CN100345986C - Method for extracting valence metal from copper ferrocobalt alloy - Google Patents
Method for extracting valence metal from copper ferrocobalt alloy Download PDFInfo
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- CN100345986C CN100345986C CNB2006100320518A CN200610032051A CN100345986C CN 100345986 C CN100345986 C CN 100345986C CN B2006100320518 A CNB2006100320518 A CN B2006100320518A CN 200610032051 A CN200610032051 A CN 200610032051A CN 100345986 C CN100345986 C CN 100345986C
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- 229910052802 copper Inorganic materials 0.000 title claims abstract description 76
- 239000010949 copper Substances 0.000 title claims abstract description 76
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 60
- 239000000956 alloy Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 19
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 title claims description 58
- 229910052751 metal Inorganic materials 0.000 title abstract description 7
- 239000002184 metal Substances 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 6
- 239000011707 mineral Substances 0.000 claims abstract description 6
- OBLMUVZPDITTKB-UHFFFAOYSA-N [Fe].[Co].[Cu] Chemical compound [Fe].[Co].[Cu] OBLMUVZPDITTKB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000007800 oxidant agent Substances 0.000 claims abstract description 3
- 239000002893 slag Substances 0.000 claims description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 235000017550 sodium carbonate Nutrition 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003595 mist Substances 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 5
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 4
- 235000010755 mineral Nutrition 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 4
- 229940001516 sodium nitrate Drugs 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 238000013467 fragmentation Methods 0.000 claims description 3
- 238000006062 fragmentation reaction Methods 0.000 claims description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 abstract description 37
- 229910017052 cobalt Inorganic materials 0.000 abstract description 37
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 34
- 238000002386 leaching Methods 0.000 abstract description 20
- 229910052742 iron Inorganic materials 0.000 abstract description 17
- 239000000843 powder Substances 0.000 abstract description 17
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229910001313 Cobalt-iron alloy Inorganic materials 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 230000004907 flux Effects 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 230000006698 induction Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000000889 atomisation Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 229910001361 White metal Inorganic materials 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000010969 white metal Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- RYTYSMSQNNBZDP-UHFFFAOYSA-N cobalt copper Chemical compound [Co].[Cu] RYTYSMSQNNBZDP-UHFFFAOYSA-N 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention relates to a method used to leach separating metal especial cobalt and copper from copper cobalt iron alloy. It includes the following steps: melting the alloy at 1300-1550 degree centigrade; atomizing to alloy powder by high pressure air or water vapor; mixing the alloy powder with flux to process heat treatment; using mineral acid to dissolve the cobalt and iron but remain the copper after smashing; or directly using the mineral acid while adding oxidizing agent into the atomized alloy powder. It has the advantages of simple, high leaching efficiency. And it is fit for industrialization production.
Description
Technical field
The invention belongs to a kind of method that from the copper ferro-cobalt closes, reclaims valuable metal, particularly a kind of method that adopts fairly simple technology from copper ferrocobalt alloy, to leach cobalt copper.
Background technology
Fast development along with world economy, the particularly fast development of battery functi on material, superfine powdery material and superhard material, the consumption that causes relevant nonferrous materials is also in quick growth, and particularly China very lacks and the swift and violent cobalt resource of the whole world consumption impetus.According to the incomplete statistics of safe and sound section, China has 26 tame manufacturers to produce all kinds of cobalt products with cobalt concentrate (import and domestic) approximately at present, and mostly more than 100 tons/month (metal content), total annual capacity is 15000 tons of cobalt amounts of metal to the production capacity of these enterprises.Chinese refining cobalt output in 2004 almost is 2 times in 2003 near 9000 tons, and wherein Jinchuan output accounts for 27%.China has become the whole world the 2nd big cobalt producing country, just lists after the Finland.This is very important in global cobalt market.
According to U.S. geology bureau statistics in 1997, there was abundant cobalt resource in Congo DR, about 2,000,000 t of the reserves of its cobalt resource, and there are 2,500,000 t on the reserves basis.Now, more domestic relevant enterprises carry out the processing of cobalt product depth one after another from national import cobalt ores such as Congo DR and Zambia after coming back home.But government of Congo DR will put into effect the outlet that limits this state's cobalt ore, and encouragement is resaled to external policy after cobalt ore is processed into the cobalt product.With electric furnace rich cobalt oxidation concentrate being smelted into copper-cobalt-iron alloy (contain cobalt and be the cobalt white metal more than 40%) as the Pan Da smelter of Congo DR send Belgium to reclaim cobalt; The appearance of this policy will cause passive situation to the considerable enterprise of China.
