CA3109876A1 - Procede de capture de dioxyde de carbone - Google Patents
Procede de capture de dioxyde de carbone Download PDFInfo
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- CA3109876A1 CA3109876A1 CA3109876A CA3109876A CA3109876A1 CA 3109876 A1 CA3109876 A1 CA 3109876A1 CA 3109876 A CA3109876 A CA 3109876A CA 3109876 A CA3109876 A CA 3109876A CA 3109876 A1 CA3109876 A1 CA 3109876A1
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- solid adsorbent
- adsorbent particles
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- 238000000034 method Methods 0.000 title claims abstract description 34
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 140
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 68
- 239000001569 carbon dioxide Substances 0.000 title claims description 58
- 239000007787 solid Substances 0.000 claims abstract description 183
- 239000003463 adsorbent Substances 0.000 claims abstract description 160
- 239000002245 particle Substances 0.000 claims abstract description 160
- 238000003795 desorption Methods 0.000 claims abstract description 121
- 238000001179 sorption measurement Methods 0.000 claims abstract description 109
- 238000004064 recycling Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000007789 gas Substances 0.000 description 109
- 238000001816 cooling Methods 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 239000003546 flue gas Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000005484 gravity Effects 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000005243 fluidization Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- -1 tertiary amine compounds Chemical class 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000003939 benzylamines Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940112112 capex Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- FEBLZLNTKCEFIT-VSXGLTOVSA-N fluocinolone acetonide Chemical compound C1([C@@H](F)C2)=CC(=O)C=C[C@]1(C)[C@]1(F)[C@@H]2[C@@H]2C[C@H]3OC(C)(C)O[C@@]3(C(=O)CO)[C@@]2(C)C[C@@H]1O FEBLZLNTKCEFIT-VSXGLTOVSA-N 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
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- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
- B01D53/12—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents according to the "fluidised technique"
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
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Abstract
La présente invention concerne un procédé de capture de CO2 à partir d'un flux de gaz, le procédé comprenant au moins les étapes consistant à : (a) fournir un flux de gaz contenant du CO2; (b) mettre en contact le flux gazeux fourni à l'étape (a) dans une zone d'adsorption avec des particules adsorbantes solides, ce qui permet d'obtenir des particules adsorbantes solides enrichies en CO2; (c) faire passer les particules adsorbantes solides enrichies en CO2 obtenues à l'étape (b) depuis le fond de la zone d'adsorption jusqu'au fond d'une première zone de désorption; (d) éliminer une partie du CO2 provenant des particules d'adsorbant solide enrichies en CO2 dans la première zone de désorption, ce qui permet d'obtenir des particules d'adsorbant solide partiellement appauvries en CO2 et un premier flux de gaz enrichi en CO2; (e) faire passer les particules d'adsorbant solide partiellement appauvries en CO2 obtenues à l'étape (d) par une colonne montante jusqu'à une seconde zone de désorption; (f) éliminer une autre partie du CO2 provenant des particules adsorbantes solides partiellement appauvries en CO2 dans la seconde zone de désorption, ce qui permet d'obtenir des particules adsorbantes solides régénérées et un second flux de gaz enrichi en CO2; et (g) recycler les particules adsorbantes solides régénérées telles qu'obtenues à l'étape (f) vers la zone d'adsorption de l'étape (b); la seconde zone de désorption étant située au-dessus de la zone d'adsorption.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP18386028.7 | 2018-08-31 | ||
EP18386028 | 2018-08-31 | ||
PCT/EP2019/073108 WO2020043833A1 (fr) | 2018-08-31 | 2019-08-29 | Procédé de capture de dioxyde de carbone |
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CA3109876A1 true CA3109876A1 (fr) | 2020-03-05 |
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CA3109876A Pending CA3109876A1 (fr) | 2018-08-31 | 2019-08-29 | Procede de capture de dioxyde de carbone |
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US (1) | US20210339188A1 (fr) |
EP (1) | EP3843879A1 (fr) |
CN (1) | CN112638502A (fr) |
AU (1) | AU2019332892B2 (fr) |
BR (1) | BR112021003608A2 (fr) |
CA (1) | CA3109876A1 (fr) |
WO (1) | WO2020043833A1 (fr) |
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CN114191965B (zh) * | 2021-12-16 | 2022-11-01 | 北京博奇电力科技有限公司 | 一种自动调节的连续性多床层脱碳系统 |
CN116177549B (zh) * | 2022-11-25 | 2024-05-10 | 新疆敦华绿碳技术股份有限公司 | 基于双解吸单元的二氧化碳生产方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2493911A (en) * | 1944-11-30 | 1950-01-10 | Pan American Refining Corp | Separation by adsorption |
US4283204A (en) * | 1979-09-07 | 1981-08-11 | Exxon Research & Engineering Co. | Process for the separation of contaminants from feed streams using magnetic beds |
US4247987A (en) * | 1979-09-26 | 1981-02-03 | Exxon Research & Engineering Co. | Continuous countercurrent fluid-solids contacting process stabilized by a magnetic field |
US4319892A (en) * | 1980-09-02 | 1982-03-16 | Exxon Research & Engineering Co. | Magnetically stabilized bed, temperature, partial pressure swing, hydrogen recovery process |
US20070283812A1 (en) * | 2006-06-09 | 2007-12-13 | General Electric Company | System and method for removing sulfur from fuel gas streams |
US20100180771A1 (en) * | 2009-01-22 | 2010-07-22 | General Electric Company | fluidized bed system for removing multiple pollutants from a fuel gas stream |
EP2463013A1 (fr) * | 2010-12-13 | 2012-06-13 | Shell Internationale Research Maatschappij B.V. | Processus pour supprimer le dioxyde de carbone d'un flux de gaz |
US8840706B1 (en) * | 2011-05-24 | 2014-09-23 | Srivats Srinivasachar | Capture of carbon dioxide by hybrid sorption |
CN103801172B (zh) * | 2014-02-19 | 2015-10-28 | 中国科学院山西煤炭化学研究所 | 使用循环流化移动床捕获电厂烟气中co2的工艺及装置 |
WO2016074980A1 (fr) * | 2014-11-10 | 2016-05-19 | Shell Internationale Research Maatschappij B.V. | Procédé de captage de co2 à partir d'un flux de gaz |
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- 2019-08-29 BR BR112021003608-3A patent/BR112021003608A2/pt not_active Application Discontinuation
- 2019-08-29 AU AU2019332892A patent/AU2019332892B2/en not_active Ceased
- 2019-08-29 CN CN201980056501.2A patent/CN112638502A/zh active Pending
- 2019-08-29 US US17/271,885 patent/US20210339188A1/en active Pending
- 2019-08-29 WO PCT/EP2019/073108 patent/WO2020043833A1/fr unknown
- 2019-08-29 CA CA3109876A patent/CA3109876A1/fr active Pending
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EP3843879A1 (fr) | 2021-07-07 |
WO2020043833A1 (fr) | 2020-03-05 |
US20210339188A1 (en) | 2021-11-04 |
BR112021003608A2 (pt) | 2021-05-18 |
AU2019332892B2 (en) | 2022-03-10 |
AU2019332892A1 (en) | 2021-04-08 |
CN112638502A (zh) | 2021-04-09 |
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