CN100410335C - Green porous solid pigment synthesis - Google Patents
Green porous solid pigment synthesis Download PDFInfo
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- CN100410335C CN100410335C CNB2005101306852A CN200510130685A CN100410335C CN 100410335 C CN100410335 C CN 100410335C CN B2005101306852 A CNB2005101306852 A CN B2005101306852A CN 200510130685 A CN200510130685 A CN 200510130685A CN 100410335 C CN100410335 C CN 100410335C
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- salt
- solid pigment
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- 239000007787 solid Substances 0.000 title claims abstract description 26
- 239000000049 pigment Substances 0.000 title claims abstract description 23
- 230000015572 biosynthetic process Effects 0.000 title claims description 3
- 238000003786 synthesis reaction Methods 0.000 title claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004411 aluminium Substances 0.000 claims abstract description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 17
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 9
- 150000002815 nickel Chemical class 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 7
- 239000010935 stainless steel Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 15
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 9
- 238000005829 trimerization reaction Methods 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 159000000013 aluminium salts Chemical class 0.000 claims description 8
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 241001249696 Senna alexandrina Species 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 6
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 5
- -1 nickel salt Chemical class 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 238000010189 synthetic method Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 230000002194 synthesizing effect Effects 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 24
- 239000010410 layer Substances 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000976 ink Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 4
- 229910000275 saponite Inorganic materials 0.000 description 4
- 238000001354 calcination Methods 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 239000001040 synthetic pigment Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 description 1
- AMDUMQZTBRMNMG-UHFFFAOYSA-N nickel nitric acid Chemical compound [Ni].O[N+]([O-])=O AMDUMQZTBRMNMG-UHFFFAOYSA-N 0.000 description 1
- HIRWGWMTAVZIPF-UHFFFAOYSA-N nickel;sulfuric acid Chemical compound [Ni].OS(O)(=O)=O HIRWGWMTAVZIPF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Images
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention belongs to a method for synthesizing green porous solid pigment. The green porous solid pigment comprises the selected raw material by the mole proportion: 1 portion of aluminum in aluminum salt, 3 to 15 portions of silicon in water glass and 3 to 12 portions of nickel in nickel salt which are strongly stirred to be mixed, and sodium hydroxide solution is used for regulating pH to 8.5 to 10.5. Then, the obtained mixture is transferred into a stainless steel reaction kettle to react for 20 to 120 hours at 280 to 300 DEG C to obtain green alizite. Aluminum sol or tridepolyhydroxy aluminium solution reacts with the alizite with the proportion that pillaring solution containing 3 to 8 millimoles of aluminium ion is added to each gram of the alizite to obtain a product which is heated for 2 to 5 hours at 150 to 300 DEG C so that the green porous solid pigment is obtained. The green porous solid pigment has the advantages of stable performance, acid resistance, alkali resistance and large specific surface area and can be used in the fields of ornaments, printing ink, paper filling material, etc.
Description
Technical field
The invention belongs to a kind of synthetic method of green porous solid pigment.
Background technology
Porous solid pigment is a kind of material that special purpose is arranged, and this class material not only can be made colorant and use also adsorbable organic dye, water, gas and metal ion etc.For example: when making the Alhue paper of photographic quality, coating one deck porous pigment on the printer paper surface forms the good seal China ink receiving layer of one deck, thereby improves the receptivity of seal China ink, to reduce the diffusion of seal China ink.This is to improving print parameters such as resolving power, print density, out of roundness, and it is very favourable to improve printing effect.Porous pigment also can be used as ornamental pigment, printing ink compound etc. in addition.At present the kind of porous solid pigment also seldom, more common carbon black, porous calcium carbonate and the porous latex particle of mainly containing.
Chrome green is broad-spectrum inorganic veridian, and its molecular formula is Cr
2O
3, it is calcined chromic anhydride and obtains between 1100～1300 ℃, and synthetic under the high like this calcining temperature, production cost is higher; In addition, chromium metal also has stronger toxic action to human body, so the use range of chrome green is subjected to certain limitation.The malachite mineral also are used as veridian and use, and its molecular formula is Cu
2(CO
3) (OH)
2, this mineral color is alkaline-resisting not acidproof, meets acid and dissolves very soon.People explore the veridian that synthesizes other kind constantly, for example: Chinese patent CN85100268A discloses the synthetic of a kind of veridian, it is can both make veridian with blue ultramarine pigment and the simple mixing of molybdenum tungsten yellow pigment or after mixing 550 ℃ of calcinings, this veridian is suitable for doing colored building coating to be used, but it does not have porous character.
