CN100376715C - Composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and its manufacturing method - Google Patents
Composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and its manufacturing method Download PDFInfo
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- CN100376715C CN100376715C CNB2004100969562A CN200410096956A CN100376715C CN 100376715 C CN100376715 C CN 100376715C CN B2004100969562 A CNB2004100969562 A CN B2004100969562A CN 200410096956 A CN200410096956 A CN 200410096956A CN 100376715 C CN100376715 C CN 100376715C
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Abstract
The present invention relates to a diamond surface coating glass, coating cubic boron nitride and plating titanium composite structure and the manufacturing method thereof. The surface of a diamond is provided with a glass layer. A cubic boron nitride layer is arranged on the glass layer. The surface layer of the cubic boron nitride layer is provided with a titanium layer. The present invention has the main advantage that cubic boron nitrides in the inner surface layer of the diamond are inert to iron element materials and the surface of the cubic boron nitrides is rough. The outer layer of the diamond is coated by a metallic titanium layer. The present invention is a special abrasive grain having the performance of the two abrasive materials of the diamond and the cubic boron nitrides and having the structural performance of rough and fine abrasive grains. When the special abrasive grain is used to manufacture grinding tools of resin bonding agent to process cutters, tools and workpieces made of hard alloy and iron element materials, workpiece quality with special requirements can be obtained. The diamond which experiences composite coating and plating treatment has an increased volume and the shape of the diamond is similar to a ball. Grinding tools made of the diamond are uniformly provided with the diamond abrasive grains. Simultaneously, the bonding strength and the holding force of the diamond and a basal body are big, which prevents the abrasive grain from dropping off soon. The diamond having the compound coating and plating layer of the coating glass, the cubic boron nitrides and the plating titanium is mainly used for the grinding tools of resin bonding agent. When the diamond is used, compound grinding effect of the diamond, the cubic boron nitrides and the rough and fine abrasive grains can be achieved.
Description
Technical field
The present invention relates to a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and manufacture method.
Background technology
Diamond is very extensive in industrial application, can make multiple instrument such as cutter, emery wheel, grinding tool etc., because the characteristic of diamond itself, combine very difficult with other material, so the matrix from instrument comes off easily, causes the work-ing life of instrument low, production cost increases.
The utility model content
The objective of the invention is to improve the prior art diamond combines the shortcoming of difficulty and a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and manufacture method is provided with other material.
For achieving the above object, the present invention takes following design: diamond surface has a glass coating; One cbn layer is arranged on described glass coating, one titanium layer is arranged on the top layer of described cbn layer.
A kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method,
Step 1: apply one deck glass at diamond surface;
Step 2: on the glass coating that applies, apply cubic boron nitride again;
Step 3: adopt the little evaporation plating of vacuum will apply diamond electroplating one deck titanium of glass and cubic boron nitride.
Advantage of the present invention mainly is: the iron cellulosic material is inertia to the cubic boron nitride on this diamond top layer and the surface is rough and uneven in surface, and skin has the layer of titanium metal parcel, it is a kind of special abrasive particle diamond and two kinds of abrasives performances of cubic boron nitride and thickness abrasive particle structure properties that has, the grinding tool that uses it to make resinoid bond comes cutter, instrument, the workpiece of processing rigid alloy and the manufacturing of iron cellulosic material, can obtain the workpiece quality of particular requirement.The diamond that compound coating of this process and plating are handled, volume increases, be bordering on spherical, the grinding tool of manufacturing, diamond abrasive grain is evenly distributed, diamond and high base strength and hold height prevent the abrasive particle early fallout simultaneously.Coated glass-cubic boron nitride-titanizing. the diamond of coating-plating layer is mainly used in the grinding tool of resinoid bond, uses it can diamond and the composite grinding effect of cubic boron nitride, thickness abrasive particle.The diamond of the cubic boron nitride that applies becomes a kind of novel special abrasive particle diamond and two kinds of abrasives performances of cubic boron nitride, thickness abrasive particle structure that has, cutter, instrument, workpiece that the grinding tool that uses it to make resinoid bond comes processing rigid alloy and iron cellulosic material to make can satisfy user's special requirement.
Description of drawings
Fig. 1 diamond particles local section of the present invention structural representation.
Embodiment
Embodiment 1: as shown in Figure 1, the present invention by: there is a glass coating 2 on diamond 1 surface; One cbn layer 3 is arranged on described glass coating 2, one titanium layer 4 is arranged on described cbn layer 3 top layers.
Embodiment 2: diamond 1 is a particulate state, and irregular scraggly type looks surface is arranged, and described glass coating 2, cbn layer 3 and titanium layer 4 form composite bed, parcel diamond 1 according to diamond 1 irregular scraggly type looks surface.
