CN100384975C - Detergent granules and process for their manufacture - Google Patents
Detergent granules and process for their manufacture Download PDFInfo
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- CN100384975C CN100384975C CNB2004800375524A CN200480037552A CN100384975C CN 100384975 C CN100384975 C CN 100384975C CN B2004800375524 A CNB2004800375524 A CN B2004800375524A CN 200480037552 A CN200480037552 A CN 200480037552A CN 100384975 C CN100384975 C CN 100384975C
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Abstract
A granulate detergent product comprising coated granules which comprise a functional core which comprises one or more detersive agents selected from surfactants and detergency builders, the coated granules further comprising up to 10% by weight of a coating which comprises encapsulated perfume.
Description
Technical field
The present invention relates to comprise the granular detergent composition of packed spices.
Background of invention
It is known that spices is introduced granular detergent composition with so-called " microcapsule " form.A form known of microcapsule is made up of the trimeric cyanamide-urea-formaldehyde microcapsule with spices nuclear.Present high bulk density detergent granules is usually by the multiviscosisty preparation of mechanically mixing and tensio-active agent and other component (generally including washing auxiliary detergent) and get, thus the formation finished product or prepare one or more other compositions may be to the pre-granulating concentrated additive of feed (post-dosed) thereafter.Yet, found that by this way perfume microcapsule is introduced the material of reuniting causes multiple shortcoming, for example Zhuo Lie dispersibility, have mechanical loss subsequently, unwanted resistates and product invalid (from the viewpoint of perfume delivery).
The dried adding of microcapsule often causes capsular loose reunion, and this is difficult to be distributed in the whole composition under the situation of not using remarkable shearing force, causes significant subsequently perfume loss.
Another alternative route that microcapsule is added drop-wise on the rest part of the composition on the transport unit also often causes unwanted gathering to form.
The solution of this problem at present is the spices introducing slurry by will be packed, and slurry is sparged on Powdered (preferably granulated in advance) composition, and said composition comprises one or more conventional ingredients of detergent composition.This has caused so-called " stratified " detergent granules, and this particle comprises the function nuclear and the skin that comprises packed spices of conventional detergent ingredients.
The what is called of detergent granules " layering " is well-known in the art, normally in the terminal stage of the non-spraying drying machinery pelletization of washing composition, add under the situation of " layering agent " (being generally aluminosilicate), for example " Surfactants in Consumer Products ", Springer Verlag, 1987, described in the 411-413 page or leaf.This is normally for particle size distribution in the flowing property of improving product and/or the control aggregation procedure.
The invention definition
First aspect present invention provides granular detergent products, it comprises the particle through applying that has comprised function nuclear, this function nuclear comprises that one or more are selected from the decontamination reagent of tensio-active agent and washing auxiliary detergent, this particle through applying further comprises the coating of 10wt% at the most, and this coating comprises packed spices.
Second aspect present invention provides granular detergent products, wherein at least 10% of the particle total amount is the particle through applying that comprises function nuclear, this function nuclear comprises that one or more are selected from the decontamination reagent of tensio-active agent and washing auxiliary detergent, and this coating comprises packed spices.
Third aspect present invention provides the method for preparing granular detergent products, and this method comprises:
(i) provide Powdered and/or the particulate state cleansing composition, composition comprises that one or more are selected from the decontamination reagent of tensio-active agent and/or washing auxiliary detergent;
(ii) preparation comprises the slurry of water and packed spices;
(iii) spray this cleansing composition to form particle through applying with described slurry.
Present method products obtained therefrom can, for example, meet the requirement of the present invention first and/or second aspect.
Obscure for avoiding any, should understand the term granular detergent products and contain the Betengent product that is used to clean and/or does washing conditioning.Therefore, the term decontamination reagent that adopts in all aspects of the invention is also contained softener material.Therefore, for all aspects of the invention, decontamination reagent can be selected from tensio-active agent, softener material and/or washing auxiliary detergent.
Detailed Description Of The Invention
For avoiding any doubt, the term " particle " that is used for the object of the invention refers to comprise the particle of a lot of compositions, for example have the complicated microlitic structure of the porous that can be formed by the coacervate of spraying drying or single particulate (crystal or unsetting), it can form by spraying drying or machinery granulate (being generally mixing/multiviscosisty).
