CN100372011C - Method of mfg. form and optical information storage medium - Google Patents
Method of mfg. form and optical information storage medium Download PDFInfo
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- CN100372011C CN100372011C CNB2004100698185A CN200410069818A CN100372011C CN 100372011 C CN100372011 C CN 100372011C CN B2004100698185 A CNB2004100698185 A CN B2004100698185A CN 200410069818 A CN200410069818 A CN 200410069818A CN 100372011 C CN100372011 C CN 100372011C
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Abstract
The present invention relates to a stencil which is used for manufacturing an optical information storage medium and comprises a basal plate and a modification layer, wherein the basal plate is provided with a plurality of pre-engraving grooves, and the modification layer is arranged on the basal plate. The present invention also discloses a manufacturing method for optical information storage media.
Description
Technical field
The present invention relates to the manufacture method of a kind of template and media for storing optical information, especially a kind of have the template of upgrading layer and a manufacture method of media for storing optical information.
Background technology
Along with the arriving of information and multimedia era, electronic product also constantly increases for the storage density of Storage Media and the demand of capacity.Traditional Storage Media can be divided into two big classes haply, is respectively magnetic recording medium and optical recording media.Be to preponderate in the market with optical recording media, its comprise CD-ROM (CD-ROM), writable disposable type CD (CD-R), rewritable type CD (CD-RW), read-only type Video CD (DVD-ROM), writable disposable type Video CD (DVD-R), rewritable formula Video CD (DVD-RW, DVD+RW) and dynamic random storage Video CD (DVD-RAM) or the like.
In the face of more and more huge audio and video information amount, improve the volume of information of CD, be the target that industrial community is pursued always.And therefore DVD has occupied certain ratio because have the information storage capacity bigger than CD on light memory medium market.Present DVD has different outward appearance patterns, to two-sided bilayer (dual side duallayer), their storage volume scope does not wait from 4.7GB to 17GB yet from individual layer single face (single side single layer), two-sided individual layer (dual side singlelayer), single-surface double-layer (single side dual layer).
Another side is blank (dummy) if having only single face to store data, and then its storage volume is about 4.7GB, is the read-only type Video CD of individual layer single face, is called DVD-5 again; If on the disc of single face, store double-deck capacity, because deduct space that bonding accounts for and the instruction that connects two-layer data, the capacity that the historical facts or anecdotes border can store data is few than the twice of single face capacity, be the read-only type Video CD of single-surface double-layer, claim DVD-9 again, its storage volume is about 8.5GB.If in conjunction with the technology of two-sided bilayer, then storage volume can increase and be 13.2GB, that is DVD-14 (single-surface single-layer adds single-surface double-layer), or the storage volume amplification is 17GB, that is DVD-18 (two-sided bilayer).Therefore wherein, acceptance is higher on DVD discs market, and for the single-surface single-layer capacity is DVD-5 and two kinds of discs of DVD-9, the disc of two kinds of specifications has all saved by access the time " turn-over " trouble, so comparatively the consumer likes.
Single-surface double-layer DVD-R with 8.5GB capacity because capacity is big, adds the structure of writable disposable, also more and more is subjected to market and payes attention to.As shown in Figure 1, existing single-surface double-layer DVD-R disc 10 contains one first substrate 11, one first organic dye layer 12, a semi-reflective layer 13, a wall 14, one second organic dye layer 15, a reflection horizon 16, one second substrate 17 in regular turn, reaches a knitting layer 19.
In the prior art, for single-surface double-layer DVD-R disc 10, photopolymerization processing procedure (Photo-Polymerization Process, 2P Process) is one of manufacture method commonly used, below just does one at the 2P processing procedure and simply introduces:
Please refer to Fig. 2, it has on first substrate 11 of pre-rail groove at quarter (pre-grooved) in one, forms first organic dye layer 12, semi-reflective layer 13, and light binding layer 14 ' successively.Then, have the template (soft stamper) 18 of prerecording ditch groove with one, be pressed on the light binding layer 14 ', and,, form wall 14 to solidify colloid through UV-irradiation.After divesting template 18, on the wall 14 that forms groove, form second organic dye layer 15 and second reflection horizon 16 again.At last, be coated with a joint glue 19 ' after, second substrate 17 is engaged with second reflection horizon 16, behind photocuring, form a knitting layer 19 again, promptly finish the making of single-surface double-layer DVD-R disc 10.
