CA3020122C - Mercaptoazole derivatives as lubricating additives - Google Patents

Abstract

Lubricating compositions comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, or compounds having at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of a mercaptoazole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.

Description

[0001] The field of the disclosed technology is generally related to lubricating 5 compositions comprising mercaptoazole derivatives.

BACKGROUND OF THE INVENTION

[0002] It is well known for lubricating oils to contain a number of surface active additives (including antiwear agents, dispersants, or detergents) used to protect internal combustion engines from wear, soot deposits and acid build up.

Often, such surface 10 active additives including zinc dialkyldithiophosphates (ZDDP) or dispersants can have harmful effects on bearing corrosion, dispersancy or friction performance.

These additive chemistries may be corrosive to lead or copper present in bearings and other metal engine components derived from alloys using copper or lead.

[0003] It is difficult for formulators to meet the present engine oil specifications by 15 employing certain beneficial additives while also meeting the specification for lead or copper corrosion.

Commonly used copper corrosion inhibitors include azoles or their derivatives, such as methyl benzyl triazole (often referred to as tolyltriazole or simply, "TTZL").

Both TTZL and TTZL derivatives may have disadvantages in certain applications. TTZL is a solid that melts at 80 °C, making it difficult to blend or suspend 20 in the lubricating oil manufacturing process. TTZL may also contribute to lead corrosion under some circumstances.

Some TTZL derivatives may contribute to seal wear in certain applications.

Thus, TTZL and its known derivatives have not sufficiently addressed the corrosion inhibition needs in lubricating oils.

[0004] It was surprisingly determined, however, that the Michael reaction product of mercaptoazoles and acrylics ("mercaptoazole derivatives") inhibit copper corrosion with minimal detriment to lead corrosion and seals.

These derivatives are oil-soluble liquids at room temperature, making them easier to blend or suspend in lubricating oils than their TTZL or TTZL derivative precursors.

Accordingly, in one embodiment, 30 lubricating compositions comprising a mercaptoazole-acrylic adduct formed by contacting an azole compound with an acrylic are disclosed.

The adduct formed has at least one sulfur-alkyl (or "S-alkyl") group comprising at least one acyl, at least one CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 2 nitrogen-alkyl (or "N-alkyl") group comprising at least one acyl, or mixtures thereof.

The lubricating composition also comprises an antiwear agent and an antioxidant.

[0005] The acrylic may comprise at least one (meth)acrylate, (meth)acrylic acid, (meth)acrylamide, or combinations thereof.

As used herein, the term "acrylic" includes 5 derivatives of acrylic or methacrylic acids, salts, esters or amides.

Further, the term "(meth)acrylate" and related terms includes both acrylate and methacrylate groups, i.e. the methyl group is optional.

Accordingly, in some embodiments, the acrylic may comprise at least one acrylate, acrylic acid, acrylamide, methacrylate, methacrylic acid, methacrylamide, or combinations thereof.

In yet other embodiments, the acrylic may 10 be a (meth)acrylate having the formula (I): O-R1 (I) wherein Risa hydrogen or a C1-C20 hydrocarbyl group and R 1 is a C1-C20 hydrocarbyl group.

In another embodiment, R may be a hydrogen or a methyl group.

[0006] In one embodiment, the (meth)acrylate may comprise at least one acrylate, 15 methacrylate, or combinations thereof.

Suitable acrylates include, but are not limited to, octadecyl acrylate, hexadecyl acrylate, tridecyl acrylate, dodecyl acrylate, decyl acrylate, 2-propylheptyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, hexyl acrylate, butyl acrylate, ethyl acrylate, methyl acrylate, or combinations thereof.

Suitable methacrylates include, but are not limited to, octadecyl methacrylate, hexadecyl 20 methacrylate, tridecyl methacrylate, dodecyl methacrylate, decyl methacrylate, 2- propylheptyl methacrylate, 2-ethylhexyl methacrylate, octyl methacrylate, hexyl methacrylate, butyl methacrylate, ethyl methacrylate, methyl methacrylate, or combinations thereof.

[0007] In another embodiment, the mercaptoazole compound may comprise at least 25 one of, 2-mercaptoimidazole, 2-mercaptoimidazole derivatives, 5-mercaptoimidazole, 5-mercaptoimidazole derivatives, 2-mercapto-1,3,4-triazole, 2-mercapto-1,3,4-triazole derivatives, 4-mercapto-1,2,3-triazole, 4-mercapto-1,2,3-triazole derivatives, 5- mercapto-1,2,3-triazole, 5-mercapto-1,2,3-triazole derivatives, 3-mercapto-1,2,4- triazole, 5-mercapto-1,2,4-triazole derivatives, 2-mercapto-thiazole, 2-mercaptoCA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 3 thiazole derivatives, 4-mercapto-thiazole, 4-mercapto-thiazole derivatives, 5- mercapto-thiazole, 5-mercapto-thiazole derivatives, 2-mercapto-benzothiazole, 2- mercapto-benzothiazole derivatives, or combinations thereof.

[0008] In one embodiment, the lubricating composition may compnse a 5 mercaptoazole-acrylic adduct represented by formula (II) or (III): (II) or (III) wherein R2 and R3 are independently a hydrogen or Ci-C20 hydrocarbyl group or, when taken together, R2 and R3 form a saturated or unsaturated ring containing 5 to 6 carbon atoms; R4 is a C2-C40 hydrocarbyl group and comprises at least one acyl, wherein the 10 hydrocarbyl group is linear, branched, homocyclic, or heterocyclic, or a combination thereof; and xi is Nor S.

In yet another embodiment, xi can be S.

[0009] In another embodiment, the mercaptoazole-acrylic adduct may have the formula (IV) or (V): 0--R8 R•-06>-/'--{ (IV) or (V) CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 4 wherein R6 is hydrogen or a C1-C20 hydrocarbyl group; R7 is a linear or branched hydrocarbyl group having at least two carbon atoms; and R8 is a C1-C20 hydrocarbyl group and is linear, branched, homocyclic, heterocyclic, or a combination thereof.

[0010] In other embodiments, the mercaptoazole-acrylic adducts may have the 5 formula (VI), or (VII): (VI) or Ra j (VII) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group, and R8 is a C1-C20 hydrocarbyl 10 group and is linear, branched, homocyclic, heterocyclic, or a combination thereof.

[0011] In yet another embodiment, the mercaptoazole-acrylic adducts may have the formula (VIII): (VIII) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group. 15

[0012] The lubricating composition may have an antiwear agent.

In one embodiment, the antiwear agent may comprise phosphorus and is present in an amount such that the lubricating composition has at least 300 ppm phosphorus based on a total weight of the lubricating composition.

[0013] In another embodiment, the lubricating composition may further comprise a nitrogen-containing dispersant.

In another embodiment, the lubricating composition 5 may comprise at least one boron-containing compound.

Exemplary boron-containing compounds include, but are not limited to, borate esters, borate alcohols, or combinations thereof.

In yet another embodiment, the lubricating composition may comprise at least one overbased detergent.

In another embodiment, the lubricating compositions described above may comprise from 0.01 wt% to 5 wt% of a 10 mercaptoazole-acrylic adduct based on a total weight of the lubricating composition.

