CA3133725C - Electrode body and cylindrical lithium battery containing the same - Google Patents
Electrode body and cylindrical lithium battery containing the sameInfo
- Publication number
- CA3133725C CA3133725C CA3133725A CA3133725A CA3133725C CA 3133725 C CA3133725 C CA 3133725C CA 3133725 A CA3133725 A CA 3133725A CA 3133725 A CA3133725 A CA 3133725A CA 3133725 C CA3133725 C CA 3133725C
- Authority
- CA
- Canada
- Prior art keywords
- bare
- negative electrode
- positive electrode
- electrode coating
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/107—Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0422—Cells or battery with cylindrical casing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Abstract
Description
Claims (15)
- CLAIMS: 1. An electrode body, applied to a cylindrical lithium battery, which is a wound body formed by winding a laminated body, the laminated body comprising: a negative electrode sheet, being a negative electrode substrate, the negative electrode substrate having a negative electrode upper surface and a negative electrode lower surface opposite to the negative electrode upper surface, the negative electrode upper surface having a first negative electrode coating, a first bare negative electrode coating, a second bare negative electrode coating and a third bare negative electrode coating, the negative electrode lower surface having a second negative electrode coating, a fourth bare negative electrode coating, a fifth bare negative electrode coating and a sixth bare negative electrode coating, wherein the first bare negative electrode coating and the fourth bare negative electrode coating are configured in opposite, the second bare negative electrode coating and the fifth bare negative electrode coating are configured in opposite, and the third bare negative electrode coating and the sixth bare negative electrode coating are configured in opposite; a first separator, disposed on the negative electrode sheet; a positive electrode sheet, disposed on the first separator, the positive electrode sheet being a positive electrode substrate, the positive electrode substrate having a positive electrode upper surface and a positive electrode lower surface opposite to the positive electrode upper surface, the positive electrode lower surface facing the negative electrode upper surface, the positive electrode upper surface having a first positive electrode coating, a first bare positive electrode coating, a second bare 24 positive electrode coating and a third bare positive electrode coating, the positive electrode lower surface having a second positive electrode coating, a fourth bare positive electrode coating, a fifth bare positive electrode coating and a sixth bare positive electrode coating, wherein the first bare positive electrode coating and the fourth bare positive electrode coating are configured in opposite, the second bare positive electrode coating and the fifth bare positive electrode coating are configured as fully staggered, and the third bare positive electrode coating and the sixth bare positive electrode coating are configured in opposite; a plurality of cathode tabs, one end of a first cathode tab among the plurality of cathode tabs being connected to the first bare positive electrode coating or the fourth bare positive electrode coating, one end of a second cathode tab among the plurality of cathode tabs being connected to the third bare positive electrode coating or the sixth bare positive electrode coating, one other end of the first cathode tab and one other end of the second cathode tab respectively extending outward and protruding from one end of the wound body; and a plurality of anode tabs, one end of a first anode tab among the plurality of anode tabs being connected to the first bare negative electrode coating or the fourth bare negative electrode coating, one end of a second anode tab among the plurality of anode tabs being connected to the second bare negative electrode coating or the fifth bare negative electrode coating, one end of a third anode tab among the plurality of anode tabs being connected to the third bare negative electrode coating or the sixth bare negative electrode coating, one other end of the first anode tab, one other 25 end of the second anode tab and one other end of the third anode tab respectively extending outward and protruding from one other end of the wound body.
- 2. The electrode body according to claim 1, wherein the first cathode tab and the second cathode tab comprise aluminum foil.
- 3. The electrode body according to claim 1, wherein the first anode tab, the second anode tab and the third anode tab comprise copper foil, nickel foil or metal foil of a copper-nickel alloy.
- 4. The electrode body according to claim 1, wherein the negative electrode sheet comprises a wound end and a tail end, the first bare negative electrode coating is disposed at the wound end of the negative electrode sheet, the second bare negative electrode coating is disposed at a distance between 1/3 and 2/3 of the negative electrode sheet from the wound end, and the third bare negative electrode coating is disposed at the tail end of the negative electrode sheet.
