CN100352634C - Shaving board without formaldehyde and producing process thereof - Google Patents

Shaving board without formaldehyde and producing process thereof Download PDF

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Publication number
CN100352634C
CN100352634C CNB031433073A CN03143307A CN100352634C CN 100352634 C CN100352634 C CN 100352634C CN B031433073 A CNB031433073 A CN B031433073A CN 03143307 A CN03143307 A CN 03143307A CN 100352634 C CN100352634 C CN 100352634C
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CN
China
Prior art keywords
parts
polymethylene polyisocyanates
water soluble
weight portion
soluble adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB031433073A
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Chinese (zh)
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CN1524669A (en
Inventor
袁运增
刘志英
段志周
马风新
崔景华
马保林
石改成
张国华
韩运山
李俊平
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Shanghai Mei Lian commercial matters information Counseling Service Co., Ltd
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张国华
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Publication date
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Priority to CNB031433073A priority Critical patent/CN100352634C/en
Publication of CN1524669A publication Critical patent/CN1524669A/en
Application granted granted Critical
Publication of CN100352634C publication Critical patent/CN100352634C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention relates to a shaving board without formaldehyde and a production method thereof. The present invention is characterized in that the raw materials comprise wooded dry shavings, polymetyhlene polyphenyl isocyanate and an isocyanate water soluble adhesive. The present invention has the advantages of reasonable and fine ingredient and simple and scientific production method. A shaving board produced by the present invention does not contain poisonous and harmful substances such as free formaldehyde, etc. The formaldehyde emission is 0 mg/100g; simultaneously, the water resisting property and the bonding strength of the shaving board are greatly improved; the present invention is an ideal shaving board for interior decoration and exterior decoration.

Description

Zero-formaldehyde particleboard and working method
One, technical field
The present invention relates to a kind of particieboard and production method thereof, particularly a kind of zero-formaldehyde particleboard and working method.
Two, background technology
The present indoor category-A environment-friendly type shaving board of E1 level low toxicity, though free formaldehyde release has wherein reached and has been lower than domestic and world's like product standard, but wherein still contain the existence of harmful substances such as formaldehyde, to exist latent threat in indoor use to health; Can bring out diseases such as multiple cancer, leukaemia in environment inhabitation or activity that formaldehyde is arranged for a long time, this is that existing particieboard uses in indoor deficiency.
Three, summary of the invention
The objective of the invention is to invent a kind of zero-formaldehyde particleboard and working method, this particieboard will no longer contain poisonous and harmful substances such as free formaldehyde, burst size of methanal is 0mg/100g, simultaneously its resistance to water and glue-joint strength are greatly improved, in order to overcome the deficiency of existing particieboard and production method thereof.
Purpose of the present invention can realize by following embodiment: the weight portion of raw material of the present invention includes the wooden dried wood shavings of 680-720 part, many benzene of polymethylene polyisocyanates of 25-30 part is the isocyanates water soluble adhesive of PAPI and 65-70 part, wherein carry out in the hot-forming process at described particieboard, utilize moisture content and many benzene of polymethylene polyisocyanates in the isocyanates water soluble adhesive under 170 ℃ hot conditions, to react curing, thereby make many benzene of polymethylene polyisocyanates some wooden dried wood shavings molding bondeds.
The weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 680 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 25 parts are PAPI and 65 parts.
The weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 700 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 27 parts are PAPI and 67 parts.
The weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 720 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 30 parts are PAPI and 70 parts.
Life side of the present invention method is: the making of A, wooden dried wood shavings: chip, flaking, screening, drying, to screen, make its weight portion be 680-720 part, feeding warehouse; B, weight portion are that the polymethylene polyisocyanates of 25-30 part be PAPI with weight portion is that the isocyanates water soluble adhesive of 65-70 part mixes the miscible glue that becomes; C, above-mentioned glue is sprayed to the wood particle surface, and be penetrated into wood particle inside, form the adhesive overlay film on the wood particle surface; D, mat formation and hot pressing, in hot-forming process, utilize moisture content and many benzene of polymethylene polyisocyanates in the isocyanates water soluble adhesive under 170 ℃ hot conditions, to react curing, thereby make many benzene of polymethylene polyisocyanates with some wood particle molding bondeds, pass through sawing, sanding, make particieboard; E, employing spray to presed-steel plate and wood particle shaping slab surface formation barrier film with remover, prevent that many benzene of polymethylene polyisocyanates from bonding together at following wood particle of hot conditions and presed-steel plate.
Advantage of the present invention is: 1, do not contain the formaldehyde material; 2, resistance to water is strong, traditional E1 level shaving board is pressed the thickness swelling rate check in the GB1T-92 standard, be 5-8% generally speaking, and particleboard with zero-formaldehyde emission is through detecting with quadrat method, thickness swelling rate only is 0.8-1% after 8 hours, soaking the back thickness swelling rate in 24 hours only is 8-9.5%, and this is that traditional E1 level moisture resistant chipboard is all inaccessiable; 3, glue-joint strength is good, product is not yielding in storing and using, because meeting water under hot conditions, many benzene of polymethylene polyisocyanates solidifies rapidly, there is not the adhesive hydrolysis when forming cooling behind the product, so this product one-shot forming intensity is better, use to store distortion not occur; 4, needn't use waterproofing agent, curing agent etc. to add assistant agent, simplify product manufacture aborning.
Four, description of drawings
The present invention is described in further detail below in conjunction with accompanying drawing.
Fig. 1 is technological process of production figure of the present invention
Five, the specific embodiment
Be three embodiment of parts by weight of raw materials of the present invention below:
1, the weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 680 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 25 parts are PAPI and 65 parts.
2, the weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 700 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 27 parts are PAPI and 67 parts.
3, the weight portion of raw material of the present invention includes the isocyanates water soluble adhesive that 720 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 30 parts are PAPI and 70 parts.
The production method of above-mentioned three embodiment is with the production method of summary of the invention part.

