CA3185797A1 - Incomplete combustion as a means of reducing carbon dioxide emissions - Google Patents

Incomplete combustion as a means of reducing carbon dioxide emissions

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Publication number
CA3185797A1
CA3185797A1 CA3185797A CA3185797A CA3185797A1 CA 3185797 A1 CA3185797 A1 CA 3185797A1 CA 3185797 A CA3185797 A CA 3185797A CA 3185797 A CA3185797 A CA 3185797A CA 3185797 A1 CA3185797 A1 CA 3185797A1
Authority
CA
Canada
Prior art keywords
energy sources
incomplete combustion
renewable
electrolysis
fischer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3185797A
Other languages
French (fr)
Inventor
Samuel Okechukwu Umealu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US17/020,957 external-priority patent/US11383977B1/en
Priority claimed from AU2021201303A external-priority patent/AU2021201303B1/en
Application filed by Individual filed Critical Individual
Publication of CA3185797A1 publication Critical patent/CA3185797A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1659Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1684Integration of gasification processes with another plant or parts within the plant with electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846Partial oxidation, i.e. injection of air or oxygen only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

What is disclosed herein is a process for the elimination Carbon dioxide (CO2), exploiting renewable energy sources, providing storage for intermittent renewable power and production of synthesis gas, a fuel gas mixture consisting primarily of carbon monoxide (CO) and hydrogen (H2), which is then utilised in the Fischer-Tropsch reaction to produce clean fuels and other chemical solvents.

Description

The title of the invention: INCOMPLETE COMBUSTION AS A MEANS OF
REDUCING CARBON DIOXIDE EMISSIONS
Background of the Invention [001] Carbon dioxide (CO2) has a significant impact on global warming.
[002] Emissions of Carbon dioxide (C0z) arise from a number of sources, mainly fossil fuel combustion to generate energy. Fossil fuel comprises Coal and hydrocarbons.
[003] Emissions of Carbon dioxide (CO2) arise from complete combustion of fossil fuel, according to the following equation:
Fossil Fuel + Oxygen(02) ¨> Carbon dioxide (CO2) + Water (H20) + Flue Gas Mixture The source of oxygen for this reaction is the atmospheric air.
[004] Carbon monoxide (CO) is produced instead of Carbon dioxide (CO2) in incomplete combustion. Incomplete combustion happens when there is a limited supply of air, according to the following equation:
Fossil Fuel + Oxygen(02) ¨> Carbon monoxide (CO) + Water (H20) + Carbon(C)
[005] Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen, according to the following equation:
2 H20 ¨> 2 H2 02 It is, in other words, electrolysis of water or the decomposition of water (1-120) into oxygen (02) and hydrogen (H2), due to an electric current being passed through it.
Production of hydrogen from water is energy intensive. In low-temperature electrolysis, the energy consumed is more valuable than the hydrogen produced. Therefore, this process is not usually considered commercially viable. I Iowever, with high-temperature electrolysis (HTE) of water, more of the initial heat energy is converted into chemical energy (hydrogen), thereby improving the commercial viability of this process.
The commercial viability of this process is further improved by use of renewable energy sources to generate electricity for electrolysis.
[006] The use of renewable energy sources in the electrolysis of water provides means of exploiting these renewable energy sources. It also provides means of storing intermittent renewable power by conversion to chemical energy in hydrogen_
[007] The Fischer-Tropsch is a reaction involving carbon monoxide (CO) and hydrogen (H2) to produce clean fuels and other chemical solvents.