Summary of the invention
The present invention is directed to above-mentioned policy, autonomous research and development one cover has metal such as the cobalt, copper of good economic benefit and comprehensively reclaims production line, to promote the comprehensive recovery of copper ferrocobalt alloy, and and then be developing direction with battery material and ultra-fine, nano-powder material and non-ferrous metal functional materials, on the basis of work on hand, further develop various high added value materials.
Because the copper ferrocobalt alloy cupric is higher, have certain ductility, be difficult to fragmentation with general disintegrating apparatus, and the copper ferrocobalt alloy that contains certain silicate under general condition is difficult to be dissolved in mineral acid commonly used.Therefore the present invention adopts the mode that atomizes behind the alloy molten with alloy refinement, under the situation that fusing assistant, slag former exist the alloy recurring structure is changed then, forms the alloy that is soluble in mineral acid commonly used, thereby realizes the separation of ferro-cobalt copper.
Purpose of the present invention aims to provide a kind of simple for process, the leaching yield height of cobalt, iron, copper, and favourable copper ferro-cobalt white metal comprehensively reclaims, and suitability for industrialized is produced a kind of processing method that leaches the copper ferro-cobalt from copper ferrocobalt alloy.
The objective of the invention is to realize by following manner:
With cobalt-copper-iron alloy 1300-1550 ℃ of fusing, utilize high pressure gas or high-pressure water mist to change into powdered alloy, to atomize the gained powdered alloy with heat-treat after fusing assistant mixes, the copper ferrocobalt alloy recurring structure is changed, after fragmentation, ferro-cobalt realizes that with inorganic acid solution ferro-cobalt separates with copper again; Or with the atomizing the alloy powder art under the situation of oxidizer, directly use inorganic acid solution, again the copper ferro-cobalt is separated.
Utilize high pressure gas or high-pressure water mist to change into the thin powdered alloy of 80-300 order.Being atomized into the thin powdered alloy of 150-200 order is preferable selection.
Copper ferrocobalt alloy after 1300-1550 ℃ of fusing, is added slag former, after removing slag, utilize high pressure gas or high-pressure water mist to change into powdered alloy again, help the subsequent product purifying.
Described slag former is selected from one or more in yellow soda ash, sodium sulfate, SODIUMNITRATE, sodium-chlor, Repone K, lime carbonate, the calcium oxide.
Described fusing assistant is selected from one or more in yellow soda ash, sodium sulfate, SODIUMNITRATE, sodium-chlor, Repone K, the lime carbonate.
To atomize the gained powdered alloy with heat-treat after fusing assistant mixes after, will generate copper and ferro-cobalt and be crushed to the 200-400 order.Disintegrating apparatus is one or more in jaw crusher, roller crusher, horizontal crusher, ball mill, the micronizer mill.
Described heat treated temperature is greater than 750 ℃, less than 1000 ℃.Soaking time is 2-8 hour in the heat treatment process, and its heat-up rate and speed of cooling are 50-200 ℃/hour.
Described mineral acid is one or more in dilute sulphuric acid, dilute hydrochloric acid, the rare nitric acid, and volumetric concentration is less than 50%, greater than 1%.
Described oxygenant is hydrogen peroxide, sodium chlorate, Sodium Persulfate, potassium permanganate, chlorine or oxygen.
The present invention can (contain cobalt 20-50% with copper ferrocobalt alloy, iron 10-50%, copper 5-30%) heat through about 20-40 minute by hot stove of medium-frequency induction furnace or ore deposit or electric arc furnace, make alloy melting, utilize high-pressure water mist to change into the thin powdered alloy of 100 orders, reach preferable atomizing effect.
Embodiment:
Following examples are intended to illustrate the present invention rather than limitation of the invention further.
