CN1003242B - Hands washing solution for workers - Google Patents
Hands washing solution for workers Download PDFInfo
- Publication number
- CN1003242B CN1003242B CN87100025A CN87100025A CN1003242B CN 1003242 B CN1003242 B CN 1003242B CN 87100025 A CN87100025 A CN 87100025A CN 87100025 A CN87100025 A CN 87100025A CN 1003242 B CN1003242 B CN 1003242B
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- CN
- China
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- hand
- content
- washing solution
- washing composition
- lanolin
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Abstract
The present invention provides a novel high-efficiency hand-washing solution and a preparation method thereof. The hand-washing solution is prepared into a uniform transparent solution from active components and adjuvants according to a certain proportion, wherein the active components contain triethanolamine oleic soap, coconut oleyl alcohol amide and sodium dodecyl benzene sulfonate, the adjuvants contain propanetriol, lanolin, etc., and the pH value is neutral. The hand-washing solution has the advantages of high stability, lubrication, softness, skin protection, cracking prevention, no toxicity, no stimulation, rust prevention, etc. Therefore, the hand-washing solution can effectively remove oil stains on hands and can also be used for washing oil work clothes and various machines, devices and instruments; the novel high-efficiency hand-washing solution is an ideal hand-washing agent for mines, factories, hospitals, military industries, etc.
Description
The present invention relates to a kind of washing composition, particularly a kind of removal is the washing composition used of greasy dirt on hand.
In the mine, factory, the common problem that exists of the workman of various contact greasy dirt operations is the difficulty of washing one's hands, they generally always coat earlier soap in hand, rub with the hands with yellow sand and wood chip again, often need repeat repeatedly, every day a lot of times of spend so not only, and because soap deflection alkalescence too much uses soap that skin is had certain infringement, the rubbing of wood chip etc. in addition, cause the workman on hand skin become very coarse, the hardship of be full of cracks is arranged winter.Besides the cleaning performance of soap wood chip and unsatisfactory, remaining on hand dirt accumulates over a long period, and is embedded in inveterately in the palm of the hand lines in the course of time, influences the clean and tidy and attractive in appearance of hand.Some workman is infected with greasy dirt for preventing in the hand, abuse is with the gloves operation unexpectedly, so that lead to work accident.
Various washing composition are come out one after another on the market in recent years, the employing foreign latest prescription that has, and what have is to succeed in developing voluntarily, wherein in fashion with the White Cat detergent especially.This class washings has removes greasy ability preferably, but the skin fat layer is had certain damage and hormesis, and foam is also more, with after need just to rinse well with a large amount of water, and wash sticking sensation always arranged on the defensive position.In a word, do not find also that up to now a kind of ideal removes the washing composition that greasy dirt is on hand used.
The object of the present invention is to provide a kind of efficient Liquid soap and compound method thereof of novelty, this Liquid soap can not only be removed greasy dirt on hand extremely effectively, and does not hinder skin, and skin is also had certain protective role.
The objective of the invention is to realize by following method: Liquid soap of the present invention mainly comprises following each component:
(1) have the trihydroxy ethylamine oleate soap of following molecular formula:
CH
3(CH
2)
7CH=CH(CH
2)
7COOHN(CH
2CH
2OH)
3This component is the important activity component of the present invention's Liquid soap, it except that having extremely strong removal greasy dirt ability, also having property breast, shrinkproof, wrinkle resistant, arrangement and stablize the usefulness of washing composition.
(2) have the Oleum Cocois alcohol amide of following molecular formula:
In the formula, R is C
12-18Alkyl, wherein R is preferably C
14-18Alkyl.This component is one of the main active component of the present invention's Liquid soap, and it all has good de-oiling ability to various greasy dirts (as animal oil, vegetables oil and mineral oil), and prevents xerosis cutis in addition, suppresses usefulness such as sodium alkyl benzene sulfonate deterioration by oxidation.
(3) Sodium dodecylbenzene sulfonate, this component are the body materials of the present invention's Liquid soap, also are one of active ingredients of Liquid soap.Its surfactivity is strong, and stable performance in alkalescence, neutrality and weakly acidic solution has good wetting, emulsification, dispersion and soil removability in hard water.
(4) glycerol, this component has good hydrotropy and oilness.
(5) lanolin, it has softness, lubricated and prevent the function of degreasing to skin.
It is benchmark with the weight of Liquid soap that the prescription of the present invention's Liquid soap is shown in percent value system in the table 1(table).