Yet, when template 18 divests,, need apply stronger pulling force wall 14 is separated with template because the adhesion between template 18 and the wall 14 is strong.But the adhesion of first organic dye layer 12 and semi-reflective layer 13 can't bear powerful pulling force a little less than going up relatively.Therefore, shown in Fig. 3 dotted line, when divesting the step of template, then easily 14 fragmentation of origination interval layer peel off or or even the phenomenon that causes first organic dye layer 12 and semi-reflective layer 13 to separate with first substrate 11, influenced the travel path of laser access, and then cause the yield of disc on the low side, increased production cost.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art and defective, the manufacture method of a kind of template and media for storing optical information is provided, when divesting template to solve existing single-surface double-layer DVD-R disc, the too strong problem of the adhesion of template and wall, and then problem such as solution disc process rate is on the low side.
A purpose of the present invention is used for the manufacturing of media for storing optical information for a kind of template is provided, and template has a upgrading layer, to change the polarity of template surface, makes template be easy to divest.
Another object of the present invention is especially utilized the surface polarity template opposite with wall for a kind of manufacture method of media for storing optical information is provided, and makes template be easy to divest.
For reaching above-mentioned purpose, according to template of the present invention, be used for the manufacturing of a media for storing optical information, template comprises a substrate and a upgrading layer.Wherein, substrate has plural prerecording ditch groove, and the upgrading layer is arranged on the substrate.
Again, according to media for storing optical information manufacture method of the present invention, it comprises formation one first record lamination on one first substrate, form one and have the template of a upgrading layer, be coated with a light binding layer, the pressing template and first substrate, solidify the light binding layer, and divest template to form a wall, and form one second record lamination on wall, engage one second substrate on the second record lamination.
From the above, the manufacture method of template of the present invention and media for storing optical information, template have a upgrading layer.Compared with prior art, the manufacture method of template of the present invention and media for storing optical information, the upgrading layer can change the polarity of template surface, makes it present the polarity opposite or different with wall, and then reduces the adhesion between wall and the template.So when divesting template, required to divest strength less, is difficult for taking place because the adhesion between wall and the template is excessive, and makes the problem that the wall fragmentation is peeled off; It is excessive because divest the strength of template also to be difficult for generation first organic dye layer or first reflection horizon, and the phenomenon of separating with first substrate.Thus, can promote the yield of product, and then also reduce production cost.
Description of drawings
Fig. 1 is the synoptic diagram of existing single-surface double-layer Video CD;
Fig. 2 A～2F is the synoptic diagram of the photopolymerization processing procedure of existing single-surface double-layer Video CD;
Fig. 3 is the enlarged diagram of existing single-surface double-layer Video CD, wherein, when template divests, causes wall or template to destroy;
Fig. 4 is the process flow diagram of the manufacture method of template of the present invention and media for storing optical information;
Fig. 5 A～5G is the processing procedure synoptic diagram of the manufacture method of template of the present invention and media for storing optical information;
Fig. 6 is another process flow diagram of the manufacture method of template of the present invention and media for storing optical information;
Fig. 7 is the another schematic flow sheet of the manufacture method of template of the present invention and media for storing optical information.
Symbol description among the figure
10 single-surface double-layer DVD-R discs
11 first substrates
12 first organic dye layers
13 semi-reflective layers
14 walls
14 ' light binding layer
15 second organic dye layers
16 second reflection horizon
17 second substrates
18 templates
19 knitting layers
19 ' joint glue
20 media for storing optical information
21 first substrates
22 first recording layers
23 first reflection horizon
24 walls
24 ' light binding layer
25 second recording layers
26 second reflection horizon
27 second substrates
28 joint glues
30 templates
31 substrates
32 upgrading layers
S100 forms one first record lamination on one first substrate
S200 forms one and has the template of a upgrading layer
S210 is coated with a solvent on substrate, forms the upgrading layer after evaporation or oven dry
S300 is coated with a light binding layer
The S400 pressing template and first substrate also solidify the light binding layer
S500 divests template to form a wall
S600 forms one second record lamination on wall
S700 engages one second substrate on the second record lamination
S710 cloth one joint glue is on the second record lamination
L
0The first record lamination
L
1The second record lamination
Embodiment
Hereinafter with reference to relevant drawings, illustrate according to the template of preferred embodiment of the present invention and the manufacture method of media for storing optical information.
At first, please refer to Fig. 4 to Fig. 7, with the manufacture method of explanation according to the media for storing optical information of preferred embodiment of the present invention.