In the method for the invention, the consumption of slurry makes coating on the particle constitute at the most 10% of these particle weights.Yet, preferably, the particulate through applying constitute coating weight at the most 5%, more preferably at the most 3%, 2.5% or 2%, be more preferably at the most 1% or even at the most 0.75% or 0.5%.
Under the situation of second aspect present invention, at least 10% of this particle constituent particle quantity, but preferably at least 15%, 20%, 25%, 30%, 35%, 40%, 45% or 50%, for example at least 80% or 90% through applying.
Also preferably some spices that do not encapsulate are introduced in slurries, preferred amounts is 0.0001%-50%, 25%-50% more preferably, based on the slurry weight meter, or preferably not the weight ratio of encapsulated fragrance and flavor capsule be 1: 10-1: 1, more preferably 1: 2-1: 1.
Introducing the alternate manner of encapsulated fragrance not is that the particle through applying is sprayed on these finished product particles with the spices blend or with it, before applying slurry or the while.
It is further preferred that, with the viscosity modifier of lubricant form for example glycerine be included in the slurry to help pumping and atomizing.
Preferably, the d of detergent granules through applying
3,2Median size is 100 μ m-2000 μ m, preferred 180 μ m-1400 μ m, more preferably 500 μ m-710 μ m.
Packed spices
The a lot of different packed spices that is applicable to detergent composition is commercially available.This capsular preferred kind is with trimeric cyanamide-urea-formaldehyde microencapsulation form, can obtain from 3MCorporation or BASF.
Preferably with the 5%-80% of slurry weight, more preferably 40%-80% is scattered in the slurry (it comprises water) packed spices.
Granulation device
Method according to second aspect present invention can be optionally to carry out at intermittence or continuous operation mode.
Method of the present invention is preferably carried out in the machinery granulate machine, most preferably low or middling speed moderate shear machine.Low or middling speed shear mixer/nodulizer has the stirring action and/or the cutting action of operation independently of one another usually.Preferred low or middling speed shear mixer nodulizer type is Fukae
RFS-G series; From Dierks ﹠amp; Sohne, the Diosna of Germany
RV series; From T.K.Fielder Ltd, the Pharma Matrix of England
RMixing tank.Other mixing tank that is applicable to the inventive method is from Fuji Sangyo Co., the Fuji of Japan
RVG-C series; From Zanchetta ﹠amp; Co.srl, the Roto of Italy
RAnd Schugi
RThe Flexomix nodulizer.
Another feasible low shear granulation machine is one of gas fluidized type, and it comprises fluidization regions, and wherein liquid adhesive is sprayed among the solid neutralizing agent or on it.Yet, can use the low bucket type mixing tank/nodulizer of shearing.When this low shear granulation machine was gas fluidized type, preferred sometimes the use had the device type of vibrating bed.If this spices load at slurry is low and be preferred when needing exsiccant.Thereby the mild heat of preferred fluidization air avoids precocious spices to discharge.
If the low shear granulation machine is gas fluidisation kind, then liquid adhesive can be on the fluidizing material and/or under and/or among spraying.
If gas fluidized nodulizer is as the low shear granulation machine, then operation is preferably at about 0.1-2.0ms
-1Surperficial air velocity under, under relatively malleation or negative pressure, and inlet air temp is-10 ℃ or 5 ℃ to 80 ℃, or at the most 200 ℃ in some cases.Service temperature typically is envrionment temperature to 60 ℃ in the bed.Depend on this method, can advantageously change this temperature (during at least a portion of this method, changing up and/or down).
Composition characteristic
Particle particle core prepared according to the methods of the invention comprises at least a tensio-active agent, softener material and/or washing auxiliary detergent.Any this composition also can be incorporated in the coating extraly by slurry.
In addition, any particle according to the present invention can be incorporated in the detergent composition, for example comprises the microgranular detergent composition of one or more back feed materials.Randomly, any particle of any aspect or microgranular detergent composition can be collapsed into tablet by known technology according to the present invention, as for example also comprising the tablet of disintegrating agent.This tablet has constituted the further aspect of the present invention.Suitable tablet form/processing for example is disclosed in: EP 1,371,729, and EP 1,405,900, and EP 1,382,368, and EP 1,375,636, and EP 1,405,901, and EP 1,405,902, and EP 1,418,224 and WO 03/104380 in.
