CA3229675A1

CA3229675A1 - Fuel agnostic compression ignition engine

Info

Publication number: CA3229675A1
Application number: CA3229675A
Authority: CA
Inventors: Julie BLUMREITER; Bernard Johnson; Robert Schanz; Manohar VITTAL
Original assignee: Clearflame Engines Inc
Current assignee: Clearflame Engines Inc
Priority date: 2021-08-25
Filing date: 2022-08-24
Publication date: 2023-03-02
Also published as: WO2023028156A3; AU2022335417A1; WO2023028156A2

Abstract

Some embodiments described herein relate to a method of operating a compression ignition (CI) engine. The CI engine can include a combustion chamber. The method of operating the CI engine includes receiving a volume of intake charge in the combustion chamber, compressing the intake charge, injecting a volume of fuel into the combustion chamber, the fuel having a cetane number less than about 40, and combusting substantially all of the volume of fuel. A delay between injecting the volume of fuel into the combustion chamber and initiation of combustion is less than about 2 ms. The CI engine includes at least a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, and/or a Wankel rotary engine.

Description

FUEL AGNOSTIC COMPRESSION IGNITION ENGINE
Cross-reference to Related Applications [0001]
This application claims priority and benefit of U.S. Provisional Application No.
63/236,965, filed August 25, 2021 and titled "Fuel Agnostic Compression Ignition Engine,"
the disclosure of which is hereby incorporated by reference in its entirety.
Technical Field

[0002]
Embodiments described herein relate to fuel agnostic compression ignition engines, and methods of operating the same.
Background

[0003]
A diesel engine is a rugged, reliable engine architecture having high torque/efficiency and simple ignition control enabled by the largely non-premixed nature of the combustion process Standard diesel engine operation depends on the fuel being sufficiently ignitable in air, which requires pre-injection temperatures at least ¨850K.
These temperatures are most commonly achieved by compressing the air in a geometric volume ratio of about 17:1.
During operation, this air compression is accomplished in the cylinder prior to fuel being sprayed in from a high-pressure direct injection from the fuel injector (i.e., the pressure in the fuel injector is greater than 800 bar at the point in time the fuel is injected). Diesel fuel itself meets this ignition criterion (i.e., igniting in air at 850K with a sufficiently short ignition delay), while numerous other fuels do not. This ignition criterion causes the exclusion of fuels with otherwise desirable attributes such as cost, regional availability, or other properties related to the way they burn. Currently, only fuels that can meet the diesel ignition criteria can be used in a diesel cycle (that is, non-premixed, mixing-controlled compression ignition). The ignition criteria is defined by a measurement of the fuel's ignition delay (a short ignition delay ¨ short compared to the other time scales in the engine cycle such as piston motion and intake or exhaust event durations ¨ is desired for a non-premixed combustion process), and is reported as a value called cetane number. A standard diesel engine has a narrow range of cetane numbers, for which the fuel can be combusted properly in the diesel engine.

Summary

[0004]
Embodiments described herein relate to engines that can operate in a diesel cycle on any fuel regardless of cetane number, and methods of operating the same.
Some embodiments described herein relate to a method of operating a compression ignition (CI) engine. The CI engine can include a combustion chamber. The method of operating the CI
engine includes receiving a volume of intake charge in the combustion chamber, compressing the intake charge, injecting a volume of fuel into the combustion chamber, the fuel having a cetane number less than about 40, and combusting substantially all of the volume of fuel. A
delay between injecting the volume of fuel into the combustion chamber and initiation of combustion is less than about 2 ms. The CI engine includes at least a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, and/or a Wankel rotary engine.
Brief Description of the Drawings

[0005]
FIG. 1 is a chart of autoignition delay times of various fuels as a function of ignition temperature

[0006]
FIG. 2 is a schematic illustration of a compression ignition architecture, according to an embodiment.

[0007]
FIG. 3 is a block diagram of a method of operating a compression ignition engine, according to an embodiment.
Detailed Description

[0008]
Chemical fuels (petroleum, alcohols, biodiesel, etc.) remain important to heavy-duty on-road transportation. Their high energy density is important for users who need to travel long distances and refuel quickly. As a result, the need for chemically fueled diesel engines will persist for decades. However, diesel fuel prices have increased substantially over the last three decades and diesel fuel is a significant contributor to greenhouse gas emissions.
Additionally, emissions standards for nitrogen dioxide and nitric oxide (collectively referred to as NON) as well as soot are becoming ever stricter.

[0009]
Embodiments described herein relate to engines that can operate in a diesel cycle on any fuel regardless of cetane number, and methods of operating the same. In some embodiments, an engine can operate as a "fuel agnostic" engine by creating a high temperature environment inside the engine or in the immediate vicinity of the engine In some embodiments, the high temperature environment can be created without having to change the traditional diesel engine architecture. In other words, the compression ratio of the diesel engine can remain the same, with only minimal changes to other components or aspects of the diesel engine. An increase in temperature can shorten the ignition delay of a fuel, allowing the fuel to behave in a similar manner to how a more ignitable fuel would behave at a lower temperature. For example, a first fuel with a cetane number of 55 can have a similar ignition delay at 700 K to the ignition delay of a second fuel with a cetane number of 15 at 1000 K. At sufficiently high temperatures, all fuels (even those most resistant to ignition) have sufficiently short ignition del ay to sustain diesel style engine operation. Fuels have ignition del ay curves that can depend on temperature, pressure, oxygen content of the air mixture in a cylinder the fuel is injected into, and/or any other factors.

[0010]
In some embodiments, the high-temperatures created to achieve a "fuel agnostic"
characteristic can be implemented in engine architectures other than a four-stroke diesel engine architecture, including but not limited to two-stroke engines, opposed-piston engines, two-stroke opposed piston engines, five-stroke engines, six-stroke engines, free-piston engines, free piston engines linear, rotary or Wankel rotary engine designs, or other internal combustion engine designs.

[0011]
FIG. 1 shows a chart of autoignition delay times of various fuels as a function of ignition temperature. The x-axis shows initial temperature upon ignition, while the y-axis shows autoignition delay times as a function of initial temperature. Fuels shown on this chart include methane, iso-octane, n-heptane, and dimethyl ether (DME). Of the fuels shown, DME
has the highest cetane number, about 55. Therefore, the other fuels shown (n-heptane, iso-octane, methane) require a higher temperature than DME to ignite after a given delay period (e.g., 2 ms). Ignition delay can be reduced or finely tuned by manipulating the temperature in the combustion chamber.

[0012]
Benefits to creating a high temperature in the combustion chamber can include enablement of a fuel-flexible engine that can match the torque and power density of a diesel engine with the freedom to operate on any fuel, regardless of cetane number.
In some embodiments, the fuel agnostic or fuel-flexible engine can be configured such that one or more on-board sensors detect fuel properties and control a temperature control mechanism employed in the engine. For example, the temperature control mechanism can add more heat to compensate when the sensor detects a low-cetane fuel. In some embodiments, the engine can be configured to adjust the amount of fuel injected, injection timing/scheduling, injection pressure, amount of exhaust gas retention (EGR), or any other suitable factors to achieve a desired engine load and combustion phasing, based on the fuel detected by the on-board sensor.
This type of versatility can allow an owner or operator of the engine to choose a fuel that is most available, most affordable, or a fuel that meets any other desired criterion on any given occasion. The fuel-agnostic combustion process can de-couple the desirable attributes of the diesel cycle from fuel having ignition characteristics similar to those of diesel fuel. Fuels can instead be chosen based on other factors, such as cost, availability, carbon intensity, or emissions criteria.

[0013]
FIG. 2 shows a compression ignition (CI) engine 200 that includes a cylinder 210, a piston 220 configured to move in the cylinder 210, a head deck 225, an intake valve 230, and an exhaust valve 240. The cylinder 210, piston 220, head deck 225, intake valve 230, and exhaust valve 240 collectively define the combustion chamber 250. The intake valve 230 can cover an intake port (not shown) and the intake valve 230 can be opened to uncover the intake port (i.e., to allow fluid flow through the intake port). The exhaust valve 240 can cover an exhaust port and the exhaust valve 240 can be opened to uncover the exhaust port (i.e., to allow fluid flow through the exhaust port). In some embodiments, the CI engine 200 can be absent of the intake valve 230 and the exhaust valve 240 and simply include the intake ports and the exhaust ports. As a non-limiting example of such an embodiment, a two-stroke engine can be absent of intake valves and/or exhaust valves.

[0014]
In some embodiments, the CI engine 200 can be absent a cylinder head, such as in the case of an opposed piston engine. In such cases, the boundaries of the combustion chamber 250 can be defined by other surfaces, such as multiple pistons, a cylinder wall, and/or other boundaries creating the combustion chamber.

[0015]
In some embodiments, the CI engine 200 can have a non-cylindrical combustion chamber, as in the case of a Wankel-style rotary engine or other rotary engine designs. In this case, rather than a "cylinder" the engine has a combustion chamber defined by pi ston(s) and a combustion chamber wall.

[0016]
As shown, the CI engine 200 further includes a first fuel supply 260a, a second fuel supply 260b (collectively referred to as fuel supplies 260), an exhaust aftertreatment device 265, a fuel injector 270, a sensor 272, a crankshaft 280, a recirculation path 290, and an EGR
cooler 295. The intake valve 240 and the exhaust valve 250 can both be in contact with camshafts (not shown) that rotate to open and close the intake valve 240 and the exhaust valve 250 in accordance with the timing and distance necessary to achieve the desired intake. In some embodiments, the intake valve 240 and the exhaust valve 250 can operate with a variable valve timing (VVT) scheme, as described in International Patent Publication WO

("the '287 publication"), filed May 14, 2020 and entitled "Cold Start for High-Octane Fuels in a Diesel Engine Architecture," the disclosure of which is hereby incorporated by reference in its entirety. In some embodiments, one or more components of the CI engine 200 can include a thermal barrier coating 255, as described in U.S. Patent No. 9,903,262 entitled, "Stoichiometric High-Temperature Direct-Inj ection Compression-Ignition Engine," filed April 6, 2015 ("the '262 patent"), the disclosure of which is incorporated herein by reference in its entirety. Examples of fuel agnostic implementations are described in International Patent Application No. PCT/US2021/019930 entitled, "Fuel Agnostic Compression Ignition Engine,"
filed February 26, 2021 ("the '930 patent"), the disclosure of which is incorporated herein by reference in its entirety.

[0017]
In some embodiments, the cylinder 210 can have a bore of at least about 1 cm, at least about 2 cm, at least about 3 cm, at least about 4 cm, at least about 5 cm, at least about 6 cm, at least about 7 cm, at least about 8 cm, at least about 9 cm, at least about 10 cm, at least about 20 cm, at least about 30 cm, at least about 40 cm, at least about 50 cm, at least about 60 cm, at least about 70 cm, at least about 80 cm, at least about 90 cm, or at least about 100 cm (1 m). In some embodiments, the cylinder 210 can have a bore of no more than about 100 cm (1 m), no more than about 90 cm, no more than about 80 cm, no more than about 70 cm, no more than about 60 cm, no more than about 50 cm, no more than about 40 cm, no more than about 30 cm, no more than about 20 cm, no more than about 10 cm, no more than about 9 cm, no more than about 8 cm, no more than about 7 cm, no more than about 6 cm, no more than about cm, no more than about 4 cm, no more than about 3 cm, or no more than about 2 cm.

[0018]
Combinations of the above-referenced bore values of the cylinder 210 are also possible (e.g., at least about 1 cm and no more than about 100 cm, or at least about 5 cm and no more than about 20 cm), inclusive of all values and ranges therebetween. In some embodiments, the cylinder 210 can have a bore of about 1 cm, about 2 cm, about 3 cm, about 4 cm, about 5 cm, about 6 cm, about 7 cm, about 8 cm, about 9 cm, about 10 cm, about 20 cm, about 30 cm, about 40 cm, about 50 cm, about 60 cm, about 70 cm, about 80 cm, about 90 cm, about 100 cm, or larger than about 100 cm.

[0019]
As shown, the first fuel supply 260a is fluidically coupled to the fuel injector 270.
The fuel injector 270 injects fuel into the combustion chamber 250. As shown, the second fuel supply 260b is also fluidically coupled to the fuel injector 270. As shown, the first fuel supply 260a and the second fuel supply 260b are both fluidically coupled to the same fuel injector 270.
In some embodiments, the first fuel supply 260a can be fluidically coupled to a first fuel injector and the second fuel supply 260b can be fluidically coupled to a second fuel injector.

In some embodiments, the first fuel supply 260a can contain a first fuel and the second fuel supply 260b can contain a second fuel. In some embodiments, the second fuel can have a different cetane number, heating value, and/or chemical composition from the first fuel. As shown, the CI engine includes two fuel supplies 260a, 260b. In some embodiments, the CI
engine can include 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, or at least 20 fuel supplies 260, inclusive of all values and ranges therebetween. In some embodiments, the exhaust aftertreatment device 265 can include a three-way catalyst.

[0020]
As shown, the fuel injector 270 injects fuel parallel to the motion of the piston 220.
In some embodiments, the fuel injector 270 can inject fuel at an angle of about 5 , about 10 , about 15 , about 20 , about 25 , about 30 , about 35 , about 40 , about 45 , about 50', about 55 , about 60 , about 65 , about 70 , about 75 , about 80 , about 85 , or about 90 relative to the motion of the piston 220, inclusive of all values and ranges therebetween.

[0021]
In some embodiments, the piston 220 can include a low heat transfer piston.
In some embodiments, the piston 220 can include a full metal piston with an insulating material.
In some embodiments, the CI engine 200 can be absent of a piston, and the compression of the contents inside the combustion chamber 250 can be achieved via other means (e.g., in a Wankel rotary engine, where the compression of the contents in the combustion chamber occur via rotation of the rotor around an eccentric shaft).