In the present embodiment, template is used in the photopolymerization processing procedure (Photo-Polymerization Process, 2P Process), to make a media for storing optical information.Media for storing optical information is the Video CD (DVD-R) of writable disposable formula, and in the present embodiment with the DVD-R of the formed single-surface double-layer of 2P processing procedure, with the preferred embodiment of the manufacture method of explanation media for storing optical information of the present invention.
As shown in Figure 4, in the present embodiment, the manufacture method of media for storing optical information comprises the following step: form one first record lamination on one first substrate (S100), form one and have the template (S200) of a upgrading layer, be coated with a light binding layer (S300), the pressing template and first substrate also solidify light binding layer (S400), divest template to form a wall (S500), form one second record lamination (S600) on wall, engage one second substrate on the second record lamination (S700).
As Fig. 4 and shown in Figure 5, in forming in the step of one first record lamination on one first substrate (S100) the first record lamination L
oComprise one first recording layer 22 and one first reflection horizon 23.Earlier first recording layer 22 is formed on first substrate 21, again first reflection horizon 23 is formed on first recording layer 22.
Wherein, the material of first recording layer 22 can be organic dyestuff or inorganic material.In the present embodiment, the material of first recording layer 22 is an organic dyestuff, and forms in the rotary coating mode.And first reflection horizon 23 is a semi-reflective layer (semi-reflective layer), and its material is metal or its alloy, for example is silver/silver alloy and aluminium/aluminium alloy or the like.And the generation type in first reflection horizon 23 normally is used to form sputter or the evaporation mode forms.
As Fig. 4 and shown in Figure 5, have in the step of template of a upgrading layer (S200) in forming one, on a substrate 31, form a upgrading layer 32.Wherein, template 30 comprises a substrate 31 and a upgrading layer 32.Wherein, substrate 31 has plural prerecording ditch groove (pre-grooved), the material of substrate 31 be selected from polycarbonate, polymethylmethacrylate, glass, and metal at least one of them, therefore, template 30 can be described as soft template (soft stamper) again.
As shown in Figure 6, in the present embodiment, the manufacture method of media for storing optical information more comprises: be coated with a solvent on substrate, form upgrading layer (S210) after evaporation or oven dry.
Upgrading layer 32 is arranged on the substrate 31, in the present embodiment, upgrading layer 32 is a solvent molecule layer, wherein, solvent is selected from tetrafluoropropanol, octafluoropentanol, methyl alcohol, ethanol, propyl alcohol, normal butyl alcohol, butyl alcohol-tert, n-amyl alcohol, n-hexyl alcohol, 2-methoxyl-ethanol, 2-propoxyl group-ethanol, 2-butoxy-ethanol, propyl ether, butyl ether, amyl ether, cyclohexane, methylcyclohexane, ethyl cyclohexane, propyl cyclohexane and 1, the 2-dimethyl cyclohexane at least wherein one.
In coating one light binding layer step (S300), coating is to form a light binding layer 24 '.And light binding layer 24 ' can be formed on the template 30 with upgrading layer 32, also can be formed on first reflection horizon 23.In the present embodiment, being formed on first reflection horizon 23 with light binding layer 24 ' is example.
Please refer to Fig. 4 and Fig. 5 again, in the pressing template and the first substrate step (S400), present embodiment with the light binding layer 24 ' pressing mutually on first substrate 21, has the light binding layer 24 ' of groove with the upgrading layer 32 of template 30 with formation.
Among Fig. 4 and Fig. 5,,, solidify the back application of force template 30 is divested, to form a wall 24 with light binding layer 24 ' irradiating ultraviolet light in solidifying the light binding layer and divesting template to form in the wall step (S500).After template 30 divested, upgrading layer 32 still was positioned on the template 30, can reuse.
Utilize the upgrading layer 32 of different solvents, can change the polarity on template 30 surfaces, in order to divesting of template 30 to form.When wall 24 is nonpolar macromolecule, then can select to be coated with the strong solvent of polarity and form upgrading layer 32, it for example is alcohols, after pervaporation or baking are sent out, still can stay some solvent molecule layers on substrate 31, alcohols with hydroxyl (OH group) then expose on template 30 surfaces, make the surface of template 30 become polar surfaces, so can separate with nonpolar wall 24 easily.And upgrading layer 32 solvent select for use the solvent with wall 24 opposed polarities, polarity to differ more better.Certainly, wall 24 also can be the polarity macromolecule, and upgrading layer 32 then selects for use nonpolar solvent to form.
