CN100339004C - Heat volatile material for preventing and controlling pests - Google Patents
Heat volatile material for preventing and controlling pests Download PDFInfo
- Publication number
- CN100339004C CN100339004C CNB2004100387133A CN200410038713A CN100339004C CN 100339004 C CN100339004 C CN 100339004C CN B2004100387133 A CNB2004100387133 A CN B2004100387133A CN 200410038713 A CN200410038713 A CN 200410038713A CN 100339004 C CN100339004 C CN 100339004C
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- Prior art keywords
- volatile material
- pest control
- carrier
- layer
- oil
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C3/00—Chairs characterised by structural features; Chairs or stools with rotatable or vertically-adjustable seats
- A47C3/18—Chairs or stools with rotatable seat
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C3/00—Chairs characterised by structural features; Chairs or stools with rotatable or vertically-adjustable seats
- A47C3/20—Chairs or stools with vertically-adjustable seats
- A47C3/30—Chairs or stools with vertically-adjustable seats with vertically-acting fluid cylinder
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
- F16F9/00—Springs, vibration-dampers, shock-absorbers, or similarly-constructed movement-dampers using a fluid or the equivalent as damping medium
- F16F9/32—Details
- F16F9/3271—Assembly or repair
Abstract
The present invention provides a heat-volatilizing material for controlling pests, in which the volatilization end point of an active ingredient can be visually recognized accurately and which has a long volatilization time of the active ingredient. A heat volatile material for controlling pests has a carrier carrying a solution of a compound represented by the formula (1) wherein R is1And R2Each represents a hydrogen atom, a methyl group or a chlorine atom, R3A polyalkylene terephthalate layer having pores, which represents a hydrogen atom, a fluorine atom, a methyl group, a methoxy group or a methoxymethyl group, is on and covers a support, wherein the support is a laminate of a base layer and an "improvement layer which makes it transparent when containing an oily liquid", and the thickness of the polyalkylene terephthalate layer is 0.002 to 0.3 mm.
Description
Technical field
The present invention relates to a kind of hot volatile material of the pest control that can use for a long time, and the method for utilizing this material pest control.
Background technology
By convention, the hot volatile material of pest control (so-called mosquito repellent pad) has been used for pest control such as mosquito and fly.The hot volatile material of this class pest control has fiber carrier or analog, carries Pesticidal compound in the above, and heating is used on heating plate.
On the other hand, in the clothes moth-proof agent field, by fading of all or part moth-proof material, the indication moth-proof material has and can be disclosed (as JP4-36123B and JP8-73301B) from visually recognizing the performance that the Pesticidal compound volatilization finishes.
In the hot volatile material of the pest control of routine, the time by heated volatile active ingredient continues about 8 hours usually, therefore need have the hot volatile material of the pest control of longer active ingredient volatilization time.In the hot volatile material of pest control with so longer active ingredient volatilization time, finish to have experienced for a long time from bringing into use to the active ingredient volatilization, therefore accurately the volatilization end point of identification active ingredient is even more important.
Summary of the invention
The hot volatile material that the purpose of this invention is to provide a kind of pest control, the volatilization end point of its active ingredient can be from accurately identifications visually, and have the lasting active ingredient volatilization time.
That is to say that the invention provides a kind of hot volatile material of pest control, it comprises the carrier of the solution of compound shown in the bearing-type (1):
R wherein
1And R
2Represent hydrogen atom, methyl or chlorine atom separately, R
3Expression hydrogen atom, fluorine atom, methyl methoxy base or methoxyl methyl, polyalkylene terephthalates layer with hole is on carrier and cover carrier, wherein carrier is the laminated material of basic unit and " improving layer that makes it become transparent when comprising oil-based liquid ", and the thickness of polyalkylene terephthalates layer is 0.002 to 0.3mm.The present invention also provides a kind of method of pest control, and this method is included in the habitat of insect or the hot volatile material of the above-mentioned pest control of infringement zone heating.
When on heating plate, heating the hot volatile material of pest control of the present invention, the volatilization time lengthening of active ingredient, and the volatilization concluding time of active ingredient is almost identical with the volatile material fading time.More particularly, adopt the polyalkylene terephthalates cover layer, the volatilization time of active ingredient is prolonged, and because the volatilization of oil-based liquid, " improving layer that when comprising oil-based liquid, makes it become transparent " by transparent to opaque variation, can be from visually recognizing the volatilization end point of active ingredient.
