CN100361797C - Method for preparing brake sheets made from macromolecule alloy - Google Patents
Method for preparing brake sheets made from macromolecule alloy Download PDFInfo
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- CN100361797C CN100361797C CNB2005100261144A CN200510026114A CN100361797C CN 100361797 C CN100361797 C CN 100361797C CN B2005100261144 A CNB2005100261144 A CN B2005100261144A CN 200510026114 A CN200510026114 A CN 200510026114A CN 100361797 C CN100361797 C CN 100361797C
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Abstract
The present invention discloses a preparing method for a macromolecule alloy brake sheet. The method comprises the following steps: step 1, cutting and drying ethylene propylene rubber for use; step 2, plasticating the rubber sheets obtained from step 1 and silicon rubber with an open mill with roll temperature of 40 to 50 DEG C and roll nip of 0.5 to 1mm; step 3, adding a complexing agent into the plasticated rubber, adjusting the roll temperature to 50 to 60 DEG C and the roll nip to 1 to 2mm, mixing the plasticated rubber and the complexing agent, mixing the mixed rubber and unsaturated polyester added short fiberglas for 10 to 20 minutes with the open mill with the roll temperature of 50 to 60 DEG C and the roll nip of 1 to 2mm, wherein the mass ratio of the ethylene propylene rubber, the silicon rubber to the unsaturated polyester added short fiberglas is (1 to 2): (5 to 3): 6; step 4, vulcanizing the blending materials obtained from step 3 at temperature of 165 to 170 DEG C and atmospheric pressure of 8 to 12MPa for 20 to 30 minutes. The preparing method of the present invention has a simple technology and high productive efficiency; brake sheet materials prepared by the present invention has the advantages of heat resistance, wear resistance, high mechanical strength, better elasticity, etc.
Description
Technical field
The present invention relates to a kind of preparation method of brake block, particularly relating to a kind of is that primary raw material, unsaturated polyester (UP) (DMC) are the preparation method of the composite material brake block of reinforcing agent with rubber.
Background technology
The brake block of using on the at present domestic and international automobile mainly divides two kinds: the one, and metal brake block; The 2nd, asbestos are mixed the brake block of metal powder.The higher relatively lightness that is unfavorable for automobile of metal brake block weight, and asbestos metal powder brake block intensity is lower, wears no resistance, and also poisonous.These two kinds of brake blocks hinder the auto industry develop rapidly.Therefore, scientist both domestic and external is seeking a kind of new traditional brake pad material of material substitution.
Summary of the invention
Technical problem to be solved by this invention provides a kind of preparation method of brake sheets made from macromolecule alloy, to remedy the deficiencies in the prior art and defective, meets the demands of production and living.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of preparation method of brake sheets made from macromolecule alloy comprises the steps: that (1) cut glue, dry for standby with EP rubbers (EPDM); (2) film that obtains of step (1) and silicon rubber are to plasticate 8～10 minutes in the mill of 0.5～1 millimeter of 40～50 ℃, roll spacing in the roller temperature, obtain broken-down rubber; (3) in broken-down rubber, add compounding ingredient, adjust the roller temperature and be 1～2 millimeter of 50～60 ℃, roll spacing, mixing 25～30 minutes, make elastomeric compound; Be in the mill of 1～2 millimeter of 50～60 ℃, roll spacing mixing 10～20 minutes with elastomeric compound, the unsaturated polyester (UP) (DMC) of dosing staple glass fibre in the roller temperature, the DMC/EPDM/ silicon rubber intermingling material that obtains mixing, parked 4～12 hours, wherein, EP rubbers, silicon rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 2～5: 3～6; (4) intermingling material that step (3) is obtained vulcanized 20～30 minutes under 165～170 ℃, 8～12MPa condition.
As optimized technical scheme: described silicon rubber is methyl vinyl silicone rubber;
Described compounding ingredient is the composition of carbon black, zinc oxide, vulcanization accelerator, vulcanizing agent, and its quality proportioning is: 40: 5: 0.8: 5;
Described vulcanization accelerator is a dibenzothiazyl disulfide; Described vulcanizing agent is a kind of or its mixture in cumyl peroxide, the dibenzoyl peroxide; The described unsaturated polyester (UP) of dosing staple glass fibre is a BMC of dosing the unsaturated polyester (UP) of staple glass fibre, and its English name is Dough-modelingcompound, abbreviates DMC as; Described EP rubbers is ethylene propylene diene rubber.