As Fig. 4 and shown in Figure 5, on wall, in the step (S600), form one second record lamination on wall in forming one second record lamination.In the present embodiment, the second record lamination L
1Comprise one second recording layer 25 and one second reflection horizon 26.Form one second recording layer 25 on wall 24, form one second reflection horizon 26 again on second recording layer 25.Wherein, the material of second recording layer 25 is an organic dyestuff, form in the rotary coating mode, and second reflection horizon 26 can be semiconductor alloy firm, conductor alloy firm or metallic film.
Please refer to Fig. 4 to Fig. 6, on the second record lamination, in the step (S700), second substrate 27 is engaged in the second record lamination L in engaging one second substrate
1On.In the present embodiment, the manufacture method of media for storing optical information more comprises: be coated with a joint glue 28 step (S710) on the second record lamination, utilize a joint glue to coat the second record lamination L
1On, to bind second substrate 27 and the second record lamination L
1
In addition, as shown in Figure 7, the manufacture method of media for storing optical information of the present invention, can certainly will form one first record lamination step (S100), and coating one light binding layer step (S300) on one first substrate, and form a template step (S200) with a upgrading layer and carry out simultaneously earlier.Then, proceed the pressing template and first substrate again and solidify light binding layer step (S400), divest template to form a wall step (S500), form one second record lamination step (S600) on wall, and engage one second substrate step (S700) on the second record lamination.
Then, please refer to Fig. 5, with the template 30 of explanation according to preferred embodiment of the present invention.
As shown in Figure 5, template 30 is used for the manufacturing of a media for storing optical information 20, and template 30 comprises a substrate 31, reaches a upgrading layer 32.
Upgrading layer 32 is arranged on the substrate 31, and upgrading layer 32 utilizes a solvent application on substrate 31, forms through spontaneous evaporation or oven dry back.In the present embodiment, upgrading layer 32 is a solvent molecule layer, wherein, solvent is selected from tetrafluoropropanol, octafluoropentanol, methyl alcohol, ethanol, propyl alcohol, normal butyl alcohol, butyl alcohol-tert, n-amyl alcohol, n-hexyl alcohol, 2-methoxyl-ethanol, 2-propoxyl group-ethanol, 2-butoxy-ethanol, propyl ether, butyl ether, amyl ether, cyclohexane, methylcyclohexane, ethyl cyclohexane, propyl cyclohexane and 1, the 2-dimethyl cyclohexane at least one of them.
Utilize the upgrading layer 32 of different solvents, can change the polarity on template 30 surfaces, in order to divesting of template 30 to form.When wall 24 is nonpolar macromolecule, then can select to be coated with the strong solvent of polarity and form upgrading layer 32, it for example is alcohols, after pervaporation or oven dry, still can stay some solvent molecule layers on substrate 31, alcohols with hydroxyl (OH group) then expose on template 30 surfaces, make the surface of template 30 become polar surfaces, so can separate with nonpolar wall 24 easily.And upgrading layer 32 solvent select for use the solvent with wall 24 opposed polarities, polarity to differ more better.Certainly, wall 24 also can be the polarity macromolecule, and upgrading layer 32 then selects for use nonpolar solvent to form.
In sum, the manufacture method of template of the present invention and media for storing optical information, template have a upgrading layer.Compared with prior art, the manufacture method of template of the present invention and media for storing optical information, the upgrading layer can change the polarity of template surface, makes it present the polarity opposite or different with wall, and then reduces the adhesion between wall and the template.So when divesting template, required to divest strength less, be difficult for taking place because wall and template between adhesion excessive, and make the problem that the wall fragmentation is peeled off; It is excessive because divest the strength of template also to be difficult for generation first organic dye layer or first reflection horizon, and the phenomenon of separating with first substrate.Thus, can promote the yield of product, and then also reduce production cost.
The above only is an illustrative, but not is restricted.Anyly do not break away from spirit of the present invention and category, and, all should be contained in the scope of claims its equivalent modifications of carrying out or change.
Claims (11)
1. a template is used for the manufacturing of a media for storing optical information, and this media for storing optical information has a wall, it is characterized in that, this template comprises:
One substrate, it has plural prerecording ditch groove; And
One upgrading layer, it is arranged on this substrate, and this upgrading layer is a solvent molecule layer, and the polarity of this upgrading layer and the polarity of this wall are inequality.