Description of drawings
Accompanying drawing 1 is the concrete generalized section of the hot volatile material of pest control of the present invention.
Embodiment
As shown in Figure 1, in the hot volatile material of pest control of the present invention, the solution of compound shown in the bearing-type on carrier (1), carrier is the laminated material that basic unit 1 and " improving layer that makes it become transparent when comprising oil-based liquid " 2 are formed, and 0.002 to 0.3mm porose thick polyalkylene terephthalates layer 3 of carrier apparatus covers.
Compound is known shown in the formula (1), and its example comprises 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methyl-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-ptfe benzyl 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 3-(2-methyl isophthalic acid-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxy-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxy-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxybenzyl 3-(2-methyl isophthalic acid-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester and 2,3,4,5,6-PFBBR 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.These compounds can adopt known method preparation.
Because cyclopropane ring and two key, compound has stereoisomer shown in the formula (1), can use any active isomer or isomer mixture.
The examples of solvents that is used for the solution of compound shown in the formula (1) comprises the esters solvent with 15 to 25 carbon atoms; as isopropyl palmitate, dioctyl adipate, dibutyl sebacate; acetyl tributyl citrate, di-2-ethylhexyl maleate and isopropyl myristate.
In the hot volatile material of pest control of the present invention, the solvent load shown in the formula (1) in the solution of compound is generally compound shown in 0.1 to 10 weight portion/every weight portion formula (1), preferred 0.5 to 5 weight portion.
If desired, the solution of compound can comprise antioxidant, synergist, stabilizing agent, spices etc. shown in the formula (1).
Examples of antioxidants comprises phenol antioxidant, as dibutyl hydroxy toluene, and butylated hydroxyanisole (BHA), 2,2-methylene two (4-methyl-6-tert butyl phenol), 2,6-two-tert-butyl group-4-cresols, 2-[1-(2-hydroxyl-3,5-two-tertiary pentyl phenyl) ethyl] 4,6-two-tertiary pentyl phenyl acrylate, 3,9-two [2-3-(3-tertiary butyl-4-hydroxy-5-methyl-benzyl) propionyl oxygen-1, the 1-dimethyl]-2,4,8,10-four oxygen spiral shell [55] hendecanes etc.
In the hot volatile material of pest control of the present invention, the antioxidant consumption that is included in the compound solution shown in the formula (1) is generally compound shown in 0.001 to 1 weight portion/every weight portion formula (1), preferred 0.1 to 1 weight portion.
The example of synergist comprises two-(2,3,3,3-tetrachloro propyl group) ether (S-421), N-(2-ethylhexyl) two ring [2.2.1] heptan-5-alkene-2,3-dicarboximide (MGK264), and α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene (PBO).
The example of stabilizing agent comprises ultra-violet absorber such as benzotriazole ultra-violet absorber, benzophenone ultra-violet absorber etc.
The carrier that is used for the hot volatile material of pest control of the present invention is the laminated material that its improving layer that becomes transparent is constituted by basic unit with when containing solution therein.
For example, can prepare solution by mixing required composition.
Usually, basic unit is made by the material of compound shown in can bearing-type (1), for example, and fibrous material and/or porous material.The example of fibrous material comprises paper, cardboard, and the synthetic fibers mixed paper, non-woven fabrics fiber resembles the felted terxture of textile and resembles the fabric of inorfil, and the example that comprises the porous material of porous ceramics.
With regard to the volatilization terminal point of chemical substance, from the preferred coloured basic unit of the angle that improves visual discrimination power.Prepare the coloured basic unit of this class, for example, can be original with regard to coloured fibrous material by using, by basic unit, perhaps by on substrate surface, applying or printing coloring agent with the colouring agent dip mold.
Basic unit is about 1 to 6cm tetragonal shape usually with the length of side, thickness is 0.2 to 5mm.