Summary of the invention
The synthetic method that the purpose of this invention is to provide a kind of porous green solid pigment.
Saponite is a kind of layered clay mineral, and it forms by the inorganic layer sheetpile that is parallel to each other is long-pending, and the structure of each inorganic laminate is that two tetrahedrallayer clip an octahedral layer.Part tetravalence Siliciumatom in the saponite tetrahedrallayer is replaced by trivalent aluminium, causes the certain negative charge of tetrahedrallayer band, so the saponite interlayer can embed positively charged ion, obtains various layer embedding type host and guest compounds.The present invention comes pillared synthetic pimelite with aluminium colloidal sol or ten trimerization oxyaluminum solution, again through calcining, thereby obtains a kind of porous green solid pigment.
The raw material that the present invention selects is respectively that divalent nickel salt, trivalent aluminium salt, sodium hydroxide and water glass, nickel salt select nickelous nitrate, nickelous chloride or single nickel salt, aluminium salt to select aluminum nitrate, aluminum chloride or Tai-Ace S 150; Wherein, the weight content of silicon-dioxide is 20%～30% in the water glass, and modulus is 2.2～3.3, and pillared solution aluminium colloidal sol and ten trimerization oxyaluminum molecular formula are respectively Al
x(OH)
y(x:2～8, y:1～15), [AlO
4Al
12(OH)
24(H
2O)
12]
7+
The synthesis step of veridian is as follows:
At room temperature, earlier that divalent nickel salt and trivalent aluminium salt water is molten altogether, dropwise add water glass solution, vigorous stirring then; The mole proportioning of various raw materials is: the aluminium in the aluminium salt: the silicon in the water glass: the nickel in the nickel salt=1: 3～15: 3～12; React after 10～30 minutes, dropping sodium solution in solution, transfer between pH to 8.5～10.5, continue to stir, again the white casse liquid that obtains is transferred in the stainless steel cauldron and sealed, in 280～300 ℃ of down reactions 20～120 hours, wash then, filter, drying, obtain green pimelite; The pimelite that obtains joined contain aluminium colloidal sol or the formulated pillared solution of ten trimerization oxyaluminum, containing the aluminum ions pillared solution of 3～8 mmoles by every gram pimelite adding carries out pillared, wore out 0.5～2 hour down at 50～80 ℃, then with the mixture filtration, washing, the drying that obtain, heated 2～5 hours down at 150～300 ℃ again, obtain green solid pigment.
Synthetic veridian of the present invention, fast light solarization and washing, after illumination 100 hours and water washed 50 times, color did not have any variation.This is because in the veridian, the nickle atom that plays the color development effect is fixed in the octahedral layer of saponite with the Sauerstoffatom bonding, is difficult for stripping from solid.Simultaneously, this veridian acid resistance is very strong, and it is joined in the 6 mol hydrochloric acid solns, soaks 3 hours, filters then, washs, drying, and it is green that the solid that obtains remains.The pigment that the present invention makes also can be used as solid adsorbent, ornamental pigment, printing ink compound and siccative etc.
Description of drawings
Accompanying drawing 1 is the X-ray powder diffraction spectrogram of embodiment 3 synthetic pigment, and a represents the synthetic pimelite among the figure, and b represents the porosu solid veridian.As seen, first diffraction peak of pimelite is 7.2 ° from the X-ray powder diffraction spectrogram, and corresponding compound layer spacing is 12.2
, and first diffraction peak of layer column type veridian is 5.0 °, corresponding interlamellar spacing is 18.0
Obviously, compare with pimelite, the interlamellar spacing of layer column type veridian has increased 6.8
, this explanation through with pillared solution reaction after the pigment that obtains bigger interlamellar spacing is arranged, its adsorption space and specific surface area are all big than pimelite.The low temperature nitrogen adsorpting data shows that the specific surface area of synthetic veridian of the present invention is about 250m
2/ g, this illustrates that this pigment is a kind of compound that bigger serface is arranged.