Obscure for avoiding any, should understand term microparticles shape detergent composition and contain the microgranular detergent composition that is used to clean and/or does washing conditioning.Therefore, microgranular detergent composition can comprise tensio-active agent, auxiliary agent, softener material, other composition as described below.
Tensio-active agent
Suitable tensio-active agent is selected from one or more negatively charged ion, nonionic, positively charged ion, zwitter-ion and amphoterics.In general, suitable tensio-active agent comprises that " Surface active agents and detergents " that Schwartz and Perry show rolls up general those that describe among the I.Optionally, by having for example C
10-C
18Saturated or the unsaturated fatty acids deutero-soap of carbon atom also can exist.
Anion surfactant can actually comprise the anionic surfactant compound that one or more are different.The preferred anionic surfactants tensio-active agent is an alkylbenzene sulfonate, and especially so-called have a C
10-C
15The linear alkylbenzene sulfonate of alkyl chain.The content of preferred linear alkylbenzene sulfonate is 0wt%-30wt%, more preferably 1wt%-25wt%, most preferably 2wt%-15wt%.
Particle of the present invention can be extraly or is alternatively comprised other anion surfactant of measuring outside the above-mentioned per-cent.Suitable anion surfactant is known to those skilled in the art.Example comprises primary and secondary alkyl-sulphate, especially C
8-C
15Primary alkyl sulphates; Sulfated alkyl ether; Alkene sulfonate; Alkylxylene sulfonate; Dialkyl sulfosuccinates; And fatty sulfonate.Common particular certain cancers.
Particle of the present invention also can comprise nonionogenic tenside.Spendable ionic surfactant pack is drawn together the primary and secondary alcohol ethoxylate, especially comes the C of ethoxylation with average 1-20 moles of ethylene oxide/1 mol of alcohol
8-C
20Fatty Alcohol(C12-C14 and C12-C18), and especially come the C of ethoxylation with average 1-10 moles of ethylene oxide/1 mol of alcohol
10-C
15The primary and secondary Fatty Alcohol(C12-C14 and C12-C18).The ionic surfactant pack of non-ethoxylatedization is drawn together alkyl polyglycoside, glycerol monoethers and polyhydroxy amides (glucamide).
The amount of preferred nonionic surfactants is 0wt%-30wt%, preferred 1wt%-25wt%, most preferably 2wt%-15wt%.
Washing auxiliary detergent
What washing auxiliary detergent was common can the introducing amount be 10wt%-70wt% (butt), preferred 25wt%-50wt%.Preferred washing auxiliary detergent is basic metal (preferred sodium) aluminosilicate auxiliary agent.
Alkali metal aluminosilicate can be crystal or amorphous or its mixture, has general formula: 0.8-1.5Na
2O.Al
2O
3.0.8-6SiO
2
These materials comprise some combination water and need have the calcium ion exchange capacity of 50mg CaO/g at least.Preferred sodium aluminium silicate comprises 1.5-3.5SiO
2Unit (with above general formula).Amorphous and crystalline material all can make easily by the reaction between water glass and the sodium aluminate, has a detailed description in the document.Suitable crystal sodium aluminium silicate ion-exchange washing auxiliary detergent is described in for example GB1429143 (Procter﹠amp; Gamble) among.Preferred such sodium aluminium silicate is well-known commercially available zeolite A and X, and composition thereof.
Zeolite can be the commercially available zeolite 4A that extensively adopts in the detergent for washing clothes powder at present.Yet according to the preferred embodiments of the invention, the zeolite builder that is incorporated into the present composition is described in EP384070A (Unilever) and the aluminium maximum zeolite P (zeolite MAP) that asks for protection.Zeolite MAP is defined as that silica alumina ratio is no more than 1.33, preferred 0.90-1.33 and the alkali metal aluminosilicate of the zeolite P type of 0.90-1.20 most preferably.
Especially preferred zeolite MAP has and is no more than 1.07, more preferably from about 1.00 silica alumina ratio.The calcium-binding capacity of zeolite MAP is generally 150mg CaO/1g anhydrous material at least.
The organic additive that can exist comprises polycarboxylate polymer such as polyacrylate, vinylformic acid/maleic acid and vinylformic acid phosphinates; The monomer multi-carboxylate is Citrate trianion, gluconate, oxygen base disuccinate, glycerine list, two and three succinates, carboxymethyl oxygen base succinate, carboxymethyl oxygen propylmalonic acid salt, two pyridine carboxylic acid salt (dipicolinate), hydroxyethyliminodia,etates, alkyl and thiazolinyl malonate and succinate for example; With Sulfonated soap.This is enumerated and is non exhaustive.
