPa, behind the vacuum-treat 5min, add C powder, Fe-Si alloy and Fe-Mn alloy, control C, Si, Mn content are respectively 0.12%, 0.39% and 1.40%, controlling CEN simultaneously is 0.28%, and vacuum processing time is 12min.Feed 800 meters of Si-Ca cored-wires (Ca weight is 35g in every meter Si-Ca cored-wire) after the vacuum-treat, carry out Ca and handle.During continuous-casting steel pouring, liquid steel temperature is controlled at 1545 ℃.Be 10 ℃/min with rate of heating again, adopt pusher-type furnace heating steel billet to 1220 ℃, and begin rolled section steel in insulation under this temperature after 1.5 hours, finishing temperature is controlled to be 850 ℃, rolls the back and adopts the air cooling mode to cool off.
The mechanical property of check shaped steel is: R EL: 485Mpa, R m: 615Mpa, Ak v: 42J.
Embodiment 2:
5min added Cu and Ni plate before the converter smelting molten steel finished, make in the molten steel that Cu content is 0.25%, Ni content is 0.27%, in C content in the molten steel was tapped ladle less than 0.05% the time immediately, the C content in the molten steel was 0.03%, P content is 0.015%, S content is 0.011%.Tapping 1/3 back adds 1 ton of pre-deoxidant Fe-Al-Mn alloy, Al content is 20% in the Fe-Al-Mn alloy, Mn content is 25%, oxygen concn to 0.003% in the control molten steel, add Fe-Si-Mn, Fe-Si and Fe-Cr alloy again, carry out Si, Mn, Cr is element alloyed, wherein, Si content is 12% in the Fe-Si-Mn alloy, Mn content is 62%, Si content is 74% in the Fe-Si alloy, Cr content is 63% in the Fe-Cr alloy, and Si content is 0.46% in the control molten steel, Mn content is 1.36%, Cr content is 0.24%.In ladle, add Al after having gone out steel 2O 3Content is 15% slag charge 500kg.After molten steel is delivered to electrical heater, behind the heating molten steel to 1610 ℃, in the RH vacuum treatment installation, carry out vacuum-treat immediately, vacuum degree control is at 10KPa, behind the vacuum-treat 5min, add C powder, Fe-Si alloy and Fe-Mn alloy, control C, Si, Mn are respectively 0.12%, 0.40% and 1.40%, controlling CEN simultaneously is 0.28%, molten steel vacuum processing time 12min.Feed 800 meters of Si-Ca cored-wires (Ca weight is 35g in every meter Si-Ca cored-wire) after the vacuum-treat, carry out Ca and handle.During continuous-casting steel pouring, liquid steel temperature is controlled to be 1550 ℃.Be 9 ℃/min with rate of heating again, adopt pusher-type furnace heating steel billet to 1200 ℃, and begin rolled section steel in insulation under this temperature after 1.5 hours, finishing temperature is controlled at 750 ℃, rolls the back and adopts the air cooling mode to cool off.
The mechanical property of check shaped steel is: R EL: 500Mpa, R m: 620Mpa, Ak v: 36J.
Embodiment 3:
5min added Cu and Ni plate before the converter smelting molten steel finished, and made in the molten steel that Cu content is 0.26%, Ni content is 0.24%, in C content in the molten steel is tapped ladle less than 0.05% the time immediately.C content in the molten steel is 0.04%, P content is 0.013%, S content is 0.008%.Tapping 1/3 back adds 1 ton of pre-deoxidant Fe-Al-Mn alloy, Al content is 20% in the Fe-Al-Mn alloy, Mn content is 25%, oxygen concn to 0.007% in the control molten steel, add Fe-Si-Mn, Fe-Si and Fe-Cr alloy again, carry out Si, Mn, Cr is element alloyed, wherein, Si content is 12% in the Fe-Si-Mn alloy, Mn content is 62%, Si content is 74% in the Fe-Si alloy, Cr content is 63% in the Fe-Cr alloy, and Si content is 0.43% in the control molten steel, Mn content is 1.34%, Cr content is 0.24%.In ladle, add Al after having gone out steel 2O 3Content is 19% slag charge 500kg.After molten steel is delivered to electrical heater, heating molten steel to 1600 ℃, in the RH vacuum treatment installation, carry out vacuum-treat immediately, vacuum degree control is at 10KPa, behind the vacuum-treat 5min, add C powder, Fe-Si alloy and Fe-Mn alloy, control C content is 0.13%, Si content is 0.42%, Mn content is 1.41%, controlling CEN simultaneously is 0.29%, and the molten steel vacuum processing time is 12min.Feed 800 meters of Si-Ca cored-wires (Ca weight is 35g in every meter Si-Ca cored-wire) after the vacuum-treat, carry out Ca and handle.During continuous-casting steel pouring, liquid steel temperature is controlled at 1545 ℃.Be 9 ℃/min with rate of heating again, adopt pusher-type furnace heating steel billet to 1200 ℃, and begin rolled section steel in insulation under this temperature after 1.5 hours, finishing temperature is controlled at 800 ℃, rolls the back and adopts the air cooling mode to cool off.
The mechanical property of check shaped steel is: R EL: 500Mpa, R m: 620Mpa, Ak v: 38J.
The present invention not only can be used for rail freight with high-strength weather-resistant hot rolling 310 second font steel, also can be used for others, and these all belong to the scope of protection of the invention.

