CA3223571A1 - Cylindrical battery and vehicle - Google Patents
Cylindrical battery and vehicle Download PDFInfo
- Publication number
- CA3223571A1 CA3223571A1 CA3223571A CA3223571A CA3223571A1 CA 3223571 A1 CA3223571 A1 CA 3223571A1 CA 3223571 A CA3223571 A CA 3223571A CA 3223571 A CA3223571 A CA 3223571A CA 3223571 A1 CA3223571 A1 CA 3223571A1
- Authority
- CA
- Canada
- Prior art keywords
- negative electrode
- positive electrode
- current collecting
- collecting disc
- tab
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/179—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/107—Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/152—Lids or covers characterised by their shape for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/249—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for aircraft or vehicles, e.g. cars or trains
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/528—Fixed electrical connections, i.e. not intended for disconnection
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/536—Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Aviation & Aerospace Engineering (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Secondary Cells (AREA)
- Battery Mounting, Suspending (AREA)
Abstract
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] The present disclosure claims priority to Chinese Patent Application No.
202110837679.X filed on July 23, 2021 and entitled "Cylindrical battery", which is incorporated herein by reference in its entirety.
FIELD
BACKGROUND
SUMMARY
a positive electrode cap connected to the positive electrode current collecting disc and a negative electrode cap connected to the negative electrode current collecting disc.
BRIEF DESCRIPTION OF THE DRAWINGS
100 cylindrical battery, 102 casing; 10 electrode core; 104 positive electrode end surface, 106 negative electrode end surface, 20 tab, 202 positive electrode tab, 204 negative electrode tab, 206 negative electrode sheet, 208 first separator, 210 positive electrode sheet, 212 second separator, 2102 positive electrode material layer, 2104 positive electrode foil layer, 2062 negative electrode material layer, 2064 negative electrode foil layer, 30 current collecting disc, 302 positive electrode current collecting disc, 304 negative electrode current collecting disc, 31 current collecting disc body, 32 connecting portion, 33 connecting sheet, 40 cap, 402 positive electrode cap, 404 negative electrode cap, 50 spacer ring, 60 insulating pad, 602 positive electrode insulating pad, 604 negative electrode insulating pad, 1000 vehicle, 110 processor.
DETAILED DESCRIPTION
At least some of the wound turns of positive electrode foil layer 2104 extends toward one end of the casing 102 to form the positive electrode tab 202. At least some of the wound turns of negative electrode foil layer 2064 extends toward the other end of the casing 102 to form the negative electrode tab 204. As a result, a portion of the positive electrode end surface 104 of the electrode core 10 that is not covered by the positive electrode tab 202 is located at at least one side of the positive electrode tab 202, and a portion of the negative electrode end surface 106 of the electrode core 10 that is not covered by the negative electrode tab 204 is located at at least one side of the negative electrode tab 204. In an embodiment, the positive electrode end surface 104 of the electrode core 10 is exposed at an inner side and/or outer side of the positive electrode tab 202, and the negative electrode end surface 106 of the electrode core 10 is exposed at an inner side and/or outer side of the negative electrode tab 204. In an embodiment, the positive electrode tab 202 extends out of the positive electrode end surface104 of the electrode core 10, and the negative electrode tab 204 extends out of the negative electrode end surface 106 of the electrode core 10. In an embodiment, as shown in FIG. 6, the positive electrode tab 202 extends out of the positive electrode end surface 104 of the electrode core 10 from an outer edge of the positive electrode end surface 104 of the electrode core 10, and the negative electrode tab 204 extends out of the negative electrode end surface 106 of the electrode core 10 from an outer edge of the negative electrode end surface 106 of the electrode core 10.
In an embodiment, as shown in FIGs. 1 and 2, the positive electrode tab 202 extends out of the positive electrode end surface 104 of the electrode core 10 from the interior of the positive electrode end surface 104 of the electrode core 10, and the negative electrode tab 204 extends out of the negative electrode end surface 106 of the electrode core 10 from the interior of the negative electrode end surface 106 of the electrode core 10.
of the electrode core 10 and the outer edge of the negative electrode end surface 106.