" improving layer that makes it become transparent when comprising oil-based liquid " is the layer that becomes transparent when comprising oil-based liquid, and be then opaque when it does not comprise oil-based liquid." improving layer that when comprising oil-based liquid, makes it become transparent " normally porous and have permeability for oil-based liquid.Here employed term " oil-based liquid " refers to the solution of the compound shown in the formula (1), or the steam of this solution evaporation formation or the steam of liquefaction.
" improving layer that makes it become transparent when comprising oil-based liquid " is by forming when comprising the mixture that oil-based liquid demonstrates the low light refraction materials constantly, for example, inorganic pigment such as amorphous silica, kaolin, calcium carbonate etc., the fine powder of organic pigment such as plastic pigments etc., or the paper pulp powder etc., and adhesive.The example of employed adhesive comprises vinyl acetate, vinyl-vinyl acetate copolymer, NBR, SBR and acrylic based emulsion or other latex.
" improving layer that makes it become transparent when comprising oil-based liquid " can be by coating, lamination in basic unit such as printing (serigraphy, hectographic printing, photogravure etc.).Usually the thickness of regulating " improving layer that makes it become transparent " when comprising oil-based liquid makes that bed thickness is 4 to 150g/m
2, preferred 10 to 60g/m
2
The mode that adopts printing is under the situation of lamination in the basic unit " improving layer that makes it become transparent when comprising oil-based liquid ", and adhesive is about usually with the ratio that shows the low light refraction materials: the demonstration low light refractive index materials of 10 to 30 weight portion adhesives/per 100 weight portions.The mode that adopts coating is under the situation of lamination in the basic unit " improving layer that makes it become transparent when comprising oil-based liquid ", and adhesive is about usually with the ratio that shows the low light refractive index materials: the demonstration low light refractive index materials of 50 weight portion adhesives/per 100 weight portions.
" improving layer that makes it become transparent when comprising oil-based liquid " can press at layers on substrates, to such an extent as to cover the whole surface of basic unit, or in basic unit, for example occur, then cover the part surface of basic unit when indicating code as " END " profiles such as " CHANGE ".
As the method for preparing the carrier of the solution of compound shown in the above-mentioned bearing-type (1), for example, with the solution impregnation of carrier with compound shown in the formula (1).With regard to the amount of compound shown in the formula (1), the amount of the solution of compound is generally 0.001 to 0.7g/1cm shown in the formula of being carried on the carrier (1)
3The carrier apparent volume.
In the hot volatile material of pest control of the present invention, the porose polyalkylene terephthalates layer of the carrier apparatus of the solution of compound shown in the bearing-type (1) covers.
The example of polyalkylene terephthalates comprises PET and polybutylene terephthalate.
Term " covering " not only comprises the mode with contact close to each other in the present invention, the polyalkylene terephthalates layer covers the situation on coverage goal (carrier) surface, and comprises that have small gap between the two the polyalkylene terephthalates layer of (for example 1cm or littler) covers the situation on coverage goal (carrier) surface.Gap between carrier and the polyalkylene terephthalates layer is at most 5mm or littler usually, preferred 3mm or littler.
The thickness of polyalkylene terephthalates layer is generally 0.002 to 3mm, and preferred 0.01 to 0.1mm.
In the hot volatile material of pest control of the present invention, the polyalkylene terephthalates layer that covers the solution carrier of compound shown in the bearing-type (1) has a hole, and active ingredient can be via this hole volatilization.
The example that the polyalkylene terephthalates cover layer has the situation in hole comprises that the polyalkylene terephthalates cover layer has the situation of cut-off parts, the polyalkylene terephthalates cover layer has many duck eyes, for example, diameter is about situation of 0.01 to 0.1mm, and the polyalkylene terephthalates cover layer is partly with the situation of permeable formation replacement with volatilization active ingredient.For ease of using, the hole in the polyalkylene terephthalates cover layer only forms in the one side towards " improving layer that makes it become transparent when comprising oil-based liquid " usually.