Especially preferred organic additive is a Citrate trianion, and suitable amounts is 5wt%-30wt%, preferred 10wt%-25wt%; And acrylate copolymer, vinylformic acid/maleic acid especially, suitable amounts is 0.5wt%-15wt%, preferred 1wt%-10wt%.
Inorganic and organic additive all preferably exists with an alkali metal salt especially sodium-salt form.
Softener material
This decontamination reagent also can comprise softener material.Be convenient, term softener material used herein is to show in the clean cycle of family expenses or automatic washing machine or the fabric in the artificial cleaning process provides material softening and/or the conditioning advantage.
When microgranular detergent composition according to the present invention comprises softener material, composition preferably includes the softener material (activeconstituents) of 10wt%-95wt%, based on composition total weight meter, more preferably 15wt%-75wt%, most preferably 20wt%-50wt%, for example 22wt%-45wt%.
Softener material preferably includes at least a positively charged ion softener material such as quaternary ammonium fabric softener material.Preferably, this quaternary ammonium fabric softener material has the C12-28 alkyl or alkenyl group that is connected in nitrogen headgroup group (head group), preferably connects by at least one ester bond.More preferably this quaternary material has two ester bonds.
Preferably, the mean chain length of alkyl or alkenyl group is at least C14, more preferably C16 at least.Most preferably half of these chains has the length of C18.
Usually preferred alkyl or alkenylene chain are mainly straight chain.
Especially preferred material is methylsulfuric acid triethanol ammonium and N-N-two (butter acyloxy ethyl) N, the dialkylene ester of N-alkyl dimethyl ammonium chloride.Commercially available example comprises Tetranyl AHT-1 (two winterized stearin acid esters of methylsulfuric acid triethanol ammonium, 80% activity), the AT-1 (dioleate of methylsulfuric acid triethanol ammonium, 90% activity), L5/90 (Methylsulfate triethanol ammonium palm ester, 90% activity), all are all from Kao
TMOther unsaturated quaternary material comprises Rewoquat
TMWE15 (reaction product of C10-C20 and C16-C18 unsaturated fatty acids and quaternised dimethyl sulfate trolamine, 90% activity) is from Witco
TMCorporation.
Other suitable preferred material comprises 1,2 pairs of [butter acyloxy]-3-trimethyl ammonium chloride propane and 1, two [oily the acyloxy]-3-trimethyl ammonium chloride propane of 2-, its preparation method is described in for example US4137180 (Lever Brothers), and its content is incorporated herein.Preferably, these materials also can comprise a small amount of corresponding monoesters, described in US4137180.
When detergent composition was used as the solid rinse amendment, said composition can be described in WO03/083027.Other suitable solid rinse amendment example is recorded among EP-A-0234 082, EP-A-0 111 074, EP-A-0 111 074, WO 92/18593, EP-B1-0568297, US-A-5 259 964, EP-A-0 107 479 (Unilever), EP-A-0 267 999 (Unilever), JP-A-06 306 769, JP-A-62 057 639 (Lion), JP-A-02 182 972, US-A-4 814 095, the GB-A-2 348 435.
Another kind of softener material is a fabric softening clay.Particularly being that those and organic fatty emollient material are collaborative provides improved laundry softening.This class clay comprises the clay that contains montmorillonite, and it has expansion character (in water) and it is smectite structure.Be best suited for smectic clays of the present invention and be wilkinite and best wilkinite and be those that in water, have abundant swelling capacity, for example sodium bentonite and potassium wilkinite.This class swelling property wilkinite also is known as western or Wyoming wilkinite, and it is sodium bentonite substantially.Other wilkinite, as calcium bentonite, be generally non-expansibility and himself generally be not suitable as fabric softener.