Moreover, based on the capacity and overcurrent requirements for the cylindrical battery 100, the number of turns is reasonably selected, such that each round tab 20 has a large thickness, to meet larger current requirement, making it suitable for use in a battery having larger capacity.
In another embodiment, the tab 20 is led out from the outside to the inside sequentially, for example, starting from the outermost turn of the electrode core 10 toward the axis L of the electrode core 10. In another embodiment, the tab 20 can be led out from the middle to both sides. For example, the electrode core 10 includes wound 2n turns in total, and the tab 20 can be led out sequentially starting from an nth turn toward the axis L of the electrode core 10 and toward the outside. As shown in FIGs. 5 and 6, the tab 20 is located at the outermost turn of the wound structure of the electrode core 10.
Similarly, the negative electrode current collecting disc 304 includes a current collecting disc body 31, a connecting portion 32 located at a peripheral side of the current collecting disc body 31, and a connecting sheet 33 facing the current collecting disc body 31. The current collecting disc body 31 is located at the inner side of the ring-shaped negative electrode tab 204. The connecting portion 32 is attached to an inner wall surface of the negative electrode tab 204 and connected to the connecting sheet 33 for electrical connection with the cap 40 of the cylindrical battery 100. In an embodiment, the connecting portion 32 can be connected to the negative electrode tab 204 by welding. In other words, in the specific embodiment shown in FIG. 1, the current collecting disc body 31 is constructed into a round disc, located at the inner side of the positive electrode tab 202 or the inner side of the negative electrode tab 204. In the process of welding the positive electrode tab 202 or the negative electrode tab 204 with the current collecting disc 30, the positive electrode tab 202 or the negative electrode tab 204 can be welded to the current collecting disc 30, to realize the "thin through thick" welding, and avoid short circuit of the cylindrical battery 100 due to the burning through of the tab 20 in the welding process, thereby improving the safety of the cylindrical battery 100.
The other end of the connecting sheet 33 extends radially along the casing towards the axis of the casing 102. As such, on the one hand, the contact area between the connecting sheet 33 and the cap 40 is increased, to improve the stability of electrical connection; and on the other hand, the connecting sheet 33 is arranged facing the end face of the electrode core 10, to reduce the size of the current collecting disc 30 occupied in the Z
direction of the cylindrical battery 100, thus further improving the energy density of the cylindrical battery 100.
An insulating pad 60 is provided between the current collecting disc 30 and the cap 40. A
positive electrode insulating pad 602 is provided between the positive electrode current collecting disc 302 and the positive electrode cap 402. A negative electrode insulating pad 604 is provided between the negative electrode current collecting disc 304 and the negative electrode cap 404. A sealing ring is provided at the periphery of the positive electrode cap 402 and the negative electrode cap 404. In this way, by the insulation of the spacer ring 50, the cap 40 and the insulating pad 60, the short circuit inside the cylindrical battery 100 is avoided, to improve the working stability and safety of the cylindrical battery 100.
