CN1003860B - Composition and usage of improvement agent for synthesis resin - Google Patents
Composition and usage of improvement agent for synthesis resin Download PDFInfo
- Publication number
- CN1003860B CN1003860B CN85109529.1A CN85109529A CN1003860B CN 1003860 B CN1003860 B CN 1003860B CN 85109529 A CN85109529 A CN 85109529A CN 1003860 B CN1003860 B CN 1003860B
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- CN
- China
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- constituent
- resin
- weight portions
- gelatin
- glue
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention relates to a resin modifier with main ingredients of glue or glutin and the combination of such ingredients for the application of improving various ties of matter. The modifier in the invention can give a modified smoothness and appearance of the product to the added resins, enhance the luster and the hydroscopic property, improve oil resistance, change the wear characteristics, improve the binding property to the produce, and the cold tolerance, etc. Therefore, according to the modification effects, a shoe supplies forming constituent with excellent sliding property, a covering adopted constituent with excellent cold tolerance, a belt constituent with anti-sliding property, a glove adopted constituent with natural leather characteristics, and a shockproof resin constituent with excellent shock absorption property are obtained.
Description
The present invention is relevant improvement agent for synthesis resin and the purposes constituent that utilizes its modification characteristic.
Improve the performance of synthetical resin products, yes wants the characteristic of improved resin, and be used for improving the various performances of product, give new features Study on Additive, development must with the resinae collaborative development,, the developmental research of additive often can't not carried out thereby fall behind owing to do not understand the performance of character that resin has and product.Also have, adopting additive to carry out modification also has individual limit, although cheap and have basic physical properties advantages such as regeneration is big as vinyl chloride resin etc., aspect other various characteristics, multi-purpose rerum natura is then very poor.For example,, just have easily and split, with the poor adhesion of leather and shortcoming such as easily sliding, in recent years at its resin combination of the various replacements of research as the constituent of sole.
In addition, also be limited as the purposes of fertile glue of the byproduct of leather industry or gelatin, also to depend on composite adhesives simultaneously, so output more reduced in positive day.
The objective of the invention is: though with the exploitation be original crude, but be not used as the additive of heterogeneous synthetic resin or modifier and be starting point as the glue of the limited above-mentioned leather industry byproduct production of purposes or the new purposes of gelatin, in the output that increases glue or gelatin, the character of all rerum naturas of the original modification of failing of resin combination of change various uses is to scheme to enlarge the purposes of resin.
Of the present invention with glue or gelatin be Main Ingredients and Appearance improvement agent for synthesis resin, can improve the appearance surfaces of naval stores, increase its gloss and water imbibition, improve oil resistivity, improve polishing machine, improvement is to the cohesive of natural goods, and improves various modified effects such as cold resistance.
Therefore, at vinyl chloride resin, polyurethane resin, synthetic rubber etc. are done and are added glue or gelatin in the resin combination that sole uses and evenly mix, and just can access the used formation constituent in the superior footwear aspect of sliding property.
Also have, glue or gelatin in adding as resin combination in usefulness such as covered electric cables, and evenly mix the constituent that just can obtain the superior coating usefulness of cold tolerance.
And then in the resin combination that belt is used, add glue or gelatin, through evenly mixing the belt constituent that just can obtain to have nonslip properties.
Add glue or bright in the synthetic resin constituent that these external gloves are used, through evenly mixing the constituent that the gloves that just can obtain to have similar natural leather characteristic are used.
Add glue or gelatin in the resin combination shockproof using in addition,, just can obtain the superior shockproof resin combination of using of shock absorbing characteristics through evenly mixing.
So-called in this specification " glue or gelatin " can use and be provided as the leather industry byproduct, dry plate or particle and contain the industrial gelatin of moisture content, sale is arranged on the open market, its use level can be come conversion according to the modification purpose that cooperates synthetic resin, will come into plain view the glue that the dry weight of resin combination interpolation 1 to 10 weight portion of general 100 weight portions arrives or bright comparatively suitable by following embodiment introduction.
Though the modified resin constituent generally is to make by the melting mixing → cooling → operations such as granulation of feedstock composition, and the whipping temp when preferably mixing will be between 70 ° to 120 ℃, so that fully mixing under the heated state, moisture in the constituent is evaporated, Yi Bian various uniform ingredients ground is mixed on one side.
Glue or gelatin can be independent in addition, also can be with other additive (plasticizer, filler, strong agent, incombustible agent, lubrication prescription, Hangzhoupro oxidant, foaming agent, crosslinking agent, antistatic agent, antidrip, antifoggant, lightning protection agent, antiseptic, metal harm prevent agent and other modifier) merge and use, but will selection and glue or gelatin the agent class of intermiscibility is arranged.