Accompanying drawing 2 is thermogravimetric-differential thermal curve spectrograms of embodiment 3 synthetic pigment, and what a represented among the figure is the thermogravimetric curve of veridian, and what b represented is the differential scanning calorimetric curve of veridian.Analyze from thermogravimetric-differential thermal curve, when temperature is heated to 810 ℃, the inverted peaks that heat absorption and heat release occur, this is that layer oxide pillars of post veridian caved in and destructurized the causing of layer, can affirm that the layer column type vesicular structure of this pigment can be stabilized to about 800 ℃.
Embodiment
Embodiment 1:
At room temperature, the water glass solution that will contain 0.75 mole of silicon dropwise joins in the aqueous solution that is dissolved with 0.6 molar nitric acid nickel and 0.05 molar nitric acid aluminium, vigorous stirring in the dropping process, the mole proportioning of various raw materials is: the aluminium in the aluminum nitrate: the silicon in the water glass: the nickel in the nickelous nitrate=1: 15: 12, stir after 10 minutes, dropping sodium solution in solution, transfer pH to 8.5, continue to stir, again the white casse liquid that obtains is transferred in the stainless steel cauldron and sealed, reacted 20 hours down at 280 ℃, then washing, filter, drying obtains green pimelite; Get the above-mentioned synthetic pimelite of 50 grams and join the pillared solution that the ten trimerization oxyaluminum that contain 150 mmole aluminium are mixed with, reacted 0.5 hour down at 50 ℃, then mixture is filtered, washs and drying, will obtain solid again and heat 5 hours down, obtain the light green solid at 150 ℃.
Embodiment 2:
At room temperature, the water glass solution that will contain 0.35 mole of silicon dropwise joins in the aqueous solution that is dissolved with 0.3 mole of nickelous chloride and 0.05 mole of aluminum chloride, vigorous stirring in the dropping process, the mole proportioning of various raw materials is: the aluminium in the aluminum chloride: the silicon in the water glass: the nickel in the nickelous chloride=1: 7: 6, stir after 20 minutes, to drips of solution hydro-oxidation sodium solution, transfer pH to 9.0, continue to stir, again the white casse liquid that obtains is transferred in the stainless steel cauldron and sealed, 290 ℃ of down reactions 60 hours, wash then, filter, drying, obtain green pimelite; Get 50 gram pimelites and join the formulated pillared solution of ten trimerization oxyaluminum that contains 225 mmole aluminium, reacted 1 hour down, with mixture filtration, washing and dry, will obtain solid again and heat 3 hours down then, obtain green solid at 200 ℃ at 60 ℃.
Embodiment 3:
At room temperature, the water glass solution that will contain 0.216 mole of silicon dropwise joins in the aqueous solution that is dissolved with 0.2 mol sulfuric acid nickel and 0.025 mol sulfuric acid aluminium, vigorous stirring in the dropping process, the mole proportioning of various raw materials is: the aluminium in the Tai-Ace S 150: the silicon in the water glass: the nickel in the single nickel salt=1: 4.32: 4, stir after 30 minutes, to drips of solution hydro-oxidation sodium solution, transfer pH to 10.5, continue to stir, again the white casse liquid that obtains is transferred in the stainless steel cauldron and sealed, reacted 48 hours down at 285 ℃, then washing, filter and drying, obtain green pimelite; Get 50 gram pimelites and join the formulated pillared solution of ten trimerization oxyaluminum that contains 325 mmole aluminium, reacted 1.5 hours down, with mixture filtration, washing and dry, will obtain solid again and heat 4 hours down then, obtain green solid at 250 ℃ at 75 ℃.
Embodiment 4:
At room temperature, the water glass solution that will contain 0.15 mole of silicon dropwise joins in the aqueous solution that is dissolved with 0.15 mole of nickelous chloride and 0.05 mole of aluminum chloride, vigorous stirring in the dropping process, the mole proportioning of various raw materials is: the aluminium in the aluminum chloride: the silicon in the water glass: the nickel in the nickelous chloride=1: 3: 3, stir after 30 minutes, to drips of solution hydro-oxidation sodium solution, transfer pH to 10.5, continue to stir, again the white casse liquid that obtains is transferred in the stainless steel cauldron and sealed, reacted 120 hours down at 300 ℃, then washing, filter and drying, obtain green pimelite; Get 50 gram pimelites and join the formulated pillared solution of aluminium colloidal sol that contains 400 mmole aluminium, reacted 2 hours down, with mixture filtration, washing and dry, will obtain solid again and heat 2 hours down then, obtain green solid at 300 ℃ at 80 ℃.
