CN100419137C - Antibiotic cellulose viscose and process for making same - Google Patents
Antibiotic cellulose viscose and process for making same Download PDFInfo
- Publication number
- CN100419137C CN100419137C CNB2003101109304A CN200310110930A CN100419137C CN 100419137 C CN100419137 C CN 100419137C CN B2003101109304 A CNB2003101109304 A CN B2003101109304A CN 200310110930 A CN200310110930 A CN 200310110930A CN 100419137 C CN100419137 C CN 100419137C
- Authority
- CN
- China
- Prior art keywords
- antiseptic
- mother liquor
- aromatic series
- quaternary ammonium
- ammonium salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000297 Rayon Polymers 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims description 18
- 230000008569 process Effects 0.000 title claims description 8
- 230000003115 biocidal effect Effects 0.000 title description 6
- 229920002678 cellulose Polymers 0.000 title description 4
- 239000001913 cellulose Substances 0.000 title description 4
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 31
- -1 aromatic halogen compound Chemical class 0.000 claims abstract description 30
- 239000000835 fiber Substances 0.000 claims abstract description 28
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 13
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 13
- 238000009987 spinning Methods 0.000 claims abstract description 9
- 239000012452 mother liquor Substances 0.000 claims description 18
- 239000003292 glue Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 238000005304 joining Methods 0.000 claims description 6
- LLDFSHBCVFHQIV-UHFFFAOYSA-M dimethyl-octadecyl-propylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCC LLDFSHBCVFHQIV-UHFFFAOYSA-M 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000012805 post-processing Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005303 weighing Methods 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a broad-spectrum antibacterial viscose fiber and production technology thereof, which aims to make the conventional viscose fiber have an endurable broad-spectrum antibacterial effect. In the production technology, a novel antiseptic comprising an aromatic halogen compound, organosilicon quaternary amine salt compound and/or organic oxidation compound is prepared into antiseptic mother liquid, and then is mixed with adhesives, and the antiseptic is uniformly distributed in the fiber at the time of spinning forming so that the viscose fiber produced by using the technology has the endurable broad-spectrum antibacterial effect.
Description
Technical field
The invention belongs to field of textiles, proposition be a kind of viscose and production technology thereof, particularly a kind of antibiotic dimension card fiber and production technology thereof with durable broad-spectrum.
Background technology
Viscose is with a kind of cellulose fibre of native cellulose fibre through the regeneration of series of chemical treatments after coagulation.Because it has performances such as good hygroscopicity, dyeing, gas permeability, applied to fields such as clothes, household goods, medical treatment widely, but along with the raising of people's living standard, the enhancing of health perception has proposed requirement to the anti-microbial property of the said goods.But because the whole process of production major part of viscose is to carry out under the condition of highly basic, strong acid, common antiseptic is difficult to apply in the production of viscose, causes being difficult to produce the dimension card fiber with durable broad-spectrum antibacterial action.
Summary of the invention
The present invention is intended to propose a kind of dimension card fiber with durable broad-spectrum antibacterial action, and the production technology of this fiber, satisfies the requirement of market to the viscose antibiotic property.
For this reason, the technical solution used in the present invention is as follows:
A kind of antibacterial viscose fiber is characterized in that: contain antiseptic in the viscose glue, this antiseptic is the combination of aromatic series halogen compound and organosilicon quaternary ammonium salt compound and organic oxidation compounds; The composition of described aromatic series halogen compound is 2,4,4---three chloro-2 '---hydroxyl---diphenyl ether; The composition of described organosilicon quaternary ammonium salt compound is 3--(dimethoxy silicyl) propyl-dimethyl octadecyl ammonium chloride; Described organic oxidation compounds is a polyoxygenated alkylene trialkyl ammonium salts.
Further, the object of the invention can realize by following scheme:
Described antiseptic contains aromatic series halogen compound, organosilicon quaternary ammonium salt compound, organic oxidation compounds, and its weight ratio is 1: 1: 1--1: 16: 20.
The ratio of first kind fiber content is 0.05%-20% in antiseptic and the viscose glue.
Further, the object of the invention also can realize by following scheme:
Described antiseptic is an aromatic series halogen compound, and its composition is 2,4,4, and---ratio of first fiber content is 0.01%-15% in three chloro-2 '---hydroxyl---diphenyl ether, itself and viscose glue.