[0022]
In some embodiments, the sensor 272 can detect or aid in detecting the type of fuel being injected into the combustion chamber 250. In some embodiments, the sensor 272 can detect or aid in detecting a certain property of the fuel once the fuel is combusted. In some embodiments, the sensor 272 can detect relative permittivity of the fuel being injected into the combustion chamber 250 or use the capacitive principle. In some embodiments, the sensor 272 can detect pH. In some embodiments, the sensor 272 can include a heating element such that the sensor 272 can detect a boiling point or a vaporization point of the fuel entering the combustion chamber 250. In some embodiments, the sensor 272 can include a pressure transducer. In some embodiments, the sensor 272 can include a temperature sensor or a temperature sensing device. In some embodiments, the sensor 272 can include tooling for infrared spectroscopy. In some embodiments, the sensor 272 can include a gel that changes color when it absorbs a certain type of fuel (e.g., carbon monoxide). In some embodiments, a light sensor can detect a change in color in the gel and can accordingly detect the type of fuel being injected. In some embodiments, if the sensor 272 is in the exhaust port, manifold, path, or near the aftertreatment device, then the detected oxygen content, temperature, and/or other quantities of the fuel or fuel's combustion products can be used to infer fuel attributes and inform a control mechanism to adjust the temperature control mechanism and fueling accordingly.

[0023]
In some embodiments, the sensor 272 can communicate with various components of the CI engine 200. In some embodiments, the sensor 272 can communicate with the recirculation path 290. For example, the sensor 272 can alert the recirculation path 290 to recirculate more exhaust to raise the temperature in the combustion chamber 250 when the sensor 272 detects a low cetane fuel. In some embodiments, the sensor 272 can communicate with the EGR cooler 295 to reduce cooling in order to raise the temperature in the combustion chamber 250 In some embodiments, the sensor 272 can communicate with a variable geometry turbocharger and/or any other variable exhaust restriction device to raise pressure in the exhaust manifold in order to drive a larger quantity of exhaust through the recirculation path 290. In some embodiments, the sensor 272 can communicate with a grid heater (not shown) to change the rate heat is added to a volume of air entering the combustion chamber 250. In some embodiments, the CI engine 200 can include an EGR crossover tube (not shown).
In some embodiments the sensor 272 can communicate with a variable valve timing mechanism to trap or re-breathe more or less exhaust to change the mass-averaged temperature of gases in the cylinder. In some embodiments, the sensor 272 can communicate with a flame stabilizer (not shown) to change the rate heat is added to the volume of air entering the combustion chamber 250. In some embodiments, the sensor 272 can communicate with a catalytic burner (not shown) to change the rate heat is added to the volume of air entering the combustion chamber 250. In some embodiments, the sensor 272 can communicate with a forced induction device (not shown) to compress air to a pressure greater than atmospheric pressure. In some embodiments, the sensor 272 can communicate with a turbocharger and/or supercharger (not shown) to change the amount of aftercooling on the turbocharger and/or supercharger. In some embodiments, the sensor 272 can communicate with a Roots blower (not shown) to change the amount of compression or aftercooling on the Roots blower. In some embodiments, the sensor 272 can substantially eliminate aftercooling on the turbocharger, supercharger, and/or other forced induction device. In some embodiments, the sensor 272 can communicate with the fuel injector 270 to modify the pressure at which fuel is injected from the fuel injector 270. In some embodiments, the sensor 272 can communicate with the fuel injector 270 to modify the timing or scheduling of fuel injection events.

[0024]
As shown, the sensor 272 is disposed in the combustion chamber 250. In some embodiments, the sensor 272 can be coupled to the fuel line at a point between the fuel supplies 260 and the fuel injector 270. In some embodiments, the sensor 272 can be coupled to a fuel tank or the fuel supply 260. In some embodiments, the sensor can be located inside the fuel tank. In some embodiments, the sensor can be coupled to an exhaust stream. In some embodiments, the sensor can be located in the exhaust port and/or exhaust manifold In some embodiments, the sensor can be located in the exhaust recirculation path 290.
In some embodiments, the sensor can be located near an aftcrtreatment device (e.g., the aftertreatment device 265). In some embodiments, the sensor 272 can be physically coupled to the fuel injector 270. In some embodiments, the sensor 272 can be physically coupled to the fuel injector 270 inside the combustion chamber 250. In some embodiments, the sensor 272 can be physically coupled to the fuel injector 270 outside the combustion chamber 250 In some embodiments, the sensor 272 can be disposed in a bowl region of the combustion chamber 250.
In some embodiments, the sensor 272 can be disposed in a squish region of the combustion chamber 250. In some embodiments, the CI engine can include multiple sensors disposed at different locations. In some embodiments the sensor 272 can be situated in the exhaust to detect temperature, oxygen concentration, or other quantities.

[0025]
Based on fuel properties the sensor 272 detects, thermal management techniques can be implemented to facilitate combustion with minimal ignition delay. For example, a grid heater can apply heat or increase its rate of heat supply based on the detection of a low-cetane fuel by the sensor 272 in order to minimize ignition delay.

[0026]
Based on fuel properties the sensor 272 detects, other attributes of the engine control can be implemented to facilitate combustion with desired phasing, such as adjusting injection timing or scheduling, addition of a pilot injection, adjusting injection pressure, exhaust back-pressure, EGR valve position, and/or any other engine control attributes.

[0027]
In some embodiments, the CI engine 200 can include an intake manifold (not shown). In some embodiments, the intake manifold can include a heater. In some embodiments, intake manifold heating can be implemented at ambient temperatures above 0 C. In some embodiments, the intake manifold heater operation can include idle or "off' operating conditions. In some embodiments, the CI engine 200 can include a control strategy of when to use and when not to use the intake manifold heating. In some embodiments, the CI
engine 200 can include a dedicated EGR cylinder (not shown). In some embodiments; the CI
engine 200 can include an external source of hot exhaust (not shown).

[0028]
In some embodiments, the CI engine 200 can include an aftercooler (not shown).
In some embodiments, the CI engine 200 can include an adjustable aftercooler bypass (not shown). In some embodiments, the CI engine 200 can employ the aftercooler bypass and control combustion air temperature.

[0029]
In some embodiments, the CI engine 200 can be equipped with a variable geometry turbocharger (VGT) or waste-gated turbocharger, allowing for adjustment of the work extracted and compression provided by the turbocharger, while simultaneously adjusting back-pressure in the exhaust manifold. In some embodiments, the CI engine 200 can be operated such that a VGT or other adjustable back-pressure device can be used to force higher flow of exhaust through the recirculation path in order to control intake conditions (e.g., temperature, pressure, and/or mixture composition of the intake charge).

[0030]
In some embodiments, the CI engine 200 can be equipped with an EGR pump, or an exhaust pumping device In some embodiments, the EGR pump or exhaust pumping device can be used to force exhaust through the recirculation path in the absence of a driving pressure gradient, or to overcome an adverse pressure gradient. In some embodiments, the EGR pump or exhaust pumping device can be used to control intake conditions (temperature, pressure, or mixture composition of the intake charge). In some embodiments, the EGR pump or exhaust pumping device can be coupled to one or many sensors detecting intake conditions, fuel properties, exhaust composition or properties, or other aspects of the engine's operation.

[0031]
FIG. 3 is a block diagram of a method 10 of operating a CI engine, according to an embodiment. As shown, the method 10 includes receiving a volume of intake charge in the combustion chamber at step 11. The method 10 optionally includes applying a temperature control strategy at step 12. In some embodiments the temperature control strategy at step 12 can take place prior to receiving intake charge in the combustion chamber at step 11. The method 10 optionally includes closing the intake valve at step 13, and optionally includes moving the piston from BDC to TDC at step 14. In some embodiments the combustion chamber contents are compressed by some other means than moving a piston from BDC to TDC such as in a rotary or Wankel engine. The method 10 includes injecting fuel into the combustion chamber at step 15, and combusting the fuel at step 16. The method 10 optionally includes injecting and combusting additional fuel (e.g., a second fuel) at step 17. In some embodiments, the CI engine and the combustion chamber can be same or substantially similar to the CI engine 200 and the combustion chamber 250, as described above with reference to FIG.
2.

[0032]
Step 11 includes receiving a volume of intake charge in the combustion chamber.
In some embodiments, using four-stroke engine crank angle convention, the intake process can begin at an engine crank angle of at least about 660 , at least about 665 , at least about 670 , at least about 675 , at least about 680 , at least about 685 , at least about 690 , at least about 695 , or at least about 700 . In some embodiments, the intake process can begin at an engine crank angle of no more than about 705', no more than about 700', no more than about 695', no more than about 690 , no more than about 685 , no more than about 6800, no more than about 675 , no more than about 670 , or no more than about 665 . Combinations of the above-referenced engine crank angles for the start of the intake process are also possible (e.g., at least about 660 and no more than about 7050 or at least about 665 and no more than about 700 ), inclusive of all values and ranges therebetween. In some embodiments, the intake process can begin at an engine crank angle of about 660 , of about 665 , of about 670 , about 675', about 680 , about 685 , about 690 , about 695 , about 700 , or about 7050 .

[0033]
In some embodiments, the volume of intake charge drawn into the combustion chamber during step 11 can include atmospheric air, humid air, air enriched with oxygen, air diluted with exhaust gas, air diluted with inert gas, air mixed with an amount of uncombusted fuel, or any combination thereof. In some embodiments, the volume of intake charge can be enriched with oxygen, such that the volume of intake charge has an oxygen content of at least about 25%, at least about 30%, at least about 35%, at least about 40%, at least about 45%, at least about 50%, or at least about 55% by volume. In some embodiments, the volume of intake charge can have an oxygen content of no more than about 60%, no more than about 55%, no more than about 50%, no more than about 45%, no more than about 40%, no more than about 35%, or no more than about 30% by volume. Combinations of the above-referenced values of oxygen content in the volume of intake charge are also possible (e.g., at least about 25% and no more than about 60% by volume or at least about 30% and no more than about 50% by volume), inclusive of all values and ranges therebetween. In some embodiments, the volume of intake charge can have an oxygen content of about 25%, about 30%, about 35%, about 40%, about 45%, about 50%, about 55%, or about 60% by volume.

[0034]
In some embodiments, the volume of intake charge drawn into the combustion chamber during step 11 can include fuel. In some embodiments, the volume of intake charge drawn into the combustion chamber during step 11 can include at least about 1%, at least about 2%, at least about 3%, at least about 4%, at least about 5%, at least about 6%, at least about 7%, at least about 8%, at least about 9%, at least about 10%, at least about 11%, at least about 12%, at least about 13%, at least about 14%, at least about 15%, at least about 16%, at least about 17%, at least about 18%, or at least about 19% v:v fuel. In some embodiments, the volume of intake charge drawn into the combustion chamber during step 11 can include no more than about 20%, no more than about 19%, no more than about 18%, no more than about 17%, no more than about 16%, no more than about 15%, no more than about 14%, no more than about 13%, no more than about 12%, no more than about 11%, no more than about 10%, no more than about 9%, no more than about 8%, no more than about 7%, no more than about 6%, no more than about 5%, no more than about 4%, no more than about 3%, or no more than about 2% v:v fuel. Combinations of the above-referenced volumetric percentages of fuel in the volume of intake charge are also possible (e.g., at least about 1% and no more than about 20% or at least about 5% and no more than about 15%), inclusive of all values and ranges therebetween. In some embodiments, the volume of intake charge drawn into the combustion chamber during step 11 can include about 1%, about 2%, about 3%, about 4%, about 5%, about 6%, about 7%, about 8%, about 9%, about 10%, about 11%, about 12%, about 13%, about 14%, about 15%, about 16%, about 17%, about 18%, about 19%, or about 20% v.v fuel.

At step 12, the method 10 optionally includes applying a temperature control strategy. In some embodiments, the temperature in the combustion chamber can be manipulated by heating the volume of intake charge prior to drawing the volume of intake charge into the combustion chamber. Since the charge is heated during the compression step of the engine cycle, inlet air temperatures can be increased before, during, or after intake, or before, during, or after the compression step to achieve a sufficiently high temperature in the combustion chamber prior to the injection of fuel into the combustion chamber.
In other words, the volume of intake charge can be heated to an intermediate value prior to or upon entering the combustion chamber, and then the compression in the combustion chamber can raise the temperature of the volume of intake charge (and the fuel) to a suitable combustion chamber with minimal ignition delay. As an example, the volume of intake charge can be heated to a temperature of about 130 C to achieve a pre-fuel injection temperature inside the combustion chamber of about 1100 C. In some embodiments, the volume of intake charge can be heated to a temperature of at least about 50 C, at least about 60 C, at least about 70 C, at least about 80 'V, at least about 90 'V, at least about 100 "V, at least about 110 C, at least about 120 CC, at least about 130 C, at least about 140 C, at least about 150 C, at least about 160 C, at least about 170 C, at least about 180 C, at least about 190 C, at least about 200 C, at least about 210 C, at least about 220 C, at least about 230 C, at least about 240 C, at least about 250 C, at least about 260 C, at least about 270 C, at least about 280 C, or at least about 290 C
prior to or upon entering the combustion chamber. In some embodiments, the volume of intake charge can be heated to a temperature of no more than about 300 CC, no more than about 290 C, no more than about 280 C, no more than about 270 C, no more than about 260 C, no more than about 250 C, no more than about 240 C, no more than about 230 C, no more than about 220 C, no more than about 210 C, no more than about 200 C, no more than about 190 C, no more than about 180 C, no more than about 170 C, no more than about 160 C, no more than about 150 C, no more than about 140 C, no more than about 130 CC, no more than about 120 C, no more than about 110 C, no more than about 100 C, no more than about 90 C, no more than about 80 C, no more than about 70 C, or no more than about 60 C prior to or upon entering the combustion chamber. Combinations of the above-referenced temperatures of the volume of intake charge prior to or upon entering the combustion chamber are also possible (e.g., at least about 50 C and no more than about 300 C or at least about 100 C and no more than about 200 C), inclusive of all values and ranges therebetween.
In some embodiments, the volume of intake charge can be heated to a temperature of about 50 C, about 60 'V, about 70 'V, about 80 'V, about 90 'V, about 100 C, about 110 'V, about 120 C, about 130 C, about 140 C, about 150 C, about 160 C, about 170 C, about 180 C, about 190 C, about 200 C, about 210 C, about 220 C, about 230 C, about 240 C, about 250 C, about 260 C, about 270 C, about 280 C, about 290 C, or about 300 C prior to or upon entering the combustion chamber.
[0036]
In some embodiments, step 12 can include eliminating aftercooling on a turbocharger, supercharger, and/or other forced induction device, using electric heating, adding heat from the engine's exhaust, adding or recirculating the engine's exhaust, or some other method to increase temperature. In some embodiments, adding heat from the CI
engine's exhaust can be via heat exchange (i.e., through the walls of a heat exchange apparatus). In some embodiments, adding heat from the CI engine's exhaust can include introducing hot exhaust gas into the volume of intake charge drawn into the combustion chamber (i.e., EGR).
In some embodiments, the volume of intake charge drawn into the combustion chamber upon opening the intake valve can include at least about 1%, at least about 2%, at least about 3%, at least about 4%, at least about 5%, at least about 10%, at least about 15%, at least about 20%, at least about 25%, at least about 30%, at least about 35%, at least about 40%, at least about 45%, at least about 50%, or at least about 55% by weight of recirculated exhaust gas. In some embodiments, the volume of intake charge drawn into the combustion chamber upon opening the intake valve can include no more than about 60%, no more than about 55%, no more than about 50%, no more than about 45%, no more than about 40%, no more than about