Claims (8)

1, the production method of high strength atmospheric corrorsion resistant section steel is characterized in that, said method comprising the steps of:
1) smelting molten steel makes P in the molten steel≤0.35%, S≤0.15%, V≤0.15%, adds Cu plate and Ni plate again, makes Cu:0.20 in the molten steel~0.40%, Ni:0.15~0.35%, when C content in the molten steel less than 0.05% the time, in the ladle of tapping,
2) in ladle, add pre-deoxidant, make that oxygen concn drops to below 0.01% in the molten steel, add the alloy of Si, Mn and Cr again, make Si:0.30 in the molten steel~0.45%, Mn:1.20~1.40%, Cr:0.20~0.40%, add again and contain Al 2O 3Slag charge,
3) to molten steel heating and Argon, add the alloy of C powder, Si and Mn, make C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, CEN:0.25~0.34%, after liquid steel temperature is 1600~1630 ℃, stop heating, continue Argon 15~30min; Or, after liquid steel temperature is 1600~1630 ℃, stop heating to molten steel heating and Argon, carry out vacuum-treat, the vacuum-treat later stage adds the alloy of C powder, Si and Mn, makes C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, CEN:0.25~0.34%
4) casting, temperature is 1548 ± 10 ℃,
5) with the speed of 8~14 ℃/min heating strand to 1100~1250 ℃, be incubated after 1.5~2.0 hours, rolled section steel, finishing temperature is 700~900 ℃, cool off after rolling, obtain high strength atmospheric corrorsion resistant section steel, its Chemical Composition comprises by weight percentage: C:0.10~0.15%, Si:0.30~0.50%, Mn:1.20~1.45%, Cu:0.20~0.40%, Ni:0.15~0.35%, Cr:0.20~0.40%, P≤0.35%, S≤0.15%, V≤0.15%.
2, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1 is characterized in that, the described pre-deoxidant of step 2 is Al piece or Fe-Al-Mn alloy.
3, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1, it is characterized in that, the described Si alloy of step 2 is Fe-Si or Fe-Si-Mn alloy, the Mn alloy is Fe-Mn or Fe-Si-Mn alloy, and the Cr alloy is middle carbon Fe-Cr, low-carbon (LC) Fe-Cr, little carbon Fe-Cr alloy or Metal Cr.
4, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1, it is characterized in that, vacuum cycle treatment unit and vacuum treatment installation are adopted in the described vacuum-treat of step 3, when adopting the vacuum cycle treatment unit, vacuum tightness is not more than 12KPa, when adopting vacuum treatment installation, vacuum tightness is not more than 10KPa.
5, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1 is characterized in that, the described Argon intensity of step 3 is 0.2~0.4Mpa.
6, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1 is characterized in that, the described vacuum processing time of step 3 is 10~15min.
7, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1 is characterized in that, carries out Ca after the described step 3 again and handles, and the add-on of Ca is steel 0.1~0.3kg per ton.
8, the production method of high strength atmospheric corrorsion resistant section steel as claimed in claim 1 is characterized in that, described step 5 adopts the air cooling mode to cool off.
CNB2005100224412A 2005-12-29 2005-12-29 Production method of high-strength atmospheric corrosion resistant section steel Active CN100427630C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100224412A CN100427630C (en) 2005-12-29 2005-12-29 Production method of high-strength atmospheric corrosion resistant section steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100224412A CN100427630C (en) 2005-12-29 2005-12-29 Production method of high-strength atmospheric corrosion resistant section steel

