CA3004544A1 - Powdered cannabis products, products containing powdered cannabis and processes of making same - Google Patents

Powdered cannabis products, products containing powdered cannabis and processes of making same Download PDF

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Publication number
CA3004544A1
CA3004544A1 CA3004544A CA3004544A CA3004544A1 CA 3004544 A1 CA3004544 A1 CA 3004544A1 CA 3004544 A CA3004544 A CA 3004544A CA 3004544 A CA3004544 A CA 3004544A CA 3004544 A1 CA3004544 A1 CA 3004544A1
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CA
Canada
Prior art keywords
cannabis
powder
paste
solvent
isolate
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Abandoned
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CA3004544A
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French (fr)
Inventor
Derrick Welsh
Igor GALITSKY
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Xanthic Biopharma Inc
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Xanthic Biopharma Inc
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Filing date
Publication date
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Priority to CA3004544A priority Critical patent/CA3004544A1/en
Publication of CA3004544A1 publication Critical patent/CA3004544A1/en
Abandoned legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
    • A23D9/04Working-up
    • A23D9/05Forming free-flowing pieces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/105Plant extracts, their artificial duplicates or their derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/40Shaping or working of foodstuffs characterised by the products free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Mycology (AREA)
  • Nutrition Science (AREA)
  • Botany (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biotechnology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Microbiology (AREA)
  • Medicinal Chemistry (AREA)
  • Medical Informatics (AREA)
  • Alternative & Traditional Medicine (AREA)
  • Medicinal Preparation (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

A process of producing an edible powder containing cannabis including providing a desired quantity of cannabis oil, a cannabis isolate or a cannabis distillate, mixing the cannabis oil, cannabis isolate or cannabis distillate with a solvent and forming an emulsion, providing a starch powder, mixing the emulsion with the starch powder to form a mixture, and removing the solvent from the mixture.