[0014] Methods of lubricating an internal combustion engine are also disclosed.

In one embodiment, the method may comprise contacting the internal combustion engine with a lubricating composition as described above.

The lubricating composition may comprise a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole 15 compound with an acrylic.

The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof.

The lubricating composition also comprises an antiwear agent and an antioxidant.

[0015] In yet other embodiments, methods of reducing corros10n and/or seal 20 deterioration in an internal combustion engine are disclosed.

The methods may comprise contacting the internal combustion engine with the lubricating compositions described above.

In another embodiment, the use of a mercaptoazole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine is disclosed. 25 DETAILED DESCRIPTION OF THE INVENTION

[0016] The mention of any document herein is not an admission that such document qualifies as prior art or constitutes the general knowledge of the skilled person in any jurisdiction.

Except in the Examples, or where otherwise explicitly indicated, all numerical quantities in this description specifying amounts of materials, reaction 30 conditions, molecular weights, number of carbon atoms, and the like, are to Date Rer;ue/Date Received 2023-09-07 CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 6 be understood as modified by the word "about." It is to be understood that the upper and lower amount, range, and ratio limits set forth herein may be independently combined.

Similarly, the ranges and amounts for each element of the invention can be used together with ranges or amounts for any of the other elements. 5

[0017] As used herein, the transitional term "comprising," which is synonymous with "including," "containing," or "characterized by," is inclusive or open-ended and does not exclude additional, un-recited elements or method steps.

However, in each recitation of "comprising" herein, it is intended that the term also encompass, as alternative embodiments, the phrases "consisting essentially of' and "consisting of," 10 where "consisting of' excludes any element or step not specified and "consisting essentially of' permits the inclusion of additional un-recited elements or steps that do not materially affect the basic and novel characteristics of the composition or method under consideration.

[0018] Various features and embodiments will be described below by way of non- 15 limiting descriptions and examples.

In one embodiment, lubricating compositions comprising a mercaptoazole-acrylic adduct formed by reacting a mercaptoazole compound with an acrylic are disclosed.

The adduct formed has at least one sulfuralkyl (''S-alkyl") group comprising at least one acyl, or compounds having at least one nitrogen-alkyl ("N-alkyl") group comprising at least one acyl, or mixtures thereof.

The 20 lubricating composition also comprises an antiwear agent and an antioxidant.

[0019] The acrylic may comprise at least one (meth)acrylate, (meth)acrylic acid, (meth)acrylamide, or combinations thereof.

In one embodiment, the acrylic may be a (meth)acrylate having the formula (I): O-R1 (I) 25 wherein Risa hydrogen or a C1-C20 hydrocarbyl group and R1 is a C1-C20 hydrocarbyl group.

In another embodiment, R may be a hydrogen or a methyl group.

[0020] As used herein, the terms "hydrocarbyl substituent" or "hydrocarbyl group" is used in its ordinary sense, which is well-known to those skilled in the art.

Specifically, it refers to a group having a carbon atom directly attached to the remainder CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 7 of the molecule and having predominantly hydrocarbon character.

The hydrocarbyl substituent or hydrocarbyl group may have more than one carbon atom.

The number of carbon atoms may also be indicated herein.

For example, the term "C1-C20 hydrocarbyl group" means a hydrocarbyl group having 1 to 20 carbon atoms.

Examples of 5 hydrocarbyl groups include: [0021] hydrocarbon substituents, that is, aliphatic (e.g., alkyl or alkenyl), alicyclic (e.g., cycloalkyl, cycloalkenyl) substituents, and aromatic-, aliphatic-, and alicyclicsubstituted aromatic substituents, as well as cyclic substituents wherein the ring is completed through another portion of the molecule (e.g., two substituents together form 10 a ring); [0022] substituted hydrocarbon substituents, that is, substituents containing nonhydrocarbon groups which, in the context of the disclosed technology, do not alter the predominantly hydrocarbon nature of the substituent (e.g., halo (especially chloro and fluoro), hydroxy, alkoxy, mercapto, alkylmercapto, nitro, nitroso, and sulfoxy); 15 hetero substituents, that is, substituents which, while having a predominantly hydrocarbon character, in the context of the disclosed technology, contain other than carbon in a ring or chain otherwise composed of carbon atoms and encompass substituents as pyridyl, furyl, thienyl and imidazolyl.

Heteroatoms include sulfur, oxygen, and nitrogen.

In general, no more than two, or no more than one, non- 20 hydrocarbon substituent will be present for every ten carbon atoms in the hydrocarbyl group; alternatively, there may be no non-hydrocarbon substituents in the hydrocarbyl group.

[0023] In other embodiments, the acrylic may comprise an acrylic acid having the formula (IX): OH (IX) wherein R is a hydrogen or a C1 -C20 hydrocarbyl group.

[0024] In yet other embodiments, the acrylic may comprise an acrylamide having the formula (X): CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 8 (X) wherein each R may independently be a hydrogen or a Ci-C20 hydrocarbyl group.

[0025] In one embodiment, the acrylic may comprise at least one methacrylate, methacrylic acid, methacrylamide, or combinations thereof.

In another embodiment, 5 the (meth)acrylate may comprise at least one acrylate, methacrylate, butylacrylate, or combinations thereof.

In yet another embodiment, the (meth)acrylate may comprise at least one acrylate, methacrylate, or combinations thereof.

[0026] Suitable acrylates include, but are not limited to, octadecyl acrylate, hexadecyl acrylate, tridecyl acrylate, dodecyl acrylate, decyl acrylate, 2-propylheptyl 10 acrylate, 2-ethylhexyl acrylate, octyl acrylate, hexyl acrylate, butyl acrylate, ethyl acrylate, methyl acrylate, or combinations thereof.

Suitable methacrylates include, but are not limited to, octadecyl methacrylate, hexadecyl methacrylate, tridecyl methacrylate, dodecyl methacrylate, decyl methacrylate, 2-propylheptyl methacrylate, 2-ethylhexyl methacrylate, octyl methacrylate, hexyl methacrylate, butyl methacrylate, 15 ethyl methacrylate, methyl methacrylate, or combinations thereof.

[0027] The mercaptoazole compound may be a substituted or unsubstituted heterocyclic azole.

In one embodiment, the lubricating composition may comprise a mercaptoazole-acrylic adduct represented by formula (II) or (III): (II) or (III) 20 wherein R2 and R3 are independently a hydrogen or Ci-C20 hydrocarbyl group or, when taken together, R2 and R3 form a saturated or unsaturated ring containing 5 to 6 carbon atoms; R 4 is a C2-C40 hydrocarbyl group and comprises at least one acyl, wherein the hydrocarbyl group is linear, branched, homocyclic, or heterocyclic, or a combination thereof; and xi is Nor S.