The invention has the beneficial effects as follows: preparation method's technology is simple, production efficiency is high, advantage such as the brake pad material of preparation is heat-resisting, wear-resisting, mechanical strength is high, nontoxic, good toughness.Enough pair of roller mill of described alloy material energy and vulcanizer carry out the one-shot forming preparation, have reduced the input of brake block equipment, have simplified its production technology.The prepared alloy material of the present invention can be in military fields such as automobile, space flight and aviations as framework material or case material.
The specific embodiment
Below in conjunction with specific embodiment the present invention is further elaborated.
Embodiment 1
Preparation was promptly cut glue, oven dry back and the methyl vinyl silicone rubber 10min that plasticates before ethylene propylene diene rubber plasticated on the roller temperature is 40 ℃, the mill of roll spacing 1mm; Add prescription then and be carbon black: zinc oxide: dibenzothiazyl disulfide, cumyl peroxide=40: 5: 0.8: 5 compounding ingredient, adjusting the roller temperature is 50 ℃, roll spacing 1mm, mixing 30min makes elastomeric compound; Be mixing again 10min on 50 ℃, the mill of roll spacing 1mm with elastomeric compound, the unsaturated polyester (UP) (DMC) of dosing staple glass fibre in the roller temperature then, the DMC/EPDM/ silicon rubber intermingling material that obtains mixing is parked 4h.Wherein, EP rubbers, methyl vinyl silicone rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 3: 4.Be that 170 ℃, pressure are sulfuration 30 minutes under the condition of 10MPa with the sizing material that mixes in temperature at last.
The preparation method of embodiment 2～5 is identical with embodiment 1, and process conditions are as follows respectively:
Embodiment 2
The prescription of compounding ingredient: carbon black, zinc oxide: dibenzothiazyl disulfide, cumyl peroxide=40: 5: 0.8: 5; EP rubbers, methyl vinyl silicone rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 3: 4; 8min plasticates under 50 ℃, roll spacing 0.5mm condition; Mixing 30min under 50 ℃, roll spacing 1mm condition; Under 165 ℃, 12MPa condition, vulcanize 30min.
Embodiment 3
The prescription of compounding ingredient: carbon black, zinc oxide: dibenzothiazyl disulfide, cumyl peroxide=40: 5: 0.8: 5; EP rubbers, methyl vinyl silicone rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 2: 3; 8min plasticates under 50 ℃, roll spacing 0.8mm condition; Mixing 25min under 55 ℃, roll spacing 1.5mm condition; Under 165 ℃, 12MPa condition, vulcanize 30min.
Embodiment 4
The prescription of compounding ingredient: carbon black, zinc oxide: dibenzothiazyl disulfide, dibenzoyl peroxide=40: 5: 0.8: 5; EP rubbers, methyl vinyl silicone rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 5: 6; 10min plasticates under 50 ℃, roll spacing 1mm condition; Mixing 30min under 60 ℃, roll spacing 1mm condition; Under 170 ℃, 8MPa condition, vulcanize 20min.
Embodiment 5
The prescription of compounding ingredient: carbon black, zinc oxide: dibenzothiazyl disulfide, dibenzoyl peroxide=40: 5: 0.8: 5; EP rubbers, methyl vinyl silicone rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are: 1: 3: 4; 10min plasticates under 50 ℃, roll spacing 1mm condition; Mixing 30min under 60 ℃, roll spacing 2mm condition; Under 170 ℃, 11MPa condition, vulcanize 30min.
Measure according to GB, the partial properties data of embodiment 2～5 and reference examples (embodiment 0) are more as shown in table 1.Can find out from table 1: the prepared material of the present invention is heat-resisting, wear-resisting, mechanical strength is high, good toughness.