Publications (2)

Publication Number Publication Date
CN1793404A CN1793404A (en) 2006-06-28
CN100427630C true CN100427630C (en) 2008-10-22

Family

ID=36805053

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005100224412A Active CN100427630C (en) 2005-12-29 2005-12-29 Production method of high-strength atmospheric corrosion resistant section steel

Country Status (1)

Country Link
CN (1) CN100427630C (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007001098A1 (en) * 2007-01-04 2008-07-10 Sms Demag Ag Process and plant for the production of steel
CN100535134C (en) * 2007-06-27 2009-09-02 攀钢集团攀枝花钢铁研究院 Copper-containing steel heating method and copper-containing steel produced by same
CN101135030B (en) * 2007-10-12 2010-09-08 莱芜钢铁集团有限公司 Weather-resistant hot rolled narrow steel strip and method for manufacturing same
JP4645761B2 (en) * 2009-03-04 2011-03-09 Jfeスチール株式会社 T-section steel
CN101838773B (en) * 2010-04-30 2012-09-26 武汉钢铁(集团)公司 Steel for acid soil corrosion-resistant hot rolling U-shaped steel sheet pile and production method thereof
CN102260834A (en) * 2010-05-26 2011-11-30 马鞍山钢铁股份有限公司 H2S corrosion resistant hot rolled steel plate for oil well pipe and preparation method thereof
CN102431567A (en) * 2010-09-29 2012-05-02 齐齐哈尔轨道交通装备有限责任公司 Center sill structure
CN103667955B (en) * 2013-12-20 2016-02-17 齐齐哈尔轨道交通装备有限责任公司 A kind of steel with high impact strength and foundry goods thereof
CN106957990B (en) * 2016-01-11 2018-11-23 无锡市法兰锻造有限公司 A kind of flange forge piece and its production technology of resistant to hydrogen steel material
CN106337153B (en) * 2016-11-16 2018-05-01 攀钢集团攀枝花钢铁研究院有限公司 The weathering steel of think gauge containing vanadium and its milling method
CN109852873B (en) * 2019-04-09 2020-10-09 攀钢集团攀枝花钢铁研究院有限公司 Steel with corrosion resistance for V-containing railway wagon combined brake beam and manufacturing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09125140A (en) * 1995-08-29 1997-05-13 Kawasaki Steel Corp Extra thick wide flange shape excellent in strength, toughness, weldability, and earthquake resistance and its production
JPH1088231A (en) * 1996-09-12 1998-04-07 Kawasaki Steel Corp Production of thick high tensile strength steel plate excellent in toughness and weldability
JPH11315341A (en) * 1998-03-05 1999-11-16 Kawasaki Steel Corp Extra thick wide flange shape excellent in toughness and having more than 325 mpa of yield strength
JP2001172736A (en) * 1999-12-13 2001-06-26 Kobe Steel Ltd Low yield ratio high tensile strength steel plate excellent in high heat input welding toughness
JP2003089841A (en) * 2001-09-14 2003-03-28 Nkk Corp Steel having excellent collision resistance, and production method therefor
CN1563468A (en) * 2004-04-14 2005-01-12 武汉钢铁(集团)公司 Manufacturing method of cold forming high intensity steel for welded structure