Yet, found that this class non-expansibility wilkinite shows even than the better fabric-softening of swelling property wilkinite when combining with the organic fatty softener material, as long as in softener composition, there is basic metal or other solubilising ion such as sodium (it can be from the sodium hydroxide that joins composition, or from sodium salt such as the auxiliary agent and the filler that can be the composition function ingredients) source.These preferred wilkinites are calcium and the magnesium wilkinites that are generally expansile sodium and potassium wilkinite and are generally non-expansibility.Among these, preferably utilize calcium (having the sodium source) and sodium bentonite.Used wilkinite can be produced in USA, Wyoming wilkinite for example, but also can comprise Italy and Spain available from Europe, and calcium bentonite for example, it can change sodium bentonite into by handling with yellow soda ash, or can use with calcium bentonite.And, performance classes be similar to described those bentonitic other contain the smectite clay clay can all or part of replacement wilkinite described herein and will obtain similar fabric-softening result.
The final size of the clay of inflatable wilkinite and similar action is at micrometer range, for example 0.01-20 micron, and actual grain size between the 100-400 sieve mesh, preferred 140-325 sieve mesh, U.S. sieve series.Wilkinite and other this type of suitable swellable clay also can be reunited and be bigger granularity, 60-120 sieve mesh for example, but this reunion is not preferred, unless they also comprise organic fatty emollient material (in any microgranular product).
For the wilkinite treated according to the present invention is provided, the initial wilkinite parent material of selection has low relatively gelling and expansion character.Particularly, select this parent material wilkinite to have following initial performance: (a) at least 85% smectite content; (b) when wilkinite by sodium ion activation, dry and when grinding to form particulate, abrasive particles can't expand above about 2.5 times during at room temperature adding 24 hours of deionized water.The wilkinite abrasive particles of measuring the expansion purpose for this paper is that at least 90% diameter is equal to or less than about 75 microns particulate.
Processing is disclosed in the Minchem with ColinStewart according to the detailed description of bentonitic method of the present invention, the WO 00/03959 that the Ltd. name is submitted to, and this paper is incorporated herein by reference its disclosure.
The main ingredient that can be used in combination with fabric softening clay is the organic fatty tenderizer.Organic tenderizer can be negatively charged ion, positively charged ion or nonionic aliphatic chain (C
10-C
22, preferred C
12-C
18).The negatively charged ion tenderizer comprises fatty acid soaps.Preferred organic tenderizer is fatty ester, Fatty Alcohol(C12-C14 and C12-C18) and the polyhydric alcohol polymer of non-ionic for example fatty ester, ethoxylation.Organic tenderizer is the high-grade aliphatic ester of tetramethylolmethane compound most preferably, and this term is used to describe the high-grade aliphatic ester of the rudimentary alkylene oxide derivatives of the high-grade aliphatic ester of rudimentary alkylene oxide derivatives of high-grade aliphatic ester, tetramethylolmethane of high-grade aliphatic ester, the tetramethylolmethane oligomer of tetramethylolmethane and tetramethylolmethane oligomer in this manual.
The tetramethylolmethane compound, this paper is abbreviated as PEC, and its explanation and abbreviation can be applicable to the arbitrary or whole of tetramethylolmethane, its oligomer and its alkoxy derivative, and be same, or more preferably and be more generally as ester, in context, pointing out.
The oligomer of tetramethylolmethane is preferably 2-5 tetramethylolmethane part, and more preferably 2 or 3, this part connects together by ehter bond.Its rudimentary alkylene oxide derivatives is preferably oxyethane or propylene oxide monomer, dimer or polymkeric substance, and it is with hydroxy-end capped and be attached on tetramethylolmethane or the tetramethylolmethane oligomer by the ether link button.Preferably, in each this alkylene oxide chain, 1-10 alkylene oxide part arranged, more preferably 2-6, and 1-10 this group arranged on PEC, depend on this oligomer.The OH group of PEC one of at least and preferably at least 2, as 1 or 2-4, by higher fatty acid or other higher aliphatic acid (its carbon atom number can be odd number) esterification.
The high-grade aliphatic ester of tetramethylolmethane compound is preferably the part ester.And after the more preferably esterification (on tetramethylolmethane, oligomer or alkoxy alkane group), have two free hydroxyl on it at least.The number of this free hydroxyl often is 2 or about 2, but sometimes can be 1, as in the tetramethylolmethane tristearate.Can be used as the higher aliphatic of esterification acid or lipid acid and be carbon content and be 8-24, preferred 12-22 and more preferably those of 12-18, for example lauric acid, tetradecanoic acid, palmitinic acid, oleic acid, stearic acid He docosoic.This can be the mixture of this type of lipid acid, available from natural origin, and for example butter or cocounut oil, or this class natural gas material of controlling oneself and being hydrogenated.The synthetic acid of odd number or even carbon atom also can be used.Often preferred lauric acid and stearic acid in these lipid acid, and this preferably can be depending on esterified tetramethylolmethane compound.