- 5. The electrode body according to claim 1, wherein the positive electrode sheet comprises a wound end and a tail end, the first bare positive electrode coating is disposed at a distance between the wound end and 1/4 of the positive electrode sheet from the wound end, and the third bare positive electrode coating is disposed at a distance between the tail end and 1/4 of the positive electrode sheet from the tail end. 26
- 6. The electrode body according to claim 1, wherein the fifth bare positive electrode coating faces the second bare negative electrode coating.
- 7. The electrode body according to claim 1, wherein the second bare positive electrode coating, the fourth bare positive electrode coating, the fifth bare positive electrode coating and the sixth bare positive electrode coating are respectively covered by adhesive tapes.
- 8. The electrode body according to claim 1, wherein the first bare positive electrode coating and the third bare positive electrode coating are respectively covered by adhesive tapes, and the adhesive tapes further respectively cover the first cathode tab and the second cathode tab.
- 9. The electrode body according to claim 1, further comprising a second separator, wherein the negative electrode sheet is between the first separator and the second separator.
- 10. The electrode body according to claim 1, wherein a part of the first anode tab protruding from the wound body is in a first radial direction and is distanced by a first distance from a center, a part of the second anode tab protruding from the wound body is in a second radial direction and is distanced by a second distance from the center, a part of the third anode tab protruding from the wound body is in a third radial direction and is distanced by a third distance from the center, the first radial 27 direction, the second radial direction and the third radial direction partition the wound body into three different regions, the third distance is greater than the second distance, and the second distance is greater than the first distance.
- 11. The electrode body according to claim 1, wherein one end of the first cathode tab and one end of the second cathode tab are respectively connected to the first bare positive electrode coating and the third bare positive electrode coating, or the one end of the first cathode tab and the one end of the second cathode tab are respectively connected to the fourth bare positive electrode coating and the sixth bare positive electrode coating; one end of the first anode tab, one end of the second anode tab and one end of the third anode tab are respectively connected to the first bare negative electrode coating, the second bare negative electrode coating and the third bare negative electrode coating, or the end of the first anode tab, the one end of the second anode tab and the one end of the third anode tab are respectively connected to the fourth bare negative electrode coating, the fifth bare negative electrode coating and the sixth bare negative electrode coating.
- 12. A cylindrical lithium battery, comprising: a housing, comprising a cover, a tank, and a top-down communicating accommodating space formed by mutually sealing and joining the cover and the tank; a positive electrode, embedded in the cover; a negative electrode, embedded in the tank; and 28 an electrode body, disposed in the accommodating space, which is a wound body formed by winding a laminated body, the laminated body comprising: a negative electrode sheet, being a negative electrode substrate, the negative electrode substrate having a negative electrode upper surface and a negative electrode lower surface opposite to the negative electrode upper surface, the negative electrode upper surface having a first negative electrode coating, a first bare negative electrode coating, a second bare negative electrode coating and a third bare negative electrode coating, the negative electrode lower surface having a second negative electrode coating, a fourth bare negative electrode coating, a fifth bare negative electrode coating and a sixth bare negative electrode coating, wherein the first bare negative electrode coating and the fourth bare negative electrode coating are configured in opposite, the second bare negative electrode coating and the fifth bare negative electrode coating are configured in opposite, and the third bare negative electrode coating and the sixth bare negative electrode coating are configured in opposite; a first separator, disposed on the negative electrode sheet; a positive electrode sheet, disposed on the first separator, the positive electrode sheet being a positive electrode substrate, the positive electrode substrate having a positive electrode upper surface and a positive electrode lower surface opposite to the positive electrode upper surface, the positive electrode lower surface facing the negative electrode upper surface, the positive electrode upper surface having a first positive electrode coating, a first bare 29 positive electrode coating, a second bare positive electrode coating and a third bare positive electrode coating, the positive electrode lower surface having a second positive electrode coating, a fourth bare positive electrode coating, a fifth bare positive electrode coating and a sixth bare positive electrode coating, wherein the first bare positive electrode coating and the fourth bare positive electrode coating are configured in opposite, the second bare positive electrode coating and the fifth bare positive electrode coating are configured as fully staggered, and the third bare positive electrode coating and the sixth bare positive electrode coating are configured in opposite; a plurality of cathode tabs, one end of a first cathode tab among the plurality of cathode tabs being connected to the first bare positive electrode coating or the fourth bare positive electrode coating, one end of a second cathode tab among the plurality of cathode tabs being connected to the third bare positive electrode coating or the sixth bare positive electrode coating, one other end of the first cathode tab and one other end of the second cathode tab respectively extending outward and protruding from one end of the wound body; and a plurality of anode tabs, one end of a first anode tab among the plurality of anode tabs being connected to the first bare negative electrode coating or the fourth bare negative electrode coating, one end of a second anode tab among the plurality of anode tabs being connected to the second bare negative electrode coating or the fifth bare negative electrode coating, one end of a third anode tab among the plurality of anode tabs being connected to the 30 third bare negative electrode coating or the sixth bare negative electrode coating, one other end of the first anode tab, one other end of the second anode tab and one other end of the third anode tab respectively extending outward and protruding from one other end of the wound body, wherein the electrode body is connected to the positive electrode through the first cathode tab and the second cathode tab, and the electrode body is connected to the negative electrode through the first anode tab, the second anode tab and the third anode tab.