In yet another embodiment, xi may be S.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 9

[0028] Suitable mercaptoazole compounds for making the mercaptoazole-acrylic adducts include, but are not limited to, at least one of 2-mercaptoimidazole, 2- mercaptoimidazole derivatives, 5-mercaptoimidazole, 5-mercaptoimidazole derivatives, 2-mercapto-1,3,4-triazole, 2-mercapto-1,3,4-triazole derivatives, 4- 5 mercapto-1,2,3-triazole, 4-mercapto-1,2,3-triazole derivatives, 5-mercapto-1,2,3- triazole, 5-mercapto-1,2,3-triazole derivatives, 3-mercapto-1,2,4-triazole, 5- mercapto-1,2,4-triazole derivatives, 2-mercapto-thiazole, 2-mercapto-thiazole derivatives, 4-mercapto-thiazole, 4-mercapto-thiazole derivatives, 5-mercaptothiazole, 5-mercapto-thiazole derivatives, 2-mercapto-benzothiazole, 2-mercapto- 10 benzothiazole derivatives, or combinations thereof.

The reaction of the mercaptoazole compound with an acrylate may take place in the presence of trimethylamine, acetonitrile, or tetrahydrofuran as catalyst or solvent.

[0029] In another embodiment, the mercaptoazole-acrylic adduct may have the formula (IV) or (V): 0--R8 R•-Or6>-/'-( (IV) or (V) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group; R7 is a linear or branched hydrocarbyl group having at least two carbon atoms; and R8 is a C1-C20 hydrocarbyl 20 group and is linear, branched, homocyclic, heterocyclic, or a combination thereof.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972

[0030] Exemplary mercaptoazole-acrylic adducts include, but are not limited to, the reaction products of 2-mercaptobenzothiazole and 2-ethylhexyl acrylate, 2- mercaptothiazole and 2-ethylhexyl acrylate, 2-mercaptoimidazole and 2-ethylhexyl acrylate, 2-mercaptobenzimidazole and 2-ethylhexyl acrylate, or combinations thereof. 5

[0031] Exemplary mercaptoazole-acrylic adducts include adducts and isomers made from 2-ethylhexyl acrylate and ethyl acrylate.

These adducts include, but are not limited, to 2-ethylhexyl 3-(benzothiazol-2-ylthio)propanoate.

[0032] In other embodiments, the mercaptoazole-acrylic adducts may have the formula (VI), or (VII): (VI) or Rs j (VII) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group, and R8 is a C1-C20 hydrocarbyl group and is linear, branched, homocyclic, heterocyclic, or a combination thereof. 15

[0033] In yet another embodiment, the mercaptoazole-acrylic adducts may have the formula (VIII): CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 11 (VIII) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group.

[0034] Further mercaptoazole-acrylic adducts include, but are not limited to, the adducts shown in the structures below.

WO 2017/176546 CA 0302oi22 2oie-io-04 12 PCT/0S2017/024972 s S-f ~N~O-C10H21 ~~ R6 s &}.~0 -c,,H,, R6 s r.-l,_}.~0 -c,.H,9 RJ~ s r.-l,,-t~ 0 -c,,H,, R$J wherein R6 is hydrogen or a C1-C20 hydrocarbyl group.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 13

[0035] The lubricating composition may have an antiwear agent.

The antiwear agent may be a phosphorus-containing or a sulfur-containing antiwear agent.

In one embodiment, the antiwear agent may comprise phosphorous that is present in an amount such that the lubricating composition has at least 300 ppm phosphorous based 5 on a total weight of the lubricating composition.

In other embodiments, the phosphorous content may be 300 to 1000 ppm or 325 to 700 ppm phosphorous based on a total weight of the lubricating composition.

[0036] In another embodiment, the lubricating composition may further comprise a nitrogen-containing dispersant.

In another embodiment, the lubricating composition 10 may comprise at least one boron-containing compound.

Exemplary boron-containing compounds include, but are not limited to, borate esters, borate alcohols, or combinations thereof.

In yet another embodiment, the lubricating composition may comprise at least one overbased detergent.

[0037] The lubricating compositions may comprise from 0.01 wt% to 5 wt% of a 15 mercaptoazole-acrylic adduct based on a total weight of the lubricating composition.

Alternatively the mercaptoazole-acrylic adduct may be present in the following ranges: 0.01 to 3 wt%; 0.01 to 1 wt%; 0.01 to 0.5 wt%; or 0.05 to 0.1 wt%.

Unless expressly stated otherwise, as used herein, reference to the amounts of components or additives present in the lubricating composition are quoted on an oil free basis, i.e., amount of 20 actives.

[0038] Methods of lubricating an internal combustion engine are also disclosed.

In one embodiment, the method may comprise contacting the internal combustion engine with the lubricating composition as described above.

The lubricating composition may comprise a mercaptoazole-acrylic adduct formed by contacting an azole compound 25 with an acrylic.

The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, or compounds having at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof.

The lubricating composition also comprises an antiwear agent and an antioxidant.

[0039] In yet other embodiments, methods of reducing corrosion and/or seal 30 deterioration in an internal combustion engine are disclosed.

The methods may comprise contacting the internal combustion engine with the lubricating compositions described above.

In another embodiment, the use of a mercaptoazole-acrylic adduct in CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 14 a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine is disclosed.

Anti wear Agents

[0040] The disclosed lubricating compositions may compnse a phosphorus- 5 containing or a sulfur-containing antiwear agent.

These antiwear agents may be corrosive, particularly to metals such as lead or copper, under some conditions.

It is believed, however, that the mercaptoazole-acrylic adducts described herein reduce the corrosive effects of the antiwear agents without affecting their efficacy in reducing wear. 10

[0041] Accordingly, in one embodiment, the disclosed technology provides a lubricating composition which further includes a phosphorus-containing and/or a sulfur-containing antiwear agent.

Typically, the phosphorus-containing antiwear agent may be zinc dialkyldithiophosphates, phosphites, phosphates, phosphonates, and ammonium phosphate salts or mixtures thereof. 15

[0042] Zinc dialkyldithiophosphates are known m the art.

Examples of zmc dithiophosphates include zinc isopropyl methylamyl dithiophosphate, zinc isopropyl isooctyl dithiophosphate, zinc di(cyclohexyl) dithiophosphate, zinc isobutyl 2- ethylhexyl dithiophosphate, zinc isopropyl 2-ethylhexyl dithiophosphate, zinc isobutyl isoamyl dithiophosphate, zinc isopropyl n-butyl dithiophosphate, and 20 combinations thereof.

Zinc dialkyldithiophosphate may be present in an amount to provide 0.01 wt¾ to 0.1 wt¾ phosphorus to the lubricating composition, or to provide 0.015 wt¾ to 0.075 wt¾ phosphorus, or 0.02 wt¾ to 0.05 wt¾ phosphorus to the lubricating composition.

[0043] In one embodiment, the lubricant composition further comprises one or 25 more zinc dialkyldithiophosphates such that the amine (thio)phosphate additive of the disclosed technology provides at least 50% of the total phosphorus present in the lubricating composition, or at least 70% of the total phosphorus, or at least 90% of the total phosphorus in the lubricating composition.

In one embodiment, the lubricant composition is free or substantially free of a zinc dialkyldithiophosphate. 30

[0044] The sulfur-containing antiwear agent may be sulfurized olefins, sulfurcontaining detergents, or sulfurized Diels-Alder adducts.