SUBSTITUTE SHEET (RULE 26) RO/AU

Detailed Description of the Invention [001] This invention transforms fuels such as coal and other hydrocarbons from "dirty" to :'clean" source of energy. Future power plants may use fossil fuels or the so-called dirty fuels to generate Clean energy by using this invention. Existing power plants that currently use fossil fuels as feedstock can be amended to commence generation of Clean energy by using this invention.
[002] This invention provides the means of harnessing renewable energy sources. It is also a viable solution to the problem of intermittent renewable power storage.
[003] This invention provides a "clean" source of cheap commercial scale synthesis gas, a fuel gas mixture consisting primarily of carbon monoxide (CO) and hydrogen (H2).
The fuel gas mixture is used to produce hydrocarbons in a Fischer-Tropsch process.
[004] These together with additional objects, features and advantages of the incomplete combustion as a means of reducing Carbon Dioxide emissions will be readily apparent to those of ordinary skill in the art upon reading the following detailed description of the presently preferred, but nonetheless illustrative, embodiments when taken in conjunction with the accompanying drawings.
[005] In this respect, before explaining the current embodiments of the incomplete combustion as a means of reducing Carbon Dioxide emissions in detail, it is to be understood that the incomplete combustion as a means of reducing Carbon Dioxide emissions is not limited in its applications to the details of design, construction and arrangements of the components set forth in the following description. Those skilled in the art will appreciate that the concept of this disclosure may be readily utilized as a basis for the design of other processes, structures, methods, and systems for carrying out the several purposes of the incomplete combustion as a means of reducing Carbon Dioxide emissions. It is therefore important that the claims be regarded as including such equivalent construction insofar as they do not depart from the spirit and scope of the incomplete combustion as a means of reducing Carbon Dioxide emissions. It is also to be understood that the phraseology and terminology employed herein are for purposes of description and should not be regarded as limiting.
[006] The following detailed description is merely exemplary in nature and is not intended to limit the described embodiments of the application and uses of the described embodiments_ As used herein, the word "exemplary" or "illustrative" means "serving as SUBSTITUTE SHEET (RULE 26) RO/AU

an example, instance, or illustration." Any implementation described herein as "exemplary" or "illustrative" is not necessarily to be construed as preferred or advantageous over other implementations. All of the implementations described below arc exemplary implementations provided to enable persons skilled in the art to practice the disclosure and are not intended to limit the scope of the appended claims.

Furthermore, there is no intention to be bound by any expressed or implied theory presented in the preceding technical field, background or the following detailed description.
[007] This invention provides a viable solution to the problem of global warming as caused by Carbon dioxide (CO2) emissions arising from fossil fuel combustion to generate energy. In step 1 of the process, this invention uses incomplete combustion to ensure an output of carbon monoxide (CO) and water (H20), instead of Carbon dioxide (CO2) and Water (F120), as would have been the case if complete combustion were used.
[008] In step 3 of the process, carbon monoxide (CO), water (H20) and carbon (C) are separated. Carbon monoxide (CO), a valuable component of synthesis is sent to step 5 where it takes part in Fischer-Tropsch reaction, in which fossil fuel in the form of hydrocarbon is produced. Carbon (C) is recycled to step 1, while water (H20) is sent to step 4, where it is used as feedstock for high-temperature electrolysis (HTE).
[009] In step 4 of the process, water (H20) from step 3 is made to undergo high-temperature electrolysis (ME), by using renewable power. This high-temperature electrolysis (HTE) results in the generation of hydrogen (H2). The use of renewable power in this step to generate hydrogen (H2) translates to conversion of these renewable energy supply to chemical energy. Hydrogen (H2) is a valuable component of synthesis gas and will be used in step 5, along with Carbon monoxide (CO) to create fossil fuel, in the form of hydrocarbons. Conversion of renewable energy to chemical energy provides a viable solution to the problem of intermittent renewable power storage.
[010] Renewable energy sources include Biofuel, Biomass, Geothermal, Hydroelectricity, Solar, Wind, Tidal and Wave. Some of these energy sources are known to produce intermittent power.
[011] This invention results in the production of synthesis gas, a fuel gas mixture consisting primarily of carbon monoxide (CO) and hydrogen (H2), in steps 1 and 4, respectively. These two gases (carbon monoxide (CO) and hydrogen (H2)) are made to SUBSTITUTE SHEET (RULE 26) RO/AU

undergo the Fischer-Tropsch reaction in step 5, to produce clean fuels and other chemical solvents. Some of the resulting fuels is recycled to step 1.
[012] According to Vvrikipedia, the Fischer¨Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150-300 C (302-572 F) and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser-Wilhelm-Institut fur Kohlenforschung in Germany, in 1925.
[013]With respect to the above description, it is to be realized that the optimum dimensional relationship for the various components of the invention described above and in following drawing include variations in size, materials, shape, form, function, and manner of operation, assembly and use, are deemed readily apparent and obvious to one skilled in the art, and all equivalent relationships to those illustrated in the drawings and described in the specification are intended to be encompassed by the invention.
[014] It shall be noted that those skilled in the art will readily recognize numerous adaptations and modifications which can be made to the various embodiments of the present invention which will result in an improved invention, yet all of which will fall within the spirit and scope of the present invention as defined in the following claims.
Accordingly, the invention is to be limited only by the scope of the following claims and their equivalents.
BRIEF DESCRIPTION OF DRAWINGS
The accompanying drawing, which is included to provide a further understanding of the invention is incorporated in and constitute a part of this specification, illustrate an embodiment of the invention and together with the description serve to explain the principles of the invention. They are meant to be exemplary illustrations provided to enable persons skilled in the art to practice the disclosure and are not intended to limit the scope of the appended claims.