The example of suitable detergent composition argillaceous comprises those that describe among US-A 6 291 421 and the US-A-6670 320.
Other optional member
Particle according to any aspect of the present invention also can comprise one or more other compositions, for example SYNTHETIC OPTICAL WHITNER and/or bleaching system, enzyme, dyestuff, anti-dye migration agent, dye-fixing agent, fluorescent agent, defoamer etc.These can mix in the nuclear, but randomly, can additionally or alternatively be incorporated in the nuclear by the slurry of waiting to mix in the nuclear.
Therefore, also can comprise bleaching system suitably according to particle of the present invention.Fabric cleaning composition can comprise peroxy bleaching compound ideally, for example inorganic persalt or organic peroxide acid, and it can produce hydrogen peroxide in the aqueous solution.
Suitable peroxy bleaching compound comprises organo-peroxide for example urea peroxide and inorganic persalt such as peroxyboric acid, percarbonic acid, peroxophosphoric acid, mistake silicic acid and persulfuric acid an alkali metal salt.Preferred inorganic persalt is sodium perborate monohydrate and four hydrated sodium perborates, with SPC-D.
Especially preferred is to have the SPC-D that anti-moisture takes off the protective cover of stabilization.SPC-D with the protective cover that comprises sodium metaborate and water glass is disclosed in GB2123044B (Kao).
The suitable amount of peroxy bleaching compound is 0.1-35wt%, preferred 0.5-25wt%.Peroxy bleaching compound can be used in combination with bleach activator (bleaching precursor) to improve the bleaching action at low cleaning temperature.The suitable amount of this bleaching precursor is 0.1-8wt%, preferred 0.5-5wt%.
Preferred bleaching precursor is a peroxycarboxylic acid precursors, especially peracetic acid precursors and n-nonanoic acid precursor excessively.Be applicable to that especially preferred bleaching precursor of the present invention is N, N, N ', N ' ,-tetra acetyl ethylene diamine (TAED) and acyloxy benzene sulfonic acid sodium salt in the ninth of the ten Heavenly Stems (SNOBS).Disclosed new quaternary ammonium and phosphorus bleaching precursor among US 4751015 and US 4818426 (Lever Brothers Company) and the EP 402971A (Unilever), and disclosed cationic bleach precursor also is suitable among EP 284292A and the EP 303520A (Kao).
This bleaching system can be replenished or replacement by peroxy acid.The example of this class peracid can be seen in US4686063 and US 5 397 501 (Unilever).Preferred example is the imino-peroxycarboxylic acid class of peracid, is described in EP A 325 288, and EP A 349 940 is among DE 382 3172 and the EP 325289.Especially preferred example is an O-phthalic amido peroxide caproic acid (PAP).The suitable amount of this type of peracid is 0.1-12%, preferred 0.5-10%.
Also can there be bleaching stibilizer (transition metal chelator).Suitable bleaching stibilizer comprises edetate (EDTA), polyphosphonic acid salt such as Dequest (trade mark) and nonphosphate stablizer such as EDDS (ethylenediamine disuccinic acid).These bleaching stibilizers also are applicable to greasiness removal, are especially containing low-level albic material or are not having in the product of albic material.
Especially preferred bleaching system comprises peroxy bleaching compound (preferred SPC-D; randomly with bleach activator together) and transition metal bleach catalyzer; as EP 458 397A, described in EP458 398A and EP 509 787A (Unilever) and claimed those.
Also can contain one or more enzymes according to particle of the present invention.Suitable enzyme comprises proteolytic enzyme, amylase, cellulase, oxydase, peroxidase and the lipase that is suitable for mixing detergent composition.Preferred proteolytic enzymes (proteolytic enzyme) is the catalytic activity protein material, when it is present in the textile stains with hydrolysis reaction degraded or change the protein type of spot.They can be any suitable sources, for example vegetables, animal, bacterium or yeast source.