- 13. The cylindrical lithium battery according to claim 12, further comprising an electrolyte, the electrolyte disposed in the accommodating space.
- 14. The cylindrical lithium battery according to claim 12, further comprising an upper insulating sheet and a lower insulating sheet, the upper insulating sheet disposed between the positive electrode and the end of the wound body, the lower insulating sheet disposed between the negative electrode and the one other end of the wound body; wherein, the upper insulating sheet is a circular sheet structure, and has a partial fan-shaped hole, allowing the one other end of the first cathode tab and the one other end of the second cathode tab to pass through the partial fan-shape hole so as to be connected to the positive electrode; the lower insulating sheet is a sheet structure shaped as a partial circle, a radius of the partial circle is smaller than a radius of the one other end of the wound body, allowing the second anode tab and the third anode tab to be electrically connected to the negative electrode along an 31 edge of the lower insulating sheet, and a center of the sheet structure shaped as a partial circle has a hole, allowing the first anode tab to pass through the hole so as to be connected to the negative electrode.
- 15. The cylindrical lithium battery according to claim 14, wherein the part of the first anode tab protruding from the wound body, the part of the second anode tab protruding from the wound body and the part of the third anode tab protruding from the wound body are sequentially laminated on the other end of the wound body, and the part of the first anode tab protruding from the wound body, the part of the second anode tab protruding from the wound body and the part of the third anode tab protruding from the wound body are welded together and are welded with the tank. 32
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW109135168A TWI768503B (en) | 2020-10-12 | 2020-10-12 | Electrode body and cylindrical lithium battery containing the same |
| TW109213311U TWM610692U (en) | 2020-10-12 | 2020-10-12 | Electrode body and cylindrical lithium battery containing the same |
| TW109213311 | 2020-10-12 | ||
| TW109135168 | 2020-10-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3133725A1 CA3133725A1 (en) | 2022-04-12 |
| CA3133725C true CA3133725C (en) | 2026-01-20 |
Family
ID=77998722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3133725A Active CA3133725C (en) | 2020-10-12 | 2021-10-08 | Electrode body and cylindrical lithium battery containing the same |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11973192B2 (en) |
| EP (1) | EP3982441A1 (en) |
| JP (1) | JP7387687B2 (en) |
| KR (1) | KR102639072B1 (en) |
| CN (1) | CN114361407B (en) |
| CA (1) | CA3133725C (en) |
| PH (1) | PH12021050502A1 (en) |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000311677A (en) | 1999-04-27 | 2000-11-07 | Shin Kobe Electric Mach Co Ltd | Wound cylindrical lithium secondary battery |
| KR100515833B1 (en) * | 2003-05-26 | 2005-09-21 | 삼성에스디아이 주식회사 | Jelly-roll type electrode assembly and secondary battery applying the same |
| CN1270400C (en) * | 2003-09-01 | 2006-08-16 | 比亚迪股份有限公司 | Columnar lithium ion secondary cell |