SUBSTITUTE SHEET (RULE 26) RO/AU

Claims

Claims What is claimed is:
Claim 1 A process for using incomplete combustion of fossil fuel is a power plant to generate electricity, with the CO component of the flue gas transferred to a Fischer-Tropsch reactor, with the 1120 component of the flue gas transferred to an Electrolysis machine where it is split into H2 and 02. and the resulting H2 is also transfeired to the same Fischer-Tropsch reactor that contains the CO component of the flue gas where a renewable fuel is created and some of it recycled to the power plant.
Claim 2 The method of claim 1, wherein carbon rnonoxide (CO) is recovered from the flue gas Claim 3 The method of claim 1, wherein carbon (C) is recovered from the flue gas and re-cycled to the first step of incomplete combustion.
Claim 4 The method of claim 1, wherein E120 is split into 112 and 02 Claim 5 The method of claim 1, wherein renewable energy sources including Biofuel, Biomass, Geothermal, Hydroelectricity, Solar, Wind, Tidal and Wave are used in electrolysis to split H20 into H2 and Oz Claim 6 The method of claim 1, wherein the use of renewable energy sources including Biofuel, Biomass, Geothermal, Hydroelectricity, Solar, Wind, Tidal and Wave in electrolysis to split H20 into H2 and 02 is considered rneans of exploiting these renewable energy sources.

Claim7 The method of claim 1, wherein the use of intermittent renewable energy sources including Geothermal, Hydroelectricity, Solar, Wind, Tidal and Wave in the electrolysis of H20 to produce hydrogen (HI) is considered means of storing power from these intermittent energy sources.
Claim8 The method of claim 1, wherein the use of renewable energy sources including Biofuel, Biomass, Geothermal, Hydroelectricity, Solar, Wind, Tidal and Wave in the electrolysis of H20 to produce hydrogen (H2) is considered means of converting these renewable energy sources to chemical energy.
Claim9 The method of claims 1 , wherein carbon monoxide (CO) resulting from claiin 2 and hydrogen (H?), resulting from 4 are used in Fischer-Tropsch reaction to produce renewable ftiels and chemical solvents Claim 10 The method of claim 1, wherein some of the renewable fuels of claim 9 are recycled to the first step of incomplete combustion.
Claim 11 The method of claim 1, wherein the energy output of the Fischer-Tropsch reaction is recovered recycled to the first step of incomplete combustion.
CA3185797A 2020-09-15 2021-03-06 Incomplete combustion as a means of reducing carbon dioxide emissions Pending CA3185797A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US17/020,957 US11383977B1 (en) 2019-12-17 2020-09-15 Incomplete combustion as a means of reducing carbon dioxide emissions
AU2021201303 2021-02-28
AU2021201303A AU2021201303B1 (en) 2021-02-28 2021-02-28 Incomplete Combustion as a means of eliminating/reducing Carbon dioxide (CO2) emission and generating renewable energy
PCT/AU2021/000024 WO2022056573A1 (en) 2020-09-15 2021-03-06 Incomplete combustion as a means of reducing carbon dioxide emissions

Publications (1)

Publication Number Publication Date
CA3185797A1 true CA3185797A1 (en) 2022-03-24

Family

ID=80777161

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3185797A Pending CA3185797A1 (en) 2020-09-15 2021-03-06 Incomplete combustion as a means of reducing carbon dioxide emissions

Country Status (4)

Country Link
EP (1) EP4189139A4 (en)
JP (1) JP2023540156A (en)
CA (1) CA3185797A1 (en)
WO (1) WO2022056573A1 (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG160406A1 (en) * 2005-03-16 2010-04-29 Fuelcor Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
US20100175320A1 (en) * 2006-12-29 2010-07-15 Pacific Renewable Fuels Llc Energy efficient system and process for the continuous production of fuels and energy from syngas
GB201120399D0 (en) * 2011-11-25 2012-01-11 Air Fuel Synthesis Ltd Convertion of carbon dioxide
US9163180B2 (en) * 2011-12-07 2015-10-20 IFP Energies Nouvelles Process for the conversion of carbon-based material by a hybrid route combining direct liquefaction and indirect liquefaction in the presence of hydrogen resulting from non-fossil resources

Also Published As

Publication number Publication date
EP4189139A1 (en) 2023-06-07
JP2023540156A (en) 2023-09-22
EP4189139A4 (en) 2024-01-24
WO2022056573A1 (en) 2022-03-24

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