should be understood in a broad sense. For example, the connection may be a fixed connection, a detachable connection, or an integral connection; or the connection may be a mechanical connection or an electrical connection; or the connection may be a direct connection, an indirect connection through an intermediate medium, internal communication between two components, or an interaction relationship between two components. For those of ordinary skill in the art, specific meanings of the terms in the present disclosure can be understood based on specific situations
Claims (11)
a casing (102), the casing (102) having an accommodating space; and a negative electrode sheet (206), a first separator (208), a positive electrode sheet (210) and a second separator (212) stacked in sequence, the negative electrode sheet (206), the first separator (208), the positive electrode sheet (210), and the second separator (212) being wound multiple turns to form an electrode core (10), the casing (102) being co-axial with the electrode core (10), the electrode core (10) being at least partially received in the accommodating space, the electrode core (10) having a positive electrode end surface (104) and a negative electrode end surface (106), the positive electrode sheet (210) comprising a positive electrode material layer (2102) and a positive electrode foil layer (2104), the negative electrode sheet(206) comprising a negative electrode material layer (2062) and a negative electrode foil layer (2064), at least some of the wound turns of the positive electrode foil layer (2104) extending toward one end of the casing(102) to form a positive electrode tab (202), at least some of the wound turns of the negative electrode foil layer (2064) extending toward the other end of the casing (102) to form a negative electrode tab (204), such that a portion of the positive electrode end surface (104) of the electrode core (10) that is not covered by the positive electrode tab (202) is located at at least one side of the positive electrode tab (202), and a portion of the negative electrode end surface (106) of the electrode core (10) that is not covered by the negative electrode tab (204) is located at at least one side of the negative electrode tab (204).
the positive electrode tab (202) is formed on the positive electrode end (101), the negative electrode tab (204) is formed on the negative electrode end (103), the positive electrode tab (202) extends out of the positive electrode end surface (104), and the negative electrode tab (204) extends out of the negative electrode end surface (106);
and the positive electrode tab (202) and the negative electrode tab (204) are both constructed to have a ring shape.
a current collecting disc (30) and a cap (40), wherein the current collecting disc (30) comprises a positive electrode current collecting disc (302) connected to the positive electrode tab (202) and a negative electrode current collecting disc (304) connected to the negative electrode tab (204), and the cap (40) comprises a positive electrode cap (402) connected to the positive electrode current collecting disc (302) and a negative electrode cap (404) connected to the negative electrode current collecting disc (304).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110837679.X | 2021-07-23 | ||
| CN202110837679.XA CN115693041A (en) | 2021-07-23 | 2021-07-23 | Cylindrical battery |
| PCT/CN2022/105350 WO2023001030A1 (en) | 2021-07-23 | 2022-07-13 | Cylindrical battery and vehicle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA3223571A1 true CA3223571A1 (en) | 2023-01-26 |
Family
ID=84978987
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3223571A Pending CA3223571A1 (en) | 2021-07-23 | 2022-07-13 | Cylindrical battery and vehicle |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20240106074A1 (en) |
| EP (1) | EP4343953A4 (en) |
| JP (1) | JP2024526602A (en) |
| KR (1) | KR20240011195A (en) |
| CN (1) | CN115693041A (en) |
| AU (1) | AU2022313342A1 (en) |
| BR (1) | BR112023027334A2 (en) |
| CA (1) | CA3223571A1 (en) |
