CN100358839C - High-crystal structure cordierite-mullite kiln furniture, kiln refractory product and roasting process - Google Patents
High-crystal structure cordierite-mullite kiln furniture, kiln refractory product and roasting process Download PDFInfo
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- CN100358839C CN100358839C CNB2005101019415A CN200510101941A CN100358839C CN 100358839 C CN100358839 C CN 100358839C CN B2005101019415 A CNB2005101019415 A CN B2005101019415A CN 200510101941 A CN200510101941 A CN 200510101941A CN 100358839 C CN100358839 C CN 100358839C
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- 239000013078 crystal Substances 0.000 title claims abstract description 57
- 229910052863 mullite Inorganic materials 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 116
- 239000000203 mixture Substances 0.000 claims abstract description 73
- 239000002131 composite material Substances 0.000 claims abstract description 52
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 238000005245 sintering Methods 0.000 claims abstract description 18
- 230000006911 nucleation Effects 0.000 claims abstract description 7
- 238000010899 nucleation Methods 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 80
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 72
- 239000000126 substance Substances 0.000 claims description 51
- 230000009970 fire resistant effect Effects 0.000 claims description 42
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 37
- 239000000395 magnesium oxide Substances 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 23
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 18
- 239000004411 aluminium Substances 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000003595 mist Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 8
- -1 attaclay Substances 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 230000035939 shock Effects 0.000 abstract description 9
- 239000011159 matrix material Substances 0.000 abstract description 8
- 238000005728 strengthening Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000010304 firing Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000011449 brick Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229910052878 cordierite Inorganic materials 0.000 description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
- 238000004134 energy conservation Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000010587 phase diagram Methods 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 208000035126 Facies Diseases 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
The trade mark | CMA | CMB | CMC | CMD | CME | ||
Volume density | ≥2.00 | ≥1.95 | ≥1.90 | ≥2.00 | ≥2.05 | ||
Apparent porosity % | ≤26 | ≤28 | ≤30 | ≤26 | ≤28 | ||
The coefficient of expansion (25 ℃~1000 ℃) 10 7K i | ≤30 | ≤24 | ≤23 | ≤26 | ≤30 | ||
Load softening point (T0.6) ℃ | ≥1410 | ≥1390 | ≥1380 | ≥1420 | ≥1430 | ||
Folding strength MPa | Normal temperature | ≥12 | ≥8 | ≥8 | ≥9 | ≥10 | |
High temperature | ≥10 | ≥7 | ≥5 | ≥8 | ≥9 | ||
Thermal shock resistance | *** | *** | **** | *** | *** | ||
Maximum operating temperature ℃ | In tunnel furnace | 1250 | 1220 | 1150 | 1250 | 1280 | |
In shuttle kiln | 1250 | 1220 | 1150 | 1250 | 1280 | ||
In roller kiln | 1280 | 1280 | 1250 | 1280 | Be not suitable for | ||
Remarks: * crosses many more, and the expression thermal shock resistance is good more |
Claims (2)
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CNB2005101019415A CN100358839C (en) | 2005-12-09 | 2005-12-09 | High-crystal structure cordierite-mullite kiln furniture, kiln refractory product and roasting process |
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CNB2005101019415A CN100358839C (en) | 2005-12-09 | 2005-12-09 | High-crystal structure cordierite-mullite kiln furniture, kiln refractory product and roasting process |
Publications (2)
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CN1785909A CN1785909A (en) | 2006-06-14 |
CN100358839C true CN100358839C (en) | 2008-01-02 |
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Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100567412C (en) * | 2006-08-31 | 2009-12-09 | 宝山钢铁股份有限公司 | Prevent coated material of carbon deposition of coke oven and preparation method thereof |
CN101456748B (en) * | 2008-11-27 | 2012-05-23 | 中钢集团洛阳耐火材料研究院有限公司 | Pushing plate for soft magnetic ferrite sintering kiln and method for producing the same |
CN101439979B (en) * | 2008-12-13 | 2011-06-29 | 郑州顺兴耐火材料有限公司 | High refractoriness under load and thermal shock resistant fireproof brick |
CN102079657B (en) * | 2009-11-27 | 2014-10-08 | 韦国文 | Method for producing and preparing high-aluminum setter plate kiln furniture with high thermal shock resistance |