Embodiment 3: a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method, and its step is as follows:
Step 1: at coated with CVD (chemical vapor deposition) diamond one deck glass; Use equipment: conventional, electric-resistance baking oven; As follows step by step;
Step 1) is placed on rosin 120g, alcohol 120ml rosin is melted fully;
Step 2) spreads placement out after diamond is fully mixed thoroughly with the proportioning of 1000CTS/60ml with above-mentioned solution, nature is dried; With glass powder, such as applying the glass powder that granularity is diamond use 230/270～270/325# of 80/100# than the thin 5-6 of a diamond grain size number;
Sodium silicate: Na
20N.SiO
2.nH
2O;
Step 3) is fully mixed glass powder and diamond thoroughly tinning with 4: 1 ratio;
Step 4) is preheating to 110 ℃ with baking oven, and the jar of step 3) was placed in the baking oven baking 2 hours, takes out cooling;
Step 2: on the glass coating that applies, apply cubic boron nitride again; Use equipment: resistance furnace, as follows step by step;
Step 1) will apply the diamond and the cubic boron nitride of glass and mix tinning thoroughly in 5: 1 ratio, be placed in the special resistors stove, be warmed up to 600 ℃ after the insulation 1 hour, again temperature is risen to 800 ℃ after the insulation 1 hour after powered-down; Get final product with the cubic boron nitride powder than the thin 5-6 of a diamond grain size number, promptly the diamond of 80/100# uses the cubic boron nitride powder of 230/270～270/325#;
Step 2) treat to come out of the stove after diamond is with the stove naturally cooling, sieve good finished product;
Step 3: the little evaporation of employing vacuum is plated in the diamond outside surface plating one deck titanium that has applied glass and cubic boron nitride; Equipment: cover of titanizing vacuum oven and vacuum unit;
1, technical process and parameter: in the special-purpose jar of packing into behind diamond and the titanium valve uniform mixing, be placed in the vacuum furnace chamber; Open the vacuum unit and be warming up to the temperature (120 orders are 745 ℃ with thick diamond, and 120 orders are 780 ℃ with thin diamond) of setting, be incubated 1 hour postcooling to 250 and ℃ close the vacuum unit; Treat to cool off fully the back jar is taken out, get product after sifting out diamond;
2, the granularity of titanium valve, proportioning, dosage, thickness of coating:
1) titanium valve granularity 120 orders with thick diamond with 230 orders with thin titanium valve, 120 orders with thin diamond with 60 orders with thick titanium valve;
2) proportioning of titanium valve activation solution: the per kilogram titanium valve adds the 20ml activation solution;
3) dosage of titanium valve: 120 orders are 30g/1000ct with thick diamond titanium valve consumption, and 120 orders are 130g/1000ct with thin diamond titanium valve consumption;
4) thickness of coating: this technology is as the criterion by coating weightening finish 0.4%, does not calculate thickness of coating.
Advantage of the present invention mainly is:
The iron cellulosic material is inertia to the cubic boron nitride on this diamond top layer and the surface is rough and uneven in surface, And skin has the layer of titanium metal parcel, is a kind of have diamond and two kinds of abrasives of cubic boron nitride Special abrasive particle performance and thickness grinding grain structure performance uses it to make the mill of resinoid bond Cutter, instrument, workpiece that tool comes processing rigid alloy and iron cellulosic material to make can obtain the spy The different workpiece quality that requires.
This diamond of processing through composite coated and plating, volume increases, be bordering on spherical, manufacturing Grinding tool, diamond abrasive grain is evenly distributed, bond strength and the hold height of while diamond and matrix, Prevent the abrasive particle early fallout. Coated glass-cubic boron nitride-titanizing. the diamond of coating-plating layer Be mainly used in the grinding tool of resinoid bond, use it can diamond and cubic boron nitride, thickness mill The composite grinding effect of grain.
Claims (7)
1. composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers, it is characterized in that: diamond surface has a glass coating; One cbn layer is arranged on described glass coating, one titanium layer is arranged on described cbn layer top layer.
2. a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers according to claim 1 is characterized in that: diamond is a particulate state.
3. composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method is characterized in that: adopt step as follows:
Step 1 is at coated with CVD (chemical vapor deposition) diamond one deck glass;
Step 2 applies cubic boron nitride again on the glass coating that applies;
Step 3, the little evaporation of employing vacuum are plated in the diamond outside surface plating one deck titanium that has applied glass and cubic boron nitride.