| US8236441B2 (en) * | 2007-07-24 | 2012-08-07 | A123 Systems, Inc. | Battery cell design and methods of its construction |
| JP2011023130A (en) | 2009-07-13 | 2011-02-03 | Panasonic Corp | Nonaqueous secondary battery |
| KR101152515B1 (en) | 2009-12-17 | 2012-06-01 | 삼성에스디아이 주식회사 | Electrode assembly and secondary battery using the same |
| KR102084659B1 (en) * | 2010-10-15 | 2020-03-04 | 에이일이삼 시스템즈, 엘엘씨 | Integral battery tab |
| US20150072201A1 (en) | 2010-11-16 | 2015-03-12 | Hitachi, Ltd. | Cylindrical secondary battery |
| CN102227031A (en) * | 2011-05-20 | 2011-10-26 | 无锡市明杨电池有限公司 | Lithium ion battery with high-rate discharge characteristic |
| KR20160108857A (en) * | 2015-03-09 | 2016-09-21 | 주식회사 엘지화학 | Cylindrical Secondary Battery Having Two More Cathode and Anode Tabs |
| KR20170030290A (en) * | 2015-09-09 | 2017-03-17 | 삼성에스디아이 주식회사 | Electrode assembly and lituim rechargeable battery |
| CN205159450U (en) * | 2015-10-15 | 2016-04-13 | 东莞市致格电池科技有限公司 | Well play utmost point ear formula electric core of coiling and power type battery |
| CN105161673B (en) * | 2015-10-23 | 2018-05-01 | 东莞市致格电池科技有限公司 | The manufacturing process and multi pole ears battery of a kind of multi pole ears battery core |
| CN106848325B (en) * | 2017-02-15 | 2020-09-15 | 宁德时代新能源科技股份有限公司 | Secondary battery pole piece, preparation method thereof and winding type battery cell |
| CN107834014B (en) * | 2017-09-18 | 2021-01-15 | 东莞市迈科新能源有限公司 | High-power cylindrical lithium ion battery cell |
| KR102702546B1 (en) * | 2018-02-14 | 2024-09-05 | 삼성에스디아이 주식회사 | Electrode assembly and secondary battery comprising the same |
| HUE072602T2 (en) * | 2018-07-20 | 2025-11-28 | Lg Energy Solution Ltd | Electrode assembly and secondary battery comprising the same |
| KR102097107B1 (en) * | 2018-07-20 | 2020-04-03 | 주식회사 엘지화학 | Electrode assembly and rechargeable battery comprising the same |
| JP7084299B2 (en) | 2018-12-27 | 2022-06-14 | 三洋電機株式会社 | Secondary battery |
| CN110518186A (en) * | 2019-09-03 | 2019-11-29 | 江西迪比科股份有限公司 | A kind of Double-pole lug low internal resistance Li-ion secondary cell |
| CN211605265U (en) * | 2019-11-25 | 2020-09-29 | 深圳市卓能新能源股份有限公司 | A low internal resistance lithium battery pole piece and cylindrical lithium battery |
| CN211605338U (en) * | 2020-03-18 | 2020-09-29 | 联动天翼新能源有限公司 | Multi-lug quick-charging cylindrical lithium battery |
-
2021
- 2021-09-27 EP EP21199124.5A patent/EP3982441A1/en active Pending
- 2021-10-01 JP JP2021162539A patent/JP7387687B2/en active Active
- 2021-10-07 KR KR1020210133467A patent/KR102639072B1/en active Active
- 2021-10-07 US US17/496,068 patent/US11973192B2/en active Active
- 2021-10-08 PH PH1/2021/050502A patent/PH12021050502A1/en unknown
- 2021-10-08 CA CA3133725A patent/CA3133725C/en active Active
- 2021-10-08 CN CN202111172014.8A patent/CN114361407B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20220115713A1 (en) | 2022-04-14 |
| KR102639072B1 (en) | 2024-02-20 |
| JP7387687B2 (en) | 2023-11-28 |
| KR20220048447A (en) | 2022-04-19 |
| JP2022063852A (en) | 2022-04-22 |
| US11973192B2 (en) | 2024-04-30 |
| PH12021050502A1 (en) | 2022-05-02 |
| CN114361407A (en) | 2022-04-15 |
| CA3133725A1 (en) | 2022-04-12 |
| CN114361407B (en) | 2025-08-05 |
| EP3982441A1 (en) | 2022-04-13 |
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