The hole area that forms in the polyalkylene terephthalates cover layer is generally carrier surface area about 0.01 to 10% of the solution of compound shown in the bearing-type (1), preferred about 0.03 to 3%
The carrier of the solution of compound shown in the bearing-type (1) can cover with the polyalkylene terephthalates layer, for example, adopt heat-sealing, ultrasonic sealing, or high frequency seals mode, with adhesive etc. the film or the thin slice of polyalkylene terephthalates adhered to each carrier surface; Adopt conventional resin-coated technology such as dip coated, the spraying coating is brushed etc., forms the polyalkylene terephthalates layer at carrier surface; Perhaps adopt carrier is placed the bag of being made by polyalkylene terephthalates, by heat-sealing, ultrasonic sealing, or high frequency seals mode, with airtight sacks such as adhesives.
The hot volatile material of pest control of the present invention can prepare like this, and for example, the polyalkylene terephthalates film covering carrier by the apparatus hole perhaps by covering carrier with the polyalkylene terephthalates film, forms the hole subsequently.
Preferably, in the hot volatile material of pest control of the present invention, preceding impermeable active ingredient is used with sealing-in (seal) sealing in the hole that forms in the polyalkylene terephthalates cover layer, when using this material, adopt and peel off, tear or cut off and remove sealing-in.
In the insect habitat or infringement zone (as indoor), by with heater (as heating plate) but the hot volatile material of heating pest control of the present invention to 50-200 ℃ of pest control.
In this case, the hot volatile material of pest control of the present invention is usually from basic unit's side heating.
Can adopt the example of insect of the method control of pest control of the present invention to comprise arthropods such as various harmful insect, mite and tick etc.In the middle of them, particularly flying insect comprises Diptera pest, as, mosquito (Calicidae) as culex pipiens pallens, three generations's beak culex etc.; Aedes such as Aedes aegypti, aedes albopictus etc.; Anopheles such as Anopheles sinensis etc.; Midge (Chironomidae); Housefly (Nuscidae) is as housefly, false stable fly, anthomyia canicularis etc.; Calliphoridae; Flesh flies; Drosophilidae; The psychid Superfamily; Phoridae; Blackfly section; Tabanidae; Sting Nuscidae; Buffalo gnat Heleidae etc.
Following preparation embodiment and experimental example further describe the present invention, but are not interpreted as qualification the present invention.
Preparation embodiment 1
By on a surface portion of purple fiber basic unit, (mixture through serigraphy amorphous silica/acrylic based emulsion=1/0.5 is so that become 15g/m for lamination " improving layer that makes it become transparent when comprising oil-based liquid "
2Thick and obtain) carrier (20.5mm * 33mm * 1.1mm is thick) of preparation; with this carrier with 2 of 2 weight portions; 3; 5; 6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2; 2-dimethyl cyclopropane carboxylic acid ester, the impregnation mixture of the 300mg that the acetyl tributyl citrate of the dibutyl hydroxy toluene of 1 weight portion and 2 weight portions is formed.This carrier is clipped in the centre (thin polypropylene layer is laminated to every film surface and is used for heat-sealing) of the polyethylene terephthalate thin film of two 37mm * 25mm, seals along the polyethylene terephthalate thin film edge subsequently.Then, section forms the hole of a 3mm * 3mm to the core of the polyethylene terephthalate thin film of " improving layer that makes it become transparent " when comprising oil-based liquid.Thereby obtain the hot volatile material (middle finger hot volatile material 1 of the present invention hereinafter) of pest control of the present invention.
Remove and adopt 2,3,4,5,6-PFBBR 1R-is anti--3-(2, the 2-dichloroethylene)-2, and 2-dimethyl cyclopropane carboxylic acid ester replaces 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2, outside the 2-dimethyl cyclopropane carboxylic acid ester, according to the same procedure of preparation embodiment 1, obtain the hot volatile material (middle finger volatile material 2 of the present invention hereinafter) of pest control of the present invention.
Remove and adopt 2,3,5,6-ptfe benzyl 1R-is anti--3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester replaces 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2, outside the 2-dimethyl cyclopropane carboxylic acid ester,, obtain the hot volatile material (middle finger volatile material 3 of the present invention hereinafter) of pest control of the present invention according to the same procedure of preparation embodiment 1.
Preparation embodiment 4
Remove and adopt 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(2-methyl isophthalic acid-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester replaces 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2, outside the 2-dimethyl cyclopropane carboxylic acid ester, according to the same procedure of preparation embodiment 1, obtain the hot volatile material (middle finger volatile material 4 of the present invention hereinafter) of pest control of the present invention.