Table 1
Amounts of components (%)
Trihydroxy ethylamine oleate soap 2-6
Oleum Cocois alcohol amide 2-4.5
Sodium dodecylbenzene sulfonate 16-21
Glycerol 0.4-1
Lanolin (medicinal) 0.08-0.12
Spices 0.1
The deionized water capacity (that is except that above component,
All the other are deionized water)
The present invention's Liquid soap is prepared as follows: successively 16-21% Sodium dodecylbenzene sulfonate, 2-4.5% Oleum Cocois alcohol amide, 0.4-1% glycerol, 2-6% trihydroxy ethylamine oleate soap, 0.08-0.12% lanolin and 0.1% spices are mixed with an amount of deionized water at normal temperatures, and stir, stir speed (S.S.) is 30-40 rev/min, and the time is 1.5-2.5 hour.
The present invention's Liquid soap has carried out acute skin irritation test by Shanghai Pharmaceutical Inst., Chinese Academy of Sciences.Experimental animal is to be the healthy guinea pig of 150-200 gram by the body weight that this Animal Experimental Study chamber provides, and is divided into five test group.Each treated animal is embrocated Liquid soap one time every day, embrocated continuously 5 days.After embrocating, wash-out after stopping 5 minutes, 15 minutes, 30 minutes, 60 minutes, 120 minutes on the skin is observed skin reaction respectively, the results are shown in table 2 at every turn.
Table 2
The test group Liquid soap stops skin reaction
The numbering time (branch)
15 feminine genders
2 15 feminine genders
3 30 feminine genders
4 60 feminine genders
The part cavy is coated with erasure in the 4th day, the 5th day skin and slight flush occurs in 5 120 these groups, restores about 1 hour.
Under same test conditions, current melissa perfumed soap liquid salable skin when the residence time is 60 minutes has positive reaction.
The present invention's Liquid soap is the neutral liquid (pH is 7-8) of homogeneous transparent, and fragrance is full of the people, have fixed resolutely, lubricated, soft, protect skin, prevent characteristics such as dry and cracked and nontoxic, non-stimulated.
The present invention's Liquid soap soil removability is extremely strong, improves 30-40% than commercially available white cat liquid detergent, and that foam reduces is over half, uses the back as long as just can clean with a small amount of clear water, and feel is smooth.Under the condition of lack of water, the material of available " hard waste " and so on replacement clear water is cleaned and is got final product, and uses so be particularly suitable for the place of field work or shortage of water.
Liquid soap of the present invention is fit to the greasy working suit of washing too, clean various machineries, equipment and instrument, clean effect is splendid, and the short-term rust inhibition is arranged, thereby is mine, factory, hospital's (can replace soft soap), vehicle manufacturing and department's ideal washing composition such as transportation and even military project.
The compound method of the present invention's Liquid soap is easy, raw material sources abundant, do not produce the three wastes.
Below will be described in further detail the present invention by concrete prescription and embodiment.
Prescription 1
A kind of better formula of the present invention's Liquid soap is as shown in table 3:
Table 3
Amounts of components (%)
Trihydroxy ethylamine oleate soap 3
Oleum Cocois alcohol amide 2
Sodium dodecylbenzene sulfonate 18
Glycerol 0.6
Lanolin (medicinal) 0.1
Spices 0.1
Deionized water capacity (that is except that above component, all the other are deionized water)
The cost of the Liquid soap of above-mentioned prescription and commercially available white cat liquid detergent are suitable, but ability of cleaning greasy dirt improves 30-40% than the latter, and foam reduces half.
Prescription 2
A kind of efficient formula of the present invention's Liquid soap is as shown in table 4:
Table 4
Amounts of components (%)
Trihydroxy ethylamine oleate soap 5
Oleum Cocois alcohol amide 4.5
Sodium dodecylbenzene sulfonate 20
Glycerol 1
Lanolin (medicinal) 0.12
Spices 0.1
Deionized water capacity (that is except that above component, all the other are deionized water)
The soil removability of the Liquid soap of above-mentioned prescription improves more than 40% than commercially available white cat liquid detergent.
The concrete preparation method of the present invention's Liquid soap is as follows: put into 126 kilograms of sodium laurylsulfonates in a suitable containers, stirred 10 minutes with 30-40 rev/min rotating speed, add 534.60 kilograms of no ions and 14 kilograms of Oleum Cocois alcohol amide then, under about 34 ℃ of temperature, stirred 45 minutes, then add 4.20 kilograms of glycerol, stir after 20 minutes, add 21 kilograms of trihydroxy ethylamine oleate soaps again, stirred 30 minutes, add 0.7 kilogram of medicinal lanolin and 0.1%(again in the Liquid soap gross weight) spices, continue to stir 30 minutes, so obtain 700 kilograms of left and right sides products.Products therefrom is injected in the storage tank, deposited 1.5 hours, can become product behind its natural froth breaking of waiting.