As the synthetic resin that will be added preferably select with modifier of the present invention have intermiscibility for well, the explanation by following embodiment can come into plain view.
Sole modification example
(1) adds industrial gelatin that contains 50% moisture or the solid film that dry measure is 1 weight portion, 2.5 weight portions, 5 weight portions, 7.5 weight portions and 10 weight portions respectively being used as in vinyl chloride resin (containing 100 parts of vinyl chloride resins, 80～100 parts of plasticizer and other an amount of blowing agents, stabilizing agent, the colorant) sheet of sole of 100 parts of weight portions, and make synthetic sole.
(2) add industrial gelatin that contains 50% moisture or the solid film that dry weight is 1 weight portion, 2.5 weight portions, 5 weight portions, 7.5 weight portions and 10 weight portions respectively being used as in the polyurethane resin sheet of sole of 100 weight portions, and make synthetic sole.(3) adding industrial gelatin that contains 50% moisture or the solid film that dry weight is 1 weight portion, 2.5 weight portions, 5 weight portions, 7.5 weight portions and 10 weight portions respectively and making synthetic sole at 100 weight portions as in the synthetic rubber resin sheet of sole.
The sliding test example
Adopt the slippage operational test machine of O-Ypull-slip-meter(Osaka City, Janpan in Guangzhou Honda machine worker system) under the test load condition of regulation, the vinyl chloride resin sheet of using at the bottom of the above-mentioned shoemaking with 100 weight portions (contains 100 parts of vinyl chloride resins by weight, 80～100 parts of plasticizer, and other an amount of foaming agent, stabilizing agent, colorant) and 10 weight portions moisture be earlier the test film that 50% industrial gelatin evenly is mixed and made into certain specification, the above-mentioned sole that will not contain gelatin is simultaneously made the comparative test sheet of same specification with the vinyl chloride resin sheet, comes the variation of its opposing friction of comparison by dilatory test.
The result as shown in Figure 1, the result shows that test film of the present invention demonstrates higher burnish resistance (being 57 kilograms to the maximum) and continuation, otherwise the friction of comparative test sheet originally repellence poor (about 30 kilograms), and the friction opposing also is provided with continuation, therefore, can show that sole of the present invention has superior slip characteristic with composition as the moulding constituent of footwear articles for use.
Cold-resistant bend test
Employing evenly mixes the sole that the composition formed is made by the sole of 100 weight portions with the industrial gelatin that contains 50% moisture content of vinyl chloride resin sheet and weight portion, makes common bend test under-30 ℃ of conditions.Do not see yet that through 10,000 bendings be full of cracks is arranged, show to have superior cold-resistant bendability.
Shock resistance improvement example
Shockproof synthetic resin sheet at 100 weight portions adds the industrial gelatin that contains 50% moisture or the solid film of 1 weight portion, 5 weight portions, 10 weight portions, 15 weight portions, 20 weight portions and 25 weight portions respectively and makes packing respectively.
Cold resistance improvement example
With the resin-coated constituent of the electric wire of 100 weight portions (vinyl chloride resin) is that 50% the industrial gelatin of containing of 1 weight portion, 2.5 weight portions, 5 weight portions, 7.5 weight portions and 100 weight portions evenly mixes with dry weight respectively, and covered electric cable, carry out low temperature resistant test.The result is as follows:
Test method JIS(Japanese Industrial Standards) K
Test film contains the industrial gelatin that 50% moisture content is arranged of 5 weight portions
The comparative test sheet does not contain the vinyl chloride resin of above-mentioned gelatin
Freezing test sheet comparative test sheet
（℃） F
0〉 -40 -15
F50 -42.5 -22.5
F100 -45 -30
Above-mentioned explanation shows, the present invention by the even mark of glue or gelatin the way that is mixed in the constituent matrix, just can bring into play following improved effect.
Fusible improvement
Add the resin of modifier of the present invention and original same synthetic resin material by comparison, the cohesive of itself and ox-hide is improved, and for example for the synthetic resin sole, need not make, and between the common operating period, it is bonding can not peel off yet.This phenomenon is firmly established.Therefore, ideal as the moulding constituent of footwear articles for use such as sole, low price particularly, the cohesive of renewable vinyl chloride resin is handled with the method for modification, has more practical value.
The improvement of sliding property
Because modification constituent of the present invention is compared with original synthetic rubber class constituent, its non-skid property is more superior, so except as, also be desirable as the belt constituent of paying attention to skid resistance at the end of footwear articles for use.
