CN100390354C - Swlfate wood-pulp enzyme-method modifying process - Google Patents
Swlfate wood-pulp enzyme-method modifying process Download PDFInfo
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- CN100390354C CN100390354C CNB2006100425632A CN200610042563A CN100390354C CN 100390354 C CN100390354 C CN 100390354C CN B2006100425632 A CNB2006100425632 A CN B2006100425632A CN 200610042563 A CN200610042563 A CN 200610042563A CN 100390354 C CN100390354 C CN 100390354C
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Abstract
The present invention relates to a method for modifying sulfate woodpulp by enzymes, which belongs to the technical field of pulping and paper-making technology. Sulfate woodpulp before pulping is treated by enzymes with the dosage of 20 to 1000g in each ton of woodpulp; woodpulp concentration is 3 to 15%; the temperature is 20 to 60 DEG C; the treatment time is 0.5 to 4 hours, and the pH is 5.0 to 8.5; in the present invention, cellulase is used to treat the sulfate pulp so that fiber swelling is improved, and therefore, the devillicate and fibrillation of fiber are improved; compared with the methods without an enzyme treatment process, the present invention has the advantages of reducing the energy consumption of pulping, enhancing the bonding force of fiber and improving the physical intensity of woodpulp.
Description
(1) technical field
The present invention relates to a kind of chemical wood pulp biologic treating technique, be specifically related to the method for sulfate wood pulp enzyme modification, belong to the pulp and paper technology field.
(2) background technology
Sulfate pulping is to produce the prevailing method of strong pulp, the high strength of sulfate pulp mainly is because kraft cooking, the preservation of fibre morphology structural integrity is got off, it is soft that fiber becomes, thereby kept single fiber intensity preferably, and give fiber bigger contact area, increased the adhesion between the fiber.But, complete fibre morphology structure has brought difficulty also for the making beating of postorder, and, sulphate cook also makes lignin be evenly distributed by thickness in the fiber finer cell wall, hindered the carrying out of making beating effect, add the high polymerization degree of primary wall carbohydrate in the sulfate pulp cell membrane, and the LCC of fiber surface, make that all the sulfate pulp making beating is very difficult.
Because sulfate pulp making beating difficulty, many researchers adopt biology enzyme to carrying out preliminary treatment before the sulfate pulp making beating, enzyme is handled the initial stage, the hemicellulose of fiber surface decomposes, and has improved the fiber surface suction and has moistened the degree that rises, and has also improved the permeability of fiber surface simultaneously, promote the enzyme molecular diffusion, be penetrated into fibrous inside, make that hemicellulose is degraded between microfibre, further promoted the fiber profit to rise, make microfibre key reaction force attenuation; Equally, also make S1 layer structural relaxation, slide between microfibre, help the removal of S1 layer and the fiber profit of S2 layer and rise and fibrillating.If suitable in addition control, make hemicellulase abolish associative key between LCC, open passage, allow cellulase act on the fiber surface generation and suitably peel off effect, P layer and S1 layer are abolished, made the S2 layer expose out just and do not suffer damage the accelerating fibers fibrillating, then can under the situation of not losing the pulp strength performance, promote making beating, thereby save beating energy consumption.
As far back as five, sixties enzyme modification paper pulp just is applied to reducing the research of beating energy consumption, the enzyme of Shi Yonging is a hemicellulase at that time.The people such as exerted in 1986 and reported the enzyme process making beating effect of zytase bleach chemical pulp.Referring to the people such as exerting, zytase is to the effect of chemical pulp fiber, wood chemistry, 6 (2): 167,1986 (No é, P.et al., Action of xylanaseson chemical pulp fibers.J Wood Chem.Technol., 6 (2): 167,1986) many in recent years researchers find when research enzyme modification needlebush Pulp Drainage Properties, add enzyme before the making beating, beating energy consumption obviously reduces.Action effect than more several commodity processing with enzyme preparation of people such as Ha Dewa softwood pulp shows, uses hemicellulase to handle softwood pulp, and beating time reduces, and pulp strength remains unchanged or decreases a little.Referring to than people such as Ha Dewa, use enzyme that fiber is carried out the beatability that modification improves paper pulp, biotechnology, 51 (1): 21-26,1996 (Bhardwaj, Nishi K.Baipai, Pratima; Bajpai, Pramod K., Use of enzymes in modification of fibres for improved beatability, Journalof Biotechnology, 51 (1): 21-26,1996).Usefulness complex cellulase NovozymeSP342 such as Mansfield optionally handle the thick long fibre fraction of pesudotsuga taxifolia slurry separately, improve the roughness of fiber surface, can improve into pulp yield, reduce the use amount of enzyme, and improve smoothness of paper, thereby improve the printability of paper, but pulp viscosity and tearability decrease.Referring to people such as Manny Mansfield morals, enzyme processing and fiber classification are in conjunction with improving the pesudotsuga taxifolia performance, US-built pulp and paper industry technology meeting magazine, Tappi J, 82 (5): 152,1999 (Mansfield Shawn D, Jason Swanson D, NormRoberts et al., Enhancing douglas-fin pulp properties with a combination of enzyme treatmentsand fiber fractionation.TAPPI Journal, 82 (5): 152-158,1999).