A kind of method of producing above-mentioned antibacterial viscose fiber, it is characterized in that: technological process is:
A, allotment antiseptic mother liquor;
Add the antiseptic mother liquor in b, the viscose glue, and mix with it;
C, spinning and post processing.
Described antiseptic mother liquor is: the combination of aromatic series halogen compound and organosilicon quaternary ammonium salt compound and organic oxidation compounds; The composition of described aromatic series halogen compound is 2,4,4---three chloro-2 '---hydroxyl---diphenyl ether; The composition of described organosilicon quaternary ammonium salt compound is 3--(dimethoxy silicyl) propyl-dimethyl octadecyl ammonium chloride; Described organic oxidation compounds is a polyoxygenated alkylene trialkyl ammonium salts.
Further, this method can realize by following scheme:
Described antiseptic mother liquor be the above three kinds of compositions of aromatic series halogen compound, organosilicon quaternary ammonium salt compound, organic oxidation compounds by 1: 1: 1-1: 16: 20 weight ratio mixing preparation forms.
The antiseptic mother liquor is diluted to antiseptic with sig water or alcohols and other organic solvents the mother liquor of 1-100g/L before joining viscose glue.
Antiseptic mother liquor addition is the 0.05%-20% of first fiber content in the viscose glue.
Further, this method also can realize by following scheme:
Described antiseptic mother liquor is an aromatic series halogen compound, its composition is 2,4,4---three chloro-2 '---hydroxyl---diphenyl ether, before joining viscose glue, it is diluted with sig water or alcohols and other organic solvents, diluted concentration is: 1-100g/L, antiseptic mother liquor addition is the 0.01%-20% of first fiber content in the viscose glue.
The temperature of diluted alkaline of the present invention is lower than 60 ℃; The antiseptic mother liquor can mix with viscose glue in any one link adding in the viscose ripening process; The spinning of antibacterial viscose fiber, concise, oven dry is consistent with the production of conventional viscose.
The invention has the advantages that:
One, the antibiotic silk that uses this explained hereafter to go out is nontoxic, harmless, non-stimulated to human body;
Two, because the antibiotic mechanism of three kinds of antiseptics has nothing in common with each other, can suppress and kill various mushrooms;
Three, the dosing apparatus of antiseptic mother liquor and process are simple;
Four, use the antibiotic silk stable performance of this explained hereafter, have durable broad-spectrum antibacterial effect.
The specific embodiment
Embodiment 1
---three chloro-2 '---hydroxyl---diphenyl ether that take by weighing 2,4,4; (trimethoxysilyl) propyl-dimethyl octadecyl alkane ammonium chloride; Each 1Kg of polyoxygenated alkylene trialkyl ammonium salts, join and be made into 60g/L in rare NaOH liquid (or other organic solvents) of 50L normal temperature and stir about 20-30 minute, allow it fully dissolve, carry out spinning in the viscose glue by joining with respect to first fibre 10%, its spinning, concise, stoving process is consistent with conventional cellulose viscose manufacturing technique.
Embodiment 2
---three chloro-2 '---hydroxyl---diphenyl ether 1Kg that take by weighing 2,4,4, join and be made into 20g/L in rare NaOH liquid (or other organic solvents) of 50L normal temperature and stir about 20-30 minute, allow it fully dissolve, carry out spinning in the viscose glue by joining with respect to first fibre 0.5%, its spinning, concise, stoving process is consistent with conventional cellulose viscose manufacturing technique.
Embodiment 3
Take by weighing 2,4,4-three chloro-2 '---hydroxyl---diphenyl ether; (trimethoxysilyl) propyl-dimethyl octadecyl alkane ammonium chloride; Each 1Kg of polyoxygenated alkylene trialkyl ammonium salts, join and be made into 60g/L in rare NaOH liquid (or other organic solvents) of 50L normal temperature and stir about 20-30 minute, allow it fully dissolve, by joining in the viscose glue blending tank with respect to first fibre 10%, stir together then, mixing time is carried out routinely, carries out deaeration, conveying, filtration, spinning, concise, oven dry etc. at last again, and technology is consistent with conventional cellulose viscose manufacturing technique.
Claims (7)
1. antibacterial viscose fiber, it is characterized in that: contain antiseptic in the viscose glue, this antiseptic is the combination of aromatic series halogen compound and organosilicon quaternary ammonium salt compound and organic oxidation compounds;
The composition of described aromatic series halogen compound is 2,4,4---three chloro-2 '---hydroxyl---diphenyl ether;
The composition of described organosilicon quaternary ammonium salt compound is 3--(dimethoxy silicyl) propyl-dimethyl octadecyl ammonium chloride;
Described organic oxidation compounds is a polyoxygenated alkylene trialkyl ammonium salts.