The improvement of outward appearance and tinctorial property
Add modifier of the present invention and can make the appearance surfaces of product more careful, give the sensation of people and prime quality than original identical materials.In addition, the face of pigment is remitted look also more satisfactory, and it is good color sensation.Therefore need not do surperficial post processing (paint decoration etc.), also have the color of gloss simultaneously.
The improvement of oil resistivity
Add modifier of the present invention, its goods are improved for the improvement of the original same material abrasiveness of the endurance ratio of industry oil.
Add modifier of the present invention, though be easier to wearing and tearing than original same material, this can give the sensation of people at the bottom of similar use natural leather.
Hygroscopic improvement
Add modifier of the present invention, though be easier to moisture absorption than original same material, this can give the quality sense of people at the bottom of similar natural leather.
The improvement of shock resistance
By to being added with modifier of the present invention and not having the same packing that adds and carry out shockproof test, the result is compared, show that its shock absorbing characteristics obviously increases, and is optimum as packing when adding glue or gelatin.
The improvement of cold resistance
Be added with the synthetic resin constituent of modifier of the present invention, under condition extremely cold below-30 ℃, also have the rerum natura of superior anti-cracking.Therefore, the synthetical resin products material that uses under utmost point cool condition as wire covering materials etc. is ideal.
Above-mentioned explanation clearly illustrates that, adopts method of the present invention, adopts original glue or the gelatin that does not use as improvement agent for synthesis resin, just can carry out the improvement of various rerum naturas to synthetic resin, so have epoch making significance.Also have, the present invention has more than and is limited to the part that embodiment introduces, and self-evident, those skilled in the art also can be applied to this method other synthetic resin.
The simple declaration of accompanying drawing.
Fig. 1 is that expression contains the synthetic resin test film of modifier of the present invention and do not contain the wear test chart as a result of the synthetic resin comparative test sheet of this modifier.
Claims (1)
1, the vinyl chloride resin modifier that replaces natural leather to use, it is characterized in that, with glue or gelatin as Main Ingredients and Appearance, the interpolation scope is in the vinyl chloride resin of the resin material that the replacement natural leather of 100 weight portions is used, add the glue or the gelatin (with dry weight basis) of 1 to 10 weight portion, make it have the intensity equal, and improved cohesive, slip characteristic and cold-resistant bendability between vinyl chloride resin and leather with natural leather.
Applications Claiming Priority (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP279623/84 | 1984-12-31 | ||
| JP59-279623 | 1984-12-31 | ||
| JP27962384A JPS61217101A (en) | 1984-12-31 | 1984-12-31 | Composition for shoe sole |
| JP653585A JPS61164502A (en) | 1985-01-16 | 1985-01-16 | Shoe sole composition |
| JP006536/85 | 1985-01-16 | ||
| JP653685A JPS61164503A (en) | 1985-01-16 | 1985-01-16 | Shoe sole composition |
| JP60-006536 | 1985-01-16 | ||
| JP60-006535 | 1985-01-16 | ||
| JP006535/85 | 1985-01-16 | ||
| JP1033685A JPS61168661A (en) | 1985-01-22 | 1985-01-22 | Synthtic resin composition for vibration insulation |
| JP010337/85 | 1985-01-22 | ||
| JP010336/85 | 1985-01-22 | ||
| JP1033785A JPS61168662A (en) | 1985-01-22 | 1985-01-22 | Modifier for synthetic resin |
| JP60-010336 | 1985-01-22 | ||
| JP60-010337 | 1985-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN85109529A CN85109529A (en) | 1986-09-10 |
| CN1003860B true CN1003860B (en) | 1989-04-12 |
Family
ID=27518723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN85109529.1A Expired CN1003860B (en) | 1984-12-31 | 1985-12-31 | Composition and usage of improvement agent for synthesis resin |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR900000909B1 (en) |
| CN (1) | CN1003860B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206778A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of impact resistance foam polyvinyl chloride plate |
| CN109206775A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of anti-oxidant foam polyvinyl chloride plate |
| CN109206777A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of flame-proof polyvinyl chloride foamed board |
| CN109206773A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of foam polyvinyl chloride plate with photostability |
| CN109206774A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of foam polyvinyl chloride plate |
| CN109206776A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of antistatic polyvinyl chloride foamed board |
-
1985
- 1985-12-28 KR KR1019850009907A patent/KR900000909B1/en not_active IP Right Cessation
- 1985-12-31 CN CN85109529.1A patent/CN1003860B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| KR860004967A (en) | 1986-07-16 |
| KR900000909B1 (en) | 1990-02-19 |
| CN85109529A (en) | 1986-09-10 |
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