The antiwear agent may be CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 present at 0.01 wt¾ to 3 wt¾, or 0.1 wt¾ to 1.5 wt¾, or 0.5 wt¾ to 0.9 wt¾ based on a total weight of the lubricating composition.

Antioxidants

[0045] In one embodiment the disclosed lubricant composition includes an 5 antioxidant, or mixtures thereof.

Antioxidants include sulfurized olefins, diarylamines, alkylated diarylamines, hindered phenols, molybdenum compounds (such as molybdenum dithiocarbamates), hydroxyl thioethers, or mixtures thereof.

The antioxidant may be present at 0.05 wt¾ to 15 wt¾, or 0.1 wt¾ to 10 wt¾, or 0.5 wt¾ to 5 wt¾, or 0.5 wt¾ to 3 wt¾, or 0.3 wt¾ to 1.5 wt¾ based on a total weight 10 of the lubricant composition.

[0046] In one embodiment the lubricant composition further comprises a phenolic or an aminic antioxidant or mixtures thereof, and wherein the antioxidant is present at 0.1 wt¾ to 3 wt¾, or 0.5 wt¾ to 2.75 wt¾, or 1 wt¾ to 2.5 wt¾ based on a total weight of the lubricant composition. 15

[0047] The antiwear agent may be present at 0 wt¾ to 3 wt¾, or 0.1 wt¾ to 1.5 wt¾, or 0.5 wt¾ to 0.9 wt¾ based on a total weight of the lubricant composition.

[0048] The diarylamine or alkylated diarylamine may be a phenyl-a-naphthylamine (PANA), an alkylated diphenylamine, or an alkylated phenylnapthylamine, or mixtures thereof.

The alkylated diphenylamine may include di-nonylated diphenylamine, nonyl 20 diphenylamine, octyl diphenylamine, di-octylated diphenylamine, di-decylated diphenylamine, decyl diphenylamine and mixtures thereof.

In one embodiment the diphenylamine may include nonyl diphenylamine, dinonyl diphenylamine, octyl diphenylamine, dioctyl diphenylamine, or mixtures thereof.

In one embodiment the alkylated diphenylamine may include nonyl di phenyl amine, or dinonyl di phenyl amine. 25 The alkylated diarylamine may include octyl, di-octyl, nonyl, di-nonyl, decyl or di-decyl phenylnapthylamines.

[0049] The hindered phenol antioxidant often contains a secondary butyl and/or a tertiary butyl group as a sterically hindering group.

The phenol group may be further substituted with a hydrocarbyl group (typically linear or branched alkyl) and/or a 30 bridging group linking to a second aromatic group.

Examples of suitable hindered phenol antioxidants include 2,6-di-tert-butylphenol, 4-methyl-2,6-di-tertbutyl phenol, 4-ethyl-2,6-di-tert-butyl phenol, 4-propyl-2, 6-di-tert-butyl phenol or 4- CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 16 butyl-2,6-di-tert-butyl phenol, or 4-dodecyl-2,6-di-tert-butyl phenol.

In one embodiment the hindered phenol antioxidant may be an ester and may include, e.g., Irganox™ L-135 from Ciba. A more detailed description of suitable ester-containing hindered phenol antioxidant chemistry is found in US Patent 6,559,105. 5

[0050] Examples of molybdenum dithiocarbamates, which may be used as an antioxidant, include commercial materials sold under the trade names such as Molyvan 822®, Molyvan® A and Molyvan® 855 from R. T.

Vanderbilt Co., Ltd., and Adeka Sakura-Lube™ S-100, S-165, S-600 and 525, or mixtures thereof.

Oils of Lubricating Viscosity

[0051] The lubricating compositions compnsmg a mercaptoazole-acrylic adduct described herein may also comprise an oil of lubricating viscosity.

Such oils include natural and synthetic oils, oil derived from hydrocracking, hydrogenation, and hydrofinishing, unrefined, refined, re-refined oils or mixtures thereof. A more detailed description of unrefined, refined and re-refined oils is provided in International 15 Publication WO2008/147704, paragraphs [0054] to [0056] (a similar disclosure is provided in US Patent Application 2010/197536, see [0072] to [0073]). A more detailed description of natural and synthetic lubricating oils is described in paragraphs [0058] to [0059] respectively of WO2008/147704 (a similar disclosure is provided in US Patent Application 2010/197536, see [0075] to [0076]).

Synthetic oils may also be 20 produced by Fischer-Tropsch reactions and typically may be hydroisomerized FischerTropsch hydrocarbons or waxes.

In one embodiment, oils may be prepared by a Fischer-Tropsch gas-to-liquid synthetic procedure as well as other gas-to-liquid oils.

[0052] Oils oflubricating viscosity may also be defined as specified in the September 2011 version of "Appendix E - API Base Oil Interchangeability Guidelines for 25 Passenger Car Motor Oils and Diesel Engine Oils", section 1.3 Sub-heading 1.3. "Base Stock Categories".

In one embodiment the oil of lubricating viscosity may be an API Group II or Group III oil.

In one embodiment, the oil of lubricating viscosity may be an API Group I oil.

[0053] The amount of the oil of lubricating viscosity present is typically the balance 30 remaining after subtracting from 100 wt¾ the sum of the amount of the compound of the invention and the other performance additives.

The amount of each chemical component or additive described is presented exclusive of any solvent or diluent oil, CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 17 which may be customarily present in the commercial material, that is, on an active chemical basis, unless otherwise indicated.

However, unless otherwise indicated, each chemical or composition referred to herein should be interpreted as being a commercial grade material which may contain the isomers, by-products, derivatives, and other such 5 materials which are normally understood to be present in the commercial grade.

[0054] The lubricating composition may be in the form of a concentrate and/or a fully formulated lubricant.

If the lubricating composition of the invention ( comprising the additives disclosed herein) is in the form of a concentrate which may be combined with additional oil to form, in whole or in part, a finished lubricant), the ratio of the of these 10 additives to the oil of lubricating viscosity and/or to diluent oil include the ranges of 1:99 to 99:1 by weight, or 80:20 to 10:90 by weight.

Boron-Containing Compounds

[0055] In one embodiment, the lubricating composition of the invention further includes a boron-containing compound.

In one embodiment the boron-containing 15 compound includes a borate ester or a borate alcohol.

[0056] The borate ester may be prepared by the reaction of a boron compound and at least one compound selected from epoxy compounds, halohydrin compounds, epihalohydrin compounds, alcohols and mixtures thereof.

The alcohols include dihydric alcohols, trihydric alcohols or higher alcohols, with the proviso for one 20 embodiment that hydroxyl groups are on adjacent carbon atoms, i.e., vicinal.

[0057] Boron compounds suitable for preparing the borate ester include the various forms selected from the group consisting of boric acid (including metaboric acid, HB02, orthoboric acid, H3BQ3, and tetraboric acid, H2B4Q7 ), boric oxide, boron trioxide and alkyl borates.

The borate ester may also be prepared from boron halides. 25

[0058] In one embodiment, suitable borate ester compounds include triethyl borate, tripropyl borate, triisopropyl borate, tributyl borate, tripentyl borate, trihexyl borate, tricyclohexyl borate, trioctyl borate, triisooctyl borate, tridecyl borate, tri (Cs-10) borate, tri (C12-1s borate) and oleyl borate, or mixtures thereof.