2. a kind of antibacterial viscose fiber according to claim 1 is characterized in that: the weight ratio of described aromatic series halogen compound, organosilicon quaternary ammonium salt compound, organic oxidation compounds is 1: 1: 1--1: 16: 20.
3. a kind of antibacterial viscose fiber according to claim 2 is characterized in that: the ratio of first kind fiber content is 0.05%-20% in antiseptic and the viscose glue.
4. method of producing the described antibacterial viscose fiber of claim 1, it is characterized in that: technological process is:
A, allotment antiseptic mother liquor;
Add the antiseptic mother liquor in b, the viscose glue, and mix with it;
C, spinning and post processing;
Described antiseptic mother liquor is: the combination of aromatic series halogen compound and organosilicon quaternary ammonium salt compound and organic oxidation compounds; The composition of described aromatic series halogen compound is 2,4,4---three chloro-2 '---hydroxyl---diphenyl ether; The composition of described organosilicon quaternary ammonium salt compound is 3--(dimethoxy silicyl) propyl-dimethyl octadecyl ammonium chloride; Described organic oxidation compounds is a polyoxygenated alkylene trialkyl ammonium salts.
5. a kind of method of producing above-mentioned antibacterial viscose fiber according to claim 4 is characterized in that: described antiseptic mother liquor be the above three kinds of compositions of aromatic series halogen compound, organosilicon quaternary ammonium salt compound, organic oxidation compounds by 1: 1: 1--1: 16: 20 weight ratio mixing preparation forms.
6. a kind of method of producing above-mentioned antibacterial viscose fiber according to claim 4 is characterized in that: the antiseptic mother liquor is diluted to antiseptic with sig water the mother liquor of 1-100g/L before joining viscose glue.
7. a kind of method of producing above-mentioned antibacterial viscose fiber according to claim 5 is characterized in that: antiseptic mother liquor addition is the 0.05%-20% of first fiber content in the viscose glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101109304A CN100419137C (en) | 2003-11-14 | 2003-11-14 | Antibiotic cellulose viscose and process for making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101109304A CN100419137C (en) | 2003-11-14 | 2003-11-14 | Antibiotic cellulose viscose and process for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1544725A CN1544725A (en) | 2004-11-10 |
| CN100419137C true CN100419137C (en) | 2008-09-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101109304A Expired - Lifetime CN100419137C (en) | 2003-11-14 | 2003-11-14 | Antibiotic cellulose viscose and process for making same |
Country Status (1)
| Country | Link |
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| CN (1) | CN100419137C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935893A (en) * | 2010-08-27 | 2011-01-05 | 山东海龙股份有限公司 | Multifunctional aromatic antibiosis viscose fiber and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09119016A (en) * | 1995-10-26 | 1997-05-06 | Kohjin Co Ltd | Antimicrobial rayon fiber and its production |
| KR970059325A (en) * | 1997-05-13 | 1997-08-12 | 홍영근 | Water-soluble, antimicrobial rayon fiber and preparation method thereof |
| CN1325462A (en) * | 1998-10-29 | 2001-12-05 | 西巴特殊化学品控股有限公司 | Incorporation of organic anti-microbials into fibres during a fibre spinning |
| CN1470683A (en) * | 2003-03-13 | 2004-01-28 | 新乡化纤股份有限公司 | Mathod for manufacturing antibacterial artificial fiber |
-
2003
- 2003-11-14 CN CNB2003101109304A patent/CN100419137C/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09119016A (en) * | 1995-10-26 | 1997-05-06 | Kohjin Co Ltd | Antimicrobial rayon fiber and its production |
| KR970059325A (en) * | 1997-05-13 | 1997-08-12 | 홍영근 | Water-soluble, antimicrobial rayon fiber and preparation method thereof |
| CN1325462A (en) * | 1998-10-29 | 2001-12-05 | 西巴特殊化学品控股有限公司 | Incorporation of organic anti-microbials into fibres during a fibre spinning |
| CN1470683A (en) * | 2003-03-13 | 2004-01-28 | 新乡化纤股份有限公司 | Mathod for manufacturing antibacterial artificial fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1544725A (en) | 2004-11-10 |
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Granted publication date: 20080917 |
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