In recent years, cellulase and half cellulase are widely used for improving the drainability of secondary stock, and a large amount of discovers, cellulase degradation can make the freedom of paper pulp rise.About the influence of cellulose treatment, it is generally acknowledged that as long as the control proper reaction conditions, enzyme is handled can not cause the variation that physical strength is big, and too much enzyme dosage and long reaction time all can be caused the decline greatly of pulp strength to pulp strength.
From present research situation, after the different biology enzyme pulp treatment, though beating energy consumption decreases, but mostly pulp strength there is to a certain degree damage, in paper making process, need to add expensive chemicals and increase strength of paper, the use of these chemicalss is limited to the effect that improves strength of paper, and the complexity that causes the wet end system to become, simultaneously the reuse meeting of plain boiled water is produced adverse influence, therefore seek the enzyme preparation that pulp strength is improved and maybe can be improved the pulp strength not damaged to the making beating characteristic and improve significant the making beating and the fibre property of sulfate pulp.
(3) summary of the invention
The present invention is directed to the present situation of the paper mill pulp beating difficulty of present use sulfate wood pulp, a kind of method of novel sulfate wood pulp enzyme modification is provided, adopt enzyme to handle before the pulp beating, the profit that can improve fiber rise and pulping process in wire-dividing broom purification, thereby the physical strength of making beating back paper pulp is provided.
The method and technology scheme of sulfate wood pulp enzyme modification of the present invention is, the sulfate wood pulp before pulling an oar added enzyme handle, and enzyme dosage is a 20-1000g/ ton slurry, starches dense 3-15%, temperature 20-60 ℃, and time 0.5-4h, pH 5.0-8.5.
Described enzyme is one or both among the cellulase-producing Novozymes476 of Novozymes Company, Novozymes342, the Nozymes51064.
Described sulfate wood pulp is needlebush or leaf wood paper pulp, and paper pulp is brown stock or bleached pulp.
Preferably, above-mentioned cellulase adds in the size degradation process.
Paper pulp after enzyme of the present invention is handled can adopt mill or other beating equipments to pull an oar.
Sulfate wood pulp making beating difficulty mainly is a fiber wire-dividing broom purification difficulty in the prior art, in the pulping process when fiber be cut off more and wire-dividing broom purification more after a little while, interfibrous adhesion descends, the intensity decreases of paper pulp.Simultaneously, general enzyme is handled the decline that can cause pulp strength when improving the making beating characteristic.The method of sulfate wood pulp enzyme modification of the present invention adopts before the pulp beating enzyme to handle, the profit that can improve fiber rise and pulping process in wire-dividing broom purification, thereby improve the physical strength of making beating back paper pulp.
Compared with prior art, excellent results of the present invention is as follows:
Existing fiber enzyme process modification technology though can improve the making beating characteristic of sulfate pulp, often causes the decline of pulp physical strength.The present invention adopts the cellulose treatment sulfate pulp, the profit that can improve fiber rises, thereby increases the wire-dividing broom purification of fiber in pulping process, compares with the paper pulp of handling without enzyme, when reducing beating energy consumption, improve interfibrous adhesion, improve the physical strength of paper pulp.
(4) specific embodiment
Used enzyme is Novozymes Company cellulase-producing Novozymes476, Novozymes342 and Nozymes51064 among the following embodiment.
Embodiment 1:
Import Canada " golden lion " board needlebush sulfate bleached pulp, the dense size degradation down of the slurry of 3-5% in the hydrabrusher, add cellulase Novozymes476 in the size degradation process separately, the enzyme addition is 100g/ ton slurry, size degradation 10 minutes, at 40-55 ℃, the following 30-2.0h that handles of pH6.0-7.5 uses the disc mill defibrination dense time at the slurry of 3-4% then then.70-75 ° of SR of pulp beating degree compares with the paper pulp of not enzyme-added processing behind the defibrination, and after the enzyme-added processing making beating, under same beating degree, tensile strength improves 20%, and bursting strength improves 15%, and tearing strength is basic identical, and beating time reduces 15% simultaneously.