Claims (1)
1. the synthetic method of a green porous solid pigment, the raw material of selection is respectively divalent nickel salt, trivalent aluminium salt, sodium hydroxide and water glass
Nickel salt is selected nickelous nitrate, nickelous chloride or single nickel salt
Aluminium salt is selected aluminum nitrate, aluminum chloride or Tai-Ace S 150, and wherein, the content of silicon-dioxide is 20%～30% in the water glass, and modulus is 2.2～3.3; Select aluminium colloidal sol or ten trimerization oxyaluminum to make pillared solution, aluminium colloidal sol molecular formula is Al
x(OH)
y, x:2～8, y:1～15, ten trimerization oxyaluminum molecular formula are [AlO
4Al
12(OH)
24(H
2O)
12]
7+
Synthesis step is as follows:
At room temperature, earlier that divalent nickel salt and trivalent aluminium salt water is molten altogether, dropwise add water glass solution then, vigorous stirring, the mole proportioning of various raw materials is: the aluminium in the aluminium salt: the silicon in the water glass: the nickel in the nickel salt=1: 3～15: 3～12, react after 10～30 minutes, dropping sodium solution in solution, transfer between pH to 8.5～10.5, continuation is stirred, and the white casse liquid that obtains is transferred in the stainless steel cauldron to seal again, reacts 20～120 hours down at 280～300 ℃, washing, filtration and dry obtain green pimelite; Green pimelite directly joined contain aluminium colloidal sol or the formulated pillared solution of ten trimerization oxyaluminum, every gram pimelite adds and contains the aluminum ions pillared solution of 3～8 mmoles, reacted 0.5～2 hour down at 50～80 ℃, then the mixture that obtains is filtered, washs and drying, heated 2～5 hours down at 150～300 ℃ again, obtain green solid pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101306852A CN100410335C (en) | 2005-12-21 | 2005-12-21 | Green porous solid pigment synthesis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101306852A CN100410335C (en) | 2005-12-21 | 2005-12-21 | Green porous solid pigment synthesis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1880386A CN1880386A (en) | 2006-12-20 |
| CN100410335C true CN100410335C (en) | 2008-08-13 |
Family
ID=37518751
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101306852A Expired - Fee Related CN100410335C (en) | 2005-12-21 | 2005-12-21 | Green porous solid pigment synthesis |
Country Status (1)
| Country | Link |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861741A (en) * | 2015-03-27 | 2015-08-26 | 浙江树人大学 | Brown porous inorganic solid pigment synthesis method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU539847A1 (en) * | 1974-09-16 | 1976-12-25 | Государсвтенный Научно-Исследовательский Институт Стекла | Silicate pigment |
| JPS54142238A (en) * | 1978-04-28 | 1979-11-06 | Toyo Soda Mfg Co Ltd | Preparation of ultramarine pigment |
| CN85108554A (en) * | 1985-11-25 | 1987-06-17 | 化工部天津化工研究院 | The manufacture method of jadeite-green pigment |
| CN1038827A (en) * | 1988-06-22 | 1990-01-17 | 北京有色金属研究总院 | Inorganic green series pigments |
| CN1044944A (en) * | 1990-03-21 | 1990-08-29 | 孙秀玲 | The manufacture method of inorganic green pigment |
| JPH1112490A (en) * | 1997-06-27 | 1999-01-19 | Nittetsu Mining Co Ltd | Green colorant and its production |
-
2005
- 2005-12-21 CN CNB2005101306852A patent/CN100410335C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU539847A1 (en) * | 1974-09-16 | 1976-12-25 | Государсвтенный Научно-Исследовательский Институт Стекла | Silicate pigment |
| JPS54142238A (en) * | 1978-04-28 | 1979-11-06 | Toyo Soda Mfg Co Ltd | Preparation of ultramarine pigment |
| CN85108554A (en) * | 1985-11-25 | 1987-06-17 | 化工部天津化工研究院 | The manufacture method of jadeite-green pigment |
| CN1038827A (en) * | 1988-06-22 | 1990-01-17 | 北京有色金属研究总院 | Inorganic green series pigments |
| CN1044944A (en) * | 1990-03-21 | 1990-08-29 | 孙秀玲 | The manufacture method of inorganic green pigment |
| JPH1112490A (en) * | 1997-06-27 | 1999-01-19 | Nittetsu Mining Co Ltd | Green colorant and its production |
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| Publication number | Publication date |
|---|---|
| CN1880386A (en) | 2006-12-20 |
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