Various quality and source and in the various pH scopes of 4-12, have active proteolytic ferment or proteolytic enzyme be can get and can be used for the present invention.The example of suitable proteolytic ferment is a subtilisin, and it is from specific
B.Subtilis B.licheniformisBacterial strain, for example commercially available subtilisin Maxatase (trade mark) is by GenencorInternational N.V., Delft, Holland supply, and Alcalase (trade mark), by Novozymes Industri A/S, Copenhagen, Denmark supply.
Especially the proteolytic enzyme that suitable is from bacillus strain, it has maximum activity in the whole pH scope of 8-12, commercially available, for example from Novozymes Industri A/S, registered trademark is called Esperase (trade mark) and Savinase (trade mark). and the preparation of these enzymes and similar enzyme is described among the GB 1243785.Other commercially available proteolytic enzyme is Kazusase (trade mark is from Showa-Denko of Japan), Optimase (trade mark, from Miles Kali-Chemie, Hannover, West Germany), and Superase (trade mark is from Pfizer of U.S.A.).
Detersive enzyme uses with particulate forms usually, and consumption is the about 3.0wt% of about 0.1-.Yet, can use the enzyme of any appropriate physical form.
Particle of the present invention also can comprise basic metal, and especially yellow soda ash is processed to increase detersive power and to be convenient to.The suitable amount of yellow soda ash is 1-60wt%, preferred 2-40wt%.Yet, contain few or the composition that do not have yellow soda ash also within the scope of the present invention.
Particle of the present invention has low bulk density: 400-900g/l suitably, or 500-800g/l, for example about 650g/l.
Said composition also can comprise the particulate filler of back feed, and it comprises inorganic salt suitably, for example sodium sulfate and sodium-chlor.This filler amount can be the 5-60% of composition weight.
Mix the detergent composition that the warp of particle produced according to the invention fully prepares and for example to comprise washing composition activeconstituents and auxiliary agent and optional one or more flow promotors, filler and other minor constituent such as color, spices, fluorescent agent, SYNTHETIC OPTICAL WHITNER and enzyme.
The present invention is existing to set forth by following non-limiting example.
Embodiment
The detergent powder feed roller that will have the prescription that provides in the following table is by being applied on the detergent powder with the slurry of nozzle spray with flavor capsule.
Fog system: Eminent E13 spray gun
Nozzle specification: 20HTE nozzle
Mixing tank: standard concrete mixing tank
Mixing time: 15 minutes
Batch weight: 20kg
Injection rate: 0.8kg hr
-1
Capsule concentration in the slurry: 50wt% (surplus: water)
| Composition | Amount (wt%) |
| LAS sodium | 11.1 |
| NI 7EO | 8.6 |
| Soap | 2.5 |
| Zeolite A24 | 26.4 |
| Sokalan CP5 (polyacrylate) | 2.1 |
| Yellow soda ash | 17.6 |
| Water glass | 2.0 |
| SCMC | 0.3 |
| Sodium sulfate | 22.3 |
| Moisture | 7.1 |
| Amount to | 100 |
Randomly, defoamer, SYNTHETIC OPTICAL WHITNER (TAED/ percarbonate blend), and proteolysis+fat hydrolase is by the back feed.
Claims (15)
1. granular detergent products, it comprises the particle through applying that has comprised function nuclear, this function nuclear comprises that one or more are selected from the decontamination reagent of tensio-active agent, softener material and washing auxiliary detergent, this particle through applying further comprises the coating of 10wt% at the most, and this coating comprises packed spices.
2. according to the granular detergent products of claim 1, wherein the particle of this coating comprises the coating of 5wt% at the most.
3. according to the granular detergent products of claim 1 or 2, wherein this coating further comprises the not spices of encapsulation.
4. according to the granular detergent products of claim 1 or 2, wherein this packed spices comprises trimeric cyanamide-urea-formaldehyde microcapsule.
5. granular detergent products, wherein at least 10% of the particle total amount is the particle through applying that comprises function nuclear, and this function nuclear comprises that one or more are selected from the decontamination reagent of tensio-active agent, softener material and washing auxiliary detergent, and this coating comprises packed spices.
6. microgranular detergent composition, it comprises each granular detergent products and one or more other solid component mixing things according to claim 1-5.
7. microgranular detergent composition, it comprises each granular detergent products, the linear alkyl sulfonate surfactant of 0wt%-30wt% and the washing auxiliary detergent of 10wt%-70wt% according to claim 1-5, in the weight of total detergent composition.
