CN100381358C - Method for modifying water glass - Google Patents

Method for modifying water glass Download PDF

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Publication number
CN100381358C
CN100381358C CNB2006100281903A CN200610028190A CN100381358C CN 100381358 C CN100381358 C CN 100381358C CN B2006100281903 A CNB2006100281903 A CN B2006100281903A CN 200610028190 A CN200610028190 A CN 200610028190A CN 100381358 C CN100381358 C CN 100381358C
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CN
China
Prior art keywords
ranges
magnetic field
percent
sodium silicate
water glass
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Expired - Fee Related
Application number
CNB2006100281903A
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Chinese (zh)
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CN1884072A (en
Inventor
潘嘉祺
孙亚琴
陈幼玲
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Shanghai Institute of Technology
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Shanghai Institute of Technology
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Priority to CNB2006100281903A priority Critical patent/CN100381358C/en
Publication of CN1884072A publication Critical patent/CN1884072A/en
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Publication of CN100381358C publication Critical patent/CN100381358C/en
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  • Glass Compositions (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

The present invention discloses a modification method of sodium silicate. Liquid sodium silicate is arranged in a container or a pipeline. A rotary magnetic field is additionally arranged outside the container or the pipeline. The rotating speed of the rotary magnetic field ranges from 1200 rpm to 1700 rpm, the strength of the magnetic field ranges from 0.01T to 0.08T, the magnetizing time ranges from 30 minutes to 50 minutes, and thus, the magnetizing modification of the liquid sodium silicate is accomplished. The present invention is used, when the module of the liquid sodium silicate ranges from 2.2 to 2.6, the density ranges from 1.3cm< 3 > (20 DEG C) to 1.4cm< 3 > (20 DEG C). When the water washing quartz sand is 100 percent, the sodium silicate ranges from two percent to four percent, the sodium fluorosilicate (a powder form) ranges from 10 percent to 15 percent, and the sodium silicate with the magnetizing modification through the rotary magnetic field is placed with 24 hours, the tensile strength is high; compared with sodium silicate which has no magnetizing modification treatment and has the same proportion, the tensile strength improves by 30 percent to 100 percent. The strength of the magnetic field of the present invention ranges from 0.01 to 0.08 T. Compared with the traditionally strong magnetic field of 1T, the device cost is low, and the energy consumption is low.

Description

A kind of method for modifying water glass
Technical field
The present invention relates to the method that a kind of elimination water glass " wears out ", more particularly relate to a kind of method that " wears out " by magnetic field elimination water glass.
Background technology
Water glass is the general name of various silicate (water glass, potassium silicate, the lithium silicate etc.) aqueous solution, and the general formula that chemistry is expressed is M 2OmSiO 2NH 2O, wherein M is Na +, K +, Li +Deng, m, n are M 2O, SiO 2, H 2The mutual ratio of three constituent quality of O.Sodium silicate is a water glass the most frequently used in the Foundry Production, and chemical expression is Na 2OmSiO 2NH 2O, from structure analysis is the mixing solutions of many sodium polysilicates, they are among the running balance, but in the seasoning process, have micelle to generate in the solution, the polymerization degree generation disproportionation of sodium polysilicate is described, produce polycondensation product, cause the water glass viscosity degradation, surface tension increases, cohesive strength reduces, and this phenomenon is commonly called as " wearing out " of water glass.Eliminate " wearing out " phenomenon of water glass, just intake in the water glass system that must " wear out " to makes the polycondensation product depolymerization.It is to eliminate the water glass a kind of effective ways of phenomenon that " wear out " that the magnetic field modification is handled, the main at present permanent magnetic field that adopts, also can adopt electromagnetic field to set up standing field in the pipeline outside of delivering liquid water glass, carrying out magnetization modification when water glass is flowed through pipeline handles, the needed magneticstrength of this magnetization modification treatment process is bigger, about about 1T, apparatus expensive, energy consumption is bigger.
Summary of the invention
Technical problem to be solved by this invention provides a kind of method that " wears out " by low-intensity magnetic field elimination water glass.
The technical solution used in the present invention: a kind of method for modifying water glass, liquid glass is placed container or pipeline, add the magnetic field of rotation at container or pipeline, the rotating speed of rotatingfield is 1200~1700rpm, magneticstrength is 0.01~0.08T, magnetizing time 30~50min can finish the magnetization modification of liquid glass.
Beneficial effect of the present invention, using the present invention is 2.2~2.6 when the modulus of liquid glass, density 1.3~1.4g/cm 3(20 ℃).Through the water glass behind the rotatingfield magnetization modification, when washing quartz sand 100%, water glass 2~4%, Sodium Silicofluoride (powdery) 10~15%, place 24h, tensile strength is higher, than adopting the water glass of handling without magnetization modification, and having above-mentioned identical proportioning, its tensile strength improves 30~100%.Magneticstrength of the present invention is 0.01~0.08T, and lower than traditional 1T high-intensity magnetic field equipment price, energy consumption is low.
Embodiment
Below by embodiment the present invention is described in further detail, a kind of method for modifying water glass, liquid glass is placed container or pipeline, add the magnetic field of rotation at container or pipeline, the rotating speed of rotatingfield is 1200~1700rpm, magneticstrength is 0.01~0.08T, and magnetizing time 30~50min can finish the magnetization modification of liquid glass.
Embodiment 1~3
1. wash quartz sand (21H) 2.5Kg, liquid glass (m=2.3, density 1.3g/cm 3) 100g, Sodium Silicofluoride (powdery) 10g, magnetizing time 40min, the tensile strength during 24h is 0.602Mpa.And adopt water glass without magnetization modification, and have above-mentioned identical proportioning, the tensile strength during its 24h is 0.187Mpa.
2. wash quartz sand (21H) 2.5Kg, liquid glass (m=2.3, density 1.3g/cm 3) 50.5g, Sodium Silicofluoride (powdery) 5g, magnetizing time 40min, the tensile strength during 24h is 0.067Mpa.
3. wash quartz sand (21H) 2.5Kg, unmagnetized liquid glass (m=2.3, density 1.3g/cm 3) 75.1g, Sodium Silicofluoride (powdery) 18.86g, the tensile strength during 24h is 0.0427Mpa.
Above said content only is the basic explanation of the present invention under conceiving, and according to any equivalent transformation that technical scheme of the present invention is done, all should belong to protection scope of the present invention.