Table 1 embodiment 2-5
| The embodiment numbering | 2 | 3 | 4 | 5 | 0 |
| Breaking strength/200 ℃ * 48h of MPa Shao Er A type hardness tester elongation at break/% hot air aging elongation at break variation/% Shao Er A type hardness tester variation abrasion/(cm3/1.61km) | 19 81 34 -3 1 0.1 | 20 85 29 -3 1 0.1 | 19 87 28 -2 1 0.1 | 21 89 28 -2 1 0.1 | 14 89 10 -3 1 0.2 |
Claims (7)
1. the preparation method of a brake sheets made from macromolecule alloy is characterized in that, comprises the steps: that (1) cut glue, dry for standby with EP rubbers; (2) film that obtains of step (1) and silicon rubber were plasticated 8～10 minutes on the roller temperature is 40～50 ℃, the mill of roll spacing 0.5～1mm, obtained broken-down rubber; (3) add compounding ingredient in broken-down rubber, adjusting the roller temperature is 50～60 ℃, roll spacing 1～2mm, mixing 25～30 minutes, makes elastomeric compound; Is on 50～60 ℃, the mill of roll spacing 1～2mm mixing 10～20 minutes with elastomeric compound, the unsaturated polyester (UP) of dosing staple glass fibre in the roller temperature, the intermingling material that obtains mixing, parked 4～12 hours, wherein, EP rubbers, silicon rubber and the mass ratio of dosing the unsaturated polyester (UP) of staple glass fibre are 1: 2～5: 3～6; (4) intermingling material that step (3) is obtained vulcanized 20～30 minutes under 165～170 ℃, 8～12MPa condition.
2. preparation method according to claim 1 is characterized in that: described silicon rubber is methyl vinyl silicone rubber.
3. preparation method according to claim 1 is characterized in that: described compounding ingredient is the composition of carbon black, zinc oxide, vulcanization accelerator, vulcanizing agent, and its quality proportioning is 40: 5: 0.8: 5.
4. preparation method according to claim 3 is characterized in that: described vulcanization accelerator is a dibenzothiazyl disulfide.
5. preparation method according to claim 3 is characterized in that: described vulcanizing agent is a kind of or its mixture in cumyl peroxide, the dibenzoyl peroxide.
6. preparation method according to claim 1 is characterized in that: the described unsaturated polyester (UP) of dosing staple glass fibre is a BMC of dosing the unsaturated polyester (UP) of staple glass fibre.
7. preparation method according to claim 1 is characterized in that: described EP rubbers is ethylene propylene diene rubber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100261144A CN100361797C (en) | 2005-05-24 | 2005-05-24 | Method for preparing brake sheets made from macromolecule alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100261144A CN100361797C (en) | 2005-05-24 | 2005-05-24 | Method for preparing brake sheets made from macromolecule alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1695914A CN1695914A (en) | 2005-11-16 |
| CN100361797C true CN100361797C (en) | 2008-01-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100261144A Expired - Fee Related CN100361797C (en) | 2005-05-24 | 2005-05-24 | Method for preparing brake sheets made from macromolecule alloy |
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| Country | Link |
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| CN (1) | CN100361797C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110185713A (en) * | 2019-07-10 | 2019-08-30 | 贝德科技有限公司 | A kind of Diesel engine pump check shaft coupling |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082559A (en) * | 1992-07-17 | 1994-02-23 | 山东省沂蒙制动材料总厂 | Semi-metallic asbestos-free sedan brake disk and production method thereof |
| CN1165255A (en) * | 1996-05-10 | 1997-11-19 | 董文瑞 | Brake plate |
| CN1203326A (en) * | 1997-06-20 | 1998-12-30 | 宋勤正 | Asbestos-free friction material and producing method thereof |
-
2005
- 2005-05-24 CN CNB2005100261144A patent/CN100361797C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082559A (en) * | 1992-07-17 | 1994-02-23 | 山东省沂蒙制动材料总厂 | Semi-metallic asbestos-free sedan brake disk and production method thereof |
| CN1165255A (en) * | 1996-05-10 | 1997-11-19 | 董文瑞 | Brake plate |
| CN1203326A (en) * | 1997-06-20 | 1998-12-30 | 宋勤正 | Asbestos-free friction material and producing method thereof |
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|---|---|
| CN1695914A (en) | 2005-11-16 |
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Granted publication date: 20080116 Termination date: 20100524 |