8. microgranular detergent composition, it comprise according to claim 1-5 each granular detergent products and the softener material of 10wt%-95wt%, in the weight of total detergent composition.
9. the method for preparing granular detergent products, this method comprises:
(i) provide Powdered and/or the particulate state cleansing composition, said composition comprises that one or more are selected from the decontamination reagent of tensio-active agent, softener material and washing auxiliary detergent;
(ii) preparation comprises the slurry of water and packed spices;
(iii) spray this cleansing composition to form particle through applying with described slurry.
10. according to the method for claim 9, wherein this slurry further comprises the not spices of encapsulation.
11. according to the method for claim 9 or claim 10, wherein this slurry further comprises viscosity modifier.
12. according to the method for claim 9 or 10, wherein this slurry is sprayed on this cleansing composition in low shear mixer or moderate shear mixing tank.
13. preparing washing agent method for compositions, this method comprise by according to each method preparation of claim 9-12 through applying particle and other solids component of particle and one or more that will be somebody's turn to do through coating mix.
14. the method for claim 9 or 13 should be according to each particle of claim 1-5 through coated particle wherein.
15., wherein should be particle through the particle of coating according to claim 6 according to the method for claim 9 or 13.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03079123.0 | 2003-12-19 | ||
| EP03079123 | 2003-12-19 | ||
| EP04076847.5 | 2004-06-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1894393A CN1894393A (en) | 2007-01-10 |
| CN100384975C true CN100384975C (en) | 2008-04-30 |
Family
ID=34924047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800375524A Active CN100384975C (en) | 2003-12-19 | 2004-11-19 | Detergent granules and process for their manufacture |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN100384975C (en) |
| ZA (1) | ZA200603871B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110785481A (en) * | 2017-06-20 | 2020-02-11 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0397245A2 (en) * | 1989-05-11 | 1990-11-14 | The Procter & Gamble Company | Perfume particles for use in cleaning and conditioning compositions |
| CN1047335A (en) * | 1989-05-11 | 1990-11-28 | 普罗格特-甘布尔公司 | The perfume particle that coats |
| DD295761A5 (en) * | 1990-06-25 | 1991-11-14 | Berlin-Chemie Gmbh,De | METHOD FOR PRODUCING AMINO-RESIN MICRO-CAPSELEDISPESIONS FOR COSMETIC PREPARATES |
| US5137646A (en) * | 1989-05-11 | 1992-08-11 | The Procter & Gamble Company | Coated perfume particles in fabric softener or antistatic agents |
| CN1092806A (en) * | 1990-02-20 | 1994-09-28 | 普罗格特-甘布尔公司 | The fabric softener composition that contains covering spice particles |
| WO2003089019A1 (en) * | 2002-04-18 | 2003-10-30 | The Procter & Gamble Company | Malodor-controlling compositions comprising odor control agents and microcapsules containing an active material |
-
2004
- 2004-11-19 CN CNB2004800375524A patent/CN100384975C/en active Active
- 2004-11-19 ZA ZA200603871A patent/ZA200603871B/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0397245A2 (en) * | 1989-05-11 | 1990-11-14 | The Procter & Gamble Company | Perfume particles for use in cleaning and conditioning compositions |
| CN1047335A (en) * | 1989-05-11 | 1990-11-28 | 普罗格特-甘布尔公司 | The perfume particle that coats |
| US5137646A (en) * | 1989-05-11 | 1992-08-11 | The Procter & Gamble Company | Coated perfume particles in fabric softener or antistatic agents |
| CN1092806A (en) * | 1990-02-20 | 1994-09-28 | 普罗格特-甘布尔公司 | The fabric softener composition that contains covering spice particles |
| DD295761A5 (en) * | 1990-06-25 | 1991-11-14 | Berlin-Chemie Gmbh,De | METHOD FOR PRODUCING AMINO-RESIN MICRO-CAPSELEDISPESIONS FOR COSMETIC PREPARATES |
| WO2003089019A1 (en) * | 2002-04-18 | 2003-10-30 | The Procter & Gamble Company | Malodor-controlling compositions comprising odor control agents and microcapsules containing an active material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110785481A (en) * | 2017-06-20 | 2020-02-11 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
| CN110785481B (en) * | 2017-06-20 | 2021-04-13 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200603871B (en) | 2007-12-27 |
| CN1894393A (en) | 2007-01-10 |
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