[0059] In one embodiment, the boron-containing compound is a borated fatty acid 30 ester of glycerol.

The borated fatty acid esters of glycerol are prepared by borating a fatty acid ester of glycerol with boric acid with removal of the water of reaction.

In one CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 18 embodiment, there is sufficient boron present such that each boron will react with from 1.5 to 2.5 hydroxyl groups present in the reaction mixture.

[0060] The reaction may be carried out at a temperature in the range of 60 °C to 13 5 °C, in the absence or presence of any suitable organic solvent such as methanol, 5 benzene, xylenes, toluene, neutral oil and the like.

[0061] Fatty acid esters of glycerol can be prepared by a variety of methods well known in the art.

Many of these esters, such as glycerol monooleate and glycerol tallowate, are manufactured on a commercial scale.

The esters useful for this invention are oil-soluble and may be prepared from Cs to C22 fatty acids or mixtures thereof such 10 as are found in natural products.

The fatty acid may be saturated or unsaturated.

Certain compounds found in acids from natural sources may include licanic acid which contains one keto group.

In one embodiment, the Cs to C22 fatty acids are those of the formula R10-COOH wherein R10 is alkyl or alkenyl.

[0062] In one embodiment, the fatty acid ester of glycerol is a monoester of glycerol, 15 however, mixtures of mono- and diesters may be used.

The mixture of mono- and di ester can contains at least 40% of the monoester.

In one embodiment, mixtures of mono- and diesters of glycerol contain from 40 to 60 percent by weight of the monoester.

For example, commercial glycerol monooleate contains a mixture of from 45% to 55% by weight monoester and from 55% to 45% diester. 20

[0063] In one embodiment, the fatty acids include oleic, stearic, isostearic, palmitic, myristic, palmitoleic, linoleic, lauric, linolenic, and eleostearic, and the acids from the natural products tallow, palm oil, olive oil, peanut oil, corn oil, neat's foot oil and the like.

In one embodiment, the fatty acid is oleic acid.

[0064] The boron-containing compound may be employed in the inventive 25 lubricating oil composition at a sufficient concentration to provide the lubricating oil composition with a boron level in the range of from 5 ppm to 2000 ppm, and in one embodiment 15 ppm to 600 ppm, and in one embodiment 20 ppm to 300 ppm.

Other Performance Additives

[0065] The composition optionally comprises other performance additives.

The 30 other performance additives may include at least one of metal deactivators, viscosity modifiers, detergents, friction modifiers, antiwear agents, corrosion inhibitors (other than the mercaptoazole derivatives presently disclosed), dispersants, dispersant CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 19 viscosity modifiers, extreme pressure agents, antioxidants, foam inhibitors, demulsifiers, pour point depressants, seal swelling agents and mixtures thereof.

These other performance additives may be in addition to the additives of the disclosed technology.

For example, additives may be corrosion inhibitors, anti wear agents and/or 5 antioxidants present in the lubricating composition in addition to those described in other embodiments of the disclosed technology.

[0066] Accordingly, in one embodiment, the disclosed technology provides a lubricating composition further comprising at least one of a dispersant, an antiwear agent, a dispersant viscosity modifier, a friction modifier, a viscosity modifier 10 (typically an olefin copolymer such as an ethylene-propylene copolymer), an antioxidant (including phenolic and aminic antioxidants), an overbased detergent (including overbased sulfonates and phenates), an extreme pressure agent, a foam inhibitor, a demulsifier, a pour point depressant, a seal swelling agent, or mixtures thereof. 15

[0067] The dispersant may be a succinimide dispersant, or mixtures thereof.

In one embodiment, the dispersant may be present as a single dispersant.

In one embodiment, the dispersant may be present as a mixture of two or three different dispersants, wherein at least one may be a succinimide dispersant.

[0068] The succinimide dispersant may be derived from an aliphatic polyamine, or 20 mixtures thereof.

The aliphatic polyamine may be aliphatic polyamine such as an ethylenepolyamine, a propylenepolyamine, a butylenepolyamine, or mixtures thereof.

In one embodiment, the aliphatic polyamine may be ethylenepolyamine.

In one embodiment, the aliphatic polyamine may be selected from the group consisting of ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, 25 pentaethylenehexamine, polyamine still bottoms, and mixtures thereof.

[0069] The dispersant may also be derived from a material having an aromatic amine.

The aromatic amine that may be useful is disclosed in International publications WO2010/062842 and WO2009/064685 (a similar disclosure is provided in US 2010/298185).

The aromatic amine of WO2009/064685 is typically reacted with 30 isatoic anhydride.

[0070] The aromatic amine may typically not be a heterocycle.

The aromatic amine may include aniline, nitroaniline, aminocarbazole, 4-aminodiphenylamine (ADPA), CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 and coupling products of ADP A.

In one embodiment, the amme may be 4-aminodiphenylamine (ADPA), or coupling products of ADP A.

The aromatic amine may include bis[p-(p-aminoanilino )phenyl ]-methane, 2-(7-amino-acridin-2-ylmethyl )N- 4-{ 4-[ 4-( 4-amino-phenylamino )-benzyl ]-phenyl }-benzene-1,4-diamine, N-{ 4-[ 4- 5 ( 4-amino-phenylamino )-benzyl ]-phenyl }-2-[ 4-( 4-amino-phenylamino )-cyclohexa- 1,5-dienylmethyl ]-benzene-1,4-diamine, N-[ 4-(7-amino-acridin-2-ylmethyl )-phenyl]benzene- 1,4-diamine, or mixtures thereof.

[0071] The dispersant may be an N-substituted long chain alkenyl succinimide.

Examples of N-substituted long chain alkenyl succinimide include polyisobutylene 10 succinimide.

Typically, the polyisobutylene from which polyisobutylene succinic anhydride is derived has a number average molecular weight of350 to 5000, or 550 to 3000 or 750 to 2500.

Succinimide dispersants and their preparation are disclosed, for instance, in US Patents 3,172,892, 3,219,666, 3,316,177, 3,340,281, 3,351,552, 3,381,022, 3,433,744, 3,444,170, 3,467,668, 3,501,405, 3,542,680, 3,576,743, 15 3,632,511, 4,234,435, Re 26,433, and 6,165,235, 7,238,650 and EP Patent Application 0 355 895 A.

[0072] The dispersant may also be post-treated by conventional methods by a reaction with any of a variety of agents.

Among these are boron compounds (such as boric acid & borate esters), urea, thiourea, dimercaptothiadiazoles, carbon disulfide, 20 aldehydes, ketones, carboxylic acids, hydrocarbon-substituted succinic anhydrides, maleic anhydride, nitriles, epoxides, and phosphorus compounds.

[0073] The dispersant may be present at 0.1 wt% to 10 wt%, or 2.5 wt% to 6 wt%, or 3 wt% to 5 wt% of the lubricating composition.

[0074] In one embodiment, the lubricating composition of disclosed technology 25 further comprises a dispersant viscosity modifier.