35%, no more than about 30%, no more than about 25%, no more than about 20%, no more than about 15%, no more than about 10%, no more than about 5%, no more than about 4%, no more than about 3%, or no more than about 2% by weight of recirculated exhaust gas.
Combinations of the above-referenced weight percentages of exhaust gas in the volume of intake charge drawn into the combustion chamber upon opening the intake valve are also possible (e.g., at least about 1% and no more than about 50% or at least about 10% and no more than about 30%), inclusive of all values and ranges therebetween. In some embodiments, the volume of intake charge drawn into the combustion chamber upon opening the intake valve can include about 1%, about 2%, about 3%, about 4%, about 5%, about 10%, about 15%, about 20%, about 25%, about 30%, about 35%, about 40%, about 45%, about 50%, about 55%, or about 60%
by weight of recirculated exhaust gas. In some embodiments, a burner with flame stabilization and/or a catalytic burner can be used to create hot combustion products in the intake channel of the CI
engine to elevate the temperature of the air drawn into the combustion chamber. In some embodiments a designated exhaust cylinder can be used to provide hot exhaust to the intake charge. In some embodiments hot exhaust or hot air can come to the intake charge from an external source In some embodiments, a grid heater can be used to apply heat to the volume of intake charge prior to being drawn into the combustion chamber.
[0037]
In addition to introducing higher temperature air or intake mixture into the CI
engine, an insulating effect within the CI engine can retain thermal energy that can achieve the sufficiently high pre-injection temperature to achieve combustion of any fuel in a diesel style architecture. In some embodiments, thermal insulation can include surface treatments, use of low thermal conductivity materials, elevated coolant temperatures, and/or any other method of reduced cooling. In some embodiments, the insulation can be located on the piston, on the intake valve surface, within the intake valve, on the exhaust valve surface, within the exhaust valve, on the cylinder head if present, and/or any other suitable locations in the CI engine.
Further examples of thermal insulation are described in the '262 patent.
[0038]
In some embodiments, any combination of the above-referenced thermal management methods can be used together in parallel and/or in series. In other words, a first thermal management method can be used for a first time period, and a second thermal management method can be used for a second time period. In some embodiments, the second thermal management method can be different from the first thermal management method. In some embodiments, the first time period can at least partially overlap with the second time period. In some embodiments, the first time period can fully overlap with the second time period. In some embodiments, the first time period can be separate from the second time period. In some embodiments, the first thermal management method can have a shorter response time than the second thermal management method. For example, in a transient situation, a heater (e.g., a grid heater or glow plug) can be used during the first time period and EGR can be used during the second time period. A heater has a shorter response time, and can be effective more quickly (i.e., in less than one second), while EGR can be slower to respond and be effective.

[0039]
In some embodiments, the method 10 can include implementing an EGR
recirculation strategy external to the combustion chamber. In some embodiments, the method can be implemented without EGR cooling up to a prescribed power level. In some embodiments, intake charge temperature can be controlled by limiting or fully eliminating EGR
cooling. In other words, the method 10 can be implemented without the use of a prechamber or a glow plug.
[0040]
In some embodiments, the first time period and/or the second time period can be about 20 ms, about 40 ms, about 60 ms, about 80 ms, 0.1 seconds, about 0.2 seconds, about 0.3 seconds, about 0.4 seconds, about 0.5 seconds, about 0.6 seconds, about 0.7 seconds, about 0.8 seconds, about 0.9 seconds, about 1 second, about 1.1 seconds, about 1.2 seconds, about 1.3 seconds, about 1.4 seconds, about 1.5 seconds, about 1.6 seconds, about 1.7 seconds, about 1.8 seconds, about 1.9 seconds, about 2 seconds, about 4 seconds, about 6 seconds, about 8 seconds, about 10 seconds, about 12 seconds, about 14 seconds, about 16 seconds, about 18 seconds, about 20 seconds, about 25 seconds, about 30 seconds, about 35 seconds, about 40 seconds, about 45 seconds, about 50 seconds, about 55 seconds, about 60 seconds, about 70 seconds, about 80 seconds, about 90 seconds, about 100 seconds, about 110 seconds, or about 120 seconds, inclusive of all values and ranges therebetween.
[0041]
The method 10 can further include closing the intake valve at step 13.
Closing the intake valve can be pertinent to engine designs that include an intake valve (e.g., some four-stroke engine designs), but can be irrelevant to engine designs without an intake valve (e.g.
some two-stroke engine designs). In some embodiments, the intake valve can be closed at an engine crank angle (using four-stroke engine crank angle convention) of at least about 160 , at least about 165', at least about 170', at least about 175', at least about 180', at least about 185', at least about 190 , at least about 195 , at least about 200 , at least about 205 , at least about 210 , at least about 215 , at least about 220 , at least about 225 , at least about 230 , at least about 235 , at least about 240 , at least about 245 , at least about 250 , or at least about 255 .
In some embodiments, the intake valve can be closed at an engine crank angle of no more than about 260 , no more than about 255 , no more than about 250 , no more than about 245 , no more than about 240', no more than about 235', no more than about 230', no more than about 225 , no more than about 220 , no more than about 215 , no more than about 210 , no more than about 205 , no more than about 200 , no more than about 195 no more than about 190 , no more than about 185 , no more than about 180 , no more than about 175 , no more than about 170 , or no more than about 165 . Combinations of the above-referenced engine crank angles for the closing of the intake valve are also possible (e.g., at least about 160' and no more than about 260 or at least about 1800 and no more than about 200 ), inclusive of all values and ranges therebetween. In some embodiments, intake valve can be closed at an engine crank angle of about 160', about 165', about 170 , about 175 , about 180", about 185", about 190 , about 195 , about 200 , about 205 , about 210 , about 215 , about 220 , about 225', about 230 , about 235 , about 240 , about 245 , about 250 , about 255 , or about 260 .
[0042]
The method 10 can further include closing the intake valve, or concluding the intake process, at step 13. Closing the intake valve can be pertinent to engine designs that include an intake valve (e.g., some four-stroke engine designs), but can be irrelevant to engine designs without an intake valve (e g some two-stroke engine designs) In some embodiments, the intake process can be concluded at a time, relative to the end of the compression process, of at least about 1 ms prior to the end of the compression process, at least about 2 ms prior to the end of the compression process, at least about 5 ms prior to the end of the compression process, at least about 10 ms prior to the end of the compression process, at least about 25 ms prior to the end of the compression process, at least about 50 ms prior to the end of the compression process, at least about 100 ms prior to the end of the compression process, at least about 250 ms prior to the end of the compression process, at least about 500 ms prior to the end of the compression process, or at least about 1 second prior to the end of the compression process. In some embodiments, the intake process can be concluded at a time of no more than about 1 second prior to the end of the compression process, no more than about 500 ms prior to the end of the compression process, no more than about 250 ms prior to the end of the compression process, no more than about 100 ms prior to the end of the compression process, no more than about 50 ms prior to the end of the compression process, no more than about 25 ms prior to the end of the compression process, no more than about 10 ms prior to the end of the compression process, no more than about 5 ms prior to the end of the compression process, no more than about 2 ms prior to the end of the compression process, or no more than about 1 ms prior to the end of the compression process.. Combinations of the above-referenced timing for the closing of the intake valve or end of induction process with respect to the end of the compression process are also possible (e.g., at least about 2 ms and no more than about 1 second, or at least about 10 ms and no more than about 50 ms prior to the end of the compression process), inclusive of all values and ranges therebetween. In some embodiments, intake valve can be closed or the intake process ended at a time with respect to the end of the compression process of about 1 ms prior, about 2 ms prior, about 5 ms prior, about 10 ms prior, about 25 ms prior, about 50 ms prior, about 100 ms prior, about 250 ms prior, about 500 ms prior, about 750 ms prior, or about 1 second prior to the end of the compression process.