Claims (1)

1. method for modifying water glass, it is characterized in that: liquid glass is placed container or pipeline, add the magnetic field of rotation at container or pipeline, the rotating speed of rotatingfield is 1200~1700rpm, magneticstrength is 0.01~0.08T, magnetizing time 30~50min can finish the magnetization modification of liquid glass.
CNB2006100281903A 2006-06-27 2006-06-27 Method for modifying water glass Expired - Fee Related CN100381358C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100281903A CN100381358C (en) 2006-06-27 2006-06-27 Method for modifying water glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100281903A CN100381358C (en) 2006-06-27 2006-06-27 Method for modifying water glass

Publications (2)

Publication Number Publication Date
CN1884072A CN1884072A (en) 2006-12-27
CN100381358C true CN100381358C (en) 2008-04-16

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Family Applications (1)

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CNB2006100281903A Expired - Fee Related CN100381358C (en) 2006-06-27 2006-06-27 Method for modifying water glass

Country Status (1)

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CN (1) CN100381358C (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1373698A1 (en) * 1986-06-18 1988-02-15 Новополоцкий Политехнический Институт Им.Ленинского Комсомола Белоруссии Method of producing siliceous fibre
CN2091189U (en) * 1991-03-27 1991-12-25 朝阳重型机器厂 Magnetic treating device for soluble glass
US6776920B1 (en) * 2001-03-08 2004-08-17 William C. Reed Heat-absorbing gel material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1373698A1 (en) * 1986-06-18 1988-02-15 Новополоцкий Политехнический Институт Им.Ленинского Комсомола Белоруссии Method of producing siliceous fibre
CN2091189U (en) * 1991-03-27 1991-12-25 朝阳重型机器厂 Magnetic treating device for soluble glass
US6776920B1 (en) * 2001-03-08 2004-08-17 William C. Reed Heat-absorbing gel material

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
强磁场对水玻璃砂性能的影响. 张岩,高波,周继扬.现代铸铁,第01期. 2003 *
旋转磁场净化钢液的实验研究. 钟云波,孟宪俭,倪丹,任忠鸣,邓,康,徐匡迪.上海金属,第28卷第2期. 2006 *
水玻璃磁化改性与性能探讨. 李东南,戴莉莉.热加工工艺,第03期. 1999 *

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Granted publication date: 20080416

Termination date: 20100627