CN101792321B (en) * | 2010-02-06 | 2012-07-04 | 揭东县热金宝新材料科技有限公司 | Energy-saving type high-temperature high-thermal shock resistance kiln furnace structural material prepared by using waste fireproof kiln furniture and method for preparing same |
CN101786893B (en) * | 2010-02-06 | 2012-07-04 | 揭东县热金宝新材料科技有限公司 | Energy-saving high heat quake-resistant kiln structure material prepared by utilizing waste refractory kiln furniture and method thereof |
CN102276239B (en) * | 2011-05-27 | 2013-03-20 | 湖北省烟叶公司 | Heat exchanger ceramic material for bulk tobacco flue-curing house and preparation method thereof |
CN102491773B (en) * | 2011-12-15 | 2013-08-28 | 广东热金宝新材料科技有限公司 | High-crystal mullite-iolite high-temperature industrial ceramic and production method for same |
CN103769528B (en) * | 2012-10-25 | 2016-02-17 | 成霖企业股份有限公司 | There is the ceramic-mould composition and method of making the same of cold-and-heat resistent sudden turn of events character |
CN102976780A (en) * | 2012-12-10 | 2013-03-20 | 广东顺祥陶瓷有限公司 | Energy-saving kiln material and preparation method thereof |
CN103936406A (en) * | 2013-01-22 | 2014-07-23 | 福建省德化县创捷窑具有限公司 | Iolite-mullite deck and preparation method thereof |
CN103626504B (en) * | 2013-11-29 | 2015-07-22 | 湖南湘钢瑞泰科技有限公司 | Combined brick and preparation method thereof |
CN104030697A (en) * | 2014-05-26 | 2014-09-10 | 浙江立鑫高温耐火材料有限公司 | Support brick |
CN104200876A (en) * | 2014-08-09 | 2014-12-10 | 张传良 | Method for preparing magnesium oxide filler for fireproof cable |
CN105272317A (en) * | 2015-11-19 | 2016-01-27 | 长兴县新宏信耐火材料有限公司 | Preparation method of andalusite and mullite composite brick |
CN105294128A (en) * | 2015-11-19 | 2016-02-03 | 长兴县新宏信耐火材料有限公司 | Andalusite-mullite composite material brick |
CN105801098A (en) * | 2016-04-19 | 2016-07-27 | 福建省德化县创捷窑具有限公司 | Economical and environment-friendly cordierite-mullite kiln furniture composite material and manufacturing method thereof |
CN107619262B (en) * | 2017-08-01 | 2020-08-14 | 德化县凯得利工艺品有限公司 | Bone china and preparation method thereof |
CN109293351A (en) * | 2018-09-28 | 2019-02-01 | 广东山摩新材料科技有限公司 | A kind of dichroite-mullite refractory slab and preparation method thereof |
CN109320222B (en) * | 2018-11-09 | 2021-06-11 | 洛阳索莱特材料科技有限公司 | Preparation method of cordierite-mullite ceramic sagger |
CN109851325A (en) * | 2019-01-21 | 2019-06-07 | 福建省威尔陶瓷股份有限公司 | A kind of high heat-resisting ceramic product and preparation method thereof |
CN112390635A (en) * | 2020-10-26 | 2021-02-23 | 醴陵市勇博精密陶瓷有限公司 | High-strength hollow edge surrounding brick for kiln car and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08283073A (en) * | 1995-04-11 | 1996-10-29 | Ngk Insulators Ltd | Kiln tool |
EP1036294A1 (en) * | 1997-11-26 | 2000-09-20 | ICRA S.p.A. | Ceramic materials for the manufacture of refractory rollers and other supports |
CN1448366A (en) * | 2003-04-28 | 2003-10-15 | 福州大学 | Method of making jolite and mullite refractory using industrial sludge from aluminium section plant |
CN1559985A (en) * | 2004-02-24 | 2005-01-05 | 北京科技大学 | Light fire resisting brick of iolite-mulbite and preparation process thereby |
-
2005
- 2005-12-09 CN CNB2005101019415A patent/CN100358839C/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08283073A (en) * | 1995-04-11 | 1996-10-29 | Ngk Insulators Ltd | Kiln tool |
EP1036294A1 (en) * | 1997-11-26 | 2000-09-20 | ICRA S.p.A. | Ceramic materials for the manufacture of refractory rollers and other supports |
CN1448366A (en) * | 2003-04-28 | 2003-10-15 | 福州大学 | Method of making jolite and mullite refractory using industrial sludge from aluminium section plant |
CN1559985A (en) * | 2004-02-24 | 2005-01-05 | 北京科技大学 | Light fire resisting brick of iolite-mulbite and preparation process thereby |
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CN1785909A (en) | 2006-06-14 |
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Owner name: GUANGDONG REJINBAO SPECIAL REFRACTORY INDUSTRIAL C Owner name: REJINBAO NEW MATERIAL TECHNOLOGY CO., LTD., JIEDON Free format text: FORMER OWNER: CHEN WENYANG Effective date: 20101207 |
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Free format text: CORRECT: ADDRESS; FROM: 515500 INSIDE OF JIEDONG REJINBAO SPECIAL REFRACTORY INDUSTRIAL CO., LTD., WEST INDUSTRIAL AREA, JIEDONG COUNTRY, GUANGDONG PROVINCE TO: 515500 WANGDI, QUXI, JIEDONG COUNTY, JIEYANG CITY, GUANGDONG PROVINCE |
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Effective date of registration: 20101207 Address after: 515500, Guangdong County, Jieyang City, Jiedong Province Qu River Network Co-patentee after: Guangdong ReJinBao Special Refractory Industrial Co., Ltd. Patentee after: Jiedong ReJinBao New Materials Science and Technology Co., Ltd. Co-patentee after: Chen Huangzhong Address before: Campbell 515500 Guangdong province Jiedong County West Industrial Zone of Jiedong County Hot special refractory Co. Ltd. in Patentee before: Chen Wenyang |