Embodiment 2:
Eucalyptus sulfate leaf wood bleached pulp, the dense size degradation down of the slurry of 3-5% in the hydrabrusher, the mixture that adds 1: 1 weight ratio of cellulase Novozymes476 and Nozymes51064 in the size degradation process, the enzyme addition is 150g/ ton slurry, size degradation 10 minutes, at 30-55 ℃, the following 0.5-2.0h that handles of pH5.0-7.5 uses the disc mill defibrination dense time at the slurry of 3.0-4.0% then then.50-55 ° of SR of pulp beating degree compares with the paper pulp of not enzyme-added processing behind the defibrination, and after the enzyme-added processing making beating, under same beating degree, tensile strength improves 15%, and bursting strength improves 10%, and tearing strength is basic identical, and beating time reduces 10% simultaneously.
Embodiment 3: as embodiment 1, different is that the enzyme pulp treatment is not for floating softwood kraft pulp
Embodiment 4: as embodiment 2, different is that the enzyme pulp treatment is not for floating broad-leaved wood sulphate pulp
Embodiment 5: as embodiment 2, different is that the enzyme treatment temperature is 20-30 ℃, and the enzyme addition is 200g/ ton slurry.
Embodiment 6: as embodiment 1, different is to add enzyme Novozymes476 and Novozymes51064 simultaneously, and enzyme dosage is respectively 200g/ ton slurry and 100g/ ton slurry.
Embodiment 7: as embodiment 2, different is that the enzyme that adds is Novozymes342 and Novozymes51064, and enzyme dosage is respectively 600g/ ton slurry and 200g/ ton slurry.
Claims (4)
1. the method for sulfate wood pulp enzyme modification is characterized in that the sulfate wood pulp before pulling an oar is added enzyme to be handled, and enzyme dosage is a 20-1000g/ ton slurry, starches dense 3-15%, temperature 20-60 ℃, and time 0.5-4h, pH 5.0-8.5; Described enzyme is two kinds among the cellulase-producing Novozymes476 of Novozymes Company, Novozymes342, the Nozymes51064.
2. the method for sulfate wood pulp enzyme modification as claimed in claim 1 is characterized in that described sulfate wood pulp is needlebush or leaf wood paper pulp.
3. the method for sulfate wood pulp enzyme modification as claimed in claim 1 is characterized in that described paper pulp is brown stock or bleached pulp.
4. the method for sulfate wood pulp enzyme modification as claimed in claim 1 is characterized in that described cellulase adds in the size degradation process.
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| CNB2006100425632A CN100390354C (en) | 2006-02-28 | 2006-02-28 | Swlfate wood-pulp enzyme-method modifying process |
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| CNB2006100425632A CN100390354C (en) | 2006-02-28 | 2006-02-28 | Swlfate wood-pulp enzyme-method modifying process |
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| CN100390354C true CN100390354C (en) | 2008-05-28 |
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Cited By (1)
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| CN102797193A (en) * | 2011-05-26 | 2012-11-28 | 金东纸业（江苏）股份有限公司 | Paper pulp processing method and coated paper manufacturing method |
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| CN101864688A (en) * | 2010-05-27 | 2010-10-20 | 岳阳纸业股份有限公司 | Pulping method of sulphate chemical pulp |
| CN103898790B (en) * | 2012-12-27 | 2016-08-24 | 东莞市绿微康生物科技有限公司 | Making beating enzyme preparation and its preparation method and application |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shandong Chenming Papermaking Industry Group Co., Ltd. Assignor: Shandong Institute of Light Industry Contract fulfillment period: 2008.11.2 to 2014.11.2 contract change Contract record no.: 2009990000071 Denomination of invention: Swlfate wood-pulp enzyme-method modifying process Granted publication date: 20080528 License type: Exclusive license Record date: 2009.2.9 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.11.2 TO 2014.11.2; CHANGE OF CONTRACT Name of requester: SHANDONG MINGFANG PAPER GROUP CO., LTD. Effective date: 20090209 |
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Assignee: Shandong Century Sunshine Paper Group Co., Ltd. Assignor: Shandong Institute of Light Industry Contract fulfillment period: 2009.11.6 to 2015.11.6 contract change Contract record no.: 2010370000025 Denomination of invention: Swlfate wood-pulp enzyme-method modifying process Granted publication date: 20080528 License type: Exclusive license Record date: 2010.1.12 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.11.6 TO 2015.11.6; CHANGE OF CONTRACT Name of requester: SHANDONG CENTURY SUNSHINE PAPER HOLDINGS GROUP CO. Effective date: 20100112 |
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Assignee: Shandong Century Sunshine Paper Group Co., Ltd. Assignor: Shandong Institute of Light Industry Contract record no.: 2010370000025 Date of cancellation: 20100730 |
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Assignee: Shandong Chenming Papermaking Industry Group Co., Ltd. Assignor: Shandong Institute of Light Industry Contract record no.: 2009990000071 Date of cancellation: 20120420 |
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