Embodiment 1
Get 50 kilograms of copper ferrocobalt alloy, utilize medium-frequency induction furnace through about 30 minutes, 1400 ℃ of fusings, add an amount of slag former (1 kilogram of yellow soda ash and 1 kilogram of sodium sulfate), after slag fallen clearly, alloy atomization is become 200 purpose alloy powders (numbering PMO-01), get 1 kilogram of PMO-01 alloy powder with high pressure water, add 100 gram yellow soda ash and 100 gram sodium sulfate, after being warming up to 850 ℃ with 50 ℃/hour, insulation is 3 hours under this temperature, is cooled to below 100 ℃ with 50 ℃/hour, be crushed to 200 orders (numbering PMO-02), to get PMO-02 powder 30 grams, add water 200 grams, add vitriol oil 20ml, 50 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 94.3%, a leaching yield of iron is 93.8%, and copper does not leach substantially.Major ingredient is a metallic copper in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 3%.
Experimental example 2
Get PMO-01 alloy powder 30 grams and add water 200 grams, add vitriol oil 20ml, add sodium chlorate 5 grams, 50 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 94.3%, a leaching yield of iron is 93.8%, and the leaching yield of copper is 92%.Major ingredient is an inorganic insoluble substance in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 3%, and the content of copper is less than 5%.
Experimental example 3
Get PMO-01 alloy powder 30 grams and add water 200 grams, add concentrated hydrochloric acid 40ml, add sodium chlorate 5 grams, 50 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 92.7%, a leaching yield of iron is 93.5%, and the leaching yield of copper is 92%.Major ingredient is an inorganic insoluble substance in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 3%, and the content of copper is less than 5%
Experimental example 4
Get PMO-01 alloy powder 30 grams and add water 200 grams, add concentrated hydrochloric acid 40ml, add hydrogen peroxide 50ml, 50 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 95.8%, a leaching yield of iron is 96.7%, and the leaching yield of copper is 94.5%.Major ingredient is an inorganic insoluble substance in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 2%, and the content of copper is less than 3%.
Embodiment 5
Get 50 kilograms of copper ferrocobalt alloy, utilize medium-frequency induction furnace through about 30 minutes, 1350 ℃ of fusings, add an amount of slag former (1 kilogram of yellow soda ash), after slag fallen clearly, alloy atomization is become 200 purpose alloy powders (numbering PMO-03), get 1 kilogram of PMO-03 alloy powder with high pressure water, add 100 gram yellow soda ash and 100 gram lime carbonate, after being warming up to 750 ℃ with 100 ℃/hour, insulation is 7 hours under this temperature, is cooled to below 100 ℃ with 100 ℃/hour, be crushed to 200 orders (numbering PMO-04), to get PMO-04 powder 30 grams, add water 200 grams, add vitriol oil 30ml, 50 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 95.3%, a leaching yield of iron is 94.8%, and copper does not leach substantially.Major ingredient is a metallic copper in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 3%.
Embodiment 6
Get 50 kilograms of copper ferrocobalt alloy, utilize medium-frequency induction furnace through about 35 minutes, 1550 ℃ of fusings, add an amount of slag former (1 kilogram of yellow soda ash and 1 kilogram of lime carbonate), after slag fallen clearly, alloy atomization is become 280 purpose alloy powders (numbering PMO-05), get 1 kilogram of PMO-05 alloy powder with high pressure water, add 200 gram yellow soda ash, after being warming up to 900 ℃ with 200 ℃/hour, insulation is 3 hours under this temperature, is cooled to below 100 ℃ with 100 ℃/hour, be crushed to 300 orders (numbering PMO-06), to get PMO-06 powder 30 grams, add water 200 grams, add vitriol oil 30ml, 80 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 96.5%, a leaching yield of iron is 95.8%, and copper does not leach substantially.Major ingredient is a metallic copper in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 3%.
Experimental example 7
Get PMO-05 alloy powder 30 grams and add water 200 grams, add concentrated hydrochloric acid 20ml, vitriol oil 25ml, add hydrogen peroxide 60ml, 60 ℃ of following stirring reactions 8 hours, filtration washing, ferro-cobalt copper content in ferro-cobalt copper and the slag in the analysis filtrate, a leaching yield that can obtain cobalt is 96.8%, and a leaching yield of iron is 95.7%, and the leaching yield of copper is 92.5%.Major ingredient is an inorganic insoluble substance in the slag, and the content of cobalt is less than 1%, and the content of iron is less than 2%, and the content of copper is less than 3%.
