CA3010168C - Production de diesel a partir de la biomasse cellulosique - Google Patents
Production de diesel a partir de la biomasse cellulosique Download PDFInfo
- Publication number
- CA3010168C CA3010168C CA3010168A CA3010168A CA3010168C CA 3010168 C CA3010168 C CA 3010168C CA 3010168 A CA3010168 A CA 3010168A CA 3010168 A CA3010168 A CA 3010168A CA 3010168 C CA3010168 C CA 3010168C
- Authority
- CA
- Canada
- Prior art keywords
- depolymerization
- slurry
- reactor
- biomass
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002028 Biomass Substances 0.000 title claims abstract description 171
- 238000004519 manufacturing process Methods 0.000 title description 8
- 238000000034 method Methods 0.000 claims abstract description 186
- 230000008569 process Effects 0.000 claims abstract description 179
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 165
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 165
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 139
- 238000000746 purification Methods 0.000 claims abstract description 36
- 238000004821 distillation Methods 0.000 claims abstract description 27
- 239000002002 slurry Substances 0.000 claims description 167
- 230000007928 solubilization Effects 0.000 claims description 105
- 238000005063 solubilization Methods 0.000 claims description 105
- 239000007788 liquid Substances 0.000 claims description 67
- 239000012530 fluid Substances 0.000 claims description 39
- 239000010802 sludge Substances 0.000 claims description 36
- 239000007787 solid Substances 0.000 claims description 34
- 239000003054 catalyst Substances 0.000 claims description 30
- 238000011282 treatment Methods 0.000 claims description 24
- 238000000926 separation method Methods 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000000227 grinding Methods 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- 238000012545 processing Methods 0.000 claims description 15
- 238000004064 recycling Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 10
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 10
- 239000004571 lime Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 5
- 235000019645 odor Nutrition 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 24
- 238000006243 chemical reaction Methods 0.000 abstract description 21
- 238000001816 cooling Methods 0.000 abstract description 6
- 239000012071 phase Substances 0.000 description 51
- 239000000047 product Substances 0.000 description 30
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 22
- 238000012546 transfer Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- 238000002156 mixing Methods 0.000 description 12
- 239000002023 wood Substances 0.000 description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 description 11
- 239000000446 fuel Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 239000002956 ash Substances 0.000 description 10
- 239000002199 base oil Substances 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 238000005191 phase separation Methods 0.000 description 10
- 238000003860 storage Methods 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 238000011144 upstream manufacturing Methods 0.000 description 9
- 241000006351 Leucophyllum frutescens Species 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 238000000197 pyrolysis Methods 0.000 description 8
- 230000003134 recirculating effect Effects 0.000 description 8
- 239000003575 carbonaceous material Substances 0.000 description 7
- 230000037361 pathway Effects 0.000 description 7
- 238000012691 depolymerization reaction Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 230000004044 response Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000010977 unit operation Methods 0.000 description 5
- 239000013043 chemical agent Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000002283 diesel fuel Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000011236 particulate material Substances 0.000 description 4
- 229920002488 Hemicellulose Polymers 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000012809 cooling fluid Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000004508 fractional distillation Methods 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000004886 process control Methods 0.000 description 3
- 238000005215 recombination Methods 0.000 description 3
- 230000006798 recombination Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 238000005549 size reduction Methods 0.000 description 3
- 239000002551 biofuel Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000035899 viability Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000009103 reabsorption Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000007320 rich medium Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Des procédés de production de diesel à partir de biomasse peuvent comprendre la soumission dune biomasse cellulosique à la dépolymérisation pour produire un matériau dhydrocarbure traité soumis au refroidissement, à la distillation et à lépuration pour produire un diesel synthétique. Divers procédés et équipements de conversion de la biomasse peuvent être utilisés.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA3091884A CA3091884A1 (fr) | 2017-07-06 | 2018-07-03 | Production de diesel a partir de la biomasse cellulosique |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2972311A CA2972311A1 (fr) | 2017-07-06 | 2017-07-06 | Production de diesel a partir de biomasse cellulosique |
| CA2972311 | 2017-07-06 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3091884A Division CA3091884A1 (fr) | 2017-07-06 | 2018-07-03 | Production de diesel a partir de la biomasse cellulosique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3010168A1 CA3010168A1 (fr) | 2019-01-06 |
| CA3010168C true CA3010168C (fr) | 2020-11-17 |
Family
ID=64998486
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2972311A Abandoned CA2972311A1 (fr) | 2017-07-06 | 2017-07-06 | Production de diesel a partir de biomasse cellulosique |
| CA3091884A Pending CA3091884A1 (fr) | 2017-07-06 | 2018-07-03 | Production de diesel a partir de la biomasse cellulosique |
| CA3010168A Active CA3010168C (fr) | 2017-07-06 | 2018-07-03 | Production de diesel a partir de la biomasse cellulosique |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2972311A Abandoned CA2972311A1 (fr) | 2017-07-06 | 2017-07-06 | Production de diesel a partir de biomasse cellulosique |
| CA3091884A Pending CA3091884A1 (fr) | 2017-07-06 | 2018-07-03 | Production de diesel a partir de la biomasse cellulosique |
Country Status (1)
| Country | Link |
|---|---|
| CA (3) | CA2972311A1 (fr) |
-
2017
- 2017-07-06 CA CA2972311A patent/CA2972311A1/fr not_active Abandoned
-
2018
- 2018-07-03 CA CA3091884A patent/CA3091884A1/fr active Pending
- 2018-07-03 CA CA3010168A patent/CA3010168C/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA3010168A1 (fr) | 2019-01-06 |
| CA2972311A1 (fr) | 2019-01-06 |
| CA3091884A1 (fr) | 2019-01-06 |
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