| WO (1) | WO2023001030A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2026044529A1 (en) * | 2024-08-28 | 2026-03-05 | 厦门新能安科技有限公司 | Cylindrical battery, battery pack and electronic device |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118553843A (en) * | 2023-02-24 | 2024-08-27 | 宁德时代新能源科技股份有限公司 | Electrode assembly, manufacturing method of electrode assembly, battery and power utilization device |
| CN220021520U (en) * | 2023-04-14 | 2023-11-14 | 比亚迪股份有限公司 | Battery cells, battery packs and electrical devices |
| CN116652464B (en) * | 2023-06-06 | 2025-10-14 | 海目星激光科技集团股份有限公司 | welding equipment |
| CN116632466B (en) * | 2023-07-21 | 2023-11-07 | 四川易纳能新能源科技有限公司 | Secondary battery structure and secondary battery |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1173995A (en) * | 1997-08-28 | 1999-03-16 | Sanyo Electric Co Ltd | Cylindrical non-aqueous electrolyte secondary battery and method of manufacturing the same |
| JP2001052679A (en) * | 1999-08-03 | 2001-02-23 | Nec Corp | Non-aqueous electrolyte secondary battery and method of manufacturing the same |
| JP3629171B2 (en) * | 1999-09-10 | 2005-03-16 | トヨタ自動車株式会社 | Electrode wound type battery |
| DE60138577D1 (en) * | 2000-03-14 | 2009-06-10 | Sanyo Electric Co | Welded current collector plates in non-aqueous electrolyte secondary cells |
| JP2002135987A (en) * | 2000-10-19 | 2002-05-10 | Toyota Motor Corp | Rechargeable battery pack |
| CN201112459Y (en) * | 2007-09-26 | 2008-09-10 | 深圳市比克电池有限公司 | Cylindrical battery insulation space ring |
| JP2012009716A (en) * | 2010-06-25 | 2012-01-12 | Shin Kobe Electric Mach Co Ltd | Lithium ion capacitor |
| US9159496B2 (en) * | 2010-09-16 | 2015-10-13 | Shin-Kobe Electric Machinery Co., Ltd. | Method of manufacturing electrode group unit for lithium ion capacitor and lithium ion capacitor |
| JP2012190739A (en) * | 2011-03-14 | 2012-10-04 | Hitachi Vehicle Energy Ltd | Secondary battery |
| JP6867746B2 (en) * | 2015-03-20 | 2021-05-12 | 株式会社Gsユアサ | Power storage element |
| KR102535745B1 (en) * | 2017-10-11 | 2023-05-23 | 삼성에스디아이 주식회사 | Secondary Battery |
| KR102410911B1 (en) * | 2017-10-11 | 2022-06-20 | 삼성에스디아이 주식회사 | Electrode assembly and secondary battery comprising the same |
| CN112310569B (en) * | 2019-10-29 | 2022-03-11 | 宁德时代新能源科技股份有限公司 | Battery monomer, battery module, battery pack, device and processing method |
| CN111081966B (en) * | 2019-11-21 | 2022-10-11 | 国轩新能源(庐江)有限公司 | Lithium ion cylindrical battery and processing method thereof |
| JP7111683B2 (en) * | 2019-11-27 | 2022-08-02 | Ckd株式会社 | Winding device and winding element manufacturing method |
| CN112510244A (en) * | 2020-12-18 | 2021-03-16 | 上海比耐信息科技有限公司 | Electrode lug shaping and welding method of full-electrode-lug cylindrical winding core and full-electrode-lug cylindrical winding core formed by same |
-
2021
- 2021-07-23 CN CN202110837679.XA patent/CN115693041A/en active Pending
-
2022
- 2022-07-13 BR BR112023027334A patent/BR112023027334A2/en unknown
- 2022-07-13 WO PCT/CN2022/105350 patent/WO2023001030A1/en not_active Ceased
- 2022-07-13 KR KR1020237044783A patent/KR20240011195A/en not_active Ceased
- 2022-07-13 EP EP22845195.1A patent/EP4343953A4/en active Pending
- 2022-07-13 AU AU2022313342A patent/AU2022313342A1/en not_active Abandoned
- 2022-07-13 JP JP2023580345A patent/JP2024526602A/en active Pending
- 2022-07-13 CA CA3223571A patent/CA3223571A1/en active Pending
-
2023
- 2023-12-01 US US18/526,259 patent/US20240106074A1/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2026044529A1 (en) * | 2024-08-28 | 2026-03-05 | 厦门新能安科技有限公司 | Cylindrical battery, battery pack and electronic device |
Also Published As
| Publication number | Publication date |
|---|---|
| EP4343953A4 (en) | 2025-09-03 |
| JP2024526602A (en) | 2024-07-19 |
| US20240106074A1 (en) | 2024-03-28 |
| AU2022313342A1 (en) | 2024-01-18 |
| EP4343953A1 (en) | 2024-03-27 |
| CN115693041A (en) | 2023-02-03 |
| KR20240011195A (en) | 2024-01-25 |
| WO2023001030A1 (en) | 2023-01-26 |
| BR112023027334A2 (en) | 2024-03-12 |
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