Claims (5)

1, a kind of particleboard with zero-formaldehyde emission, it is characterized in that: the weight portion of raw material includes the wooden dried wood shavings of 680-720 part, many benzene of polymethylene polyisocyanates of 25-30 part is the isocyanates water soluble adhesive of PAPI and 65-70 part, wherein carry out in the hot-forming process at described particieboard, utilize moisture content and many benzene of polymethylene polyisocyanates in the isocyanates water soluble adhesive under 170 ℃ hot conditions, to react curing, thereby make many benzene of polymethylene polyisocyanates some wooden dried wood shavings molding bondeds.
2, particieboard according to claim 1 is characterized in that: the weight portion of raw material includes the isocyanates water soluble adhesive that 680 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 25 parts are PAPI and 65 parts.
3, particieboard according to claim 1 is characterized in that: the weight portion of raw material includes the isocyanates water soluble adhesive that 700 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 27 parts are PAPI and 67 parts.
4, particieboard according to claim 1 is characterized in that: the weight portion of raw material includes the isocyanates water soluble adhesive that 720 parts wooden dried wood shavings, many benzene of polymethylene polyisocyanates of 30 parts are PAPI and 70 parts.
5, a kind of production method of particleboard with zero-formaldehyde emission is characterized in that: the making of A, wooden dried wood shavings: chip, flaking, screening, drying, screening, making its weight portion is 680-720 part, feeding warehouse; B, weight portion are that the polymethylene polyisocyanates of 25-30 part be PAPI with weight portion is that the isocyanates water soluble adhesive of 65-70 part mixes the miscible glue that becomes; C, above-mentioned glue is sprayed to the wood particle surface, and be penetrated into wood particle inside, form the adhesive overlay film on the wood particle surface; D, mat formation and hot pressing, in hot-forming process, utilize moisture content and many benzene of polymethylene polyisocyanates in the isocyanates water soluble adhesive under 170 ℃ hot conditions, to react curing, thereby make many benzene of polymethylene polyisocyanates with some wood particle molding bondeds, pass through sawing, sanding, make particieboard; E, employing spray to presed-steel plate and wood particle shaping slab surface formation barrier film with remover, prevent that many benzene of polymethylene polyisocyanates from bonding together at following wood particle of hot conditions and presed-steel plate.
CNB031433073A 2003-09-18 2003-09-18 Shaving board without formaldehyde and producing process thereof Expired - Fee Related CN100352634C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB031433073A CN100352634C (en) 2003-09-18 2003-09-18 Shaving board without formaldehyde and producing process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB031433073A CN100352634C (en) 2003-09-18 2003-09-18 Shaving board without formaldehyde and producing process thereof

Publications (2)

Publication Number Publication Date
CN1524669A CN1524669A (en) 2004-09-01
CN100352634C true CN100352634C (en) 2007-12-05

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105082316A (en) * 2015-07-07 2015-11-25 鸿伟木业(仁化)有限公司 Production process for eucalyptus veneer formaldehyde-free shaving board
CN105922427A (en) * 2016-05-03 2016-09-07 福建农林大学 Zero-formaldehyde particle board and preparation method thereof
CN106182310A (en) * 2016-07-12 2016-12-07 福建农林大学 A kind of be suitable to particleboard with zero-formaldehyde emission engraving Milling Machining and preparation method thereof
CN106182327A (en) * 2016-07-12 2016-12-07 福建农林大学 A kind of zero formaldehyde bamboo shaving plate and preparation method thereof
CN106313199A (en) * 2016-08-15 2017-01-11 宁波中科朝露新材料有限公司 Non-formaldehyde adhesive particle board and preparation method thereof
CN109591148A (en) * 2018-12-20 2019-04-09 山东新港环保材料科技有限公司 The manufacturing process of the negative oxygen functionality particieboard of antibacterial

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061556A (en) * 1990-11-20 1992-06-03 湖南省澧县刨花板厂 A kind of artificial chipboard

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061556A (en) * 1990-11-20 1992-06-03 湖南省澧县刨花板厂 A kind of artificial chipboard

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
异氰酸酯生产轻质刨花板的研究 刘彦龙,唐朝发,刘学艳,元正龙,刘培育.吉林林学院学报,第15卷第4期 1999 *
异氰酸酯胶无毒低密度杉木刨花板的制造 林巧佳,何修善,吴纯初,何勇.木材工业,第14卷第3期 2000 *
我国刨花模压制品生产工艺及设备 鲍逸培.木材加工机械,第1期 1998 *
结构人造板用二苯基甲烷二异氰酸酯(MDI)胶合剂 李远陵.木材加工机械,第3期 1995 *

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GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Hebei Golden Sunbird Panel Co., Ltd.

Assignor: Zhang Guohua

Contract fulfillment period: 2009.10.1 to 2026.9.30 contract change

Contract record no.: 2009130000242

Denomination of invention: Shaving board without formaldehyde and producing process thereof

Granted publication date: 20071205

License type: Exclusive license

Record date: 2009.11.6

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.10.1 TO 2026.9.30; CHANGE OF CONTRACT

Name of requester: HEBEI SUNBIRD BOARD CO., LTD.

Effective date: 20091106

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Address after: 057250 Hebei Quzhou four Tuan agricultural high technology zone

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Address before: 057250 in Quzhou County in Hebei Province revitalization of Hebei Road No. 8 Cyberspaces board group

Patentee before: Zhang Guohua

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CF01 Termination of patent right due to non-payment of annual fee