4. a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method according to claim 3 is characterized in that,
In the step 1 of claim 3: adopt step as follows;
Step 1) is placed on rosin 120g, alcohol 120ml rosin is melted fully;
Step 2) spreads placement out after diamond is fully mixed thoroughly with the proportioning of 1000CTS/60ml, nature is dried;
Step 3) is mixed glass powder and diamond thoroughly tinning with 4: 1 ratio;
Step 4) is preheating to 110 ℃ with baking oven, and the jar of step 3) was placed in the baking oven baking 2 hours, takes out cooling;
In the step 2 of claim 3: adopt step as follows;
Step 1) will apply the diamond and the cubic boron nitride of glass and mix tinning thoroughly in 5: 1 ratio, be placed in the special resistors stove, be warmed up to 600 ℃ after the insulation 1 hour, again temperature is risen to 800 ℃ after the insulation 1 hour after powered-down;
Step 2) treat to come out of the stove after diamond is with the stove naturally cooling, sieve good finished product;
In the step 3 of claim 3: adopt step as follows;
In the special-purpose jar of packing into behind diamond and the titanium valve uniform mixing, be placed in the vacuum furnace chamber; Open the vacuum unit and be warming up to the temperature of setting, 120 orders are 745 ℃ with thick diamond, and 120 orders are 780 ℃ with thin diamond, are incubated 1 hour postcooling to 250 and ℃ close the vacuum unit; Treat to cool off fully the back jar is taken out, get product after sifting out diamond.
5. according to claim 3 or 4 described a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method, it is characterized in that, in the step 3 of claim 3 or 4: adopt titanium valve granularity 120 orders with thick diamond with 230 orders with thin titanium valve, 120 orders with thin diamond with 60 orders with thick titanium valve; The per kilogram titanium valve adds the 20ml activation solution; The dosage of titanium valve: 120 orders are 30g/1000ct with thick diamond titanium valve consumption, and 120 orders are 130g/1000ct with thin diamond titanium valve consumption.
6. according to claim 3 or 4 described a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method, it is characterized in that, in the step 2 of claim 3 or 4: use cubic boron nitride powder than the thin 5-6 of a diamond grain size number.
7. according to claim 3 or 4 described a kind of composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers manufacture method, it is characterized in that, in the step 1 of claim 3 or 4: use glass powder than the thin 5-6 of a diamond grain size number.
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| CNB2004100969562A CN100376715C (en) | 2004-12-08 | 2004-12-08 | Composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and its manufacturing method |
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| CNB2004100969562A CN100376715C (en) | 2004-12-08 | 2004-12-08 | Composite structure of diamond surface coated with glass, cubic boron nitride and titanium layers and its manufacturing method |
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| CN1786258A CN1786258A (en) | 2006-06-14 |
| CN100376715C true CN100376715C (en) | 2008-03-26 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104762592B (en) * | 2015-03-26 | 2017-05-03 | 河南黄河旋风股份有限公司 | Manufacturing method of resin film plated on diamond surface |
| JP6564624B2 (en) * | 2015-06-10 | 2019-08-21 | 株式会社ディスコ | Grinding wheel |
| TWI718755B (en) * | 2019-05-23 | 2021-02-11 | 國立臺灣科技大學 | Diamond cutter and its manufacturing method |
| CN114645306B (en) * | 2022-02-25 | 2024-04-09 | 中国航发北京航空材料研究院 | Method for preparing large-size cBN particle nickel-based coating on surface of complex-shaped workpiece |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300779A (en) * | 2002-04-09 | 2003-10-21 | Denki Kagaku Kogyo Kk | Electrically conductive ceramics, production method therefor and use thereof |
| US20040142173A1 (en) * | 2003-01-21 | 2004-07-22 | Chapman Lloyd R. | Carbon material and process of manufacturing |
| JP2004238266A (en) * | 2003-02-07 | 2004-08-26 | Denki Kagaku Kogyo Kk | Method of manufacturing conductive ceramic |
| CN2771200Y (en) * | 2004-12-08 | 2006-04-12 | 上海江信超硬材料有限公司 | Diamond composite structure |
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- 2004-12-08 CN CNB2004100969562A patent/CN100376715C/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300779A (en) * | 2002-04-09 | 2003-10-21 | Denki Kagaku Kogyo Kk | Electrically conductive ceramics, production method therefor and use thereof |
| US20040142173A1 (en) * | 2003-01-21 | 2004-07-22 | Chapman Lloyd R. | Carbon material and process of manufacturing |
| JP2004238266A (en) * | 2003-02-07 | 2004-08-26 | Denki Kagaku Kogyo Kk | Method of manufacturing conductive ceramic |
| CN2771200Y (en) * | 2004-12-08 | 2006-04-12 | 上海江信超硬材料有限公司 | Diamond composite structure |
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