Description

POWDERED CANNABIS PRODUCTS, PRODUCTS CONTAINING
POWERED CANNABIS AND PROCESSES OF MAKING SAME
FIELD
[0001] The present disclosure relates generally to powdered cannabis products, products containing powdered cannabis, and processes of making same.
BACKGROUND
[0002] Cannabis can be consumed by humans in a number of ways. Some people prefer to consume edible cannabis products, such as drinks containing cannabis oil. Cannabis oil, however, is not naturally soluble in water, and attempts have been made at producing powered cannabis oil products that can be used in a drink.
In certain jurisdictions, the amount of cannabinoids in edible cannabis products is regulated. In Canada for example, products meant for ingestion have a limit of 10 mg of the cannabinoid tetrahydrocannabinol ("THC") per dose. Producing powdered cannabis products with a consistent distribution of THC and/or one or more other cannabinoids that meet local regulations has proved challenging.
SUMMARY
[0003] In one aspect, the present disclosure relates to a process of producing an edible powder containing cannabis including providing a desired quantity of a cannabis oil, mixing the cannabis oil with a solvent to form an emulsion, providing a desired amount of a starch powder, mixing the emulsion with the starch powder to form a mixture, and removing the solvent from the mixture. In one aspect, a paste is formed with the mixture. In one aspect, the solvent is ethanol. In one aspect, the starch powder is a maltodextrin powder. In one aspect, the starch powder includes a maltodextrin powder and a tapioca powder. In one aspect, the process further includes heating the mixture under vacuum conditions to remove the solvent or substantially all of the solvent from the paste. In another aspect, the process further includes breaking up the mixture into a powder following removal of the solvent. In another aspect, the process further includes subjecting the emulsion to sonification. In another aspect, the process further includes remixing the mixture and repeating the step of heating the mixture under a vacuum to remove ethanol from the mixture. In another aspect, the present disclosure relates to a product made according to the processes described above.
[0004] In another aspect, the present disclosure relates to a powdered cannabis product including a cannabis oil and a maltodextrin powder, such that the ratio of cannabis oil to the maltodextrin powder is in the range of 1:100 to 1:10. In another embodiment, the powered cannabis product further includes a tapioca starch powder. In one embodiment, the ratio of the maltodextrin powder to the tapioca powder is 3:1. In one embodiment, the ratio of cannabis oil to the combined maltodextrin powder and the tapioca powder is in the range of 1:100 to 1:10.
[0005] In another aspect, the present disclosure relates a powdered cannabis =
product including a cannabis isolate and a maltodextrin powder, such that the ratio of cannabis isolate to the maltodextrin powder is in the range of 1:100 to 1:10.
In another embodiment, the powered cannabis product further includes a tapioca starch powder. In one embodiment, the ratio of the maltodextrin powder to the tapioca powder is 3:1. In one embodiment, the ratio of cannabis isolate to the combined maltodextrin powder and the tapioca powder is in the range of 1:100 to 1:10.
[0006] In another aspect, the present disclosure relates to a process of producing an edible powder containing cannabis isolate including providing a desired quantity of a cannabis isolate, mixing the cannabis isolate with a solvent to form an emulsion, providing a desired quality of a starch powder, mixing the emulsion and the starch powder to form a mixture, and removing the solvent from the mixture. In one aspect, the mixture is a paste. In one aspect, the solvent is ethanol. In one aspect, the starch is maltodextrin powder. In one aspect, the starch includes a maltodextrin powder and a tapioca powder. In one aspect, the process further includes heating the mixture and applying a vacuum to the mixture to remove solvent from the paste. In another aspect, the process further includes breaking the paste into a powder following removal of the solvent. In another aspect, the process further includes subjecting the emulsion to sonification. In another aspect, the process further includes remixing the mixture and repeating the step of heating the mixture in a vacuum to remove ethanol from the mixture. In another aspect, the present disclosure relates to a product made according to the processes disclosed in the present disclosure.
BRIEF DESCRIPTIONS OF DRAWINGS