The dispersant viscosity modifier may be present at O wt% to 5 wt%, or O wt% to 4 wt%, or 0.05 wt% to 2 wt% of the lubricating composition.

[0075] The dispersant viscosity modifier may include functionalized polyolefins, for example, ethylene-propylene copolymers that have been functionalized with an 30 acylating agent such as maleic anhydride and an amine; polymethacrylates functionalized with an amine, or styrene-maleic anhydride copolymers reacted with an amine.

More detailed description of dispersant viscosity modifiers are disclosed in CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 21 International Publication WO2006/015130 or U.S.

Patents 4,863,623; 6,107,257; 6,107,258; and 6,117,825.

In one embodiment, the dispersant viscosity modifier may include those described in U.S.

Patent 4,863,623 (see column 2, line 15 to column 3, line 52) orin International Publication WO2006/015130 (see page 2, paragraph [0008] 5 and preparative examples are described paragraphs [0065] to [0073]).

[0076] In one embodiment, the dispersant viscosity modifier may include those described in U.S.

Patent 7,790,661 column 2, line 48 to column 10, line 38.

The dispersant viscosity modifier of 7,790,661 includes (a) a polymer comprising carboxylic acid functionality or a reactive equivalent thereof, said polymer having a 10 number average molecular weight of greater than 5,000; and (b) an amine component comprising at least one aromatic amine containing at least one amino group capable of condensing with said carboxylic acid functionality to provide a pendant group and at least one additional group comprising at least one nitrogen, oxygen, or sulfur atom, wherein said aromatic amine is selected from the group consisting of (i) a nitro- 15 substituted aniline, (ii) amines comprising two aromatic moieties linked by a - C(O)NR11 - group, a -C(O)O- group, an -0- group, an -N-N- group, or an -SO2- group, wherein R 11 is hydrogen or hydrocarbyl, one of said aromatic moieties bearing said condensable amino group, (iii) an aminoquinoline, (iv) an aminobenzimidazole, (v) an N,N-dialkylphenylenediamine, and (vi) a ring-substituted benzylamine. 20

[0077] In one embodiment, the disclosed technology can be a lubricating composition further compnsmg a molybdenum compound.

The molybdenum compound may be selected from the group consisting of molybdenum dialkyldithiophosphates, molybdenum dithiocarbamates, amine salts of molybdenum compounds, and mixtures thereof.

The molybdenum compound may provide the 25 lubricating composition with Oto 1000 ppm, or 5 to 1000 ppm, or 10 to 750 ppm, 5 ppm to 300 ppm, or 20 ppm to 250 ppm of molybdenum.

[0078] In one embodiment, the disclosed technology can be a lubricating composition further comprising an overbased detergent.

Overbased detergents are known in the art.

The overbased detergent may be selected from the group consisting 30 of non-sulfur containing phenates, sulfur containing phenates, sulfonates, salixarates, salicylates, and mixtures thereof.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 22

[0079] The overbased detergent may also include "hybrid" detergents formed with mixed surfactant systems including phenate and/or sulfonate components, e.g., phenate/salicylates, sulfonate/phenates, sulfonate/salicylates, sulfonates/phenates/salicylates, as described, for example, in US Patents 6,429,178; 5 6,429,179; 6,153,565; and 6,281,179.

Where, for example, a hybrid sulfonate/phenate detergent is employed, the hybrid detergent would be considered equivalent to amounts of distinct phenate and sulfonate detergents introducing like amounts of phenate and sulfonate soaps, respectively.

[0080] Typically an overbased detergent may be sodium, calcium or magnesium salt 10 of the phenates, sulfur containing phenates, sulfonates, salixarates and salicylates.

Overbased phenates and salicylates typically have a total base number of 180 to 450 TBN.

Overbased sulfonates typically have a total base number of 250 to 600, or 300 to 500.

In one embodiment, the sulfonate detergent may be a predominantly linear alkylbenzene sulfonate detergent having a metal ratio of at least 8 as is described in 15 paragraphs [0026] to [0037] of US Patent Application 2005065045 (and granted as US 7,407,919).

Linear alkyl benzenes may have the benzene ring attached anywhere on the linear chain, usually at the 2, 3, or 4 position, or mixtures thereof.

The predominantly linear alkylbenzene sulfonate detergent may be particularly useful for assisting in improving fuel economy.

In one embodiment, the sulfonate detergent may 20 be a metal salt of one or more oil-soluble alkyl toluene sulfonate compounds as disclosed in paragraphs [0046] to [0053] of US Patent Application 2008/0119378.

The overbased detergent may be present at O wt% to 15 wt%, or 1 wt% to 10 wt%, or 3 wt% to 8 wt%.

For example, in a heavy duty diesel engine, the detergent may be present at or 3 wt% to 5 wt% of the lubricating composition.

For a passenger car engine, 25 the detergent may be present at 0.2 wt% to 1 wt% of the lubricating composition.

[0081] In one embodiment, the lubricating composition includes an antioxidant, or mixtures thereof.

The antioxidant may be present at O wt% to 15 wt%, or 0.1 wt% to 10 wt%, or 0.5 wt% to 5 wt% of the lubricating composition.

[0082] Antioxidants include sulfurized olefins, alkylated diphenylamines (typically 30 dinonyl diphenylamine, octyl diphenylamine, dioctyl diphenylamine), phenyl-anaphthylamine (PANA), hindered phenols, molybdenum compounds (such as molybdenum dithiocarbamates), or mixtures thereof.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 23

[0083] The hindered phenol antioxidant often contains a secondary butyl and/or a tertiary butyl group as a sterically hindering group.

The phenol group may be further substituted with a hydrocarbyl group (typically linear or branched alkyl) and/or a bridging group linking to a second aromatic group.

Examples of suitable hindered 5 phenol antioxidants include 2,6-di-tert-butylphenol, 4-methyl-2,6-di-tert-butylphenol, 4-ethyl-2, 6-di-tert-butyl phenol, 4-propyl-2,6-di-tert-butyl phenol or 4-butyl-2, 6-ditert- butyl phenol, or 4-dodecyl-2,6-di-tert-butylphenol.

In one embodiment, the hindered phenol antioxidant may be an ester and may include, e.g., Irganox™ L-135 from Ciba. A more detailed description of suitable ester-containing hindered phenol 10 antioxidant chemistry is found in US Patent 6,559,105.

[0084] Examples of suitable friction modifiers include long chain fatty acid derivatives of amines, fatty esters, or fatty epoxides; fatty imidazolines such as condensation products of carboxylic acids and polyalkylene-polyamines; amine salts of alkylphosphoric acids; fatty alkyl tartrates; fatty alkyl tartrimides; or fatty alkyl 15 tartramides.

[0085] Friction modifiers may also encompass materials such as sulfurized fatty compounds and olefins, molybdenum dialkyldithiophosphates, molybdenum dithiocarbamates, sunflower oil or monoester of a polyol and an aliphatic carboxylic acid. 20

[0086] In one embodiment, the friction modifier may comprise at least one of long chain fatty acid derivatives of amines, long chain fatty esters, or long chain fatty epoxides; fatty imidazolines; amine salts of alkyl phosphoric acids; fatty alkyl tartrates; fatty alkyl tartrimides; and fatty alkyl tartramides.