[0043]
In some embodiments, thermal energy can be added to the CI engine during the compression stroke from sources other than the compression process. In some embodiments, the combustion chamber can include heating devices such as a glow plug, a hot air jet, plasma, and/or any other device for introduction of additional thermal energy to the volume of intake charge and/or the volume of fuel in the combustion chamber prior to ignition.
In some embodiments, the temperature of the volume of intake charge and/or the volume of fuel in the combustion chamber prior to ignition can be tuned to the ignition characteristics of each fuel being used in the engine. In some embodiments, the rise in temperature of the volume of intake charge and/or the volume of fuel in the combustion chamber can be held constant at a value high enough that any fuel to be used in the engine would ignite with minimal ignition delay (e.g., an ignition delay of less than 2 ms).
[0044]
The method 10 optionally includes moving the piston from BDC to TDC at step to compress the charge. Step 14 of the method 10 can include other ways of compressing the charge to a pressure higher than the pressure upon intake. In many engines compressing the charge can be accomplished using piston movement. In engines such as rotary or Wankel engines compressing the charge can be accomplished through other movement of components defining the combustion chamber boundary to accomplish the compression. In some embodiments, the CI engine can have a compression ratio of at least about 10.1, at least about 11:1, at least about 12:1, at least about 13:1, at least about 14:1, at least about 15:1, at least about 16:1, at least about 17:1, at least about 18:1, at least about 19:1, at least about 20:1, at least about 21:1, at least about 22:1, at least about 23:1, at least about 24:1, at least about 25:1, at least about 26:1, at least about 27:1, at least about 28:1, or at least about 29:1. In some embodiments, the CI engine can have a compression ratio of no more than about 30:1, no more than about 29:1, no more than about 28:1, no more than about 27:1, no more than about 26:1, no more than about 25:1, no more than about 24:1, no more than about 23:1, no more than about 22:1, no more than about 21:1, no more than about 20:1, no more than about 19:1, no more than about 18:1, no more than about 17:1, no more than about 16:1, no more than about 15:1, no more than about 14:1, no more than about 13:1, no more than about 12:1, or no more than about 11:1. Combinations of the above-referenced compression ratios are also possible (e.g., at least about 10:1 and no more than about 30:1 or at least about 13:1 and no more than about 20:1), inclusive of all values and ranges therebetween. In some embodiments, the CI
engine can have a compression ratio of about 10:1, about 11:1, about 12:1, about 13:1, about 14:1, about 15:1, about 16:1, about 17:1, about 18:1, about 19:1, about 20:1, about 21:1, about 22:1, about 23:1, about 24:1, about 25:1, about 26:1, about 27:1, about 28:1, about 29:1, or about 30:1.
[0045]
In some embodiments, moving the piston(s) or other features of the combustion chamber to accomplish compression can occur at least partially concurrently with the induction of intake charge into the combustion chamber. In some embodiments, moving the piston(s) or other features of the combustion chamber to accomplish compression can occur substantially concurrently with the induction of intake charge into the combustion chamber.
In some embodiments, moving the piston(s) or other features of the combustion chamber to accomplish compression can occur with little or no overlap to the induction of intake charge into the combustion chamber. In some embodiments, moving the piston from BDC to TDC (in the case of two-stroke, four-stroke, or other engine designs having BDC and TDC
designations) can occur at least partially concurrently with the closing of the intake valve. In some embodiments, moving the piston(s) or other features of the combustion chamber to accomplish compression can occur substantially concurrently with the induction of intake charge into the combustion chamber. In some embodiments, moving the piston(s) or other features of the combustion chamber to accomplish compression can occur with little or no overlap to the induction of intake charge into the combustion chamber.
[0046]
The method 10 includes injecting a volume of fuel into the combustion chamber at step 15. In some embodiments, the volume of fuel and the volume of intake charge can be introduced into the combustion chamber in a stoichiometric ratio. In some embodiments, the volume of fuel and the volume of intake charge can be introduced into the combustion chamber in a non-stoichiometric ratio.
[0047]
In some embodiments, the fuel can have a cetane number of at least about -10, at least about -5, at least about 0, at least about 5, at least about 10, atleast about 15, at least about 20, at least about 25, at least about 30, or at least about 35. In some embodiments, the fuel can have a cetane number of no more than about 40, no more than about 35, no more than about 30, no more than about 25, no more than about 20, no more than about 15, no more than about 10, no more than about 5, no more than about 0, or no more than about -5.
Combinations of the above-referenced cetane numbers of the fuel are also possible (e.g., at least about -10 and no more than about 40 or at least about 10 and no more than about 20), inclusive of all values and ranges therebetween. In some embodiments, the fuel can have a cetane number of about -10, about -5, about 0, about 5, about 10, about 15, about 20, about 25, about 30, about 35, or about 40. In some embodiments, the fuel can include naphtha, gasoline, alcohol, butanol, propanol, ethanol, methanol, gaseous hydrocarbons, natural gas, methane, ethane, propane, butane, hexane, alternative fuels, hydrogen, ammonia, syngas, and/or CO. In some embodiments, the fuel can include Cl (single carbon atom per molecule) hydrocarbons, C2 (two carbon atoms per molecule) hydrocarbons, C3 hydrocarbons, C4 hydrocarbons, and/or fuels having no carbon atoms. In some embodiments, the fuel can have a low amount of additives that result in a substantial change in cetane number. In some embodiments, the fuel can include a small amount of additives to modify lubricity or viscosity of the fuel.
[0048]
In some embodiments, the fuel can include any blend or combination of any of the aforementioned fuels (e.g., methanol/ethanol, methane/ethane, methane/propane, ethane/propane, m ethane/ethane/propane, methane/butane, ethane/butane, propane/butane, methane/ethane/butane, ethane/propane/butane, methane/ethane/propane/butane, hydrogen/syngas, hydrogen/CO). In some embodiments, the fuel can include any blend or combination of any of the aforementioned fuels with gasoline or any other high hydrocarbon fuels added thereto (e.g., methanol/ethanol + gasoline, methane/ethane +
gasoline, methane/propane + gasoline, ethane/propane + gasoline, methane/ethane/propane + gasoline, methane/butane + gasoline, ethane/butane + gasoline, propane/butane gasoline, methane/ethane/butane gasoline, ethane/propane/butane gasoline, methane/ethane/propane/butane + gasoline, hydrogen/syngas + gasoline, hydrogen/CO +
gasoline). In some embodiments, the fuel can include blends of two or more of the aforementioned fuels.
[0049]
In some embodiments, the fuel can include less than about 5,000 ppm, less than about 4,000 ppm, less than about 3,000 ppm, less than about 2,000 ppm, less than about 1,000 ppm, less than about 900 ppm, less than about 800 ppm, less than about 700 ppm, less than about 600 ppm, or less than about 500 ppm by weight of additives that result in a substantial change in cetane number. In some embodiments, the fuel can be substantially free of additives that result in a substantial change in cetane number.
[0050]
In some embodiments, the fuel can include less than about 5,000 ppm, less than about 4,000 ppm, less than about 3,000 ppm, less than about 2,000 ppm, less than about 1,000 ppm, less than about 900 ppm, less than about 800 ppm, less than about 700 ppm, less than about 600 ppm, or less than about 500 ppm by weight of additives that result in a substantial change in lubricity or viscosity. In some embodiments, the fuel can be substantially free of additives that result in a substantial change in lubricity or viscosity.
[0051]
In some embodiments, the fuel can have an octane number (i.e., calculated via (RON + MON)/2 method) of at least about 50, at least about 55, at least about 60, at least about 65, at least about 70, at least about 75, at least about 80, at least about 85, at least about 90, at least about 95, at least about 100, at least about 105, at least about 110, at least about 115, at least about 120, at least about 125, at least about 130, at least about 135, at least about 140, or at least about 145. In some embodiments, the fuel can have an octane number of no more than about 150, no more than about 145, no more than about 140, no more than about 135, no more than about 130, no more than about 125, no more than about 120, no more than about 115, no more than about 110, no more than about 105, no more than about 100, no more than about 95, no more than about 90, no more than about 85, no more than about 80, no more than about 75, no more than about 70, no more than about 65, no more than about 60, or no more than about Combinations of the above-referenced octane numbers are also possible (es, at least about 50 and no more than about 150 or at least about 80 and no more than about 120, inclusive of all values and ranges therebetween. In some embodiments, the fuel can have an octane number of about 50, about 55, about 60, about 65, about 70, about 75, about 80, about 85, about 90, about 95, about 100, about 105, about 110, about 115, about 120, about 125, about 130, about 135, about 140, about 145, or about 150.
[0052]
In some embodiments, the fuel can have a flash point of at least about 0 C, at least about 5 C, at least about 10 C, at least about 15 C, at least about 20 C, at least about 25 C, at least about 30 C, at least about 35 C, at least about 40 C, or at least about 45 C. In some embodiments, the fuel can have a flash point of no more than about 50 C, no more than about 45 C, no more than about 40 C, no more than about 35 C, no more than about 30 C, no more than about 25 C, no more than about 20 C, no more than about 15 C, no more than about 10 C, or no more than about 5 C. Combinations of the above-referenced flash points of the fuel are also possible (e.g., at least about 0 C and no more than about 50 C or at least about 10 C and no more than about 40 'V, inclusive of all values and ranges therebetween. In some embodiments, the fuel can have a flash point of about 0 C, about 5 C, about 10 C, about 15 C, about 20 C, about 25 C, about 30 C, about 35 C, about 40 C, about 45 C, or about 50 C.
[0053]
In some embodiments, the volume of fuel can be injected from a fuel injector (e.g., the fuel injector 270, as described above with reference to FIG. 2) at an injection pressure of at least about 400 bar (absolute), at least about 500 bar, at least about 600 bar, at least about 700 bar, at least about 800 bar, at least about 900 bar, at least about 1,000 bar, at least about 1,100 bar, at least about 1,200 bar, at least about 1,300 bar, at least about 1,400 bar, at least about 1,500 bar, at least about 1,600 bar, at least about 1,700 bar, at least about 1,800 bar, at least about 1,900 bar, at least about 2,000 bar, at least about 2,100 bar, at least about 2,200 bar, at least about 2,300 bar, at least about 2,400 bar, at least about 2,500 bar, at least about 2,600 bar, at least about 2,700 bar, at least about 2,800 bar, or at least about 2,900 bar. In some embodiments, the volume of fuel can be injected from the fuel injector at an injection pressure of no more than about 3,000 bat, no more than about 2,900 bar, no more than about 2,800 bar, no more than about 2,700 bar, no more than about 2,600 bar, no more than about 2,500 bar, no more than about 2,400 bar, no more than about 2,300 bar, no more than about 2,200 bar, no more than about 2,100 bar, no more than about 2,000 bar, no more than about 1,900 bar, no more than about 1,800 bar, no more than about 1,700 bar, no more than about 1,600 bar, no more than about 1,500 bar, no more than about 1,400 bar, no more than about 1,300 bar, no more than about 1,200 bar, no more than about 1,100 bar, no more than about 1,000 bar, no more than about 900 bar, no more than about 800 bar, no more than about 700 bar, no more than about 600 bar, no more than about 500 bar, no more than about 400 bar.
Combinations of the above-referenced injection pressures are also possible (e.g., at least about 400 bar and no more than about 3,000 bar or at least about 1,200 bar and no more than about 2,000 bar), inclusive of all values and ranges therebetween. In some embodiments, the fuel can be injected from the fuel injector at an injection pressure of about 800 bar, about 900 bar, about 1,000 bar, about 1,100 bar, about 1,200 bar, about 1,300 bar, about 1,400 bar, about 1,500 bar, about 1,600 bar, about 1,700 bar, about 1,800 bar, about 1,900 bar, about 2,000 bar, about 2,100 bar, about 2,200 bar, about 2,300 bar, about 2,400 bar, about 2,500 bar, about 2,600 bar, about 2,700 bar, about 2,800 bar, about 2,900 bar, or about 3,000 bar.
[0054]
In some embodiments, the fuel can include a fuel with 1 carbon atom per molecule (e.g., methane, methanol, CO). In some embodiments, the fuel can be free of carbon atoms (e.g., hydrogen, ammonia). In some embodiments, the fuel can include a fuel with at least about 1 carbon atom per molecule, at least about 2 carbon atoms per molecule, at least about 3 carbon atoms per molecule, at least about 4 carbon atoms per molecule, at least about 5 carbon atoms per molecule, at least about 6 carbon atoms per molecule, at least about 7 carbon atoms per molecule, at least about 8 carbon atoms per molecule, or at least about 9 carbon atoms per molecule. In some embodiments, the fuel can include a fuel with no more than about 10 carbon atoms per molecule, no more than about 9 carbon atoms per molecule, no more than about 8 carbon atoms per molecule, no more than about 7 carbon atoms per molecule, no more than about 6 carbon atoms per molecule, no more than about 5 carbon atoms per molecule, no more than about 4 carbon atoms per molecule, no more than about 3 carbon atoms per molecule, or no more than about 2 carbon atoms per molecule. Combinations of the above-referenced numbers of carbon atoms per molecule are also possible (e.g., at least about 1 carbon atom per molecule and no more than about 10 carbon atoms per molecule or at least about 1 carbon atom per molecule and no more than about 3 carbon atoms per molecule), inclusive of all values and ranges therebetween. In some embodiments, the fuel can include a fuel with about 1 carbon atom per molecule, about 2 carbon atoms per molecule, about 3 calbon atoms per molecule, about 4 carbon atoms per molecule, about 5 carbon atoms per molecule, about 6 carbon atoms per molecule, about 7 carbon atoms per molecule, about 8 carbon atoms per molecule, about 9 carbon atoms per molecule, or about 10 carbon atoms per molecule.
[0055]
In some embodiments, the volume of fuel can be injected at an engine crank angle (using four-stroke engine crank angle convention) of at least about 310 degrees, at least about 315 degrees, at least about 320 degrees, at least about 325 degrees, at least about 330 degrees, at least about 335 degrees, at least about 340 degrees, at least about 345 degrees, at least about 350 degrees, at least about 355 degrees, at least about 360 degrees, at least about 365 degrees, or at least about 370 degrees. In some embodiments, the volume of fuel can be injected at an engine crank angle of no more than about 375 degrees, no more than about 370 degrees, no more than about 365 degrees, no more than about 360 degrees, no more than about 355 degrees, no more than about 350 degrees, no more than about 345 degrees, no more than about 340 degrees, no more than about 335 degrees, no more than about 330 degrees, no more than about 325 degrees, no more than about 320 degrees, or no more than about 315 degrees.
Combinations of the above-referenced engine crank angles at injection of the volume of fuel are also possible (e.g., at least about 310 degrees and no more than about 375 degrees or at least about 330 degrees and no more than about 365 degrees), inclusive of all values and ranges therebetween. In some embodiments, the volume of fuel can be injected at an engine crank angle of about 310 degrees, about 315 degrees, about 320 degrees, about 325 degrees, about 330 degrees, about 335 degrees, about 340 degrees, about 345 degrees, about 350 degrees, about 355 degrees, about 360 degrees, about 365 degrees, about 370 degrees, or about 375 degrees [0056]
In some embodiments, the volume of fuel can be injected at a time at least about 10 ms prior to the end of the compression process, at least about 8 ms prior to the end of the compression process, at least about 6 ms prior to the end of the compression process, at least about 4 ms prior to the end of the compression process, at least about 2 ms prior to the end of the compression process, at least about 1 ms prior to the end of the compression process, at about the same time as the end of the compression process, at least about 1 ms after the end of the compression process, at least about 2 ms after the end of the compression process, at least about 4 ms after the end of the compression process, at least about 6 ms after the end of the compression process, at least about 8ms after the end of the compression process, at least about ms after the end of the compression process.
[0057]
In some embodiments, the volume of fuel can be injected at a time of no more than about 10 ms after the end of the compression process, no more than about 8 ms after the end of the compression process, no more than about 6 ms after the end of the compression process, no more than about 4 ms after the end of the compression process, no more than about 2 ms after the end of the compression process, no more than about 1 ms after the end of the compression process, no more than about 1 ms prior to the end of the compression process, no more than about 2 ms prior to the end of the compression process, no more than about 4 ms prior to the end of the compression process, no more than about 6 ms prior to the end of the compression process, no more than about 8 ms prior to the end of the compression process, or no more than about 10 ms prior to the end of the compression process.
Combinations of the above-referenced timing at injection of the volume of fuel are also possible (e.g., at least about 10 ms prior and no more than about 2 ms after the end of the compression process or at least about 5ms prior to the end of the compression process and no more than about lms after the end of the compression process), inclusive of all values and ranges therebetween. In some embodiments, the volume of fuel can be injected at a timing with respect to the end of the compression process (t = 0) of about -10 ms, about -8 ms, about -6 ms, about -4 ms, about -2 ms, about -1 ms, about 0 ms (or approximately coinciding with the end of the compression process), about 1 ms, about 2 ms, about 4 ms, about 6 ms, about 8 ms, or about 10 ms.
[0058]
In some embodiments, no more than 10% of the volume of fuel is injected prior to a crank angle degree (using four-stroke engine crank angle convention) of about 310 degrees, about 315 degrees, about 320 degrees, about 325 degrees, about 330 degrees, about 335 degrees, about 340 degrees, about 345 degrees, about 350 degrees, about 355 degrees, about 360 degrees, about 365 degrees, about 370 degrees, about 375 degrees, about 380 degrees, about 385 degrees, or about 390 degrees, inclusive of all values and ranges therebetween.
[0059]
In some embodiments, no more than 10% of the volume of fuel is injected prior to a timing in the engine cycle, with respect to the end of the compression process (t = 0) of about -10 ms, about -8 ms, about -6 ms, about -4 ms, about -2 ms, about -1 ms, approximately coinciding with the end of the compression process Oms, about 1 ms, about 2 ms, about 4 ms, about 6 ms, about 8 ms, about 10 ms, inclusive of all values and ranges therebetween.
[0060]
In some embodiments, injection of the volume of fuel can occur at least partially concurrently with moving the piston from BDC to TDC (in the case of two stroke, four stroke, or other engine designs having BDC and TDC designations). In some embodiments, injection of the volume of fuel can occur substantially concurrently with moving the piston from BDC
to TDC. In some embodiments, injection of the volume of fuel can occur with little or no overlap to moving the piston from BDC to TDC.
[0061]
In some embodiments, injection of the volume of fuel can occur at least partially concurrently with compressing the charge inside the combustion chamber. In some embodiments, injection of the volume of fuel can occur substantially concurrently with compressing the charge inside the combustion chamber. In some embodiments, injection of the volume of fuel can occur with little or no overlap to the compression process.
[0062]
In some embodiments, injection of the volume of fuel can be modified to control the rate of pressure rise in the combustion chamber from combustion of the volume of fuel.
Pressure rise rate is often treated as a constraint in engines in attempting to minimize engine noise and vibration. Some alternative combustion strategies (e.g., homogeneous charge compression ignition engines) can struggle to minimize pressure rise rate, particularly at high loads. Embodiments described herein relate to methods of controlling pressure rise rate by controlling the rate of combustion (i.e., by controlling mixing and injection in a mixing-limited system). In other words, pressure rise rate can be as low as desired to reduce noise and vibration, and controlled in the same manner as a conventional diesel engine.
[0063]
In some embodiments, the rate of pressure rise can be less than about 15 bar per crank angle degree, less than about 14 bar per crank angle degree, less than about 13 bar per crank angle degree, less than about 12 bar per crank angle degree, less than about 11 bar per crank angle degree, less than about 10 bar per crank angle degree, less than about 9 bar per crank angle degree, less than about 8 bar per crank angle degree, less than about 7 bar per crank angle degree, less than about 6 bar per crank angle degree, less than about 5 bar per crank angle degree, less than about 4 bar per crank angle degree, less than about 3 bar per crank angle degree, less than about 2 bar per crank angle degree, or less than about 1 bar per crank angle degree, inclusive of all values and ranges therebetween. In some embodiments, controlling the rate of pressure rise can be done independently from changing the injection timing of the volume of fuel. In some embodiments, controlling the rate of pressure rise from the combustion chamber can be exclusively via changing the injection timing of the volume of fuel. In some embodiments, injection timing can be changed by an engine control unit using either electrical or hydraulic means to trigger fuel injector opening at a desired time to shift timing either earlier or later. In some embodiments, injection timing can be changed mechanically based on a mechanical linkage to a cam or other device in response to changing operating conditions such as engine speed.
-)3 [0064]
In some embodiments, the rate of pressure rise can be less than about 36 MPa/ms, less than about 34 MPa/ms, less than about 32 MPa/ms, less than about 30 MPa/ms, less than about 28 MPa/ms, less than about 26 MPa/ms, less than about 24 MPanns, less than about 22 MPa/ms, less than about 20 MPa/ms, less than about 18 MPa/ms, less than about 16 MPa/ms, less than about 14 MPa/ms, less than about 12 MPa/ms, less than about 10 MPa/ms, less than about 8 MPa/ms, less than about 6 MPa/ms, less than about 4 MPa/ms, less than about 2 MPa/ms, or less than about 1 MPa/ms, inclusive of all values and ranges therebetween.
[0065]
In some embodiments, controlling the rate of pressure rise can be done independently from changing the inj ecti on timing of the volume of fuel In some embodiments, controlling the rate of pressure rise from the combustion chamber can be exclusively via changing the injection timing of the volume of fuel. In some embodiments, injection timing can be changed by an engine control unit using either electrical or hydraulic means to trigger fuel injector opening at a desired time to shift timing either earlier or later. In some embodiments, injection timing can be changed mechanically based on a mechanical linkage to a cam or other device in response to changing operating conditions such as engine speed.
[0066]
The method 10 includes combusting the volume of fuel at step 16. In some embodiments, combusting the volume of fuel at step 16 can occur at least partially concurrently with injecting the fuel into the combustion chamber at step 15. In some embodiments, step 16 can include combusting substantially all of the volume of fuel. In some embodiments, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 500 K, at least about 550 K, at least about 600 K, at least about 650 K, at least about 700 K, at least about 750 K, at least about 800 K, at least about 850 K, at least about 900 K, at least about 950 K, at least about 1,000 K, at least about 1,050 K, at least about 1,100 K, at least about 1,150 K, at least about 1,200 K, at least about 1,250 K, at least about 1,300 K, at least about 1,350 K, at least about 1,400 K, or at least about 1,500 K. In some embodiments, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,500 K, no more than about 1,450 K, no more than about 1,400 K, no more than about 1,350 K, no more than about 1,300 K, no more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, no more than about 1,100 K, no more than about 1,050 K, no more than about 1,000 K, no more than about 950 K, no more than about 900 K, no more than about 850 K, no more than about 800 K, no more than about 750 K, no more than about 700 K, no more than about 650 K, no more than about 600 K, or no more than about 550 K. Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e.g., at least about 500 K