[0007] For the purpose of illustrating the invention, the drawings show aspects of one or more embodiments of the invention. However, it should be understood that the present invention is not limited to the precise arrangements and instrumentalities shown in the drawings, wherein:
[0008] FIG. 1 is a flowchart of an embodiment of the process for producing a powdered cannabis oil product; and
[0009] FIG. 2 is a is a flowchart of another embodiment of the process for producing a powdered cannabis isolate or distillate product.
DETAILED DESCRIPTION
[0010] In one embodiment, the present invention relates to a process of producing an edible powder containing cannabis. A desired quantity of a cannabis oil extract is measured 10 and a solvent selected 20 and the cannabis oil is mixed with a solvent to form an emulsion 30. In one embodiment, the solvent is ethanol. In certain other embodiments, the solvent is selected from the group consisting of ethanol, isopropanol, chloroform, methane, hexane, cyclohexane, acetone, pentane and combinations thereof. Local food contact regulations and/or fire codes may govern which solvent(s) are permitted. In one embodiment, the cannabis oil and the solvent is heated while forming the emulsion. Heating promotes fluidization of the mixture. In one embodiment, the emulsion is made in a beaker and stirred while being heated to a temperature of about 79 C for approximately 25-30 minutes. Mixing times may vary but in one embodiment, the emulsion is mixed until there is no significant phase separation in the emulsion. Forming an emulsion promotes the even distribution of cannabinoids throughout the emulsion. Heating of the emulsion also promotes decarboxylation provided that the emulsion is heated to suitable temperatures because the two main catalysts for decarboxylation are heat and time. In one embodiment, heating of the emulsion to a temperature in the range of about 240 F to 243 F promotes decarboxylation. Temperatures above about 243 F denature the cannabinoid(s) in cannabis oil. In another embodiment, where decarboxylation is not required because the cannabis oil has previously been decarboxylated, the emulsion is heated to about 80 C. In another embodiment, the emulsion is subjected to sonication to further break down cannabis oil droplets in the emulsion into nanoparticles and/or microparticles.
Reducing the size of the cannabis oil droplets increases the bioavailability of the cannabinoids in the cannabis oil. Smaller cannabis oil droplets also improve the resulting powdered product by promoting more uniform distribution of the cannabinoids in the resulting powder. In one embodiment, sonication of the emulsion can be carried out with a cavitational homogenizer.
[0011] A starch powder is selected 40 and a desired quantify of the starch powder is measured and the cannabis oil emulsion is mixed with the starch powder 50.
In one embodiment, the starch is a maltodextrin powder. In another embodiment, the starch is a mixture of a maltodextrin powder and a tapioca powder. In one embodiment, the starch powder is a mixture of a maltodextrin powder and a tapioca powder in a ratio of about 3:1. In one embodiment, the emulsion and the starch powder are mixed to form a paste. In one embodiment, the proportion of cannabis oil to starch powder is 10 mg cannabis oil to 1 g starch powder. In other embodiments, the proportion of cannabis oil to starch powder ranges from 20 to 100 mg of cannabis oil to 1 g of starch powder. In other embodiments, the ratio of cannabis oil to starch powder ranges from 1:100 to 1:10.
[0012] In a next step, the solvent or substantially all of the solvent is removed from the mixture 60. In one embodiment, where a paste has been formed from the mixture, the paste is flattened on a pan and placed in a vacuum purge oven. In one embodiment, the oven temperature used is about 230 C. In another embodiment, the oven temperature is about 120 C when a vacuum purge is not used. Care should be taken not to heat the paste to a temperature where a substantial amount of the cannabinoids in the paste are "boiled off". In one embodiment, the paste is purged for about 24 hours. In another embodiment, the paste is purged until substantially all of the solvent has been removed from the paste. In another embodiment, after purging, the paste is re-blended, flattened again and placed again in the vacuum purge oven for a second purge session. In one embodiment, the second purge session is about 12 hours in duration.
[0013] In another embodiment, the present invention relates to a process of producing an edible powder containing cannabis. A desired quantity of a cannabis isolate or distillate is measured 70, a solvent is selected 80, and the cannabis isolate or distillate and the solvent are mixed and emulsified 90. In certain embodiments, the cannabinoid isolate may be selected from the group consisting of:
[0014] BGA (Cannabigerolic acid)
[0015] THCA (A9-tetrahydrocannabinolic acid)
[0016] CBDA (Cannabidiolic acid)
[0017] CBCA (Cannabichromenenic acid)
[0018] CBGVA (Cannabigerovarinic acid)
[0019] THCVA (Tetrahydrocanabivarinic acid)
[0020] CBDVA (Cannabidivarinic acid)
[0021] CBCVA (Cannabichromevarinic acid)
[0022] CBG (Cannabigerol)
[0023] THC (A9¨tetrahydrocannabinol)
[0024] CBD (Cannabidiol)
[0025] CBC (Cannabichromene)
[0026] CBGV (Cannabigerivarin)
[0027] THCV (Tetrahydrocannabivarin)
[0028] CBDV (Cannabidivarin)
[0029] CBCV (Cannabichromevarin)
[0030] and combinations thereof.
[0031] In one embodiment, the solvent is ethanol. In certain other embodiments, the solvent is selected from the group consisting of ethanol, chloroform, methane, hexane, cyclohexane, acetone, pentane and combinations thereof. Heating promotes fluidization of the mixture. In one embodiment, the mixture is made in a beaker and stirred while heated to a temperature of about 79 C for approximately 25-30 minutes.
Mixing times may vary but preferably, mixing should continue until there is no significant phase separation in the mixture. The emulsion also promotes the even distribution of the isolate throughout the emulsion. Heating of the emulsion also promotes decarboxylation provided that the emulsion is heated to suitable temperatures because the two main catalysts for decarboxylation are heat and time. In one embodiment, heating the emulsion to a temperature of in the range of about 240 F to 243 F
promotes decarboxylation. Temperatures above about 243 F denature the isolate.
[0032] In another embodiment, the emulsion is heated to about 80 C where decarboxylation is not required because the isolate has previously been decarboxylated. In another embodiment, the mixture is subjected to sonication to break down isolate droplets in the mixture into nanoparticles and/or microparticles.
Reducing the size of the isolate droplets increases the bioavailability of the cannabinoids in the isolate. Smaller isolate droplets also improves the resulting powdered product by promoting more uniform distribution of the cannabinoids in the resulting powder. In one embodiment, sonication can be carried out with a cavitational homogenizer.
[0033] A starch powder is selected 100 and a desired quantity of starch powder is measured and mixed with the emulsion to form a mixture 110. In one embodiment, the starch is a maltodextrin powder. In another embodiment, the starch is a mixture of a maltodextrin powder and a tapioca powder. In one embodiment, the starch powder is a mixture of a maltodextrin powder and a tapioca powder in a ratio of about 3:1.
In one embodiment, the emulsion and the starch powder are mixed to form a paste. In one embodiment, the proportion of cannabis oil to starch powder is 10 mg cannabis oil to 1 g starch powder. In other embodiments, the proportion of cannabis oil to starch powder ranges from 20 to 100 mg of cannabis oil to 1 g of starch powder. In other embodiments, the ratio of cannabis oil to starch powder ranges from 1:100 to 1:10.
[0034] In a next step, the solvent is removed from the mixture 120. In one embodiment, the paste is flattened on a pan and placed in a vacuum purge oven.
In one embodiment, the oven temperature is about 230 C. In another embodiment, the oven temperature is about 120 C when a vacuum purge is not used. The paste should not be heated too much such that cannabinoids in the paste are "boiled off. In one embodiment, the paste is purged for about 24 hours. In another embodiment, the paste is purged until substantially all of the solvent has been removed from the paste. In another embodiment, after purging, the paste is re-blended, flattened again and placed again in the vacuum purge oven for a second purge session. In one embodiment, the second purge session is about 12 hours in duration.
[0035]
According to certain embodiments of the processes of the present invention, following removal of the solvent, the resulting paste is chalk-like in consistency and can be processed into a powder. Powderization can be achieved through mechanical means such as pulverization or milling using for example a blender or grinder.
[0036]
Powdered products made according to embodiments of processes of the present invention can be added to a variety of edible products. For example, the powdered product can be used in drinks such as fruit drinks, rescue drinks and energy drinks. The powdered product can also be added to a wide variety of foods such as for example cake mixes, soups, chocolate, dips and toppings.