Comparative preparation embodiment 1
By on a surface portion of purple fiber basic unit, lamination makes its improving layer that becomes transparent when comprising liquid (mixture through serigraphy amorphous silica/acrylic based emulsion=1/0.5 is so that become 15g/m
2Thick and obtain) carrier (20.5mm * 33mm * 1.1mm is thick) of preparation; this carrier is used by 2 of 2 weight portions; 3; 5; 6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2; 2-dimethyl cyclopropane carboxylic acid ester, the 300mg impregnation mixture that the acetyl tributyl citrate of the dibutyl hydroxy toluene of 1 weight portion and 2 weight portions is formed, hot volatile material (middle finger contrast volatile material 1 hereinafter) obtained with the pest control that compares.
Remove and adopt 2,3,4,5,6-PFBBR 1R-is anti--3-(2, the 2-dichloroethylene)-2, and 2-dimethyl cyclopropane carboxylic acid ester replaces 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2, outside the 2-dimethyl cyclopropane carboxylic acid ester, according to the same procedure of comparative preparation embodiment 1, obtain hot volatile material (middle finger contrast volatile material 2 hereinafter) with the pest control that compares.
Remove and adopt 2,3,5,6-ptfe benzyl 1R-is anti--3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester replaces 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 1R-is anti--3-(1-acrylic (E/Z=1/8))-2, outside the 2-dimethyl cyclopropane carboxylic acid ester,, obtain hot volatile material (middle finger contrast volatile material 3 hereinafter) with the pest control that compares according to the same procedure of comparative preparation embodiment 1.
Experimental example 1
The hot volatile material of every kind of pest control that makes through preparation embodiment and comparative preparation embodiment is heated on about 170 ℃ heating plate, measure and become the opaque time up to " improving layer that when comprising oil-based liquid, makes it become transparent ".The results are shown in (three repetitions) in the table 1.
Table 1
| Up to become the opaque time (hour) | |
| Volatile material 1 of the present invention | 336 to 360 hours |
| | 144 to 216 hours |
| | 144 to 216 hours |
| Contrast volatile material 1 | 0.5 to 24 hours |
| Contrast | 0.5 to 24 hours |
| Contrast | 0.5 to 24 hours |
Experimental example 2
Every kind of hot volatile material of pest control for examination is heated on about 170 ℃ heating plate, begin to heat and carried out culex pipiens pallens in back 144 hours, 216 hours and 336 hours and knock down test.
Culex pipiens pallens is knocked down test
Every kind of hot volatile material through the pest control of heating plate heating is placed the core of the cuboid box of 3m (bottom surface) * 4m (another bottom surface) * 2.3m (height).Immediately, about 100 female culex pipiens pallens adults (emergence back 3 to 5 days) are discharged in the inlet.Discharge the back in the given quantity of knocking down culex pipiens pallens in the inspection box in blanking time of 60 minutes that is at most, to determine the KT50 value.
After the test, continue to heat on the heating plate outside case hot volatile material for the pest control of examination.The results are shown in the table 2.
Table 2
| KT50 (minute) | |||
| 144 hours | 216 hours | 336 hours | |
| Volatile material 1 of the present invention | 28 | 26 | 40 |
| | 31 | ＞60 | ＞60 |
| | 25 | ＞60 | ＞60 |
| Contrast volatile material 1 | ＞60 | ＞60 | ＞60 |
| Contrast | ＞60 | ＞60 | ＞60 |
| Contrast | ＞60 | ＞60 | ＞60 |
The hot volatile material of pest control of the present invention has the lasting active ingredient volatilization time, and the volatilization concluding time of active ingredient almost matches with the volatile material fading time.