The friction modifier may be present at O wt¾ to 6 wt¾, or 0.05 wt¾ to 4 wt¾, or 0.1 wt¾ to 2 wt¾ of the lubricating 25 composition.

In one embodiment, the lubricating composition may be free of long chain fatty esters (typically glycerol monooleate).

[0087] As used herein, the term "fatty alkyl" or "fatty" in relation to friction modifiers means a carbon chain having IO to 22 carbon atoms, typically a straight carbon chain.

Alternatively, the fatty alkyl may be a mono branched alkyl group, with 30 branching typically at the f3-position.

Examples of mono branched alkyl groups include 2-ethylhexyl, 2-propylheptyl or 2-octyldodecyl.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 24

[0088] In one embodiment, the friction modifier may comprise at least one of long chain fatty acid derivatives of amines, fatty esters, or fatty epoxides; fatty alkyl citrates, fatty alkyl tartrates; fatty alkyl tartrimides; and fatty alkyl tartramides.

[0089] In one embodiment, the friction modifier may be a long chain fatty acid ester. 5 In another embodiment, the long chain fatty acid ester may be a mono-ester and in another embodiment the long chain fatty acid ester may be a triglyceride.

[0090] Other performance additives such as corrosion inhibitors include those described in paragraphs 5 to 8 of WO2006/047486, octyl octanamide, condensation products of dodecenyl succinic acid or anhydride and a fatty acid such as oleic acid 10 with a polyamine.

In one embodiment, the corrosion inhibitors include the Synalox® (a registered trademark of The Dow Chemical Company) corrosion inhibitor.

The Synalox® corrosion inhibitor may be a homopolymer or copolymer of propylene oxide.

The Synalox® corrosion inhibitor is described in more detail in a product brochure with Form No. 118-01453-0702 AMS, published by The Dow Chemical Company.

The 15 product brochure is entitled "SYNALOX Lubricants, High-Performance Polyglycols for Demanding Applications."

[0091] Metal deactivators include derivatives of benzotriazoles (typically tolyltriazole), dimercaptothiadiazole derivatives, 1,2,4-triazoles, benzimidazoles, 2- alkyldithiobenzimidazoles, or 2-alkyldithiobenzothiazoles. 20

[0092] In one embodiment, the corrosion inhibitors and metal deactivators described above may be used in addition to the mercaptoazole-acrylic adducts described herein.

In yet another embodiment, the corrosion inhibitors and metal deactivators described above may be substituted with the mercaptoazole-acrylic adducts described herein.

[0093] Foam inhibitors include polysiloxane or copolymers of ethyl acrylate and 2- 25 ethylhexyl acrylate and optionally vinyl acetate.

Demulsifiers include trialkyl phosphates, polyethylene glycols, polyethylene oxides, polypropylene oxides and (ethylene oxide-propylene oxide) polymers.

Pour point depressants include esters of maleic anhydride-styrene, polymethacrylates, polyacrylates or polyacrylamides.

[0094] In different embodiments, the lubricating composition may have a 30 composition as described in Table 1.

The weight percents (wt%) shown in Table 1 below are on an actives basis.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 Table 1 Additive Embodiments (wt%) A B C Mercaptoazole-acrylic adducts 0.01 - 3 0.01 - 3 0.01 - 3 Boron-Containing Compound 0.0 to 8 0.05 to 4 0.05 to 3 Nitrogen-Containing Dispersant 0.05 to 12 0.5 to 8 Ito 5 Dispersant Viscosity Modifier 0 to 5 0 to 4 0.05 to 2 Overbased Detergent Oto 15 0.1 to 8 0.5 to 3 Antioxidant 0 to 15 0.1 to 10 0.5 to 5 Phosphorous Antiwear Agent 0.1 to 15 0.2 to 6 0.3 to 2 Friction Modifier 0 to 6 0.05 to 4 0.1 to 2 Viscosity Modifier 0 to 10 0.5 to 8 1 to 6 Any Other Performance Additive 0 to 10 0 to 8 0 to 6 Oil of Lubricating Viscosity Balance to Balance to Balance to 100 % 100 % 100 % Industrial Application 5

[0095] The lubricating composition may be utilized in an internal combustion engine.

The engine or engine components may be made of an alloy comprising lead or copper.

The engine components may have a surface of steel or aluminum (typically a surface of steel).

[0096] An aluminum surface may be derived from an aluminum alloy that may be 10 a eutectic or hyper-eutectic aluminum alloy (such as those derived from aluminum silicates, aluminum oxides, or other ceramic materials).

The aluminum surface may be present on a cylinder bore, cylinder block, or piston ring having an aluminum alloy, or aluminum composite.

[0097] The internal combustion engme may or may not have an Exhaust Gas 15 Recirculation system.

The internal combustion engine may be fitted with an emission control system or a turbocharger.

Examples of the emission control system include diesel particulate filters (DPF), or systems employing selective catalytic reduction (SCR).

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 26

[0098] In one embodiment, the internal combustion engine may be a diesel fueled engine (typically a heavy duty diesel engine), a gasoline fueled engine, a natural gasfueled engine or a mixed gasoline/alcohol fueled engine.

In one embodiment, the internal combustion engine may be a diesel fueled engine and in another embodiment 5 a gasoline fueled engine.

In one embodiment, the internal combustion engine may be a heavy duty diesel engine.

[0099] The internal combustion engine may be a 2-stroke or 4-stroke engine.

Suitable internal combustion engines include marine diesel engines, aviation piston engines, low-load diesel engines, and automobile and truck engines.

[0100] The lubricant composition for an internal combustion engme may be suitable for any engine lubricant irrespective of the sulfur, phosphorus or sulfated ash (ASTM D-874) content.

The lubricating composition may be characterized as having at least one of (i) a sulfur content of 0.2 wt% to 0.4 wt% or less, (ii) a phosphorus content of0.08 wt% to 0.15 wt%, and (iii) a sulfated ash content of 0.5 wt% to 1.5 wt% 15 or less.

The lubricating composition may also be characterized as having (i) a sulfur content of 0.5 wt% or less, (ii) a phosphorus content of 0.1 wt% or less, and (iii) a sulfated ash content of 0.5 wt% to 1.5 wt% or less.

In yet another embodiment, the lubricating composition may be characterized as having a sulfated ash content of 0.5 wt% to 1.2 wt%. 20

[0101] It is known that some of the materials described above may interact in the final formulation, so that the components of the final formulation may be different from those that are initially added.

For instance, metal ions (of, e.g., a detergent) can migrate to other acidic or anionic sites of other molecules.

The products formed thereby, including the products formed upon employing the disclosed compositions, 25 may not be susceptible of easy description.

Nevertheless, all such modifications and reaction products are included within the scope of the present invention and the disclosed compositions encompass products formed by admixing the components and/or materials described above.

[0102] The following examples provide illustrations of the invention.

These 30 examples are non-exhaustive and are not intended to limit the scope of the invention.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 27 EXAMPLES - SYNTHESIS OF MERCAPTOAZOLE-ACRYLIC ADDUCTS

[0103] The following examples show the synthesis of various Michael reaction products, including the mercaptoazole-acrylic adducts described herein.