Claims (43)

We claim:
1. A process of producing an edible powder containing cannabis comprising:
providing a desired quantity of cannabis oil, mixing the cannabis oil with a solvent to form an emulsion, providing a desired quality of a starch powder, mixing the emulsion and the starch powder to form a mixture, and removing the solvent from the mixture.
2.The process of claim 1, further including forming a paste with the mixture.
3. The process of claim 2, wherein the solvent is ethanol.
4. The process of claim 3, wherein the starch powder is maltodextrin.
5. The process of claim 3, wherein the starch powder comprises maltodextrin and tapioca.
6. The process of claim 1, further comprising heating the mixture in a vacuum to remove solvent from the paste.
7. The process of claim 1, wherein the solvent is selected from the group consisting of ethanol, isopropyl alcohol, chloroform, methane, hexane, cyclohexane, acetone, pentane and mixtures thereof.
8. The process of claim 6, following removal of the solvent, further comprising breaking the paste into a powder.
9. The process of claim 1, further comprising subjecting the emulsion to sonification.
10. The process of claim 6, further comprising remixing the paste and repeating the step of heating the paste in a vacuum to further remove the solvent from the paste.
11. The process of claim 4, wherein the ratio of the cannabis oil to the starch powder is mg cannabis oil to every 1 g of the starch powder.
12. The process of claim 4, wherein in the ratio of the cannabis oil to the starch powder, the quantity of the cannabis oil is selected from the group consisting of 20 mg, 30 mg, 40 mg, 50 mg, 60 mg, 70 mg, 80 mg, 90 mg and 100 mg of cannabis oil.
13. The process of claim 4, wherein the ratio of the cannabis oil to the starch powder is in the range of 1:100 to 1:10.
14. The process of claim 1, wherein the step of heating the paste under vacuum is carried out for a period of about 24 hours.
15. The process of claim 4, wherein the paste is heated to a temperature of about 240°F
to 243°F.
16. The process of claim 15, wherein the step of heating the paste is carried out until substantially all of the solvent is removed from the paste.
17. The process of claim 14, further comprising the step of forming the paste into a flattened layer for heating.
18. The process of claim 17, wherein the layer is about 1/4 inch in thickness.
19. A powdered cannabis oil product comprising: a cannabis oil; a maltodextrin powder, and a tapioca powder, wherein the cannabis oil has been absorbed by the maltodextrin and tapioca powder, such that the ratio of cannabis oil to the combined amount of maltodextrin powder, and tapioca powder is in the range of 1:100 to 1:10.
20. A powdered cannabis product comprising: a cannabis isolate; a maltodextrin powder, and a tapioca powder, wherein the cannabis isolate has been absorbed by the maltodextrin and tapioca powder, such that the ratio of cannabis isolate to the combined amount of maltodextrin powder, and tapioca powder is in the range of 1:100 to 1:10.
21. A powdered cannabis oil product made according to the process of claim 1.
22. A powdered cannabis oil product made according to the process of claim 5.
23. A process of producing an edible powder containing cannabis comprising:
providing a desired quantity of a cannabis isolate or distillate, mixing the cannabis isolate or distillate with a solvent to form an emulsion, providing a desired quality of a starch powder, mixing the emulsion and the starch powder to form a mixture, and removing the solvent from the mixture.
24.The process of claim 23, further including forming a paste with the mixture.
25. The process of claim 24, wherein the solvent is ethanol.
26. The process of claim 25, wherein the starch powder is maltodextrin.
27. The process of claim 25, wherein the starch powder comprises maltodextrin and tapioca.
28. The process of claim 23, further comprising heating the mixture in a vacuum to remove solvent from the paste.
29. The process of claim 23, wherein the solvent is selected from the group consisting of ethanol, isopropyl alcohol, chloroform, methane, hexane, cyclohexane, acetone, pentane and mixtures thereof.
30. The process of claim 28, following removal of the solvent, further comprising breaking the paste into a powder.
31. The process of claim 23, further comprising subjecting the emulsion to sonification.
32. The process of claim 28, further comprising remixing the paste and repeating the step of heating the paste in a vacuum to further remove the solvent from the paste.
33. The process of claim 26, wherein the ratio of the cannabis isolate to the starch powder is 10 mg cannabis isolate to every 1 g of the starch powder.
34. The process of claim 26, wherein in the ratio of the cannabis isolate to the starch powder, the quantity of the cannabis isolate is selected from the group consisting of 20 mg, 30 mg, 40 mg, 50 mg, 60 mg, 70 mg, 80 mg, 90 mg and 100 mg of cannabis isolate.
35. The process of claim 26, wherein the ratio of the cannabis isolate to the starch powder is in the range of 1:100 to 1:10.
36. The process of claim 23, wherein the step of heating the paste under vacuum is carried out for a period of about 24 hours.
37. The process of claim 26, wherein the paste is heated to a temperature of about 240°F to 243°F.
38. The process of claim 37, wherein the step of heating the paste is carried out until substantially all of the solvent is removed from the paste.
39. The process of claim 36, further comprising the step of forming the paste into a flattened layer for heating.
40. The process of claim 39, wherein the layer is about 1/4 inch in thickness.
41. The process of claim 23, wherein the cannabis isolate or distillate is selected from the group consisting of BGA (Cannabigerolic acid), THCA (.DELTA.9-tetrahydrocannabinolic acid), CBDA (Cannabidiolic acid), CBCA (Cannabichromenenic acid), CBGVA
(Cannabigerovarinic acid), THCVA (Tetrahydrocanabivarinic acid), CBDVA
(Cannabidivarinic acid), CBCVA (Cannabichromevarinic acid), CBG
(Cannabigerol), THC (.DELTA.9-tetrahydrocannabinol), CBD (Cannabidiol), CBC (Cannabichromene), CBGV
(Cannabigerivarin), THCV (Tetrahydrocannabivarin), CBDV (Cannabidivarin), CBCV

(Cannabichromevarin), and combinations thereof.
42. A powdered cannabis product made according to the process of claim 23.
43. A powdered cannabis oil product made according to the process of claim 26.
CA3004544A 2018-05-10 2018-05-10 Powdered cannabis products, products containing powdered cannabis and processes of making same Abandoned CA3004544A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA3004544A CA3004544A1 (en) 2018-05-10 2018-05-10 Powdered cannabis products, products containing powdered cannabis and processes of making same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA3004544A CA3004544A1 (en) 2018-05-10 2018-05-10 Powdered cannabis products, products containing powdered cannabis and processes of making same

Publications (1)

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CA3004544A1 true CA3004544A1 (en) 2019-11-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11084770B2 (en) 2016-12-07 2021-08-10 Treehouse Biotech, Inc. Cannabis extracts
US11202771B2 (en) * 2018-01-31 2021-12-21 Treehouse Biotech, Inc. Hemp powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11084770B2 (en) 2016-12-07 2021-08-10 Treehouse Biotech, Inc. Cannabis extracts
US11202771B2 (en) * 2018-01-31 2021-12-21 Treehouse Biotech, Inc. Hemp powder

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Effective date: 20220301