and no more than about 1,500 K or at least about 700 K and no more than about 1,100 K), inclusive of all values and ranges therebetween. In some embodiments, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 500 K, about 550 K, about 600 K, about 650 K, about 700 K, about 750 K, about 800 K, about 850 K, about 900K, about 950K, about 1,000K, about 1,050K, about 1,100 K, about 1,150K, about 1,200 K, about 1,250 K, about 1,300 K, about 1,350K, about 1,400 K, or about 1,500 K
[0067]
In some embodiments, the volume-average temperature in the combustion chamber immediately prior to ignition can be a function of the cetane number of the fuel. In some embodiments, if the fuel has a cetane number between about 30 and about 40, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 700 K, at least about 750 K, at least about 800 K, at least about 850 K, at least about 900 K, at least about 950K, at least about 1,000 K, at least about 1,050 K, at least about 1,100 K, at least about 1,150 K, at least about 1,200 K, or at least about 1,250K. In some embodiments, if the fuel has a cetane number between about 30 and about 40, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,300 K, no more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, no more than about 1,100 K, no more than about 1,050 K, no more than about 1,000 K, no more than about 950 K, no more than about 900 K, no more than about 850 K, no more than about 800 K, or no more than about 750 K. Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e.g., at least about 700 K and no more than about 1,300 K or at least about 800 K
and no more than about 1,000 K), inclusive of all values and ranges therebetween. In some embodiments, if the fuel has a cetane number between about 30 and about 40, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 700 K, about 750 K, about 800 K, about 850 K, about 900 K, about 950 K, about 1,000 K, about 1,050 K, about 1,100 K, about 1,150 K, about 1,200 K, about 1,250 K, or about 1,300 K.
[0068]
In some embodiments, if the fuel has a cetane number between about 20 and about 30, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 800 K, at least about 850 K, at least about 900 K, at least about 950 K, at least about 1,000 K, at least about 1,050 K, at least about 1,100 K, at least about 1,150 K, at least about 1,200 K, at least about 1,250 K, at least about 1,300 K, or at least about 1,350 K.
In some embodiments, if the fuel has a cetane number between about 20 and about 30, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,400 K, no more than about 1,350 K, no more than about 1,300 K, no -)5 more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, no more than about 1,100 K, no more than about 1,050 K, no more than about 1,000 K, no more than about 950 K, no more than about 900 K, or no more than about 850 K.
Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e.g., at least about 800 K and no more than about 1,400 K or at least about 900 K and no more than about 1,100 K), inclusive of all values and ranges therebetween. In some embodiments, if the fuel has a cetane number between about 20 and about 30, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 800 K, about 850 K, about 900 K, about 950 K, about 1,000 K, about 1,050 K, about 1,100 K, about 1,150 K, about 1,200 K, about 1,250 K, about 1,300 K, about 1,350 K, or about 1,400 K.
[0069]
In some embodiments, if the fuel has a cetane number between about 10 and about 20, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 850 K, at least about 900 K, at least about 950 K, at least about 1,000 K, at least about 1,050 K, at least about 1,100 K, at least about 1,150 K, at least about 1,200 K, at least about 1,250 K, at least about 1,300 K, at least about 1,350 K, or at least about 1,400 K.
In some embodiments, if the fuel has a cetane number between about 10 and about 20, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,450 K, no more than about 1,400 K, no more than about 1,350 K, no more than about 1,300 K, no more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, no more than about 1,100 K, no more than about 1,050 K, no more than about 1,000 K, no more than about 950 K, or no more than about 900 K.
Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e.g., at least about 850 K and no more than about 1,450 K or at least about 950 K and no more than about 1,150 K), inclusive of all values and ranges therebetween. In some embodiments, if the fuel has a cetane number between about 10 and about 20, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 850 K, about 900 K, about 950 K, about 1,000 K, about 1,050 K, about 1,100 K, about 1,150 K, about 1,200 K, about 1,250 K, about 1,300 K, about 1,350 K, about 1,400 K, or about 1,450 K.
[0070]
In some embodiments, if the fuel has a cetane number between about 0 and about 10, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 950 K, at least about 1,000 K, at least about 1,050 K, at least about 1,100 K, at least about 1,150K, at least about 1,200K, at least about 1,250K, at least about 1,300K, at least about 1,350 K, at least about 1,400 K, at least about 1,450 K, or at least about 1,500 K.
In some embodiments, if the fuel has a cetane number between about 0 and about 10, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,550 K, no more than about 1,500 K, no more than about 1,450 K, no more than about 1,400 K, no more than about 1,350 K, no more than about 1,300 K, no more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, no more than about 1,100K, no more than about 1,050 K, or no more than about 1,000 K.
Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e g , at least about 950 K and no more than about 1,550 K or at least about 1,050 K and no more than about 1,250 K), inclusive of all values and ranges therebetween. In some embodiments, if the fuel has a cetane number between about 0 and about 10, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 950 K, about 1,000 K, about 1,050 K, about 1,100 K, about 1,150 K, about 1,200 K, about 1,250 K, about 1,300 K, about 1,350 K, about 1,400 K, about 1,450 K, about 1,500 K, or about 1,550 K.
[0071]
In some embodiments, if the fuel has a cetane number less than about 0, the volume-average temperature in the combustion chamber immediately prior to ignition can be at least about 1,050 K, at least about 1,100 K, at least about 1,150 K, at least about 1,200 K, at least about 1,250 K, at least about 1,300 K, at least about 1,350 K, at least about 1,400 K, at least about 1,450 K, at least about 1,500 K, at least about 1,550 K, or at least about 1,600 K. In some embodiments, if the fuel has a cetane number less than about 0, the volume-average temperature in the combustion chamber immediately prior to ignition can be no more than about 1,650 K, no more than about 1,600 K, no more than about 1,550 K, no more than about 1,400 K, no more than about 1,450 K, no more than about 1,400 K, no more than about 1,350 K, no more than about 1,300 K, no more than about 1,250 K, no more than about 1,200 K, no more than about 1,150 K, or no more than about 1,100 K. Combinations of the above-referenced volume-average temperatures in the combustion chamber immediately prior to ignition are also possible (e.g., at least about 1,050 K and no more than about 1,650 K or at least about 1,150 K and no more than about 1,350 K), inclusive of all values and ranges therebetween. In some embodiments, if the fuel has a cetane number of less than about 0, the volume-average temperature in the combustion chamber immediately prior to ignition can be about 1,050 K, about 1,100 K, about 1,150 K, about 1,200 K, about 1,250 K, about 1,300 K, about 1,350 K, about 1,400 K, about 1,450 K, about 1,500 K, about 1,550 K, about 1,600 K, or about 1,650 K.