2. template as claimed in claim 1, wherein, this media for storing optical information is for writing dispensable mould single-surface double-layer Video CD.
3. template as claimed in claim 1, wherein, the material of this substrate be selected from polycarbonate, polymethylmethacrylate, glass, and metal one of them.
4. template as claimed in claim 1, wherein, this solvent is selected from tetrafluoropropanol, octafluoropentanol, methyl alcohol, ethanol, propyl alcohol, normal butyl alcohol, butyl alcohol-tert, n-amyl alcohol, n-hexyl alcohol, 2-methoxyl-ethanol, 2-propoxyl group-ethanol, 2-butoxy-ethanol, propyl ether, butyl ether, amyl ether, cyclohexane, methylcyclohexane, ethyl cyclohexane, propyl cyclohexane and 1, the 2-dimethyl cyclohexane at least one of them.
5. the manufacture method of a media for storing optical information is characterized in that, comprises:
Form one first record lamination on one first substrate;
Form one and have the template of a upgrading layer;
Be coated with a light binding layer;
This template of pressing and this first substrate;
Solidify this light binding layer, and divest this template to form a wall, wherein, the polarity of this upgrading layer and the polarity of this wall are inequality;
Form one second record lamination on this wall; And
Engage one second substrate on this second record lamination.
6. the manufacture method of media for storing optical information as claimed in claim 5, wherein, this first record lamination comprises one first recording layer, and one first reflection horizon.
7. the manufacture method of media for storing optical information as claimed in claim 5 wherein, more comprises:
Be coated with a solvent on this substrate, after evaporation or oven dry, form this upgrading layer.
8. the manufacture method of media for storing optical information as claimed in claim 5, wherein, the material of this upgrading layer is selected from tetrafluoropropanol, octafluoropentanol, methyl alcohol, ethanol, propyl alcohol, normal butyl alcohol, butyl alcohol-tert, n-amyl alcohol, n-hexyl alcohol, 2-methoxyl-ethanol, 2-propoxyl group-ethanol, 2-butoxy-ethanol, propyl ether, butyl ether, amyl ether, cyclohexane, methylcyclohexane, ethyl cyclohexane, interior basic ring hexane and 1, the 2-dimethyl cyclohexane at least one of them.
9. the manufacture method of media for storing optical information as claimed in claim 5, wherein, this second record lamination comprises one second recording layer, and one second reflection horizon.
10. the manufacture method of media for storing optical information as claimed in claim 5 wherein, more comprises:
Be coated with a joint glue on this second record lamination.
11. the manufacture method of media for storing optical information as claimed in claim 5, wherein, this second record lamination comprises one second recording layer, reaches one second reflection horizon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100698185A CN100372011C (en) | 2004-07-09 | 2004-07-09 | Method of mfg. form and optical information storage medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100698185A CN100372011C (en) | 2004-07-09 | 2004-07-09 | Method of mfg. form and optical information storage medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1719529A CN1719529A (en) | 2006-01-11 |
| CN100372011C true CN100372011C (en) | 2008-02-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100698185A Expired - Fee Related CN100372011C (en) | 2004-07-09 | 2004-07-09 | Method of mfg. form and optical information storage medium |
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| CN (1) | CN100372011C (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114512150A (en) * | 2020-11-16 | 2022-05-17 | 华为技术有限公司 | Optical storage medium, optical storage medium preparation method and system |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10106039A (en) * | 1996-09-30 | 1998-04-24 | Toshiba Corp | Information recording medium and formation of information recording medium |
| CN1196817A (en) * | 1996-06-28 | 1998-10-21 | 汤姆森多媒体公司 | Optical disk compatible with two different reading system |
| CN1253068A (en) * | 1998-11-02 | 2000-05-17 | 罗姆和哈斯公司 | Method and equipment for forming plastic sheet |
-
2004
- 2004-07-09 CN CNB2004100698185A patent/CN100372011C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1196817A (en) * | 1996-06-28 | 1998-10-21 | 汤姆森多媒体公司 | Optical disk compatible with two different reading system |
| JPH10106039A (en) * | 1996-09-30 | 1998-04-24 | Toshiba Corp | Information recording medium and formation of information recording medium |
| CN1253068A (en) * | 1998-11-02 | 2000-05-17 | 罗姆和哈斯公司 | Method and equipment for forming plastic sheet |
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| CN1719529A (en) | 2006-01-11 |
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