Claims (6)
1, a kind of washing composition, particularly a kind of removal is the washing composition used of greasy dirt on hand, it comprises the active ingredient of significant quantity, and an amount of adjuvant and suitable solvent etc. is characterized in that the active ingredient of said significant quantity comprises that content is the trihydroxy ethylamine oleate soap CH with following molecular formula of 2-6%
3(CH
2)
7CH=CH(CH
2)
7COOHN(CH
2CH
2OH)
3(1) and content be the Oleum Cocois alcohol amide of 2-4.5% with following molecular formula:
R is C in the formula
12-18Alkyl, and the Sodium dodecylbenzene sulfonate of 16-21%; Said an amount of adjuvant comprises that 0.4-1% glycerol and the said solvent of the medicinal lanolin of 0.08-0.12 (above percentage number average is in the gross weight of washing composition) are deionized waters.
2, washing composition according to claim 1, the content that it is characterized in that trihydroxy ethylamine oleate soap is preferably 3%, the content of Oleum Cocois hydramine is preferably 2%, the content of Sodium dodecylbenzene sulfonate is preferably 18%, the content of glycerol is preferably 0.6%, the content of medicinal lanolin is preferably 0.1%, and the R in the formula (2) is preferably C
14-18Alkyl.
3, a kind of compound method of washing composition as claimed in claim 1, it is characterized in that at normal temperatures successively Sodium dodecylbenzene sulfonate, 2-4.5% Oleum Cocois alcohol amide, 0.4-1% glycerol, 2-6% trihydroxy ethylamine oleate soap and the medicinal lanolin of 0.08-0.12% of 16-21% are mixed mutually with deionized water, and stir, stir speed (S.S.) is 30-40 rev/min, time 1.5-2.5 hour (above percent value is all in the washing composition gross weight).
4, method according to claim 3, the consumption that it is characterized in that Sodium dodecylbenzene sulfonate is preferably 18%, and the consumption of Oleum Cocois alcohol amide is preferably 2%, and the consumption of glycerol is preferably 0.6%, the consumption of trihydroxy ethylamine oleate soap is preferably 3%, and the consumption of lanolin is preferably 0.1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87100025A CN1003242B (en) | 1987-01-03 | 1987-01-03 | Hands washing solution for workers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87100025A CN1003242B (en) | 1987-01-03 | 1987-01-03 | Hands washing solution for workers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87100025A CN87100025A (en) | 1988-03-16 |
| CN1003242B true CN1003242B (en) | 1989-02-08 |
Family
ID=4812676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87100025A Expired CN1003242B (en) | 1987-01-03 | 1987-01-03 | Hands washing solution for workers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1003242B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100441670C (en) * | 2004-06-09 | 2008-12-10 | 上海斯麦尔日化厂 | Detergent composition |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182431B (en) * | 2006-11-14 | 2010-05-12 | 上海斯麦尔日化厂 | Cleaning agent composition |
| CN102429833B (en) * | 2011-12-29 | 2014-05-14 | 北京绿伞化学股份有限公司 | Environmentally-friendly hand sanitizer and preparation method thereof |
| CN102994267B (en) * | 2012-11-29 | 2015-07-29 | 陈小康 | The precious preparation method of a kind of Efficient antibacterial scale protective type cleaning toilet |
| CN103027876A (en) * | 2012-12-14 | 2013-04-10 | 吴江市德佐日用化学品有限公司 | Skincare hand sanitizer |
| CN103343356A (en) * | 2013-07-10 | 2013-10-09 | 大连三星恒业科技发展有限公司 | Multifunctional metal water-based antirust cleaning agent and preparation method and application thereof |
| CN104287985A (en) * | 2014-10-11 | 2015-01-21 | 江苏常州酞青新材料科技有限公司 | Method for preparing hand sanitizer |
| CN104893861A (en) * | 2015-06-15 | 2015-09-09 | 江苏常州酞青新材料科技有限公司 | Method for preparing cleaning agent |
-
1987
- 1987-01-03 CN CN87100025A patent/CN1003242B/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100441670C (en) * | 2004-06-09 | 2008-12-10 | 上海斯麦尔日化厂 | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN87100025A (en) | 1988-03-16 |
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