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09125140A (en) * 1995-08-29 1997-05-13 Kawasaki Steel Corp Extra thick wide flange shape excellent in strength, toughness, weldability, and earthquake resistance and its production
JPH1088231A (en) * 1996-09-12 1998-04-07 Kawasaki Steel Corp Production of thick high tensile strength steel plate excellent in toughness and weldability
JPH11315341A (en) * 1998-03-05 1999-11-16 Kawasaki Steel Corp Extra thick wide flange shape excellent in toughness and having more than 325 mpa of yield strength
JP2001172736A (en) * 1999-12-13 2001-06-26 Kobe Steel Ltd Low yield ratio high tensile strength steel plate excellent in high heat input welding toughness
JP2003089841A (en) * 2001-09-14 2003-03-28 Nkk Corp Steel having excellent collision resistance, and production method therefor
CN1563468A (en) * 2004-04-14 2005-01-12 武汉钢铁(集团)公司 Manufacturing method of cold forming high intensity steel for welded structure

Also Published As

Publication number Publication date
CN1793404A (en) 2006-06-28

Similar Documents

Publication Publication Date Title
CN100427630C (en) Production method of high-strength atmospheric corrosion resistant section steel
CN101928885B (en) Hydrothion corrosion resistant pipe steel and production method thereof
CN112301276B (en) Manufacturing method of high-strength and high-weather-resistance cold-rolled dual-phase weather-resistant steel
CN111455278A (en) Thick hot-rolled high-strength steel plate coil with excellent low-temperature toughness and for 800MPa cold forming and manufacturing method thereof
CN104694822A (en) High-strength hot rolled steel plate with 700 MPa grade yield strength and manufacturing method thereof
CN101660107A (en) Atmosphere corrosion resistance structural steel with ultralow temperature impact performance and manufacturing method thereof
CN110317936B (en) Cold-rolled weather-resistant steel for motor car carriage shell and preparation method thereof
CN103882297A (en) 390 MPa-grade low-temperature marine steel with excellent toughness and manufacturing method thereof
CN106591707A (en) Titanium-containing low-nickel high-strength weathering steel and production method thereof
CN103343295B (en) The high intensity high-corrosion resistance steel board of a kind of yield strength 700MPa and production method thereof
CN110284060B (en) High-strength and high-toughness corrosion-resistant steel for coal mine transportation truck body and manufacturing method thereof
CN103667906B (en) Tensile strength 590MPa level hot rolling High Tensile Thin Steel Plate and production method thereof
CN103194689A (en) High-strength ferrite stainless steel with excellent formability and corrosion-resistant performance and preparation method thereof
CN107893187A (en) Based on the method that low-alloy high-strength steel is produced completely without head bar strip continuous casting and rolling flow path
CN104862588A (en) Hot-rolled H-shaped profile steel and production method thereof
CN104264038A (en) 440 MPa-grade continuous-annealed and cold-rolled structural steel plate and production process thereof
CN101824581A (en) High-yield strength (450MPa), high-strength and weather-resistant steel plate and production method thereof
CN109321846B (en) Steel plate for large heat input welding with yield strength of 355MPa and preparation method thereof
CN113846269B (en) Cold-rolled high-weather-resistance steel plate with high strength and plasticity and preparation method thereof
CN103695771A (en) 610MPa-tensile-strength hot-rolled high-strength steel sheet and production method thereof
CN104831164A (en) H-shaped steel and production method thereof
CN110578085A (en) Hot-rolled steel plate with yield strength of 500MPa and atmospheric corrosion resistance
CN112251674A (en) Hot-rolled low-yield-ratio high-weather-resistant steel for railway passenger car and manufacturing method thereof
CN101376950A (en) Superhigh intensity cold rolling weather resisting steel plate and manufacturing method thereof
CN103469066B (en) A kind of utilize plate mill to produce high-mouldability energy steel plate method and obtained steel plate

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: PANGANG GROUP CO., LTD.

Free format text: FORMER NAME: PANZHIHUA STEEL (GROUP) CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: 617000 No. 1, Jianshe Road, Sichuan, Panzhihua

Patentee after: Pangang Group Co., Ltd.

Address before: 617000 No. 1, Jianshe Road, Sichuan, Panzhihua

Patentee before: Panzhihua Iron and Steel (Group) Co., Ltd.