[0072]
In some embodiments, less than 50% of the volume of fuel can be pre-mixed with the volume of intake charge upon initiation of combustion. In other words, the ignition of the volume of fuel can be fluxing controlled, or MCCI. In some embodiments, the fuel can include gasoline, and the ignition of the volume of fuel can include MCCI of gasoline (i.e., not HCCI
of gasoline, nor HCCI of any other fuel). In some embodiments, at least about 5%, at least about 10%, at least about 15%, at least about 20%, at least about 25%, at least about 30%, at least about 35%, at least about 40%, or at least about 45% of the volume of fuel can be pre-mixed with the volume of intake charge upon initiation of combustion. In some embodiments, no more than about 50%, no more than about 45%, no more than about 40%, no more than about 35%, no more than about 30%, no more than about 25%, no more than about 20%, no more than about 15%, or no more than about 10% of the volume of fuel can be pre-mixed with the volume of intake charge upon initiation of combustion. Combinations of the above-referenced percentages of the volume of fuel pre-mixed with the volume of intake charge are also possible (e.g., at least about 5% and no more than about 50% or at least about 10% and no more than about 40%), inclusive of all values and ranges therebetween. In some embodiments, about 5%, about 10%, about 15%, about 20%, about 25%, about 30%, about 35%, about 40%, about 45%, or about 50% of the volume of fuel can be pre-mixed with the volume of intake charge upon initiation of combustion. In some embodiments, the local equivalence ratio at points within the combustion chamber can be at least about 1.5, at least about 2, at least about 3, at least about 4, at least about 5, at least about 6, at least about 7, at least about 8, at least about 9, or at least about 10, inclusive of all values and ranges therebetween.
[0073]
In some embodiments, at least about 25% of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber. In some embodiments, at least about 30% of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber. In some embodiments, at least about 35%, at least about 40%, at least about 45%, at least about 50%, at least about 55%, at least about 60%, at least about 65%, at least about 70%, at least about 75%, at least about 80%, at least about 85%, or at least about 90% of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber. In some embodiments, no more than about 95%, no more than about 90%, no more than about 85%, no more than about 80%, no more than about 75%, no more than about 70%, no more than about 65%, no more than about 60%, no more than about 55%, no more than about 50%, no more than about 45%, no more than about 40%, no more than about 35%, or no more than about 30%
of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber. Combinations of the above-referenced percentages of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber (e.g., at least about 40% and no more than about 95% or at least about 60% and no more than about 80%), inclusive of all values and ranges therebetween. In some embodiments, about 25%, about 30%, about 35%, about 40%, about 45%, about 50%, about 55%, about 60%, about 65%, about 70%, about 75%, about 80%, about 85%, about 90%, or about 95% of the energy generated from combustion of the volume of fuel can be generated while the volume of fuel is being injected into the combustion chamber.
[0074]
In some embodiments, the volume of intake charge can have a temperature of at least about 80 C, at least about 90 C, at least about 100 C, at least about 150 C, at least about 200 C, at least about 250 'V, at least about 300 "V, at least about 350 'V, at least about 400 C, at least about 450 'V, at least about 500 C, at least about 550 C, at least about 600 C, at least about 650 C, at least about 700 C, or at least about 750 C upon initially being drawn into the combustion chamber. In some embodiments, the volume of intake charge can have a temperature of no more than about 800 C, no more than about 750 C, no more than about 700 C, no more than about 650 C, no more than about 600 C, no more than about 550 CC, no more than about 500 CC, no more than about 450 CC, no more than about 400 C, no more than about 350 C, no more than about 300 C, no more than about 250 C, no more than about 200 C, no more than about 150 C, no more than about 100 C, or no more than about 90 C upon initially being drawn into the combustion chamber. Combinations of the above-referenced temperatures of the volume of intake charge upon initially being drawn into the combustion chamber are also possible (e.g., at least about 80 C and no more than about 800 C or at least about 200 C and no more than about 600 C), inclusive of all values and ranges therebetween. In some embodiments, the volume of intake charge can have a temperature of about 80 C, about 90 C, about 100 C, about 150 C, about 200 C, about 250 C, about 300 C, about 350 C, about 400 C, about 450 C, about 500 C, about 550 C, about 600 C, about 650 'V, about 700 'V, about 750 C, or about 800 C upon initially being drawn into the combustion chamber. In some embodiments, the volume of fuel can produce, upon continued injection, a mixing-limited plume. In some embodiments, the volume of fuel and the volume of intake charge can combine in a chemical reaction in the mixing-limited plume.
[0075]
In some embodiments, a delay between the initial injection of the volume of fuel into the combustion chamber and the onset of combustion can be less than about 5 ms, less -)9 than about 4.9 ms, less than about 4.8 ms, less than about 4.7 ms, less than about 4.6 ms, less than about 4.5 ms, less than about 4.4 ms, less than about 4.3 ms, less than about 4.2 ms, less than about 4.1 ms, less than about 4 ms, less than about 3.9 ins, less than about 3.8 ms, less than about 3.7 ms, less than about 3.6 ms, less than about 3.5 ms, less than about 3.4 ms, less than about 3.3 ms, less than about 3.2 ms, less than about 3.1 ms, less than about 3 ms, less than about 2.9 ms, less than about 2.8 ms, less than about 2.7 ms, less than about 2.6 ms, less than about 2.5 ms, less than about 2.4 ms, less than about 2.3 ms, less than about 2.2 ms, less than about 2.1 ms, less than about 2 ms, less than about 1.9 ms, less than about 1.8 ms, less than about 1.7 ms, less than about 1.6 ms, less than about 1.5 ms, less than about 1.4 ms, less than about 1.3 ms, less than about 1.2 ms, less than about 1.1 ms, less than about 1 ms, less than about 0.9 ms, less than about 0.8 ms, less than about 0.7 ms, less than about 0.6 ms, or less than about 0.5 ms, inclusive of all values and ranges therebetween.
[0076]
In some embodiments, the method 10 can include opening and closing the exhaust valve to exhaust combusted fuel, uncombusted fuel, excess air, and/or other gases or liquids.
In some embodiments, the exhaust process to expel combusted fuel, uncombusted fuel, excess air, and/or other gases or liquids can take place in absence of an exhaust valve. Opening or closing the exhaust valve can be pertinent to engine designs that include an exhaust valve (e.g., some four-stroke engine designs), but can be irrelevant to engine designs without an exhaust valve (e.g. some two-stroke engine designs). In some embodiments, the exhaust process can be started at a time, relative to the end of the work extraction process, of at least about is prior to the end of the work extraction process, at least about 750 ms prior to the end of the work extraction process, at least about 500 ms prior to the end of the work extraction process, at least about 250 ms prior to the end of the work extraction process, at least about 100 ms prior to the end of the work extraction process, at least about 50 ms prior to the end of the work extraction process, at least about 10 ms prior to the end of the work extraction process, at least about 5 ms prior to the end of the work extraction process, at least about 2 ms prior to the end of the work extraction process, at least about 1 ms prior to the end of the work extraction process, approximately coincident with the end of the work extraction process, at least about 1 ms after the end of the work extraction process, at least about 2 ms after the end of the work extraction process, at least about 5 ms after the end of the work extraction process, at least about 10 ms after the end of the work extraction process, at least about 25ms after the end of the work extraction process, at least about 50 ms after the end of the work extraction process, at least about 100 ms after the end of the work extraction process, at least about 250 ms after the end of the work extraction process, at least about 500 ms after the end of the work extraction process, at least about 750 ms after the end of the work extraction process, or at least about is after the end of the work extraction process. In some embodiments, the exhaust process can begin at least about 1 second, at least about 750 ms, at least about 500 ins, at least about 250 ms, at least about 100 ms, at least about 50 ms, at least about 25 ms, at least about 10 ms, at least about 5 ms, at least about 2 ms, or at least about 1 ms prior to the end of the work extraction process.
[0077]
In some embodiments the exhaust process can begin at no more than about lms after the work extraction process, no more than about 2 ms after the work extraction process, no more than about 5 ms after the work extraction process, no more than about 10 ms after the work extraction process, no more than about 25 ms after the work extraction process, no more than about 50 ms after the work extraction process, no more than about 100 ms after the work extraction process, no more than about 250 ms after the work extraction process, no more than about 500 ms after the work extraction process, no more than about 750 ms after the work extraction process, or no more than about 1 second after the work extraction process.
Combinations of the above-referenced timing for beginning the exhaust process are also possible (e.g., at least about 10 ms before and no more than about 750 ms before conclusion of the work extraction, or at least about 50 ms and no more than about 100 ms before conclusion of the work extraction), inclusive of all values and ranges therebetween. In some embodiments, the exhaust valve can be opened at about 1 second, about 750 ms, about 500 ms, about 250 ms, about 100 ms, about 50 ms, about 25 ms, about 10 ms, about 5 ms, about 2 ms, about or about 1 ms prior to the end of the work extraction, or about 1 ms, about 2 ms, about 5 ms, about 10 ms, about 25 ms, about 50 ms, about 100 ms, about 250 ms, about 500 ms, about 750 ms, or about 1 second after the end of the work extraction process.
[0078]
In some embodiments, the closing of the exhaust valve can be timed to trap exhaust gas in the combustion chamber to aid in thermal management. In some embodiments, the closing of the exhaust valve can be timed to re-introduce exhaust gas into the combustion chamber to aid in thermal management. In some embodiments (using four-stroke engine crank angle convention), the exhaust valve can be closed at an engine crank angle of at least about -20 , at least about -15 , at least about -10 , at least about -5 , at least about 0 , at least about 50, or at least about 10 . In some embodiments, the exhaust valve can be closed at an engine crank angle of no more than about 150, no more than about 100, no more than about 5 , no more than about 0 , no more than about -5 , no more than about -10 , or no more than about -IS . Combinations of the above-referenced engine crank angles for the closing of the exhaust valve are also possible (e.g., at least about -20 and/or no more than about 150 or at least about -10 and no more than about 5 ), inclusive of all values and ranges therebetween. In some embodiments, the exhaust valve can be closed at an engine crank angle of about -20 , about -IS', about -10', about -5', about 0', about 5', about 10', or about 15' [0079]
In some embodiments, the method 10 can include injecting and combusting additional fuel at step 17. In some embodiments, a first fuel can be injected during step 15, and a second fuel can be injected during step 17, the second fuel having a different cetane number, heating value, and/or chemical composition from the first fuel. In some embodiments, the second fuel can be injected during a different engine cycle than the first fuel. In some embodiments, the second fuel can be subject to the same or substantially similar steps as those described above with reference to the first fuel. In other words, the method 10 can include receiving a second volume of intake charge into the combustion chamber, optionally applying a temperature control strategy, closing the intake valve, moving the piston from BDC to TDC, injecting a volume of the second fuel into the combustion chamber, and combusting substantially all of the volume of the second fuel. In some embodiments, the second fuel can be subject to the same or substantially similar parameters (e.g., engine crank angle upon fuel injection, pressure of fuel upon injection, ignition delay, etc.) as those described above with reference to the first fuel.
[0080]
In some embodiments, the volume of intake charge received at step 11 can have a first temperature just prior to the injection of the first fuel (i.e., 0.5 ms, 1 ms, 1.5 ms, or 2 ms prior to the beginning of the injection of the first fuel). In some embodiments, the second volume of intake charge can have a second temperature just prior to the injection of the second fuel. In some embodiments, the second temperature can be greater than the first temperature by about 1 `V, about 2 C, about 3 C, about 4 C, about 5 'V, about 6 C, about 7 C, about 8 C, about 9 C, about 10 C, about 15 C, about 20 C, about 25 C, about 30 C, about 35 C, about 40 C, about 45 C, about 50 C, about 60 C, about 70 C, about 80 C, about 90 C, or about 100 C.
[0081]
In some embodiments, the second fuel can have a different cetane number from the first fuel. In some embodiments, the second fuel can have a higher cetane number than the first fuel. In some embodiments, the second fuel can have a lower cetane number than the first fuel.
In some embodiments, the second fuel can have a cetane number of at least about -5, at least about 0, at least about 5, at least about 10, at least about 15, at least about 20, at least about 25, at least about 30, at least about 35, at least about 40, at least about 45, at least about 50, at least about 55, at least about 60, or at least about 65. In some embodiments, the second fuel can have a cetane number of no more than about 70, no more than about 65, no more than about 60, no more than about 55, no more than about 50, no more than about 45, no more than about 40, no more than about 35, no more than about 30, no more than about 25, no more than about 20, no more than about 15, no more than about 10, no more than about 5, or no more than about 0. Combinations of the above-referenced cetane numbers of the second fuel are also possible (e.g., at least about -5 and no more than about 70 or at least about 20 and no more than about 50), inclusive of all values and ranges therebetween. In some embodiments, the second fuel can have a cetane number of about -5, about 0, about 5, about 10, about 15, about 20, about 25, about 30, about 35, about 40, about 45, about 50, about 55, about 60, about 65, or about 70.

In some embodiments, the second fuel can have a different octane number from the first fuel. In some embodiments, the second fuel can have a lower octane number than the first fuel. In some embodiments, the second fuel can have a higher octane number than the first fuel. In some embodiments, the second fuel can have an octane number of at least about 40, at least about 45, at least about 50, at least about 55, at least about 60, at least about 65, at least about 70, at least about 75, at least about 80, at least about 85, at least about 90, at least about 95, at least about 100, at least about 105, at least about 110, at least about 115, at least about 120, at least about 125, at least about 130, or at least about 135. In some embodiments, the fuel can have an octane number of no more than about 140, no more than about 135, no more than about 130, no more than about 125, no more than about 120, no more than about 115, no more than about 110, no more than about 105, no more than about 100, no more than about 95, no more than about 90, no more than about 85, no more than about 80, no more than about 75, no more than about 70, no more than about 65, no more than about 60, no more than about 55, no more than about 50, or no more than about 45. Combinations of the above-referenced octane numbers are also possible (e.g., at least about 40 and no more than about 140 or at least about 70 and no more than about 110, inclusive of all values and ranges therebetween. In some embodiments, the fuel can have an octane number of about 40, about 45, about 50, about 55, about 60, about 65, about 70, about 75, about 80, about 85, about 90, about 95, about 100, about 105, about 110, about 115, about 120, about 125, about 130, about 135, or about 140.

In some embodiments, a sensor can adjust conditions in the engine based on the fuel being injected. In some embodiments, the sensor can have the same or substantially similar properties to the sensor 272, as described above with reference to FIG. 2. In some embodiments, conditions of the combustion can be adjusted based on the type of fuel being injected. In some embodiments, the parameters of the temperature control mechanism can be modified based on the type of fuel being injected. For example, if the second fuel has a higher cetane number than the first fuel, the intensity of the heat applied to the volume of intake charge prior to injection can be reduced, as the temperature inside the combustion chamber would not have to be as high to facilitate a timely ignition (e.g., less than about 2 ms) of the second fuel.
In some embodiments, the crank angle at fuel injection can be modified based on the type of fuel being injected. In some embodiments, the composition of the volume of intake charge drawn into the combustion chamber can change based on the type of fuel being injected. For example, a fuel with a higher cetane number may not have to be mixed with a volume of intake charge with as high of a level of oxygen enrichment as a lower cetane fuel in order to ignite timely. In some embodiments, the pressure in the combustion chamber can be modified based on the type of fuel being injected.
[0084]
In some embodiments, the first fuel can be injected during a first time period and the second fuel can be injected during a second time period. In some embodiments, the first time period can have substantially no overlap with the second time period. In some embodiments, the first time period can have a partial overlap with the second time period. In other words, the first fuel can be phased out while the second fuel is phased in. In some embodiments, the first time period can have a substantial overlap with the second time period.
In some embodiments, an overlap period between the first time period and the second time period can be at least about 0.1 seconds, at least about 0.2 seconds, at least about 0.3 seconds, at least about 0.4 seconds, at least about 0.5 seconds, at least about 0.6 seconds, at least about 0.7 seconds, at least about 0.8 seconds, at least about 0.9 seconds, at least about 1 second, at least about 2 seconds, at least about 3 seconds, at least about 4 seconds, at least about 5 seconds, at least about 6 seconds, at least about 7 seconds, at least about 8 seconds, or at least about 9 seconds. In some embodiments, the overlap period between the first time period and the second time period can be no more than about 10 seconds, no more than about 9 seconds, no more than about 8 seconds, no more than about 7 seconds, no more than about 6 seconds, no more than about 5 seconds, no more than about 4 seconds, no more than about 3 seconds, no more than about 2 seconds, no more than about 1 second, no more than about 0.9 seconds, no more than about 0.8 seconds, no more than about 0.7 seconds, no more than about 0.6 seconds, no more than about 0.5 seconds, no more than about 0.4 seconds, no more than about 0.3 seconds, or no more than about 0.2 seconds. Combinations of the above-referenced overlap periods between the first time period and the second time period are also possible (e.g., at least about 0.1 seconds and no more than about 10 seconds or at least about 0.3 seconds and no more than about 0.5 seconds), inclusive of all values and ranges therebetween. In some embodiments, the overlap period between the first time period and the second time period can be about 0.1 seconds, about 0.2 seconds, about 0.3 seconds, about 0.4 seconds, about 0.5 seconds, about 0.6 seconds, about 0.7 seconds, about 0.8 seconds, about 0.9 seconds, about 1 second, about 2 seconds, about 3 seconds, about 4 seconds, about 5 seconds, about 6 seconds, about 7 seconds, about 8 seconds, about 9 seconds, or about 10 seconds.
[0085]
In some embodiments, the method 10 can further include injecting and combusting a third fuel, the third fuel different from the first fuel and the second fuel. In some embodiments, the method 10 can include injecting and combusting a fourth, a fifth, a sixth, a seventh, an eighth, a ninth, a tenth fuel, an eleventh fuel, a twelfth fuel, a thirteenth fuel, a fourteenth fuel, a fifteenth fuel, a sixteenth fuel, a seventeenth fuel, an eighteenth fuel, a nineteenth fuel, a twentieth fuel, or any number of additional fuels [0086]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented on an engine having ports for intake and exhaust processes, which are uncovered based on piston movement or based on movement of other components such as the "sleeve valve" design of a Cleeves cycle engine.
[0087]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented on an opposed piston engine, having two or more pistons working together to compress the gas through their combined motion, and to extract work through their combined motion. The opposed piston motion can be symmetric or asymmetric, and the intake and exhaust processes can proceed with or without conventional valves, ports, sleeve valves, or other means of blocking and unblocking a path for intake and exhaust processes.
[0088]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented in a free piston engine, where the piston is not coupled to a crank shaft directly, but rather moves freely in the combustion chamber, often coupled electromagnetically to a linear motor system to impart motion upon the piston and to extract electrical work resulting from the combustion. An example of a free piston architecture is that developed by Miller, Svrcek, Edwards, later commercialized by Main spring (originally Etagen).
[0089]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented in a non-conventional four-stroke or two-stroke architecture such as an engine employing an Atkinson linkage, Miller valve timing, or other methods to accomplish an asymmetric compression and expansion stroke.
[0090]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented in a low-speed engine, having rpm lower than about 200 rpm.
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be implemented in a high-speed engine, having rpm higher than about 3000 rpm.

