CN100336587C - Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application - Google Patents
Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application Download PDFInfo
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- CN100336587C CN100336587C CNB2005100353127A CN200510035312A CN100336587C CN 100336587 C CN100336587 C CN 100336587C CN B2005100353127 A CNB2005100353127 A CN B2005100353127A CN 200510035312 A CN200510035312 A CN 200510035312A CN 100336587 C CN100336587 C CN 100336587C
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- Prior art keywords
- porous carbon
- zine oxide
- nano zine
- porous
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title abstract description 67
- 239000011787 zinc oxide Substances 0.000 title abstract description 33
- 239000003795 chemical substances by application Substances 0.000 title abstract 5
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims abstract description 56
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 17
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 10
- 230000001699 photocatalysis Effects 0.000 claims abstract description 8
- 230000003115 biocidal effect Effects 0.000 claims abstract description 7
- 238000003421 catalytic decomposition reaction Methods 0.000 claims abstract description 5
- 238000000593 microemulsion method Methods 0.000 claims abstract description 5
- 239000003463 adsorbent Substances 0.000 claims description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 11
- 239000005416 organic matter Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 230000008030 elimination Effects 0.000 claims description 8
- 238000003379 elimination reaction Methods 0.000 claims description 8
- 239000008247 solid mixture Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 8
- 229940007718 zinc hydroxide Drugs 0.000 claims description 8
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 8
- 241000191967 Staphylococcus aureus Species 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 6
- 238000007146 photocatalysis Methods 0.000 claims description 6
- 241000588724 Escherichia coli Species 0.000 claims description 5
- 239000003242 anti bacterial agent Substances 0.000 claims description 4
- 229940088710 antibiotic agent Drugs 0.000 claims description 4
- 241000894006 Bacteria Species 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 244000198134 Agave sisalana Species 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 31
- 239000002131 composite material Substances 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 244000005700 microbiome Species 0.000 abstract description 5
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 239000000047 product Substances 0.000 description 19
- 229960001296 zinc oxide Drugs 0.000 description 18
- 239000013078 crystal Substances 0.000 description 16
- 238000004458 analytical method Methods 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 239000002105 nanoparticle Substances 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000002156 adsorbate Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- -1 are nano-ZnOs Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000012905 visible particle Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
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Abstract
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Priority Applications (1)
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CNB2005100353127A CN100336587C (en) | 2005-06-22 | 2005-06-22 | Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application |
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CNB2005100353127A CN100336587C (en) | 2005-06-22 | 2005-06-22 | Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application |
Publications (2)
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CN1724138A CN1724138A (en) | 2006-01-25 |
CN100336587C true CN100336587C (en) | 2007-09-12 |
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CNB2005100353127A Expired - Fee Related CN100336587C (en) | 2005-06-22 | 2005-06-22 | Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application |
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Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101947442B (en) * | 2010-09-07 | 2012-11-28 | 桂林理工大学 | Method for synthesizing nano zinc oxide/bamboo charcoal photocatalysis material by precipitation and impregnation |
CN102898681B (en) * | 2012-09-27 | 2014-04-23 | 河南科技大学 | Loaded type nano-zinc oxide composite material |
CN102898682B (en) * | 2012-09-27 | 2014-04-23 | 河南科技大学 | Supported nano zinc oxide composite material |
CN103041797B (en) * | 2012-12-20 | 2016-03-09 | 山东晟博生物科技有限公司 | A kind of method of composite photo-catalyst and preparation thereof, process waste gas |
CN103059409A (en) * | 2012-12-24 | 2013-04-24 | 上海普利特复合材料股份有限公司 | Low-odor low-volatilization modified polypropylene material and preparation method thereof |