Example A-1 - Reaction product of 2-mercaptobenzothiazole and 2-ethylhexyl 5 acrylate

[0104] For Example A-1, 2-mercaptobenzothiazole MBZL (100 grams, 0.6 mole), 2-ethylhexyl acrylate (111 g., 0.6 mol.), triethyl amine (60 g., 0.6 mol.) and 300 mL of a mixture of acetonitrile and tetrahydrofuran are added to a 4-necked, 1-L round bottom flask.

The mixture is stirred vigorously to facilitate dissolution of the MBZL.

The 10 reaction is held between 50 °C and 75 °C until the reaction is complete.

The reaction mixture comprising the mercaptoazole-acrylic adduct is obtained upon rotary evaporation and filtration over calcined diatomaceous earth.

Example A-2 (Prophetic) - Reaction product of 2-mercapto-1,3,4-triazole and 2- ethylhexyl acrylate 15

[0105] For Example A-2, 2-mercapto-1,3,4-triazole and 2-ethylhexyl acrylate are reacted under the same reaction conditions as Example A-1.

Example A-3 (Prophetic) - Reaction product of 5-mercaptoimidazole and 2- ethylhexyl acrylate

[0106] For Example A-3, 5-mercaptoimidazole and 2-ethylhexyl acrylate are 20 reacted under the same reaction conditions as Example A-1.

Example A-4 (Prophetic) - Reaction product of 4-mercapto-1,2,3-triazole and 2- ethylhexyl acrylate

[0107] For Example A-4, 4-mercapto-1,2,3-triazole_and 2-ethylhexyl acrylate are reacted under the same reaction conditions as Example A-1. 25 Example A-5 (Prophetic) - Reaction product of 5-mercapto-1,2,3-triazole and 2- ethylhexyl acrylate

[0108] For Example A-5, 5-mercapto-1,2,3-triazole and 2-ethylhexyl acrylate are reacted under the same reaction conditions as Example A-1.

Example A-6 (Prophetic) - Reaction product of 3-mercapto-1,2,4-triazole and 2- 30 ethylhexyl acrylate

[0109] For Example A-6, 3-mercapto-1,2,4-triazole and 2-ethylhexyl acrylate are reacted under the same reaction conditions as Example A-1.

CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 28 Example A-7 (Prophetic) - Reaction product of 2-mercaptobenzothiazole and butyl acrylate

[0110] For Example A-7, 2-mercaptobenzothiazole and butyl acrylate are reacted under the same reaction conditions as Example A-1. 5 Example A-8 (Prophetic) - Reaction product of tolyltriazole and ethyl acrylate

[0111] For Example A-8, 2-mercaptobenzothiazole and ethyl acrylate are reacted under the same reaction conditions as Example A-1.

EXAMPLES - PERFORMANCE OF MERCAPTOAZOLE-ACRYLIC ADDUCTS

[0112] A series of 15W-40 engine lubricants in Group II base oil of lubricating 10 viscosity are prepared containing the additives described above as well as conventional additives including a polymeric viscosity modifier, an ashless succinimide dispersant, overbased detergents, antioxidants (combination of phenolic ester, diarylamine, and sulfurized olefin), and zinc dialkyldithiophosphate (ZDDP), and other performance additives.

All of the lubricants are prepared as follows in Table 2.

Table 2 - Lubricant Compositions1 Baseline Comparative Comparative (BL) Example 1 (CE-I) Group II Base Oil Balance Balance to to 100% 100% TTZL 0.05 Irgamet® 302 Example A-1 Calcium overbased detergent3 1.73 1.73 Zinc dialkyldithiophosphate 1.09 1.09 Antioxidant 1.23 1.23 Active Dispersant4 4.76 4.76 Viscosity Modifier 0.56 0.56 Additional additives4 1.16 1.16 % Phosphorus 0.11 0.11 1 - All concentrations are on an oil free (i.e. active basis) 2 - Metal Deactivator that is a triazole derivative available from BASF 3 - Combination alkylsulfonate and sulfur-coupled alkylphenol 4 - 2200 Mn PIB succinimide dispersant (TBN - 55) Example 2 (CE-2) Balance to 100% 0.05 1.73 1.09 1.23 4.76 0.56 1.16 0.11 Inventive Example 1 (IE-I) Balance to 100% 0.05 1.73 1.09 1.23 4.76 0.56 1.16 0.11 5 - Additional additives include friction modifiers, foam inhibitors, surfactant, and soot dispersant viscosity modifier

[0113] The lubricants described above are evaluated in copper bench corrosion tests according to D6594 High Temperature Corrosion Bench Test (HTCBT) CA 0302oi22 2oie-io-04 WO 2017/176546 PCT/0S2017/024972 29 protocol.

The amount of copper (Cu) in the oils at the end of test (336 hours) is measured and compared to the amount at the beginning of the test.

Lower copper content in the oil indicates decreased copper corrosion.

Overall the results obtained for each lubricant are shown in Table 3 below. 5 Table 3 - Corrosion Bench Test Results I Cu ppm BL CE-1 CE-2 IE-1 218 26 160 13

[0114] While certain representative embodiments and details have been shown for the purpose of illustrating the subject invention, it will be apparent to those skilled in this art that various changes and modifications can be made therein without departing 10 from the scope of the subject invention.

In this regard, the scope of the invention is to be limited only by the following claims.

Claims

What is claimed is: 1. A lubricating composition comprising: a. an oil of a lubricating viscosity; b. 0.01 wt% to 5 wt% of a mercaptoazole-acrylic adduct having the formula (IV) or (V): (IV) or (V) wherein R6 is hydrogen or a C1-C20 hydrocarbyl group; R7 is a linear or branched hydrocarbyl group having at least two carbon atoms; and R8 is a C1- C20 hydrocarbyl group and is linear, branched, homocyclic, heterocyclic, or a combination thereof; c. an antiwear agent containing phosphorus and is present in an amount such that said lubricating composition has at least 300 ppm phosphorus based on a total weight of said lubricating composition; and d. an antioxidant. 31 2. The lubricating composition of claim 1, wherein said mercaptoazole-acrylic adduct has the formula (VI) or (VII): (VI) or (VII). 3. The lubricating composition of claim 1 or 2, wherein said mercaptoazole-acrylic adduct has the formula (VIII): (VIII). 4. The lubricating composition of any one of claims 1 to 3, further comprising at least one nitrogen-containing dispersant. 5. The lubricating composition of any one of claims 1 to 4, further comprising at least one boron-containing compound. 32 6. The lubricating composition of claim 5, wherein said boron-containing compound comprises borate ester, borate alcohol, or combinations thereof. 7. The lubricating composition of any one of claims 1 to 6, further comprising at least one overbased detergent. 8. A method of lubricating an internal combustion engine comprising contacting said internal combustion engine with the lubricating composition as defined in any one of claims 1 to 7. 9. Use of the mercaptoazole-acrylic adduct in the lubricating composition as defined in any one of claims 1 to 7 to reduce corrosion and/or seal deterioration in an internal combustion engine.