[0091]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can be coupled to additional exhaust or other thermal energy extraction devices such as waste heat recovery (wherein a working fluid is used in a create additional work using thermal energy from the exhaust to run a thermodynamic cycle such as a Brayton, Stirling, Rankine, or other cycle).
[0092]
In some embodiments, the high-temperature fuel-agnostic strategy described herein can include a turbo-compounding device, where additional work can be extracted from the exhaust stream, than is needed to drive the compressor or forced induction stage. This additional work can be compounded mechanically to the drive shaft, extracted electrically, or used in some other useful way in the operation of the engine.
[0093]
In some embodiments, an engine can employ the strategies described herein in parallel. While independent use of each of these methods is possible, their combination is within the scope of this disclosure.
[0094]
Various concepts may be embodied as one or more methods, of which at least one example has been provided. The acts performed as part of the method may be ordered in any suitable way. Accordingly, embodiments may be constructed in which acts are performed in an order different than illustrated, which may include performing some acts simultaneously, even though shown as sequential acts in illustrative embodiments Put differently, it is to be understood that such features may not necessarily be limited to a particular order of execution, but rather, any number of threads, processes, services, servers, and/or the like that may execute serially, asynchronously, concurrently, in parallel, simultaneously, synchronously, and/or the like in a manner consistent with the disclosure. As such, some of these features may be mutually contradictory, in that they cannot be simultaneously present in a single embodiment. Similarly, some features are applicable to one aspect of the innovations, and inapplicable to others.
[0095]
In addition, the disclosure may include other innovations not presently described.
Applicant reserves all rights in such innovations, including the right to embodiment such innovations, file additional applications, continuations, continuations-in-part, divisionals, and/or the like thereof. As such, it should be understood that advantages, embodiments, examples, functional, features, logical, operational, organizational, structural, topological, and/or other aspects of the disclosure are not to be considered limitations on the disclosure as defined by the embodiments or limitations on equivalents to the embodiments.
Depending on the particular desires and/or characteristics of an individual and/or enterprise user, database configuration and/or relational model, data type, data transmission and/or network framework, syntax structure, and/or the like, various embodiments of the technology disclosed herein may

36 be implemented in a manner that enables a great deal of flexibility and customization as described herein.
[0096]
All definitions, as defined and used herein, should be wide' stood to control over dictionary definitions, definitions in documents incorporated by reference, and/or ordinary meanings of the defined terms.
[0097]
As used herein, in particular embodiments, the terms "about" or "approximately"
when preceding a numerical value indicates the value plus or minus a range of 10%. Where a range of values is provided, it is understood that each intervening value, to the tenth of the unit of the lower limit unless the context clearly dictates otherwise, between the upper and lower limit of that range and any other stated or intervening value in that stated range is encompassed within the disclosure. That the upper and lower limits of these smaller ranges can independently be included in the smaller ranges is also encompassed within the disclosure, subject to any specifically excluded limit in the stated range. Where the stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included in the disclosure.
[0098]
The phrase "and/or," as used herein in the specification and in the embodiments, should be understood to mean "either or both" of the elements so conjoined, i.e., elements that are conjunctively present in some cases and disjunctively present in other cases. Multiple elements listed with "and/or" should be construed in the same fashion, i.e., "one or more" of the elements so conjoined. Other elements may optionally be present other than the elements specifically identified by the "and/or" clause, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, a reference to "A
and/or B", when used in conjunction with open-ended language such as "comprising" can refer, in one embodiment, to A only (optionally including elements other than B); in another embodiment, to B only (optionally including elements other than A); in yet another embodiment, to both A
and B (optionally including other elements); etc.
[0099]
As used herein in the specification and in the embodiments, "or" should be understood to have the same meaning as "and/or" as defined above. For example, when separating items in a list, "or" or "and/or" shall be interpreted as being inclusive, i.e., the inclusion of at least one, but also including more than one, of a number or list of elements, and, optionally, additional unlisted items. Only terms clearly indicated to the contrary, such as "only one of" or "exactly one of," or, when used in the embodiments, "consisting of," will refer to the inclusion of exactly one element of a number or list of elements. In general, the term "or"
as used herein shall only be interpreted as indicating exclusive alternatives (i.e. "one or the

37 other but not both") when preceded by terms of exclusivity, such as "either,"
"one of," "only one of," or "exactly one of." "Consisting essentially of," when used in the embodiments, shall have its ordinary meaning as used in the field of patent law.
[0100]
As used herein in the specification and in the embodiments, the phrase "at least one," in reference to a list of one or more elements, should be understood to mean at least one element selected from any one or more of the elements in the list of elements, but not necessarily including at least one of each and every element specifically listed within the list of elements and not excluding any combinations of elements in the list of elements. This definition also allows that elements may optionally be present other than the elements specifically identified within the list of elements to which the phrase "at least one" refers, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, "at least one of A and B" (or, equivalently, "at least one of A or B," or, equivalently "at least one of A and/or B") can refer, in one embodiment, to at least one, optionally including more than one, A, with no B present (and optionally including elements other than B); in another embodiment, to at least one, optionally including more than one, B, with no A present (and optionally including elements other than A); in yet another embodiment, to at least one, optionally including more than one, A, and at least one, optionally including more than one, B
(and optionally including other elements); etc.
[0101]
As used herein, "fuel" can refer to any material capable of producing an exothermic chemical reaction with an intake mixture, regardless of the fuel's cetane number. This can include fuels and blends of: naphtha, gasoline, alcohol fuels (including butanol, propanol, ethanol, and methanol), gaseous hydrocarbons (including natural gas, methane, ethane, propane, butane, hexane, etc.) and alternative fuels such as hydrogen, ammonia, syngas, CO, etc.
[0102]
As used herein, "plume" can refer to a mass of fuel spreading from an injection point, which may be entraining or mixing with the volume of intake charge as it progresses spatially and/or temporally during a fuel injection event.
[0103]
As used herein, "intake charge" refers to a volume of material that enters a combustion chamber prior to a combustion event. The intake charge can include air, atmospheric air, humid air, air enriched with oxygen, air diluted with exhaust gas, air diluted with inert gas, fuel, uncombusted fuel, or any combination thereof.
[0104]
As used herein, "combustion efficiency" can refer to the degree to which air and fuel are fully combusted to form the products of complete combustion. As a non-limiting example, combustion efficiency can be calculated using lower heating value (LHV) of the fuel

38 (e.g., ethanol, methanol, etc.) and combustion products (e.g., CO2, H20, etc.), as set forth below:
LHVproductsmassproducts 71 combustion ¨ 1 LHV mass fuel fuel Where:
71 combustion is the combustion efficiency;
LliVproducts is the LHV of the combustion products (MJ/kg);
maSSproducts is the mass of the combustion products (kg);
LHVfue/ is the LHV of the fuel (MJ/kg); and massfuet is the mass of the fuel (kg).
[0105]
As used herein, "efficiency," "thermal efficiency," or "LHV efficiency" can refer to the conversion of fuel energy to mechanical work, calculated as follows:
Work 17 = LHVfueimass fuel Where:
17 is the efficiency;
Work is the amount of mechanical work achieved (J), which can be the indicated work calculated from the pressure in the engine cylinder, or the brake work, where the work is measured at the point of the rotating shaft going from the engine into a transmission or generator (i.e., the "brake thermal efficiency);
LHVfuei is the LHV of the fuel (J/kg); and massfuet is the mass of the fuel (kg).
[0106]
As used herein, a numerical definition of a "crank angle" or an "engine crank angle"
should be understood as the crank angle relative to a fixed point in the engine cycle (as described below in Table 1 for the case of a four-stroke engine). In other words, in a four-

39 stroke engine, the engine crank angle is 00 (or 7200) when the piston is in the TDC position between the exhaust stroke and the intake stroke. The engine crank angle is 3600 when the piston is in the TDC position between the compression stroke and the expansion stroke. The engine crank angle is 540 when the piston is in the BDC position between the expansion stroke and the exhaust stroke. The engine crank angle is 180 when the piston is in the BDC position between the intake stroke and the compression stroke. Negative numbers can also be used to describe the crank angle relative to the TDC position between the exhaust stroke and the intake stroke. In other words, 540' can also be described as -180', 360' can also be described as -360 , and 180 can also be described as -540 In a two-stroke engine, an engine cycle is 360 in duration, described in table 2 below. A six-stroke engine would likewise have 1080 total degrees.
Table 1. Crank Angle Descriptions for a Four Stroke Engine Crank Angle (Degrees) Piston Position Stroke Description 360 TDC Between compression stroke and expansion stroke. In some (-360) literature, this crank angle is referred to as "TDC
Combustion"
Between 360 and 540 Transitioning from Expansion stroke TDC to BDC
(Between -360 and -180) 540 BDC Between expansion stroke and exhaust stroke (-180) Between 540 and 720 Transitioning from Exhaust stroke BDC to TDC
(Between -180 and 0) 0 or 720 TDC Between exhaust stroke and intake stroke. In some literature, this crank angle is referred to as "TDC gas exchange"
Between 0 and 180 Transitioning from Intake stroke TDC to BDC
(Between -720 and -540) 180 BDC Between intake stroke and compression stroke (-540) Between 180 and 360 Transitioning from Compression stroke BDC to TDC
(Between -540 and -360) 360 TDC Between compression stroke and expansion stroke. In some (-360) literature, this crank angle is referred to as "TDC
Combustion"
Table 2: Crank angle convention for two-stroke engines Crank Angle (Degrees) Piston Position Stroke Description 0 TDC Between compression stroke and expansion stroke. In some (360) literature, this crank angle is referred to as "TDC
Combustion"
Between 1-180 Transitioning from Expansion stroke TDC to BDC

Between ¨90-270 Transition past BDC Exhaust, scavenging, and intake from expansion to compression Between 180 and 360 Transitioning from Compression stroke BDC to TDC
(Between -180 and 0) [0107]
In some embodiments, the term "immediately prior to ignition" or "just prior to ignition" can refer to a temporal point, at which the engine crank angle is about 3000, about 305 , about 310 , about 315 , about 320 , about 325 , about 330 , about 335 , about 340 , about 345 , about 350 , about 355 , about 360 , about 365 , about 370 , about 375 , or about 380 , inclusive of all values and ranges therebetween.
[0108]
In some embodiments, the term "immediately prior to ignition" or "just prior to ignition" can refer to a temporal point of approximately 50 ms, approximately

40 ms, approximately 30 ms, approximately 20 ms, approximately 10 ms, approximately 5 ms, approximately 2 ms, or approximately 1 ms prior to ignition, inclusive of all values and ranges therebetween.
[0109]
In some embodiments, the term "immediately prior to ignition" or "just prior to ignition" can refer to a temporal point preceding the time at which 5% of the fuel exothermi city is observed to have happened. In other words, the fuel can be considered to have ignited when a measurable deviation in pressure could be detected to indicate exothermic fuel oxidation is occurring.
[0110]
In some embodiments, the term "immediately prior to ignition- or "just prior to ignition" can refer to a temporal point about 1 crank angle degree, about 2 crank angle degrees, about 3 crank angle degrees, about 4 crank angle degrees, about 5 crank angle degrees, about 6 crank angle degrees, about 7 crank angle degrees, about S crank angle degrees, about 9 crank angle degrees, about 10 crank angle degrees, about 11 crank angle degrees, about 12 crank angle degrees, about 13 crank angle degrees, about 14 crank angle degrees, about 15 crank angle degrees, about 16 crank angle degrees, about 17 crank angle degrees, about 18 crank angle degrees, about 19 crank angle degrees, or about 20 crank angle degrees prior to ignition, inclusive of all values and ranges therebetween.

[0111]
In some embodiments, the term "immediately prior to ignition" or "just prior to ignition" can refer to a temporal point about 50 ms, about 40 ms, about 30 ms, about 20 ms, about 10 ms, about 5 ins, about 2 ins, or about 1 ins prim to ignition, inclusive of all values and ranges therebetween.
[0112]
In some embodiments, the term "immediately prior to fuel injection" or "just prior to fuel injection" can refer to a temporal point about 1 crank angle degree, about 2 crank angle degrees, about 3 crank angle degrees, about 4 crank angle degrees, about 5 crank angle degrees, about 6 crank angle degrees, about 7 crank angle degrees, about 8 crank angle degrees, about 9 crank angle degrees, about 10 crank angle degrees, about 11 crank angle degrees, about 12 crank angle degrees, about 13 crank angle degrees, about 14 crank angle degrees, about 15 crank angle degrees, about 16 crank angle degrees, about 17 crank angle degrees, about 18 crank angle degrees, about 19 crank angle degrees, or about 20 crank angle degrees prior to fuel injection, inclusive of all values and ranges therebetween.
[0113]
In some embodiments, the term "immediately prior to fuel injection" or "just prior to fuel injection" can refer to a temporal point about 50 ms, about 40 ms, about 30 ms, about 20 ms, about 10 ms, about 5 ms, about 2 ms, or about 1 ms prior to fuel injection, inclusive of all values and ranges therebetween.
[0114]
In some embodiments, the term "valve closing" (e.g., "intake valve closing"
or "exhaust valve closing") can refer to a temporal point, wherein the valve becomes fully seated (i.e., 0 mm valve lift). In some embodiments, the term "valve opening" (e.g., "intake valve opening" or "exhaust valve opening") can refer to a temporal point, wherein the valve becomes unseated (i.e., >0 mm lift).
[0115]
In the embodiments, as well as in the specification above, all transitional phrases such as "comprising," "including," "carrying," "having," "containing,"
"involving," "holding,"
"composed of," and the like are to be understood to be open-ended, i.e., to mean including but not limited to. Only the transitional phrases "consisting of' and "consisting essentially or shall be closed or semi-closed transitional phrases, respectively, as set forth in the United States Patent Office Manual of Patent Examining Procedures, Section 2111.03.
[0116]
In some embodiments, the novel, high-temperature mixing-controlled strategy described herein can be implemented in an opposed piston engine. This could include 2 or more pistons configured to compress an inducted charge, the engine potentially having no cylinder head. This could be a two-four-or other number of stroke design.
[0117]
While specific embodiments of the present disclosure have been outlined above, many alternatives, modifications, and variations will be apparent to those skilled in the art.