Claims (5)
1. the hot volatile material of a pest control, it comprises the carrier of the solution of compound shown in the bearing-type (1):
R wherein
1And R
2Represent hydrogen atom, methyl or chlorine atom separately, R
3Expression hydrogen atom, fluorine atom, methyl, methoxyl group or methoxy, polyalkylene terephthalates layer with hole is on carrier and cover carrier, wherein carrier is the laminated material of basic unit and " improving layer that makes it become transparent when comprising oil-based liquid ", and the thickness of polyalkylene terephthalates layer is 0.002 to 0.3mm, wherein said basic unit is fibrous material and/or porous material, and described " improving layer that makes it become transparent when comprising oil-based liquid " is the layer of porous and has permeability for oil-based liquid; The area of its mesopore is the long-pending 0.01-10% of apparent surface of carrier; And the amount of solution is 0.001-0.7g/lcm
3Carrier apparent volume, the solvent in the solution of wherein said compound are the esters solvents with 15 to 25 carbon atoms, and solvent load is 0.1 to 10 weight portion/every weight portion compound.
2. according to the hot volatile material of the pest control of claim 1, the compound shown in its Chinese style (1) is 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methyl-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-ptfe benzyl 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro 4-methoxyl methyl benzyl 3-(2-methyl isophthalic acid-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, or 2,3,4,5,6-PFBBR 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.
3. according to the hot volatile material of the pest control of claim 1, wherein only provide towards the hole of " improving layer that makes it become transparent when comprising an oil-based liquid " side, wherein said " improving layer that makes it become transparent when comprising oil-based liquid " is the layer of porous and has permeability for oil-based liquid.
4. the method for a pest control, it is included in insect habitat or infringement zone, and heating is according to each the hot volatile material of pest control of claim 1 to 3.
5. according to the method for claim 4, wherein heat the hot volatile material of pest control from basic unit's side.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003116765 | 2003-04-22 | ||
| JP116765/03 | 2003-04-22 | ||
| JP116765/2003 | 2003-04-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1568698A CN1568698A (en) | 2005-01-26 |
| CN100339004C true CN100339004C (en) | 2007-09-26 |
Family
ID=34509626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100387133A Expired - Fee Related CN100339004C (en) | 2003-04-22 | 2004-04-22 | Heat volatile material for preventing and controlling pests |
Country Status (6)
| Country | Link |
|---|---|
| KR (1) | KR101107973B1 (en) |
| CN (1) | CN100339004C (en) |
| AR (1) | AR044035A1 (en) |
| BR (1) | BRPI0401131B1 (en) |
| IT (1) | ITTO20040237A1 (en) |
| MY (1) | MY138871A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008255039A (en) * | 2007-04-03 | 2008-10-23 | Sumitomo Chemical Co Ltd | Heat transpirator for pest controlling use |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1247468A (en) * | 1997-10-28 | 2000-03-15 | 坂东化学株式会社 | Dermatological patch sheet and process for producing base sheet therefor |
| CN2428980Y (en) * | 2000-06-15 | 2001-05-09 | 上海吉臣实业有限公司 | Substrates for electric heating mosquito repellent incense |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002265304A (en) * | 2001-03-08 | 2002-09-18 | Sumitomo Chem Co Ltd | Heating transpiration body for insect pest control |
-
2004
- 2004-04-12 MY MYPI20041334A patent/MY138871A/en unknown
- 2004-04-16 BR BRPI0401131-7B1A patent/BRPI0401131B1/en active IP Right Grant
- 2004-04-16 IT IT000237A patent/ITTO20040237A1/en unknown
- 2004-04-20 KR KR1020040027077A patent/KR101107973B1/en not_active IP Right Cessation
- 2004-04-21 AR ARP040101337A patent/AR044035A1/en active IP Right Grant
- 2004-04-22 CN CNB2004100387133A patent/CN100339004C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1247468A (en) * | 1997-10-28 | 2000-03-15 | 坂东化学株式会社 | Dermatological patch sheet and process for producing base sheet therefor |
| CN2428980Y (en) * | 2000-06-15 | 2001-05-09 | 上海吉臣实业有限公司 | Substrates for electric heating mosquito repellent incense |
Also Published As
| Publication number | Publication date |
|---|---|
| MY138871A (en) | 2009-08-28 |
| CN1568698A (en) | 2005-01-26 |
| BRPI0401131A (en) | 2005-06-14 |
| KR20040091568A (en) | 2004-10-28 |
| BRPI0401131B1 (en) | 2013-07-16 |
| KR101107973B1 (en) | 2012-01-30 |
| AR044035A1 (en) | 2005-08-24 |
| ITTO20040237A1 (en) | 2004-07-16 |
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