CN103606657A (en) * | 2013-12-10 | 2014-02-26 | 北京理工大学 | Lithium ion battery zinc oxide/porous carbon composite negative electrode material with high capacity and preparation method thereof |
CN103877961B (en) * | 2014-03-05 | 2016-01-27 | 北京大学 | A kind of charcoal base zinc oxide nanosphere composite and preparation method thereof |
CN104857945A (en) * | 2015-04-30 | 2015-08-26 | 信阳师范学院 | Preparation method of zinc oxide/carbon micro-sphere composite material |
CN105001571B (en) * | 2015-07-03 | 2017-11-03 | 北京理工大学 | Metal oxide-loaded activated carbon synergistic expandable flame retardant CABLE MATERIALS and preparation method |
CN106334520A (en) * | 2015-07-09 | 2017-01-18 | 惠州市银嘉环保科技有限公司 | Antibacterial water-purification active carbon based on nano ZnO and preparation method and application thereof |
CN106000380A (en) * | 2016-05-19 | 2016-10-12 | 天津大拇指环境工程有限公司 | Activated carbon-loaded nano-zinc oxide ozonation catalyst and preparation and use thereof |
CN106381682B (en) * | 2016-08-26 | 2018-11-16 | 上海师范大学 | A kind of nano-titanium dioxide/active carbon fiber felt three-dimensional porous material of high absorption-photocatalysis performance and preparation method thereof |
CN106609477A (en) * | 2016-11-14 | 2017-05-03 | 蚌埠市风驰滤清器有限公司 | An oil-proof filter paper for filters |
CN107213701A (en) * | 2017-06-05 | 2017-09-29 | 中国第汽车股份有限公司 | A kind of in-car air cleaning material and its preparation technology containing butadiene-styrene rubber |
CN109499563A (en) * | 2017-09-15 | 2019-03-22 | 张家港市沐和新材料技术开发有限公司 | A kind of preparation method of zinc oxide-active carbon composite catalyst |
CN108620095B (en) * | 2018-05-16 | 2020-09-29 | 扬州工业职业技术学院 | Composite catalyst and application thereof in synthesis of glyceraldehyde |
CN109369994B (en) * | 2018-11-15 | 2020-11-17 | 赛轮集团股份有限公司 | Low-zinc rubber composition |
CN110016814B (en) * | 2019-04-16 | 2021-07-13 | 青岛华世洁环保科技有限公司 | Antibacterial asymmetric total heat exchange membrane, total heat exchange core and total heat exchanger |
CN110053229B (en) * | 2019-04-22 | 2022-03-22 | 成都新柯力化工科技有限公司 | Anti-haze functional waterproof roll for building and preparation method thereof |
CN112403456A (en) * | 2020-11-23 | 2021-02-26 | 泉州师范学院 | Synthesis of ZnO/C nano composite material and application thereof in photocatalysis antibiosis |
CN113426410A (en) * | 2021-06-16 | 2021-09-24 | 珠海格力电器股份有限公司 | Porous carbon material and preparation method thereof |
CN114804906B (en) * | 2022-05-27 | 2023-02-14 | 陕西美兰德炭素有限责任公司 | High-purity carbon/carbon composite material and preparation method and application thereof |
CN115382506B (en) * | 2022-10-26 | 2023-05-30 | 成都天佑晶创科技有限公司 | Zinc-silver-copper-loaded active carbon composite material and preparation method and application thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4677096A (en) * | 1983-11-18 | 1987-06-30 | Dragerwerk A.G. | Air cleaning material for use in air filters |
CN1309090A (en) * | 2000-02-14 | 2001-08-22 | 苏才元 | Nm-class material, process for preparing it from activated carbon and its use |
US6471886B1 (en) * | 2000-10-27 | 2002-10-29 | Sandia National Laboratories | Absorption media for irreversibly gettering thionyl chloride |
CN1398808A (en) * | 2002-08-20 | 2003-02-26 | 浙江大学 | Glass with plated nano zinc oxide film |
CN2619931Y (en) * | 2003-04-23 | 2004-06-09 | 宜兴市瑞盛水处理设备有限公司 | Nano-base system for supplying and purifying high-quality water |
-
2005
- 2005-06-22 CN CNB2005100353127A patent/CN100336587C/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4677096A (en) * | 1983-11-18 | 1987-06-30 | Dragerwerk A.G. | Air cleaning material for use in air filters |
CN1309090A (en) * | 2000-02-14 | 2001-08-22 | 苏才元 | Nm-class material, process for preparing it from activated carbon and its use |
US6471886B1 (en) * | 2000-10-27 | 2002-10-29 | Sandia National Laboratories | Absorption media for irreversibly gettering thionyl chloride |
CN1398808A (en) * | 2002-08-20 | 2003-02-26 | 浙江大学 | Glass with plated nano zinc oxide film |
CN2619931Y (en) * | 2003-04-23 | 2004-06-09 | 宜兴市瑞盛水处理设备有限公司 | Nano-base system for supplying and purifying high-quality water |
Non-Patent Citations (1)
Title |
---|
活性碳纤维ZnO-SACF的制备及其对Ag+的氧化还原吸附 岳中仁等,离子交换与吸附,第11卷第2期 1995 * |
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CN1724138A (en) | 2006-01-25 |
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Assignee: Guangdong Taibao Medical Science Technology Co., Ltd. Assignor: Sun Yat-sen University Contract fulfillment period: 2009.5.8 to 2014.5.8 contract change Contract record no.: 2009440000453 Denomination of invention: Porous carbon adsorbing agent containing nano zinc oxide micropartical and its preparation process and application Granted publication date: 20070912 License type: Exclusive license Record date: 2009.6.8 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.5.8 TO 2014.5.8; CHANGE OF CONTRACT Name of requester: GUANGDONG TAIBAO SCIENCE AND TECHNOLOGY MEDICAL SU Effective date: 20090608 |
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Granted publication date: 20070912 Termination date: 20130622 |