Accordingly, the embodiments set forth herein are intended to be illustrative, not limiting.
Various changes may be made without departing from the spirit and scope of the disclosure.
Where methods and steps described above indicate certain events occurring in a certain order, those of ordinary skill in the art having the benefit of this disclosure would recognize that the ordering of certain steps may be modified and such modification are in accordance with the variations of the invention Additionally, certain of the steps may be performed concurrently in a parallel process when possible, as well as performed sequentially as described above. The embodiments have been particularly shown and described, but it will be understood that various changes in form and details may be made

Claims

1. A method of operating a compression ignition engine, the compression ignition engine including a combustion chamber, the method comprising the steps of:
receiving a volume of intake charge in the combustion chamber;
compressing the intake charge;
injecting a volume of fuel into the combustion chamber, the fuel having a cetane number less than about 40; and combusting substantially all of the volume of fuel, wherein a delay between injecting the volume of fuel into the combustion chamber and initiation of combustion is less than about 2 ms, and wherein the compression ignition engine includes at least one of a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, or a Wankel rotary engine.

2. The method of claim 1 wherein the intake charge is manipulated to aid in producing a temperature in the combustion chamber sufficient to limit the delay between injecting the volume of fuel into the combustion chamber and initiation of combustion to be less than about 2 ms.

3. The method of claim 1, wherein no more than about 50% of the volume of the fuel is pre-mixed with the volume of intake charge upon initiation of combustion.

4. The method of claim 3, wherein no more than about 20% of the volume of fuel is pre-mixed with the volume of intake charge upon initiation of combustion.

5. The method of any of the preceding claims, wherein at least 40% of the energy generated from combusting the volume of fuel is generated while the volume of fuel is being injected into the combustion chamber.

6. The method of any of the preceding claims, wherein the effective compression ratio is between about 15:1 and about 25:1.

7. The method of any of the preceding claims, wherein the effective compression ratio is greater than about 15:1.

8. The method of any of the preceding claims, wherein the fuel is a first fuel, the volume of intake charge is a first volume of intake charge, and the timing of fuel injection is a first timing with respect to the events of the engine cycle, the method further comprising:
receiving a volume of intake charge in the combustion chamber;
compressing the intake charge;
injecting a volume of a second fuel into the combustion chamber at a second timing with respect to the events of the engine cycle, during a second time period, the second fuel having a different cetane number, heating value, and/or chemical composition from the first fuel;
combusting substantially all of the volume of the second fuel, wherein the second engine crank angle is sufficiently late in the compression process such that no more than about 50% of the volume of the second fuel is pre-mixed with the second volume of intake charge upon initiation of combustion.

9. The method of claim 8, wherein the second fuel has a cetane number lower than the cetane number of the first fuel.

10. The method of any of the preceding claims, wherein the volume of fuel and the volume of intake charge are introduced into the combustion chamber in a non-stoichiometric fuel-air ratio.

11. The method of any of the preceding claims, further comprising: applying a temperature control strategy to the volume of intake charge at any point prior to fuel inj ecti on.

12. The method of any of the preceding claims, further comprising:
applying a temperature control strategy to the volume of intake charge prior to it entering the combustion chamber.

13. The method of claim 1 1 or 12, wherein the temperature control strategy includes exposing the volume of intake charge to an electric heater.

14. The method of any of the preceding claims, wherein the volume of intake charge has a temperature of at least about 80 C prior to entering the combustion chamber.

15. The method of claim 11 or 12, wherein the temperature control strategy includes exposing the volume of intake charge to a burner with flame stabilization and/or a catalytic burner.

16 The method of any of the preceding claims, wherein the compression ignition engine includes a forced induction device to pressurize air from atmospheric pressure to a pressure higher than atmospheric pressure, including but not limited to a turbocharger and/or supercharger, compressor, and/or blower, the method further comprising:
substantially eliminating aftercooling on the forced induction device.

17. The method of any of claims 11-16, wherein the temperature control strategy includes transferring heat from an exhaust gas to the volume of intake charge.

18. The method of any of the preceding claims, wherein the temperature control strategy includes at least partial retention, rebreathing and/or recirculation of the exhaust gas.

19. The method of claim 18, wherein the exhaust gas is trapped, rebreathed, or manipulated to aid in producing a temperature in the combustion chamber sufficient to limit the delay between injecting the volume of fuel into the combustion chamber and initiation of combustion to be less than about 2 ms.

20. The method of claim 18 or 19, wherein the exhaust gas is at least partially mixed with a volume of air in the intake charge prior to receiving the intake charge in the combustion chamber.

21. The method of any of the preceding claims, wherein the volume of fuel produces, upon continued injection, a mixing-limited plume, reacting the volume of fuel and the volume of intake charge.

72. The method of any of the preceding claims, wherein the first fuel has a cetane number of less than about 10.

23. The method of any of the preceding claims, wherein the average temperature of the volume of intake charge in engine cylinder just prior to fuel injection is in a range between about 1000 K and about 1250 K.

24. The method of any of the preceding claims, wherein the volume of fuel includes less than about 3 wt% of additives that result in a substantial change in cetane number.

25. The method of claim 24, wherein the volume of fuel includes less than about 1 wt%
of additives that result in a substantial change in cetane number.

26. The method of claim 25, wherein the volume of fuel includes less than 1,000 ppm of additives that result in a substantial change in cetane number.

27. The method of any of the preceding claims, wherein the volume of intake charge includes atmospheric air, humid air, air enriched with oxygen, air diluted with exhaust gas, and/or air diluted with inert gas.

28. The method of any of the preceding claims, wherein the fuel includes the following or blends of the following: naphtha, gasoline, alcohol, butanol, propanol, ethanol, methanol, gaseous hydrocarbons, natural gas, methane, ethane, propane, butane, hexane, alternative fuels, hydrogen, ammonia, syngas, and/or CO.

29. The method of any of the preceding claims, wherein the volume of fuel is injected into the combustion chamber at a pressure of at least about 800 bar absolute.

30. The method of any of the preceding claims, wherein the compression ignition engine includes a sensor configured to detect properties of the fuel and control the temperature control strategy or other aspects of engine operation, based on the properties of the fuel.

31. The method of any of the preceding claims, wherein the compression ignition engine includes insulation to aid in producing a temperature in the combustion chamber sufficient to limit the delay between injecting the volume of fuel into the combustion chamber and initiation of combustion to be less than about 2 ms.

32. A method of operating a compression ignition engine, the compression ignition engine including a combustion chamber, the method comprising the steps of:
receiving a volume of intake chat ge in the combustion chambet, compressing the volume of intake charge to arrive at an effective compression ratio of at least about 15:1;
injecting a volume of fuel into the combustion chamber, the fuel having a cetane number less than about 40; and combusting substantially all of the volume of fuel, wherein the injection timing is sufficiently late in the compression process such that at least 30% of the energy generated from combusting the volume of fuel is generated while the volume of fuel is being injected into the combustion chamber, and wherein the compression ignition engine includes at least one of a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, or a Wankel rotary engine.

33 The method of claim 32, wherein the combustion chamber includes points with local equivalence ratios of at least about 2.

34. Thc mcthod of either of claims 32 or 33, wherein thc temperature and pressure within the combustion chamber at the time of fuel injection create conditions such that no more than about 2 ms elapse between the start of fuel injection and ignition of the volume of fuel.

35. The method of either of claims 32 or 33, wherein the injection timing is sufficiently late in the compression process such that no more than about 50% of the volume of the fuel is pre-mixed with the volume of intake charge upon initiation of combustion.

36. The method of either of claims 32-35, wherein the temperature and pressure within the combustion chamber at the time of fuel injection create conditions such that no more than about 50% of the volume of the fuel is pre-mixed with the volume of intake charge upon initiation of combustion.

37. The method of any of claims 32-35, wherein the fuel is a first fuel, the volume of intake charge is a first volume of intake charge, and the injection timing is a first timing with respect to the othei events in the engine cycle, the method further comprising.
receiving a second volume of intake charge into the combustion chamber;
compressing the second volume of intake charge;
injecting a volume of a second fuel into the combustion chamber at a second injection timing with respect to the other events in the engine cycle, the second fuel having a different cetane number, heating value, and/or chemical composition from the first fuel;
combusting substantially all of the volume of the second fuel, wherein the second injection timing is sufficiently late in the compression process such that no more than about 50% of the volume of the second fuel is pre-mixed with the second volume of intake charge upon initiation of combustion.

38. The method of claim 37, wherein the second fuel has a cetane number lower than the cetane number of the first fuel.

39. The method of any of claims 32-38, further comprising:
applying a temperature control strategy to the volume of intake charge prior to receiving the intake charge into the combustion chamber.

40. The method of claim 39, wherein the temperature control strategy includes exposing the volume of intake charge to a burner with flame stabilization and/or a catalytic burner.

41. The method of any of claims 39-40, wherein the temperature control strategy includes transferring heat from an exhaust gas to the volume of intake charge.

42. The method of claim 41, wherein the temperature control strategy includes at least partial retention, rebreathing, and/or recirculation of the exhaust gas.

43. The method of any of claims 32-42, wherein the average temperature of the volume of intake charge in the combustion chamber just prior to fuel injection is in a range between about 1000 K and about 1250 K.

44. The method of any of claims 32-43, wherein the volume of fuel includes less than about 3 wt% of additives that result in a substantial change in cetane number.

45. A method of operating a compression ignition engine, the compression ignition engine including a combustion chamber, the method comprising the steps of:
receiving a volume of intake charge in the combustion chamber;
compressing the volume of intake charge in the engine to arrive at an effective compression ratio of at least about 15:1, and a pressure and temperature sufficient to induce autoignition in the combustion chamber, injecting a volume of fuel into the combustion chamber at a first timing, the volume of fuel having a cetane number less than about 30; and changing the injection timing of the volume of fuel to control the rate of pressure rise from the combustion of the volume of fuel in the volume of intake charge to be less than about 15 MPa/ms, wherein the compression ignition engine includes at least one of a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, or a Wankel rotary engine.

46. The method of claim 45, wherein controlling the rate of pressure rise from the combustion chamber is exclusively via changing the injection timing of the volume of fuel.

47. The method of either of claims 45 or 46, wherein the injection timing sufficiently late in the compression process such that no more than about 50% of the volume of the fuel is pre-mixed with the volume of intake charge upon initiation of combustion

48. The method of either of claims 45-47, wherein the temperature and pressure within the combustion chamber at the time of fuel injection create conditions such that no more than about 50% of the volume of the fuel is pre-mixed with the volume of intake charge upon initiation of combustion.

49. The method of any of claims 45-48, wherein the fuel is a first fuel, the volume of intake charge is a first volume of intake charge, and the injection timing is a first injection timing, the method further comprising:

receiving a second volume of intake charge into the combustion chamber;
compressing the volume of intake charge;
injecting a volume of a second fuel into the combustion chamber at a second injection timing during a second time period, the second fuel having a different cetane number, heating value, and/or chemical composition from the first fuel;
combusting substantially all of the volume of the second fuel, wherein the second injection timing is sufficiently late in the compression process such that no more than about 50% of the volume of the second fuel is pre-mixed with the second volume of intake charge upon initiation of combustion

50 The method of claim 49, wherein the second fuel has a cetane number lower than the cetane number of the first fuel.

51. The method of any of claims 45-50, further comprising:
applying a temperature control strategy to the volume of intake charge prior to receiving it into the combustion chamber.

52. A method of operating a compression ignition engine, the compression ignition engine including a combustion chamber, the method comprising the steps of:
receiving a first volume of intake charge in the combustion chamber;
compressing the volume of intake charge in order to arrive at an effective compression ratio of the volume of intake charge of at least about 15;
injecting a volume of a first fuel into the combustion chamber at a first injection timing during a first time period into the volume of intake charge having a first temperature, the first temperature measured at 1 ms prior to injecting the volume of the first fuel into the combustion chamber, the first fuel having a first cetane number less than about 40;
combusting substantially all of the volume of the first fuel;
receiving a second volume of intake charge in the combustion chamber;
compressing the second volume of intake charge and arrive at an effective compression ratio of at least about 15, injecting a volume of a second fuel into the combustion chamber during a second time period into the second volume of intake charge, the second volume of intake charge having a second temperature higher than the first temperature, the second temperature measured at 1 ms prior to injecting the volume of the second fuel into the combustion chamber, the second fuel different than the first fuel and having a second cetane number lower than the first cetane number;
coinbusting substantially all of the volume of the second fuel, wherein a delay between injecting the volume of the first fuel and the second fuel into the combustion chambcr and initiation of combustion of each fuel is less than about 2 ms, and wherein the compression ignition engine includes at least one of a two-stroke engine, an opposed-piston engine, a two-stroke opposed piston engine, a five-stroke engine, a six-stroke engine, a free-piston engine, a free piston engine linear, a rotary engine, or a Wankel rotary engine

53 The method of claim 52, wherein the compression ignition engine includes an on-board fuel sensor.

54. The method of claim 53, further comprising:
implementing a thermal management technique to adjust the temperature of the combustion chamber based on fuel properties detected by the fuel sensor.

55. The method of any of claims 52-54, wherein the first fuel has a cetane number between about 30 and about 40, and the first temperature is at least about 900 K.

56. The method of any of claims 52-54, wherein the first fuel has a cetane number between about 20 and about 30, and the first temperature is at least about 1000 K.

57 The method of any of claims 52-54, wherein the first fuel has a cetane number between about 10 and about 20, and the first temperature is at least about 1050 K.

58. The method of any of claims 52-54, wherein the first fuel has a cetane number between about 0 and about 10, and the first temperature is at least about 1150 K.

59. The method of any of claims 52-54, wherein the first fuel has a cetane number less than about 0, and the first temperature is at least about 1250 K.