Claims (10)
1. method that from copper ferrocobalt alloy, leaches the copper ferro-cobalt, it is characterized in that: with copper ferrocobalt alloy 1300-1550 ℃ of fusing, utilize high pressure gas or high-pressure water mist to change into powdered alloy, to atomize the gained powdered alloy with heat-treat after solubility promoter mixes, after the fragmentation, ferro-cobalt can directly separate with copper with inorganic acid solution in the alloy again; Or with the atomizing powdered alloy under the situation of oxidizer, directly use inorganic acid solution, again the copper ferro-cobalt is separated.
2. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 1 is characterized in that: utilize high pressure gas or high-pressure water mist to change into the thin powdered alloy of 80-300 order.
3. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 1 is characterized in that: cobalt-copper-iron alloy after 1300-1550 ℃ of fusing, is added slag former, after removing slag, utilize high pressure gas or high-pressure water mist to change into powdered alloy.
4. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 3, it is characterized in that: described slag former is selected from one or more in yellow soda ash, sodium sulfate, SODIUMNITRATE, sodium-chlor, Repone K, lime carbonate, the calcium oxide.
5. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 1, it is characterized in that: described fusing assistant is selected from one or more in yellow soda ash, sodium sulfate, SODIUMNITRATE, sodium-chlor, Repone K, the calcium oxide.
6. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 1 is characterized in that: will atomize the gained powdered alloy with heat-treat after solubility promoter mixes, be crushed to the 200-400 order.
7. according to each described a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy of claim 1-6, it is characterized in that: described heat treated temperature is greater than 750 ℃, less than 1000 ℃.
8. described a kind of method that from copper ferrocobalt alloy, leaches the copper ferro-cobalt according to claim 7, it is characterized in that: soaking time is 2-8 hour in the heat treatment process, its heat-up rate and speed of cooling are 50-200 ℃/hour.
9. a kind of method that leaches the copper ferro-cobalt from copper ferrocobalt alloy according to claim 1, it is characterized in that: mineral acid is one or more in dilute sulphuric acid, dilute hydrochloric acid, the rare nitric acid, and volumetric concentration is less than 50%, greater than 1%.
10. a kind of method that leaches the copper ferro-cobalt from cobalt-copper-iron alloy according to claim 1, it is characterized in that: described oxygenant is hydrogen peroxide, sodium chlorate, Sodium Persulfate, potassium permanganate, chlorine or oxygen.
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| CNB2006100320518A CN100345986C (en) | 2006-08-04 | 2006-08-04 | Method for extracting valence metal from copper ferrocobalt alloy |
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| CNB2006100320518A CN100345986C (en) | 2006-08-04 | 2006-08-04 | Method for extracting valence metal from copper ferrocobalt alloy |
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| CN101818250B (en) * | 2009-02-27 | 2012-10-24 | 浙江华友钴业股份有限公司 | Method for processing cobalt-copper-iron alloy |
| CN101524761B (en) * | 2009-04-17 | 2010-10-13 | 戴煜 | Method for preparing raw cobalt mineral powder |
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| CN104611565A (en) * | 2014-12-24 | 2015-05-13 | 金川集团股份有限公司 | A method of selectively recovering cobalt and copper from a cobalt-copper-zinc-manganese production waste solution |
| CN105063349B (en) * | 2015-08-17 | 2017-07-07 | 长沙矿冶研究院有限责任公司 | The method that copper cobalt nickel is leached from molten alloy |
| CN107640961B (en) * | 2017-09-28 | 2020-06-23 | 江西理工大学 | Preparation method of high-thermal-conductivity aluminum oxide ceramic copper-clad plate |
| CN108977662A (en) * | 2018-07-13 | 2018-12-11 | 兰州金川新材料科技股份有限公司 | A method of cobalt chloride solution and copper-bath are prepared using ferro-cobalt |
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| WO2000073520A1 (en) * | 1999-05-27 | 2000-12-07 | Hatch Associates Ltd. | Recovery of cobalt and nickel from iron-rich mattes and alloys by leaching |
| CN1510151A (en) * | 2002-12-26 | 2004-07-07 | 中国科学院过程工程研究所 | Cobalt slag containing treating method |
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| CN101717862B (en) * | 2009-11-20 | 2011-06-08 | 湖南铠通金属有限公司 | Production process for comprehensively recovering valuable metal of copper, cobalt and iron alloy |
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